Amino acid synthesis from CO-N2 and CO-N2-H2 gas mixtures via complex organic compounds.

Reaction among hydrogen cyanide (HCN), formaldehyde (H2CO) and ammonia (NH3) are generally considered an important reaction in amino acid synthesis by electric discharge. Precursors of glycine and aspartic acid were, however, synthesized by adding water to metastable complex compounds produced by quenching a CO-N2 high-temperature plasma. In order to investigate effects of water remaining in an experimental vacuum chamber, optical emission spectroscopic and mass spectrometric measurements were conducted with CO-N2 and CO-N2-H2 gas mixtures. Although residual hydrogen atoms were detected in the CO-N2 experiment, the amount of them was much less than that in the CO-N2-H2 experiment.     

The Genesis Solar Wind Concentrator: Flight and Post-Flight Conditions and Modeling of Instrumental Fractionation

The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

The Freja Hot Plasma Experiment—Instrument and first results

The Hot Plasma Experiment, F3H, on boardFreja is designed to measure auroral particle distribution functions with very high temporal and spatial resolution. The experiment consists of three different units; an electron spectrometer that measures angular and energy distributions simultaneously, a positive ion spectrometer that is using the spacecraft spin for three-dimensional measurements, and a data processing unit. The main scientific objective is to study positive ion heating perpendicular to the magnetic field lines in the auroral region. The high resolution measurements of different positive ion species and electrons have already provided important information on this process as well as on other processes at high latitudes. This includes for example high resolution observations of auroral particle precipitation features and source regions of positive ions during magnetic disturbances. TheFreja orbit with an inclination of 63° allows us to make detailed measurements in the nightside auroral oval during all disturbance levels. In the dayside, the cusp region is covered during magnetic disturbances. We will here present the instrument in some detail and some outstanding features in the particle data obtained during the first months of operation at altitudes around 1700 km in the northern hemisphere auroral region.     

The WIND magnetic field investigation

The magnetic field experiment on WIND will provide data for studies of a broad range of scales of structures and fluctuation characteristics of the interplanetary magnetic field throughout the mission, and, where appropriate, relate them to the statics and dynamics of the magnetosphere. The basic instrument of the Magnetic Field Investigation (MFI) is a boom-mounted dual triaxial fluxgate magnetometer and associated electronics. The dual configuration provides redundancy and also permits accurate removal of the dipolar portion of the spacecraft magnetic field. The instrument provides (1) near real-time data at nominally one vector per 92 s as key parameter data for broad dissemination, (2) rapid data at 10.9 vectors s^–1 for standard analysis, and (3) occasionally, snapshot (SS) memory data and Fast Fourier Transform data (FFT), both based on 44 vectors s^–1. These measurements will be precise (0.025%), accurate, ultra-sensitive (0.008 nT/step quantization), and where the sensor noise level is <0.006 nT r.m.s. for 0–10 Hz. The digital processing unit utilizes a 12-bit microprocessor controlled analogue-to-digital converter. The instrument features a very wide dynamic range of measurement capability, from ±4 nT up to ±65 536 nT per axis in eight discrete ranges. (The upper range permits complete testing in the Earth's field.) In the FTT mode power spectral density elements are transmitted to the ground as fast as once every 23 s (high rate), and 2.7 min of SS memory time series data, triggered automatically by pre-set command, requires typically about 5.1 hours for transmission. Standard data products are expected to be the following vector field averages: 0.0227-s (detail data from SS), 0.092 s (detail in standard mode), 3 s, 1 min, and 1 hour, in both GSE and GSM coordinates, as well as the FFT spectral elements. As has been our team's tradition, high instrument reliability is obtained by the use of fully redundant systems and extremely conservative designs. We plan studies of the solar wind: (1) as a collisionless plasma laboratory, at all time scales, macro, meso and micro, but concentrating on the kinetic scale, the highest time resolution of the instrument (=0.022 s), (2) as a consequence of solar energy and mass output, (3) as an external source of plasma that can couple mass, momentum, and energy to the Earth's magnetosphere, and (4) as it is modified as a consequence of its imbedded field interacting with the moon. Since the GEOTAIL Inboard Magnetometer (GIM), which is similar to the MFI instrument, was developed by members of our team, we provide a brief discussion of GIM related science objectives, along with MFI related science goals.     

Magnetic holes in the solar wind and their relation to mirror-mode structures

Data obtained by the Ulysses magnetometer and solar wind analyzer have been combined to study the properties of magnetic holes in the solar wind between 1 and 5.4 AU and to 23° south latitude. Although the plasma surrounding the holes was generally stable against the mirror instability, there are indications that the holes may have been remnants of mirror mode structures created upstream of the points of observation. Those indications include: (1) For the few holes for which proton or alpha-particle pressure could be measured inside the hole, the ion thermal pressure was always greater than in the plasma adjacent to the holes. (2) The plasma surrounding many of the holes was marginally stable for the mirror mode, while the plasma environment of all the holes was significantly closer to mirror instability than was the average solar wind. (3) The plasma containing trains of closely spaced holes was closer to mirror instability than was the plasma containing isolated holes. (4) The near-hole plasma had much higher ion (ratio of thermal to magnetic pressure) than did the average solar wind.     

The elemental composition in energetic particle events at high heliospheric latitudes

The relative abundances of low energy ions (0.6–2.0 MeV/n) in solar energetic particle (SEP) and corotating interaction region (CIR) events have been measured by the EPAC experiment aboard Ulysses since launch in October 1990 until the present time. We give an overview of the abundances of heavy ions (He, C, Ne, Fe) relative to oxygen during energetic particle events lasting longer than 5 days during the in- and out-of-ecliptic phase of the mission. While the period Oct. 1990 to Aug. 1992 was dominated by high solar activity the Ulysses out of ecliptic passage at solar latitudes up to 45° went parallel to the declining phase of solar activity. Thus a very clear structure of corotating interaction regions was observed. While the in-ecliptic composition is in general agreement with measurements made near the Earth, the development of the CIR-composition shows two phases: From Aug. 1992 to May 1993 the C/O-ratio is 0.55–0.70, afterwards it increases to 0.8–0.9. This increase is correlated to the disappearance of the current sheet at 30° solar latitude reported by Smithet al. (1993).     

Gasdynamics of the solar wind interaction with the interstellar medium

A survey of the present-day situation in gasdynamical models of solar wind interaction with the local interstellar medium is presented. A role of these models in interpreting a number of observed physical phenomena is investigated. Experimental data and possible observations are considered from the viewpoint of their interpretation on the basis of theoretical models. Our attention is concentrated on the main limitations of the gasdynamical models, in particular, two-shocks model developed by Baranovet al. (1981, 1982).     

False-Alarm Regulation in Log-Normal and Weibull Clutter

Automatic detection radars require some method of adapting to variations in the background clutter in order to control their false-alarm rate. Conventional cell-averaging techniques designed to maintain a constant false-alarm rate in Rayleigh clutter will fail to control the false-alarm rate in more severe clutter environments such as log-normal or Weibull clutter. A processor is described which is capable of maintaining false-alarm regulation in log-normal clutter and in Weibull clutter (and, under certain conditions, over the entire family of log-normal and Weibull distributions).     

Numerical Results on the Convergence of Relative Efficiencies

This paper considers the detection of a known constant signal in an additive non-Gaussian noise under the assumptions of discrete time and statistically independent noise samples. The objective is to determine how large sample size must be before the easily computed asymptotic relative efficiency becomes a valid measure of performance. The exact small-sample error probabilities are calculated for a Neyman-Pearson optimal nonlinear detector consisting of a zeromemory nonlinearity followed by summation and threshold comparison. "Large-tailed" noise having a double exponential distribution is used as an example. The exact distribution of the test statistics for a linear detector and for the Neyman-Pearson optimal detector are calculated. Then the relative efficiency of the Neyman-Pearson optimal detector, as compared to a linear detector, is computed in order to study the rate of approach of the relative efficiency to its asymptotic value.     

Hard Limiting in Synthetic Aperture Signal Processing

In synthetic aperture radar a large linear phased array is formed from the rapid movement of a single element through each position in the array. Storage and coherent combining of the successive radar echoes are central to the array-forming process. Optical processing is the most common technique because of the efficiency with which Fourier transformation may be accomplished with simple optics. Real-time operation, however, requires all-electronic processing, which is difficult to accomplish because of the huge quantity of data to be manipulated. Dynamic range compression by hard limiting may ease the problem by reducing the number of bits per frame. The effects of hard limiting are analyzed in this paper. It is shown that large targets simultaneously illuminated by the radar antenna will produce image targets or ghosts displaced in angle. Statistically homogeneous clutter will "linearize" the hard-limited receiver and suppress the ghosts without loss in contrast, as does thermal noise if it is larger than the target echoes. Pulse compression reduces the probability of images from prominent targets. Judicious choice of the pulse-compression waveform is a powerful tool for destroying coherent buildup of images from all large targets not in the same range resolution cell. Linear FM, the most common choice, unfortunately does not exhibit this desirable property.