The SDI agreement between Bonn and Washington: Review of the first four years

This article provides an evaluation of the significance of the memorandum of Understanding (MOU) signed by the US and West German governments in March 1986. The author examines the expectations and fears it created in the FRG and compares them with the reality of actual economic benefit and exchange of information derived: the FRG's influence on arms control; and the effects on its standing and trading relations. The author argues that the MOU has had a negligible effect in securing contracts for West German firms and increasing technological cooperation, while damaging the FRG's standing in the arms control arena.     

CRISTA-NF measurements of water vapor during the SCOUT-O3 Tropical Aircraft Campaign

The new remote sensing experiment CRISTA-NF (Cryogenic Infrared Spectrometers and Telescopes for the Atmosphere – New Frontiers) successfully participated in the SCOUT-O3 Tropical Aircraft Campaign in November and December 2005. CRISTA-NF operated aboard the high-altitude research aircraft M-55 Geophysica. Mid-infrared spectra (4–15 μm) were measured in the limb sounding geometry with high spatial resolution (250 m vertical sampling, 5–15 km along track sampling). Measurements were carried out during transfer flights between Oberpfaffenhofen, Germany, and Darwin, Australia, as well as during several local flights near Darwin. Water vapor volume mixing ratios in the upper troposphere and lower stratosphere were derived from the CRISTA-NF radiance measurements by utilizing a rapid radiative transfer forward model and the optimal estimation retrieval approach. CRISTA-NF water vapor measurements below the hygropause have a total retrieval error of 15–40% (i.e. root mean square of accuracy and precision). The systematic terms are dominating in the retrieval error budget. The contributions of a priori information to the retrieval results are less than 5–10%. The vertical resolution of the observations is about 250–500 m when permitted by instrument sampling. In this paper we present first results for three transfer flights of the campaign. Being generally in good agreement with corresponding ECMWF operational analyzes, the CRISTA-NF measurements show significantly higher variability and local structures in the upper tropospheric water vapor distributions.     

A multi-disciplinary plan for easier access, management, and analysis of science data

NASA's COST LESS Team is pursuing strategies to reduce the cost and complexity of planning and executing space missions. The team's technical goal is to reverse the trend of constructing unique solutions for similar problems. To this end, the team is exploring ways to represent mission functionality in terms of building blocks and is discovering approaches that could accommodate the same building blocks for seemingly disparate activities, such as organizing processed telemetry data, controlling onboard experiments, searching science archives, reducing and presenting information to science users, and supporting educational outreach. Reusable object technology (UOT), a research undertaking by the authors, is showing promise in recognizing similarities in functions which were previously viewed as unique because they appeared in different programs or mission phases. Since UOT is aimed at being implementation independent (i.e. the function performed could be accomplished manually, by an automated process, by a specialized instrument, etc.), no premature judgment for automation or autonomy need be made. In this paper, the authors attempt to strike a balance between theory and reality as they describe UOT, including its beginnings, its underpinning, its utility, and its potential for achieving substantive reductions in cost and complexity for the Agency's space programs. The authors discuss their collaboration with the Center for EUV Astrophysics, University of California, Berkeley to reduce the cost and complexity of science investigations. Their multi-disciplinary plan incorporates both UOT and a complementary technology introduced in this paper, called interactive archives.     

Abiotic synthesis of organic compounds from carbon disulfide under hydrothermal conditions

Abiotic formation of organic compounds under hydrothermal conditions is of interest to bio, geo-, and cosmochemists. Oceanic sulfur-rich hydrothermal systems have been proposed as settings for the abiotic synthesis of organic compounds. Carbon disulfide is a common component of magmatic and hot spring gases, and is present in marine and terrestrial hydrothermal systems. Thus, its reactivity should be considered as another carbon source in addition to carbon dioxide in reductive aqueous thermosynthesis. We have examined the formation of organic compounds in aqueous solutions of carbon disulfide and oxalic acid at 175 degrees C for 5 and 72 h. The synthesis products from carbon disulfide in acidic aqueous solutions yielded a series of organic sulfur compounds. The major compounds after 5 h of reaction included dimethyl polysulfides (54.5%), methyl perthioacetate (27.6%), dimethyl trithiocarbonate (6.8%), trithianes (2.7%), hexathiepane (1.4%), trithiolanes (0.8%), and trithiacycloheptanes (0.3%). The main compounds after 72 h of reaction consisted of trithiacycloheptanes (39.4%), pentathiepane (11.6%), tetrathiocyclooctanes (11.5%), trithiolanes (10.6%), tetrathianes (4.4%), trithianes (1.2%), dimethyl trisulfide (1.1%), and numerous minor compounds. It is concluded that the abiotic formation of aliphatic straight-chain and cyclic polysulfides is possible under hydrothermal conditions and warrants further studies.     

Condensation reactions and formation of amides, esters, and nitriles under hydrothermal conditions

Hydrothermal pyrolysis experiments were performed to assess condensation (dehydration) reactions to amide, ester, and nitrile functionalities from lipid precursors. Beside product formation, organic compound alteration and stability were also evaluated. Mixtures of nonadecanoic acid, hexadecanedioic acid, or hexadecanamide with water, ammonium bicarbonate, and oxalic acid were heated at 300 degrees C for 72 h. In addition, mixtures of ammonium bicarbonate and oxalic acid solutions were used to test the abiotic formation of organic nitrogen compounds at the same temperature. The resulting products were condensation compounds such as amides, nitriles, and minor quantities of N-methylalkyl amides, alkanols, and esters. Mixtures of alkyl amide in water or oxalic acid yielded mainly hydrolysis and dehydration products, and with ammonium bicarbonate and oxalic acid the yield of condensation products was enhanced. The synthesis experiments with oxalic acid and ammonium bicarbonate solutions yielded homologous series of alkyl amides, alkyl amines, alkanes, and alkanoic acids, all with no carbon number predominances. These organic nitrogen compounds are stable and survive under the elevated temperatures of hydrothermal fluids.