有机废水的TiO2光催化氧化处理技术浅析

TiO2以优良的催化性能，被有机废水处理领域日益广泛采用。本文对TiO2光催化氧化技术的研究发展进程作了概要综述，并对该技术在有机污水处理领域的应用作了阐述，对实际工作具有一定的指导意义。     

TiO_2薄膜的制备及其光催化性能的研究

采用溶胶-凝胶法制备了TiO2薄膜,以10mg/L甲基橙为目标降解物,研究了焙烧温度、镀膜层数、紫外线光照时间对TiO2薄膜光催化性能的影响.实验结果表明,焙烧温度为500℃,镀膜层数为三层所制得TiO2薄膜光催化活性最好,并且具有稳定、持续的降解效果.     

纳米光催化技术在客机座舱空气质量控制中的应用

纳米光催化技术是一种新型的空气净化技术,近年来已成为空气净化领域的研究热点之一。本文简要介绍了纳米光催化技术的发展历史、净化机理以及国内外的研究进展;分析了实际应用中存在的问题;并指出了纳米光催化技术在客机座舱空气质量控制中的应用前景。     

纳米TiO2/Fe2O3复合材料的制备及其红外吸收性能研究

用溶胶-凝胶法制备了纳米TiO2／Fe2O3复合材料，并用XRD、TEM等方法对其进行了表征，给出了相关的工艺参数。研究了不同组分的纳米TiO2／Fe2O3的红外吸收特性。结果表明，纳米TiO2／Fe2O3复合材料在400cm^-1～1000cm^-1内随Fe2O3含量的增加，吸收峰明显宽化。     

纳米级材料及其在航空上的应用前景

纳米级材料及其在航空上的应用前景石汶为了改善材料的性能，航空材料的发展经历了从粗晶到细晶、微晶到纳米晶的过程。早在８０年代中期，ＨｅｒｂｅｒｔＧｌｅｉｔｅｒ就用一种简单的物理气相沉积法合成了“一种新形式的物质”，取名为“纳米相”（也称作“纳米晶”）材...     

纳米雷达隐身材料研究进展

从纳米材料的结构特征出发，简单阐述了纳米材料在雷达隐身方面的应用前景及近年来国内外不同的纳米雷达隐身材料的制备方法、结构特点和雷达吸波性能。结合实际需求和国外发展动态指出了我国未来纳米雷达隐身材料的发展方向。     

纳米微波吸收剂研究现状与进展

介绍了纳米材料作为微波吸收剂的基本原理及其优异的吸波性能。综述了纳米材料（纳米金属粉，纳米铁氧体及其复合物）作为吸波材料损耗介质的国内外最新研究进展及发展趋势。展望了高性能的纳米吸波材料今后的发展前景。     

溶胶-凝胶法制备纳米TiO2 及粒径控制工艺

采用溶胶-凝胶法,以钛酸丁酯为前驱体,乙二醇作为螯合剂制备纳米TiO2 粒子。考察钛的乙二

醇盐的浓度、pH 值、温度等因素对TiO2 粒径的影响,并用红外光谱和SEM 对纳米TiO2 粒子进行结构和形貌表

征。结果表明,采用溶胶凝胶法可以制备出呈椭圆形且粒径分布均匀的TiO2 纳米粒子。使用硝酸铵可以有效

阻止TiO2 纳米粒子团聚。当pH 值为2 ~3、温度为20 ~40℃,钛的乙二醇盐在丙酮中的浓度为0. 03、0. 05 及

0. 07 M 时,粒径分别为150、240 及600 nm。

     

WS2/TiO2异质结构的制备及其模拟太阳光下的分解水性能研究

二氧化钛(TiO₂)因其合适的带隙、稳定的化学性质、耐腐蚀和绿色环保等特点作为光催化材料被广泛应用。然而，在实际应用中，因TiO₂存在光催化活性低、光利用率低等缺点而极大地限制了其作为光催化材料的应用前景。鉴于此引入半导体层状材料二硫化钨(WS₂),通过绿色、无污染的超临界流体技术成功地制备出了二维WS₂/TiO₂异质结构。以透射电镜、X射线衍射图谱与光电子射线能谱图等测试方法对WS₂/TiO₂异质结构的形貌、结构进行表征。通过紫外可见吸收光谱、线性扫描伏安曲线、光电流密度以及电化学阻抗谱等测试方法，对WS₂/TiO₂异质结构的光吸收性能及光电催化性能进行表征。结果表明，WS₂纳米片的引入可以明显增强体系的光吸收强度，提高了光电流密度并且降低其阻抗，使得WS₂/TiO₂异质结构展现出优异的光电化学活性。     

高性能抗氧化SmCo高温永磁材料

航空航天及现代工业高技术领域对使用温度达到500℃的永磁材料提出了明确需求。SmCo永磁材料因其高的居里温度、强的磁晶各向异性和高的饱和磁化强度成为现有永磁材料中高温永磁材料的首选。然而,商用的2∶17型SmCo合金因其高的矫顽力温度系数使其最大工作温度不超过300℃。本文重点研究了2∶17型SmCo高温永磁材料、1∶7型纳米晶SmCo高温永磁材料以及SmCo高温永磁材料的抗氧化行为;研制出了可以在500℃及550℃应用的2∶17型SmCo高温永磁体;获得了具有各向异性的1∶7型纳米晶SmCo磁体;1∶7型纳米晶SmCo永磁材料在500℃具有良好的结构和磁性能时效稳定性;合金化和表面改性显著提高了SmCo磁体的高温抗氧化能力。     

纳米管开创高级材料新天地

本文简要介绍了碳纳米管的基本结构,描述了其主要的机械性能、电性能和热性能,讨论了其当前的研究开发状况和存在的问题。     

薄膜生长工艺对TiO_2基紫外探测器光电性能的影响

分别采用磁控溅射和溶胶-凝胶工艺制备了相同厚度的TiO2薄膜,并用以制备了金属-半导体-金属(MSM)结构TiO2基紫外探测器。通过紫外光电性能测试、扫描电子显微镜(SEM)观察及X射线衍射(XRD)分析,研究了TiO2薄膜生长工艺对探测器光电性能的影响规律。结果表明:磁控溅射工艺下,探测器的光电流虽然较低,但响应时间和暗电流远小于溶胶-凝胶工艺制备的探测器,其具备了高辐射灵敏度和快速响应特性。磁控溅射工艺制备的TiO2薄膜结构较为致密,晶界和缺陷较少,方阻较高,这是其取得优良的光电特性的原因。     

飞机座舱有机玻璃透明导电膜的制备及透光和微波散射性能

研究了用溅射法在飞机座舱有机玻璃上镀制金属-介质组合透明导电膜的工艺 ;测试和分析了金膜、银膜、氧化钛膜的光学特性、导电性及形貌结构 ;按薄膜光学原理进行膜系匹计算 ,并分别镀制了 Ti O2-Au-Ti O2 、 Ti O2-Ag-Ti O2 组合透明导电膜。在 40 0～ 760 nm可见光波段内 ,透光率分别达到了 74%和 81 % ,在 8～ 1 2 GHz频段内对垂直入射的微波 ,反射率分别达到-1 .1 d B和-0 .8d B。     

First-principle Calculations of V/Fe Doped Anatase TiO_2

The electronic structures of the titanium dioxide(TiO2) doped with V and Fe were analyzed by using first-principle calculations based on the density functional theory(DFT) with the full potential linearized augmented plane wave method (FP-LAPW). The fully optimized structure and the relaxation introduced by impurity were obtained by minimizing the total energy and atomic forces. The unit cell of the V-doped anatase TiO2 is smaller than that of the non-doped one, but for the Fe-doped one, the case is just the opposite. It is found that the apical Ti-O and impurity-O bond lengths of the V/Fe-doped anatase TiO2 are greater than those of the non-doped structure, but smaller for the equatorial bond length. Through the band structures and the density of states, the V-doped TiO2 is shown to be a kind of half-metal, while the Fe-doped TiO2 a kind of metal. The magnetic moments of the V/Fe-doped system are mainly generated by the dopants. The results may be helpful for us to understand the experimental outcome of this system.     

Effect of sodium tartrate concentrations on morphology and characteristics of anodic oxide film on titanium alloy Ti–10V–2Fe–3Al

The effect of sodium tartrate concentrations on morphology and characteristics of ano-dic oxide film on titanium alloy was investigated. The alloy substrates were anodized in different concentration solutions of sodium tartrate with the addition of PTFE emulsion and their morphol-ogy and characteristics were analyzed. The anodic oxide film presented a uniform petaloid drums and micro-cracks morphology. Additionally, micro-cracks dramatically swelled with the increase of the tartrate concentrations. The thickness of the anodic oxide film increased with the concentra-tions until the concentration reached 15 g/L. The results of Raman analysis illustrate that all sam-ples have similarity in the crystal structure, consisting of mainly amorphous TiO2, some anatase TiO2 and a small amount of rutile TiO2. And the ratios of anatase TiO2 and rutile TiO2 increase with the concentrations until it reaches 15 g/L. Furthermore, the intensity of the peaks increases with enhanced concentrations until the concentration reaches 15 g/L. The corrosion resistance of the anodic oxide film is increased by the sodium tartrate with higher concentrations before 15 g/L. The coefficient of friction of the anodic oxide film reduces with the concentrations until the concentration reaches 15 g/L, then the coefficient of friction of the anodic oxide film increases with the concentrations.     

无机粒子对石墨烯微片／环氧树脂复合材料导电性能的影响

以 KNG-CZ030石墨烯（graphene nanoplatelets,GNPs）为导电填料,环氧树脂（E-54）为聚合物基体,2-乙基-4甲基咪唑（2,4-EMI）为固化剂,采用溶液混合和超声分散的方法制备导电复合材料。通过添加无机粒子（NaCl, TiO2）,研究了无机粒子对石墨烯微片分散均匀性的影响以及对 GNPs ／E-54复合材料导电性能的影响。实验结果表明：加入 NaCl 和 TiO2提高了石墨烯微片在基体中的分散性,降低了复合材料室温体积电阻率,即提高了导电性能;NaCl ／GNPs ／E-54和 TiO2／GNPs ／E-54复合材料室温体积电阻率为106Ω·m 时,石墨烯质量分数分别为0．75％和0．73％,与未添加无机粒子的 GNPs ／E-54复合材料质量分数0．97％相比有所降低。     

Compound Ceramic Coatings Grown by Micro-plasma Oxidation on Ti-6Al-4V Alloy

Compound ceramics coatings on the Ti-6Al-4V alloy were prepared by the direct current micro-plasma oxidation (MPO) in NaAlO2 solution. The composition and morphology of the coatings were studied with the X-ray diffraction (XRD) and the scanning electron microscopy (SEM), respectively. Inductively coupled plasma atomic emission spectrometer technique was used to analyze the solution features of Ti-6Al-4V alloy in the process of preparation. The results reveal that Al2TiO5 forms in the coatings at the initial stages of MPO reaction, and its content changes rapidly with the reaction continuing: after 20 min, the ceramics coatings are composed of α-Al2O3, γ-Al2O3 and Al2TiO5, but after 40 min, its main composition is of α-Al2O3. The content of Ti in the solution will increase when the MPO time extends, and as will Al in the anode area until, after 30 min, it reaches the maximum and keeps constant from then on. Both substrata of Ti and Al in the electrolyte join the MPO reaction at the initial stage, where the formation of Al2TiO5 happens; but as the MPO reaction prolongs, more and more Al in the electrolyte will take part in the reaction, leading to the appearance of a large amount of Al2O3.     

活性剂对不锈钢激光-TIG电弧复合焊接的影响

选用氧化物TiO<,2>、Cr<,2>O<,3>、B<,2>O<,3>、SiO<,2>和氟化物CaF<,2>为活性剂,研究了它们对激光-TIG电弧复合焊接不锈钢的影响.结果表明,Cr<,2>O<,3>和B<,2>O<,3>使焊缝更对称,而TiO<,2>、SiO<,2>和CaF<,2>则可消除焊缝的喇叭口收边,Cr<,2...