On the Existence of Distributed Sources in Comet Comae

The main production process of species occurring in the coma of comets is the photodestruction of molecules initially present in the nucleus ices and non-refractory grains or trapped inside the nucleus "material". Grains can also be a source of molecules in the coma. Chemical reactions may occur between coma species. Consequently, although chances that an abundant coma species has not been detected are now small, the coma composition is certainly quite different from that of the nucleus. Except for the molecules released directly at the nucleus surface, all coma species are produced in an "extended region" or come from "a distributed source". Since the recent literature is rich in reports on observations of molecules and species possibly not initially present in the comet ices or not released at the nucleus, a general discussion of how coma species are stored, processed or produced is presented, based mostly on observational results. What is at stake is the proper modeling of the coma structure, hence an accurate derivation of the nucleus composition from coma observations. This revised version was published online in June 2006 with corrections to the Cover Date.     

From Coma Abundances to Nucleus Composition

A major goal of comet research is to determine conditions in the outer solar nebula based on the chemical composition and structure of comet nuclei. The old view was to use coma abundances directly for the chemical composition of the nucleus. However, since the composition of the coma changes with heliocentric distance, r, the new view is that the nucleus composition msut be determined from analysis of coma mixing ratios as a function of r. Taking advantage of new observing technology and the early detection of the very active Comet Hale-Bopp (C/1995 O1) allows us to determine the coma mixing ratios over a large range of heliocentric distances. In our analysis we assume three sources for the coma gas: (1) the surface of the nucleus (releasing water vapor), (2) the interior of the porous nucleus (releasing many species more volatile than water), and (3) the distributed source (releasing gases from ices and hydrocarbon polycondensates trapped and contained in coma dust). Molecules diffusing inside the nucleus are sublimated by heat transported into the interior. The mixing ratios in the coma are modeled assuming various chemical compositions and structural parameters of the spinning nucleus as it moves in its orbit from large heliocentric distance through perihelion. We have combined several sets of observational data of Comet Hale-Bopp for H₂O (from OH) and CO, covering the spectrum range from radio to UV. Many inconsistencies in the data were uncovered and reported to the observers for a reanalysis. Since post-perihelion data are still sparse, we have combined pre- and post-perihelion data. The resulting mixing ratio of CO relative to H₂O as a function of r is presented with a preliminary analysis that still needs to be expanded further. Our fit to the data indicates that the total CO release rate (from the nucleus and distributed sources) relative to that of H₂O is 30% near perihelion. This revised version was published online in June 2006 with corrections to the Cover Date.     

Reservoirs for Comets: Compositional Differences Based on Infrared Observations

Tracing measured compositions of comets to their origins continues to be of keen interest to cometary scientists and to dynamical modelers of Solar System formation and evolution. This requires building a taxonomy of comets from both present-day dynamical reservoirs: the Kuiper Belt (hereafter KB), sampled through observation of ecliptic comets (primarily Jupiter Family comets, or JFCs), and the Oort cloud (OC), represented observationally by the long-period comets and by Halley Family comets (HFCs). Because of their short orbital periods, JFCs are subjected to more frequent exposure to solar radiation compared with OC comets. The recent apparitions of the JFCs 9P/Tempel 1 and 73P/Schwassmann-Wachmann 3 permitted detailed observations of material issuing from below their surfaces—these comets added significantly to the compositional database on this dynamical class, which is under-represented in studies of cometary parent volatiles. This chapter reviews the latest techniques developed for analysis of high-resolution spectral observations from ～2–5 μm, and compares measured abundances of native ices among comets. While no clear compositional delineation can be drawn along dynamical lines, interesting comparisons can be made. The sub-surface composition of comet 9P, as revealed by the Deep Impact ejecta, was similar to the majority of OC comets studied. Meanwhile, 73P was depleted in all native ices except HCN, similar to the disintegrated OC comet C/1999 S4 (LINEAR). These results suggest that 73P may have formed in the inner giant planets’ region while 9P formed farther out or, alternatively, that both JFCs formed farther from the Sun but with 73P forming later in time.     

Composition Measurements of a Comet from the Rosetta Orbiter Spacecraft

The European Space Agency (ESA) Rosetta Spacecraft, launched on March 2, 2004 toward Comet 67P/Churyumov-Gerasimenko (C-G), carries a complementary set of instruments on both the orbiter and lander (Philae) portions of the spacecraft, to measure the composition of the Comet C-G. The primary composition measuring instruments on the Orbiter are Alice, COSIMA, ICA, MIRO, OSIRIS, ROSINA and VIRTIS. These instruments collectively are capable of providing compositional information, including temporal and spatial distributions of important atomic, molecular, and ionic species, minerals, and ices in the coma and nucleus. The instruments utilize a variety of techniques and wavelength ranges to accomplish their objectives. This paper provides an overview of composition measurements that will be possible using the suite of orbiter composition measuring instruments. A table is provided that lists important species detectable (depending on abundances) with each instrument.     

Reaction Networks for Interstellar Chemical Modelling: Improvements and Challenges

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes—ion-neutral reactions, neutral-neutral reactions, radiative association, and dissociative recombination—is reviewed. Emphasis is placed on those key reactions that have been identified, by sensitivity analyses, as ‘crucial’ in determining the predicted abundances of the species observed in the interstellar medium. These sensitivity analyses have been carried out for gas-phase models of three representative, molecule-rich, astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the expanding circumstellar envelope IRC +10216. Our review has led to the proposal of new values and uncertainties for the rate coefficients of many of the key reactions. The impact of these new data on the predicted abundances in TMC-1 and L134N is reported. Interstellar dust particles also influence the observed abundances of molecules in the interstellar medium. Their role is included in gas-grain, as distinct from gas-phase only, models. We review the methods for incorporating both accretion onto, and reactions on, the surfaces of grains in such models, as well as describing some recent experimental efforts to simulate and examine relevant processes in the laboratory. These efforts include experiments on the surface-catalyzed recombination of hydrogen atoms, on chemical processing on and in the ices that are known to exist on the surface of interstellar grains, and on desorption processes, which may enable species formed on grains to return to the gas-phase.     

3He-Rich Solar Energetic Particle Events

³He-rich solar energetic particle (SEP) events show huge enrichments of ³He and association with kilovolt electrons and Type-III radio bursts. Observations from a new generation of high resolution instruments launched on the Wind, ACE, Yohkoh, SOHO, TRACE, and RHESSI spacecraft have revealed many new properties of these events: the particle energy spectra are found to be either power-law or curved in shape, with the ³He spectrum often being distinctly different from other species. Ultra-heavy nuclei up to >200 amu are found to be routinely present at average enrichments of >200 times solar-system abundances. The high ionization states previously observed near ∼1 MeV/nucleon have been found to decrease towards normal solar coronal values in these events. The source regions have been identified for many events, and are associated with X-ray jets and EUV flares that are associated with magnetic reconnection sites near active regions. This paper reviews the current experimental picture and theoretical models, with emphasis on the new insights found in the last few years.     

Near-surface stratigraphy in comets inferred from observation,laboratory studies,and modeling

A brief discussion is given of the physical processes that may lead to a differentiation of the nucleus of short period comets. It is concluded that samples from the near-surface layers of such comets may give us important information on the initial state of cometary organics and refractories. Cometary ices are more likely to be indicators of the recent evolution of the comet.     

Interstellar Reservoirs of Cometary Matter

We review the evidence for the products of interstellar chemistry in volatile cometary matter. We compare the organic inventory of star-forming cores with that measured in various comets and point out the similarities and differences. The conditions necessary to fractionate interstellar molecules in the heavier isotopes of H, C, O and N are summarised and compared to the measured fractionation ratios in cometary ices. We give a list of future measurements that would shed further light on the putative connection between cometary and interstellar molecules.     

A study of M100 in X-rays

During a search for X-ray emission from Supernova 1979c, the parent galaxy M100 (NGC 4321) was repeatedly observed with the IPC and HRI instruments aboard the Einstein X-ray Observatory. The X-ray data reveal two possible sources in the arms of the spiral galaxy, two components in the nuclear bulge and extended X-ray emission from the central part of the galaxy (160x160 square arc seconds centered on the nucleus). We find that the estended X-ray emission cannot be explained in terms of inverse Compton effect on radio, optical or 3 K blackbody photons but rather it is likely to originate from supernova remnants (M100 is indeed a prolific supernova producer) and/or early type stars. As for M100 as a whole, the ratio of X-ray to optical liminosity places it half way between normal galaxies e.g. M31 or M33 and peculiar or active galaxies.     

Rosetta Radio Science Investigations (RSI)

The Rosetta spacecraft has been successfully launched on 2nd March 2004 to its new target comet 67 P/Churyumov-Gerasimenko. The science objectives of the Rosetta Radio Science Investigations (RSI) experiment address fundamental aspects of cometary physics such as the mass and bulk density of the nucleus, its gravity field, its interplanetary orbit perturbed by nongravitational forces, its size and shape, its internal structure, the composition and roughness of the nucleus surface, the abundance of large dust grains, the plasma content in the coma and the combined dust and gas mass flux. The masses of two asteroids, Steins and Lutetia, shall be determined during flybys in 2008 and 2010, respectively. Secondary objectives are the radio sounding of the solar corona during the superior conjunctions of the spacecraft with the Sun during the cruise phase. The radio carrier links of the spacecraft Telemetry, Tracking and Command (TT&C) subsystem between the orbiter and the Earth will be used for these investigations. An Ultrastable oscillator (USO) connected to both transponders of the radio subsystem serves as a stable frequency reference source for both radio downlinks at X-band (8.4 GHz) and S-band (2.3 GHz) in the one-way mode. The simultaneous and coherent dual-frequency downlinks via the High Gain Antenna (HGA) permit separation of contributions from the classical Doppler shift and the dispersive media effects caused by the motion of the spacecraft with respect to the Earth and the propagation of the signals through the dispersive media, respectively. The investigation relies on the observation of the phase, amplitude, polarization and propagation times of radio signals transmitted from the spacecraft and received with ground station antennas on Earth. The radio signals are affected by the medium through which the signals propagate (atmospheres, ionospheres, interplanetary medium, solar corona), by the gravitational influence of the planet on the spacecraft and finally by the performance of the various systems involved both on the spacecraft and on ground.     

Thermal and Chemical Evolution of Comet Nuclei and Kuiper Belt Objects

The structure and composition of comet nuclei are mainly altered during two short phases that are separated by a very long hibernation phase. Early evolution—during and immediately after formation—is the result of heating caused by radioactive decay, the most important source being ²⁶Al. Several studies are reviewed, dealing with evolution throughout this phase, calculated by means of 1-D numerical codes that solve the heat and mass balance equations on a fixed spherically symmetric grid. It is shown that, depending on parameters, the interior may reach temperatures above the melting point of water. The models thus suggest that comets are likely to lose the ices of very volatile species during early evolution; ices of less volatile species are retained in the cold subsurface layer. As the initially amorphous ice is shown to crystallize in the interior, some objects may also lose part of the volatiles trapped in amorphous ice. Generally, the outer layers are far less affected than the inner part, resulting in a stratified composition and altered porosity distribution. The second phase of evolution occurs when comet nuclei are deflected into the inner solar system and is dominated by the effect of solar radiation. Now the outer layers are those mostly affected, undergoing crystallization, loss of volatiles, and significant structural changes. If any part of a comet nucleus should retain its pristine structure and composition, it would be well below the surface and also well above the core.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Expectations for Infrared Spectroscopy of 9P/Tempel 1 from Deep Impact

The science payload on the Deep Impact mission includes a 1.05–4.8 μm infrared spectrometer with a spectral resolution ranging from R∼200–900. The Deep Impact IR spectrometer was designed to optimize, within engineering and cost constraints, observations of the dust, gas, and nucleus of 9P/Tempel 1. The wavelength range includes absorption and emission features from ices, silicates, organics, and many gases that are known to be, or anticipated to be, present on comets. The expected data will provide measurements at previously unseen spatial resolution before, during, and after our cratering experiment at the comet 9P/Tempel 1. This article explores the unique aspects of the Deep Impact IR spectrometer experiment, presents a range of expectations for spectral data of 9P/Tempel 1, and summarizes the specific science objectives at each phase of the mission.     

Rheological and Thermal Properties of Icy Materials

Laboratory measurements of physical properties of planetary ices generate information for dynamical models of tectonically active icy bodies in the outer solar system. We review the methods for measuring both flow properties and thermal properties of icy planetary materials in the laboratory, and describe physical theories that are essential for intelligent extrapolation of data from laboratory to planetary conditions. This review is structured with a separate and independent section for each of the two sets of physical properties, rheological and thermal. The rheological behaviors of planetary ices are as diverse as the icy moons themselves. High-pressure water ice phases show respective viscosities that vary over four orders of magnitude. Ices of CO₂, NH₃, as well as clathrate hydrates of CH₄ and other gases vary in viscosity by nearly ten orders of magnitude. Heat capacity and thermal conductivity of detected/inferred compositions in outer solar system bodies have been revised. Some low-temperature phases of minerals and condensates have a deviant thermal behavior related to paramount water ice. Hydrated salts have low values of thermal conductivity and an inverse dependence of conductivity on temperature, similar to clathrate hydrates or glassy solids. This striking behavior may suit the dynamics of icy satellites.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Observations of interplanetary shocks: Recent progress

Interplanetary shock observations since the prior Solar Terrestrial Physics Symposium in 1978 are reviewed. Since the interval coincides with the recent solar maximum, emphasis is placed on shocks associated with transient solar phenomena, including coronal transients and eruptive prominences as well as flares. A good correlation between shocks and Storm Sudden Commencements has persisted into the recent maximum. Shocks have been identified that are associated with disappearing filaments and coronal transients rather than with flares. Significant progress has been made in the indirect observation of shocks near the Sun as a result of radio wave measurements in interplanetary space and measurement of the scintillation and spectral broadening of spacecraft radio transmissions. Preliminary results regarding the thickness of interplanetary shocks have appeared. Several quasi-parallel shocks propagating more nearly along, rather than across, the magnetic field have been identified. The plasma drivers accompanying interplanetary shocks have received increased attention and distinctive features have been found in electron, ion and magnetic field data.     

The origin of cosmic rays in spiral galaxies

The problem of the origin and distribution of cosmic rays in the Galaxy is introduced by summarizing the literature on the radio and -ray studies of the Galaxy, discussing the propagation of cosmic rays in the interstellar medium, and listing the observed properties of cosmic rays. The localization of cosmic-ray electrons to their parent galaxies is an indicator that processes leading to cosmic-ray production may be common to galaxies like our own. The studies of external galaxies are therefore relevant to our own and have the advantage of better perspective.Studies of cosmic rays in exsternal galaxies are limited to the electron component which radiates synchrotron emission at radio frequencies. Multi-colour photometry of galaxies allows the separation of stellar populations that harbour particular classes of cosmic-ray sources. Statistical studies aimed at correlating integrated radio and optical properties of galaxies have reached conflicting conclusions. Although a correlation of cosmic rays with the older stellar population is proposed by some authors, others argue that the young stellar population harbours cosmic ray sources.Morphological studies of resolved galaxies provide information on the distributions of cosmic-ray electrons in galaxies. Studies in which the resolution of the radio images is much lower than in the optical are limited and have also produced contradictory results. Radio imaging at optical resolution is required for a direct comparison of cosmic-ray distributions with stellar distributions. Such studies are reviewed and the constraints they impose on cosmic-ray propagation and distribution of cosmic-ray sources is discussed.Theoretical cosmic-ray acceleration mechanisms are surveyed and an attempt is made to determine likely contributors. Mechanisms associated with shock waves in a variety of astrophysical settings are reviewed. Acceleration mechanisms not involving shocks, are also discussed. Finally, the status of the field is summarized along with some speculation on the future directions the field may take.     

Changes in the Structure of Comet Nuclei Due to Radioactive Heating

The initial structure of a comet nucleus is most probably a homogeneous, porous, fine-grained mixture of dust and ices, predominantly water. The water ice is presumably amorphous and includes considerable fractions of occluded gases. This structure undergoes significant changes during the early evolution of the nucleus at large heliocentric distances, due to internal radiogenic heating. Structural changes occur mainly as a result of gas flow through the porous medium: the gas pressure that builds up in the interior is capable of breaking the fragile structure and altering the pore sizes and porosity. These effects are modeled and followed numerically, testing a large number of parameters. This revised version was published online in June 2006 with corrections to the Cover Date.