Thermal Polymerization of Cyanate Ester-Benzoxazine：Study of a Functional Model Compound

A novel benzoxazine (BOZ) monomer is synthesized by a pot method with solvent-free to blend with cyanate ester (CE). A soluble intermediate is obtained after being cured for 20 h at 80 ℃. The two model compound and the blends are analyzed with the infrared radiation (IR)， nuclear magnetic resonance (NMR) spectroscopy， and differential scanning calorimetry (DSC). The results show that an intermediate of the iminocarbonate and BOZ structures is formed by the ring-open BOZ reacting with the cyanate groups and ring-unopened BOZ. Moreover， rearrangement and ring-opening occur in the postcure of the intermediate to form the alkyl isocyanurate structure with polybenzoxazine.     

Tírez lake as a terrestrial analog of Europa

Tírez Lake (La Mancha, central Spain) is proposed as a terrestrial analogue of Europa's ocean. The proposal is based on the comparison of the hydrogeochemistry of Tírez Lake with the geochemical features of the alteration mineralogy of meteoritic precursors and with Galileo's Near Infrared Mapping Spectrometer data on Europa's surface. To validate the astrobiological potential of Tírez Lake as an analog of Europa, different hydrogeochemical, mineral, and microbial analyses were performed. Experimental and theoretical modeling helped to understand the crystallization pathways that may occur in Europa's crust. Calculations about the oxidation state of the hypothetical Europan ocean were estimated to support the sulfate-rich neutral liquid model as the origin of Europa's observed hydrated minerals and to facilitate their comparison with Tírez's hydrogeochemistry. Hydrogeochemical and mineralogical analyses showed that Tírez waters corresponded to Mg-Na-SO(4)-Cl brines with epsomite, hexahydrite, and halite as end members. A preliminary microbial ecology characterization identified two different microbial domains: a photosynthetically sustained community represented by planktonic/benthonic forms and microbial mat communities, and a subsurficial anaerobic realm in which chemolithotrophy predominates. Fluorescence in situ hybridization has been used to characterize the prokaryotic diversity of the system. The subsurficial community seemed to be dominated by sulfate-reducing bacteria and methanogens. Frozen Tírez brines were analyzed by Fourier-transform infrared techniques providing spectra similar to those reported previously using pure components and to the Galileo spectral data. Calorimetric measurements of Tírez brines showed pathways and phase metastability for magnesium sulfate and sodium chloride crystallization that may aid in understanding the processes involved in the formation of Europa's icy crust. The use of fluorescence hybridization techniques for microbial detection and characterization in hypersaline environments makes this methodology strongly advisable for future Europa astrobiological missions.     

Peculiarities of the formation of a thin current sheet in the Earth’s magnetosphere

We investigate the process of the self-consistent formation of a thin current sheet with a thickness close to the ion Larmor gyroradius in the presence of decreasing magnetic field’s normal component B_n. This behavior is typical of the current sheet of the Earth’s magnetospheric tail during geomagnetic substorms. It has been shown that, in a numerical model of the current sheet, based on the particle-in-cell method, the appearance of self-consistent electric field component E_y in the current sheet vicinity can lead to its significant thinning and, eventually, to the formation of a multiscale configuration with a thin current sheet (TCS) in the central region supported by transient particles. The structure of the resulting equilibrium is determined by the initial parameters of the model and by the particle dynamics during the sheet thinning. Under certain conditions, the particle drift in the crossed electric and magnetic fields leads to a significant portion of ions becoming trapped near the neutral sheet and, in this way, to the formation of a wider configuration with an embedded thin current sheet. The population of trapped particles produces diamagnetic negative currents that manifest in the form of negative wings at the periphery of the sheet. Correspondingly, in the direction perpendicular to the sheet, a nonmonotonic coordinate dependence of the magnetic field appears. The mechanisms of the evolution of the current sheet in the Earth’s magnetotail and the formation of a multiscale structure are discussed.     

Lossless compression of stromatolite images: a biogenicity index?

It has been underappreciated that inorganic processes can produce stromatolites (laminated macroscopic constructions commonly attreibuted to microbiological activity), thus calling into question the long-standing use of stromatolites as de facto evidence for ancient life. Using lossless compression on unmagnified reflectance red-green-blue (RGB) images of matched stromatolite-sediment matrix pairs as a complexity metric, the compressibility index (delta(c), the log ratio of the ratio of the compressibility of the matrix versus the target) of a putative abiotic test stromatolite is significantly less than the delta(c) of a putative biotic test stromatolite. There is a clear separation in delta(c) between the different stromatolites discernible at the outcrop scale. In terms of absolute compressibility, the sediment matrix between the stromatolite columns was low in both cases, the putative abiotic stromatolite was similar to the intracolumnar sediment, and the putative biotic stromatolite was much greater (again discernible at the outcrop scale). We propose tht this metric would be useful for evaluating the biogenicity of images obtained by the camera systems available on every Mars surface probe launched to date including Viking, Pathfinder, Beagle, and the two Mars Exploration Rovers.     

Is the presence of oxygen on an exoplanet a reliable biosignature?

We revisit the validity of the presence of O(2) or O(3) in the atmosphere of a rocky planet as being a biosignature. Up to now, the false positive that has been identified applies to a planet during a hot greenhouse runaway, which is restricted to planets outside the habitable zone (HZ) of the star that are closer to the star. In this paper, we explore a new possibility based on abiotic photogeneration of O(2) at the surface of a planet that could occur inside the HZ. The search for such a process is an active field of laboratory investigation that has resulted from an ongoing interest in finding efficient systems with the capacity to harvest solar energy on Earth. Although such a process is energetically viable, we find it to be a very unlikely explanation for the observation of O(2) or O(3) in the atmosphere of a telluric exoplanet in the HZ. It requires an efficient photocatalyst to be present and abundant under natural planetary conditions, which appears unlikely according to our discussion of known mineral photochemical processes. In contrast, a biological system that synthesizes its constituents from abundant raw materials and energy has the inherent adaptation advantage to become widespread and dominant (Darwinist argument). Thus, O(2) appears to continue to be a good biosignature.     

Did evolution select a nonrandom "alphabet" of amino acids?

The last universal common ancestor of contemporary biology (LUCA) used a precise set of 20 amino acids as a standard alphabet with which to build genetically encoded protein polymers. Considerable evidence indicates that some of these amino acids were present through nonbiological syntheses prior to the origin of life, while the rest evolved as inventions of early metabolism. However, the same evidence indicates that many alternatives were also available, which highlights the question: what factors led biological evolution on our planet to define its standard alphabet? One possibility is that natural selection favored a set of amino acids that exhibits clear, nonrandom properties-a set of especially useful building blocks. However, previous analysis that tested whether the standard alphabet comprises amino acids with unusually high variance in size, charge, and hydrophobicity (properties that govern what protein structures and functions can be constructed) failed to clearly distinguish evolution's choice from a sample of randomly chosen alternatives. Here, we demonstrate unambiguous support for a refined hypothesis: that an optimal set of amino acids would spread evenly across a broad range of values for each fundamental property. Specifically, we show that the standard set of 20 amino acids represents the possible spectra of size, charge, and hydrophobicity more broadly and more evenly than can be explained by chance alone.     

Development and Application of a Carrier-free Impulse Sub-surface Detecting Radar in China

This paper describes the design and features of the Image Detecting Impulse (IDI) radar developed by Beijing Institute of Remote Sensing Equipment affiliated to China Aerospace Corp.,which has been successfully used to get three-dimension images of sub-surface objects.It also discusses the radar's development,tests and wide applications.     

On Saturn’s rotation relative to a center of mass under the action of the gravitational moments of the Sun and Jupiter

Saturn’s rotation relative to a center of mass is considered within an elliptic restricted three-body problem. It is assumed that Saturn is a solid under the action of gravity of the Sun and Jupiter. The motions of Saturn and Jupiter are considered elliptic with small eccentricities e_S and e_J, respectively; the mean motion of Jupiter n_J is also small. We obtain the averaged Hamiltonian function for a small parameter of ε = n_J and integrals of evolution equations. The main effects of the influence of Jupiter on Saturn’s rotation are described: (α) the evolution of the constant parameters of regular precession for the angular momentum vector I₂; (β) the occurrence of new libration zones of oscillations I₂ near the plane of the celestial equator parallel to the plane of the Jupiter’s orbit; (γ) the occurrence of additional unstable equilibria of vector I₂ at the points of the north and south poles of the celestial sphere and, as a result, the existence of homoclinic trajectories; and (δ) the existence of periodic trajectories with arbitrarily large periods near the homoclinic trajectory. It is shown that the effects of (β), (γ), and (δ) are caused by the eccentricity e of the Jupiter’s orbit and are practically independent of Jupiter’s mass (within satellite approximation).     

Diurnal and longitudinal variations in the earth’s ionosphere in the period of solstice in conditions of a deep minimum of solar activity

The results of studies of longitudinal and LT variations in parameters of the ionosphere–plasmasphere system, obtained using the Global Self-Consistent Model of the Thermosphere, Ionosphere and Protonosphere (GSM TIP), assimilation ionospheric model IRI Real-Time Assimilation Mapping (IRTAM), and satellite and ground-based observational data are presented in the paper. The study of the main morphological features of longitudinal and LT variations in the critical frequency of the ionospheric F2 layer (foF2) and total electron content (TEC) depending on latitude in the winter solstice during a solar-activity minimum (December 22, 2009) is carried out. It is shown that the variations in foF2 and TEC, on the whole, are identical, and so mutually substitutable, while creating empirical models of these parameters in quiet geomagnetic conditions. The longitudinal and LT variations in both foF2 and TEC are within an order of magnitude everywhere except for the equator anomaly region, where LT variation is larger by an order of magnitude than longitudinal variation. According to the results of the study, in the American longitudinal sector at all latitudes of the Southern (summer) Hemisphere, maxima of foF2 and TEC are formed. The near-equatorial and high-latitudinal maxima are separated out from these. The estimate of the contribution into the longitudinal variation in foF2 and TEC for various local time sectors and at various latitudes has been obtained for the first time. In the Southern (summer) Hemisphere, longitudinal variation in foF2 and TEC is formed in the nighttime.     

Large eddy simulation based studies of jet–cavity interactions in a supersonic flow

Interactions of a cavity flameholder with an upstream injected jet in a Ma 2.52 supersonic flow are investigated numerically. A hybrid RANS/LES (Reynolds-Averaged Navier–Stokes/Large Eddy Simulation) method acting as wall-modeled LES is adopted, for which the recycling/rescaling method is introduced to treat the unsteady turbulent inflow. Patterns of the fluid entrainment into the cavity and escape from the cavity are identified using a scalar-tracing method. It is found that the jet–cavity interactions remarkably enhanced the mass exchange between the fluids in and out of the cavity, resulting in reduced residence time of the cavity fluids. Increasing the distance between the fuel injection and the cavity leading edge tends to attenuate the jet–cavity interactions, leading to weaker mass exchange. Raising the injection pressure appears to enhance the jet–cavity interactions, resulting in a shorter residence time of the cavity fluids. Moreover, the mass decay processes for the fuel and air within the cavity are basically the same while the entrainment processes for the fuel and air into the cavity seem quite different.     

A preliminary assessment of an orbiter in the Haumean system: How quickly can a planetary orbiter reach such a distant target?

With the recent discoveries of planetary objects beyond Neptune and Pluto, the vast majority of all sizeable Solar System planetary objects lie now beyond Uranus, where insertion into orbit after a reasonably short travel is still not within the current capabilities of our spacecraft. Being able to go and stop at a transneptunian dwarf planet would represent a step stone for ambitious long-term goals. The pressure to send spacecraft to these bodies will grow, as, among the tens or hundreds of large objects, some will emerge as high priorities for science and exploration missions. It is subsequently necessary to prepare the technologies required for such spacecraft. In addition, being able to achieve a fast journey to a distant object will benefit also missions to closer targets.Thales Alenia Space has carried out a preliminary parameter exploration of such a mission with a challenging target: an orbiter in the Haumean system. The main parameters are the characteristics of the propulsion and power system, as well as the masses of the spacecraft. The exploration has inferred the technological improvement needed for reaching these objects within a reasonable time.     

Global impulse burst of geomagnetic pulsations in the frequency range of 0.2–5 Hz as a precursor of the sudden commencement of St. Patrick’s Day 2015 geomagnetic storm

We have analyzed a short-term (3–4 s) burst of geomagnetic pulsations in the frequency range of 0.2–5 Hz observed during the commencement of a magnetic storm on March 17, 2015. The burst was observed by a network of observatories in different sectors of local time and at different latitudes. The spectra of pulsations involves a resonant structure with a global maximum at a frequency of 2.78 ± 0.38 Hz, despite some differences at different observatories. There is a delay by almost 4 s in the maximum of the train amplitude at nightside observatories with respect to a dayside observatory. The burst of pulsations has been shown to be on the front of the magnetic disturbance associated with sudden storm commencement (SSC) and, therefore, can be considered as a precursor. The observations of particle fluxes by low-orbit satellites have shown that the SSC is accompanied by a dramatic increase in the fluxes of precipitating protons and electrons. We have suggested that the mechanism of oscillation generation may be the ion–cyclotron instability of ring current protons and the resonant structure of pulsations may be associated with the ionospheric Alfvén resonator.     

Biogeochemistry of hypersaline springs supporting a mid-continent marine ecosystem: an analogue for martian springs?

Hypersaline springs that host unique mid-continent marine ecosystems were examined in central Manitoba, Canada. The springs originate from a reflux of glacial meltwater that intrudes into underlying bedrock and dissolved buried salt beds. Two spring types were distinguished based both on flow rate and geochemistry. High flow springs (greater than 10 L/s) hosted extensive marine microbial mats, which were dominated by algae but also included diverse microbes. These varied somewhat between springs as indicated by changes in profiles of fatty acid methyl esters. Culture studies confirmed the presence of sulfate-reducing bacteria in sediments at the high flow sites. In contrast, low flow springs were affected by solar evaporation, increasing salinity, and temperature. These low flow springs behaved more like closed nutrient-limited systems and did not support microbial mats. Direct comparison of the high and low flow springs revealed interesting implications for the potential to record biosignatures in the rock record. High flow springs have abundant, well-developed microbial mats, which desiccate and are cemented along the edges of the spring pools; however, the high mass flux overwhelms any geochemical signature of microbial activity. In contrast, the nutrient-limited low flow sites develop strong geochemical signatures of sulfate reduction, even in the absence of microbial mats, due to less dilution with the lower flows. Geochemical and physical evidence for life did not correlate with the abundance of microbial life but, rather, with the extent to which the biological system formed a closed ecosystem.     

Can identification of a fourth domain of life be made from sequence data alone, and could it be done on Mars?

A central question in astrobiology is whether life exists elsewhere in the universe. If so, is it related to Earth life? Technologies exist that enable identification of DNA- or RNA-based microbial life directly from environmental samples here on Earth. Such technologies could, in principle, be applied to the search for life elsewhere; indeed, efforts are underway to initiate such a search. However, surveying for nucleic acid-based life on other planets, if attempted, must be carried out with caution, owing to the risk of contamination by Earth-based life. Here we argue that the null hypothesis must be that any DNA discovered and sequenced from samples taken elsewhere in the universe are Earth-based contaminants. Experience from studies of low-biomass ancient DNA demonstrates that some results, by their very nature, will not enable complete rejection of the null hypothesis. In terms of eliminating contamination as an explanation of the data, there may be value in identification of sequences that lie outside the known diversity of the three domains of life. We therefore have examined whether a fourth domain could be readily identified from environmental DNA sequence data alone. We concluded that, even on Earth, this would be far from trivial, and we illustrate this point by way of examples drawn from the literature. Overall, our conclusions do not bode well for planned PCR-based surveys for life on Mars, and we argue that other independent biosignatures will be essential in corroborating any claims for the presence of life based on nucleic acid sequences.     

Can enantiomorphic crystals like quartz play a role in the origin of homochirality on earth?

This communication reviews the possible actions of enantiomorphic crystals on the surface of Earth as sources of homochirality of organic compounds. The discovery of asymmetric adsorption and asymmetric catalysis involving optically active quartz crystals has led some authors to conclude that this source of asymmetry played an important role as a source of homochirality in nature, a concept that later proved erroneous. Moreover, data regarding the preponderance in nature of l-quartz crystals have been used to confirm calculations of the parity violation energy difference (PVED) for l-quartz and, hence, to explain the prevalence of L-amino acids and D-sugars in living matter. As discussed here, quartz and other enantiomorphs such as sodium chlorate can produce chiral intermediates active in autocatalytical processes. Our most recent compilation of the literature, however, reveals that the distribution of d- and l-quartz crystals at the surface of the Earth when all possible locations are included is quite random. Although quartz can serve as an effective asymmetric inductor in autocatalytic processes, it cannot be the source of homochirality of living matter because of the random occurrence of the two types of enantiomorphs. The calculations of PVED values for quartz therefore lack a sound physical basis.     

Characteristics of Near-Polar Atmosphere/Thermosphere of Mars at Altitudes of 125–145 km: The Data of a Radio Occultation Experiment onboard the <Emphasis Type="Italic">Mars Global Surveyor</Emphasis> Spacecraft

Using data from a radio occultation experiment onboard the Mars Global Surveyor spacecraft, altitude variations of the scale height of the neutral atmosphere in the northern and southern hemispheres of Mars are analyzed. The averaged altitude gradient of temperature for neutrals in the thermosphere is estimated. The revealed variations of the scale height of the neutral atmosphere at zenith angles of less than 82° indicate that the near polar atmosphere is not isothermal at altitudes of 125–145 km, which experimentally confirms predictions of models of the Martian atmosphere. It is shown that when one approaches the terminator the near polar atmosphere is cooled and the effects of variation of the solar zenith angle modulate the local time effects in both hemispheres.