Structure and UV absorption of QCCs: carbonaceous dust analogues.

"Quenched Carbonaceous Composites (QCCs)" are carbonaceous interstellar dust analogues synthesized in the laboratory from a hydrocarbon plasma. We produced new types of carbonaceous condensates from the ejecta of plasma with mixtures of methane and hydrogen as source gases. We find that QCC with an absorbance peak at 220 nm is composed of onion-like spherules, and QCCs with an absorbance peak at 230-240 nm are composed of polyhedral particles. The onion-like QCC contains aromatic hydrogen bonds, and it shows the 3.3 and 11.4 micrometers absorption bands. The QCC with an absorbance peak at 230-240 nm is composed of ribbons with bent graphitic layers. This suggests that the carrier of the interstellar 220 nm extinction band might also be an emitter of the interstellar diffuse emission bands.     

Quenched Carbonaceous Composite: a laboratory analog for carbonaceous material in the interstellar medium.

We review the properties of Quenched Carbonaceous Composite (QCC), a residue produced from a hydrocarbon plasma, and the properties of its derivatives. A. Sakata and his colleagues have shown that QCC has a 220 nm absorption band, visible fluorescence matching the extended red emission seen in reflection nebulae, and infrared absorption bands that correspond to the infrared emission features in reflection nebulae, HII regions, and planetary nebulae. These properties make QCC a strong candidate material as a laboratory analog to the carbonaceous material in the interstellar medium. QCC is distinguished from the PAH hypothesis in that (1) it is a condensate composed of aromatic and aliphatic molecules, as well as radicals; (2) it exhibits a 220 nm absorption that is very similar in wavelength to the 217 nm absorption in the interstellar medium; (3) it exhibits visible fluorescence consistent with that seen in reflection nebulae; and (4) the bands at 7.7 and 8.6 microns are caused by ketone bands in oxidized QCC. The aromatic component in QCC is thought to be typically 1-4 rings, with the majority being about 1-2 rings.     

金属橡胶力学特性的热处理工艺影响

针对应用于高温工作环境的金属橡胶的热稳定性问题,结合其冷态成型工艺特征,提出通过去应力退火消除加工残余应力、稳定高温性能的金属橡胶热处理工艺,并以高温合金GH4169制备的金属橡胶为例,通过试验对比研究了热处理工艺对其力学性能的影响.结果表明,去应力退火工艺使金属橡胶构件的刚度提高1.5倍以上,但是对损耗因子几乎没有影响.经过退火处理的金属橡胶构件在高温工作环境下具有稳定的刚度和阻尼性能,并且刚度和阻尼的变化规律受安装约束条件影响.而未经热处理的金属橡胶构件在高温工作条件下将偏离几何尺寸及力学性能的初始设计值.因此,应用于高温环境的金属橡胶阻尼构件为了满足初始设计的力学性能并保持稳定,有必要进行合理的热处理.     

论航天器的热试验

论述了各种类型热试验 （热平衡试验、热真空试验、热循环试验） 在航天器研制中的重要性及它们的做法要点。针对当前试验中出现的问题, 强调了组件级, 尤其是电子电工产品热试验 （热真空试验及热循环试验） 和整星级发射星热真空试验对提高航天器可靠性所起的重要作用, 并提出了相应的建议。     

微处理器中含噪热传感器位置分布优化方法

高性能处理器普遍集成热传感器,采用动态热管理技术对芯片实施连续热监控。然而,由于实际芯片中的模拟或者数字热传感器不可避免伴随噪声,使动态热管理的可靠性受到很大影响。因此,为了提高热监控的精确性,本文运用主成分分析（PCA）技术对原始热图像样本矩阵进行降维近似处理,并结合矩阵扰动分析提出基于模拟退火算法的热传感器位置分布优化方法。实验结果表明：该方法比现有的贪婪算法在热重构误差、信噪比（SNR）和误警率等性能方面有了一定提高,能够有效运用在动态热管理中实现精确的热监控。     

Complex organics in laboratory simulations of interstellar/cometary ices.

We present the photochemical and thermal evolution of both non-polar and polar ices representative of interstellar and pre-cometary grains. Ultraviolet photolysis of the non-polar ices comprised of O2, N2, and CO produces CO2, N2O, O3, CO3, HCO, H2CO, and possibly NO and NO2. When polar ice analogs (comprised of H2O, CH3OH, CO, and NH3) are exposed to UV radiation, simple molecules are formed including: H2, H2CO, CO2, CO, CH4, and HCO (the formyl radical). Warming produces moderately complex species such as CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), R-CN and/or R-NC (nitriles and/or isonitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. Infrared spectroscopy, 1H and 13C nuclear magnetic resonance (NMR) spectroscopy, and gas chromatography-mass spectrometry demonstrate that after warming to room temperature what remains is an organic residue composed primarily of hexamethylenetetramine (HMT, C6H12N4) and other complex organics including the amides above and polyoxymethylene (POM) and its derivatives. The formation of these organic species from simple starting mixtures under conditions germane to astrochemistry may have important implications for the organic chemistry of interstellar ice grains, comets and the origins of life.     

Cr对ZrO2/Ni热障涂层界面结合的影响

热障涂层广泛用于航空、航天领域,涂层与基体的界面结合强弱是决定涂层寿命的一个关键因素.为了提高其使用寿命,必须要求涂层与基体的界面有较好的结合.利用密度泛函理论框架下的第一性原理离散变分(DV)方法研究了ZrO₂Ni热障涂层界面的能量学和电子结构,讨论了替位型掺杂的Cr在ZrO₂Ni热障涂层界面中的作用.结果表明:Cr容易偏聚于界面处(偏聚能达6.03eV),Cr使得体系结合能增加,体系更稳定,有利于界面的结合;界面处原子电荷占据数和电荷密度计算表明:加入Cr后跨界面方向的电荷密度增加,同时也使得界面内电荷密度增加,这有利于跨界面方向的以及沿界面方向的成键,从而加强了涂层与基体材料的结合.     

Competition between links in "producer-consumer" trophic chains in an aquatic closed system with spatially separated components.

The work analyzes functioning of a "producer-consumer" closed aquatic system with spatially separated links, where each component consisted of two species. Producers in the system were the microalgae of Chlorella vulgaris and Scenedesmus sp., consumers--Paramecium caudatum infusoria and Brachionus sp. rotifers. In the experiment the competing predators were consuming on a mixed culture of algae, and the competition of algae was studied under nitrogen limitation. Under these conditions competitiveness of Scenedesmus was higher than that of Chlorella vulgaris. Metabolism products of Scenedesmus algae have been found to have negative effect on reproduction of Paramecium caudatum protozoa. Predator population dynamics in the "consumer" link demonstrated that the rotifers that consume two algal species are more competitive compared to protozoa feeding on chlorella only. Grant numbers: N99-04-96017, N25.     

喷涂粉末对Al-Cu-Fe准晶涂层组织结构的影响

准晶材料具有低热导率、低磨擦系数、良好的耐磨性和抗氧化性、高硬度、高温塑性等优异性能,使之适于作为表面防护涂层.为了提高钛合金的抗高温氧化性能和耐磨性能, 采用低压等离子喷涂方法LPPS (Low Pressure Plasma Spraying)在钛合金表面制备了Al-Cu-Fe准晶涂层.通过改变喷涂粉末的成分和粒度大小,研究了喷涂粉末对制备态涂层相结构及微观形貌的影响. 由X-射线衍射XRD(X-Ray Diffraction)、扫描电镜SEM(Scanning Electronic Microscope)分析得出:采用原子比为Al70Cu20Fe10、粒度为-325目的粉末制备的涂层,在800℃下真空退火处理2?h后,结构均匀致密,二十面体准晶相(I相)含量高,并只含有少量的β相.     

The atmosphere of the primitive earth and the prebiotic synthesis of organic compounds.

The prebiotic synthesis of organic compounds using a spark discharge on various simulated prebiotic atmospheres at 25 degrees has been studied. Methane mixtures contained H2 + CH4 + H2O + N2 + NH3 with H2/CH4 molar ratios from 0 to 4 and pNH3 = 0.1 torr. A similar set of experiments without added NH3 was performed. The yields of amino acids (1.2 to 4.7% based on the carbon) are approximately independent of the H2/CH4 ratio and the presence of added NH3, and a wide variety of amino acids are obtained. Mixtures of H2 + CO + H2O + N2 and H2 + CO2 + H2O + N2, with and without added NH3, all give about 2% yields of amino acids at H2/CO and H2/CO2 ratios of 2 to 4. For the H2/CO and H2/CO2 ratios less than 1, the yields fall off drastically to as low as 10(-3)%. Glycine is almost the only amino acid produced from CO and CO2 atmospheres. These results show that the maximum yield is about the same for the three carbon sources at high H2/carbon ratios, but that CH4 is superior at low H2/carbon ratios. In addition, CH4 gives a much greater variety of amino acids than either CO or CO2. If it is assumed that amino acids more complex than glycine were required for the origin of life, then these results indicate the need for CH4 in the primitive atmosphere. The yields of cyanide and formaldehyde parallel the amino acid results, with yields of HCN and H2CO as high as 13% based on the carbon. Ammonia is also produced from N2 in experiments with no added NH3 in yields as high as 4.9%. These results show that large amounts of NH3 would have been synthesized on the primitive earth by electric discharges. The amount of ammonia formed by hydrolysis of HCN and various nitriles may have exceeded that formed directly in electric discharges.     

反演航天器在轨瞬态外热流的导热反问题

获得航天器在轨飞行过程中的外热流数据对于研究热控涂层在轨退化规律、各种空间因素对热控产品的影响以及航天器姿轨控发动机羽流热效应都有非常重要的意义,然而直接测量热流存在很多困难,因此可以通过求解导热反问题得到满足一定精度的结果.首先,通过研究利用航天器设备在轨遥测温度值反演出航天器在轨瞬态外热流的导热反问题方法,建立了反演航天器在轨瞬态外热流的数学模型,采用共轭梯度法求解导热反问题并从物理概念角度改进了共轭梯度法的迭代过程以增加其抗不适定性;然后构造了两组能够代表目前大多数地球轨道航天器以及深空探测航天器在轨吸收外热流变化的数值试验对共轭梯度法的反演效果进行了检验.除阶跃变化位置以外反演值与真实值的最大相对偏差为2.9%,反演效果非常好;对于阶跃变化位置的吸收外热流在对反演结果进行分析处理后也能够得到较好的反演结果.      

太阳耀斑显著的热和非热事件的统计特征

本文利用GOES卫星和SMM卫星软、硬X射线耀斑观测资料,分析耀斑中软、硬X射线辐射流量的分布,发现太阳耀斑存在着显著的热事件(PT事件)和显著的非热事件(PNT事件),它们主要特征是:(1)PT事件为缓变型耀斑,PNT事件为脉冲型耀斑;(2)PT事件的硬X射线谱较软,PNT事件能谱较硬;(3)PNT事件非热能量释放速率比PT事件快3—10倍;(4)耀斑发展趋缓慢,PT事件中软X射线峰值流量越大;(5)耀斑中PNT事件约占60％,PT事件约占40％.最后定性讨论了产生PT和PNT事件的可能机制.      

Radiolysis of aqueous formaldehyde relevant to cometary environments.

The radiation chemistry of aqueous solutions of formaldehyde was studied in order to obtain an insight into the possible role of ionizing radiation on cometary environments. Aqueous solutions of 1.0 mol dm-3 formaldehyde were exposed to gamma-radiation in the dose range from 0.01 to 1200 kGy at 298 K. The radiation chemical yield of decomposition of formaldehyde was determined to be: G(-CH2(OH)2)-26.3 +/- 1.2. The high radiation chemical yield of decomposition was explained by a chain reaction initiated by the radical CH(OH)2 with formaldehyde. Computer fitting of the experimental data gives k(CH(OH)2 + CH2(OH)2)- 8.0xl0(1) dm3 mol-1 s-1. In the computer treatment of experimental findings we used 54 equations to consider the radiolysis of water and 11 reactions for the radiolysis of aqueous formaldehyde. Based on previous estimates of the total dose of ionizing radiation that comets have accumulated over 4.6 billion years, we predict a radiation damage-depth curve of formaldehyde in comet nuclei.     

气氦制冷系统的研制

气氦制冷系统是为内装式深冷泵提供冷源的一套系统。它是采用带液氮预冷的布雷顿闭式循环系统。设计了先进的氦气螺杆压缩机及先进的氦气透平膨胀机，同时还设计了独特的可拆式的多功能集成的冷箱系统及具有独特结构形式的内纯化系统，自动化程度高，该系统研制成功后，为“神舟一号”试验飞船，提供了做热真空试验的条件，同时还为今后需要20K冷背景的各种航天器的特殊试验提供了保障条件。     

真空与磁场热处理改善FeCo合金的软磁性能

针对发电机中转子用FeCo合金(国产牌号1J22)进行了组织结构与磁性能的研究.通过对该合金进行真空处理以及磁场热处理,研究了组织结构对软磁性能的影响规律;研究了附加磁场强度以及热处理温度对磁场处理效果的影响,并结合该合金的磁致伸缩伸缩系数的变化规律,分析了磁场热处理效果的微观机制.当合金组织为轧制态时,磁场热处理效果不明显;在合金的再结晶温度以上进行磁场热处理时,获得了显著的磁场热处理效果,矫顽力下降至72A/m(0~9Oe)以下.     

Organic solids produced from simple C/H/O/N ices by charged particles: applications to the outer solar system.

CH4, CO, and CO2 are all potential one-carbon molecular repositories in primitive icy objects. These molecules are all found in the Comet Halley coma, and are probable but, (except for CH4 detected on Triton and Pluto) undetected subsurface constituents in icy outer solar system objects. We have investigated the effects of charged particle irradiation by cold plasma discharge upon surfaces of H2O:CH4 clathrate having a 200:1 ratio, as well as upon ices composed of H2O plus C2H6 or C2H2 (sometimes plus NH3) which are also plausible constituents. These materials color and darken noticeably after a dose 10(9) - 10(10) erg cm-2, which is deposited rapidly (< or = 10(4) yr.) in solar system environments. The chromophore is a yellowish to tan organic material (a tholin) which we have studied by UV-VIS reflection and transmission, and IR transmission spectroscopy. Its yield, -1 C keV-1, implies substantial production of organic solids by the action of cosmic rays and radionuclides in cometary crusts and interiors, as well as rapid production in satellite surfaces. This material shows alkane bands which Chyba and Sagan have shown to well match the Halley infrared emission spectrum near 3.4 microns, and also bands due to aldehyde, alcohol and perhaps alkene/aromatic functional groups. We compare the IR spectral properties of these tholins with the spectra of others produced by irradiation of gases and ices containing simple hydrocarbons.     

可重复使用火箭发动机再生冷却槽失效分析

完成了可重复使用液体火箭发动机推力室再生冷却槽热力循环载荷下的蠕变非弹性热结构分析,对比研究了各向同性硬化和随动硬化定律对冷却槽结构分析的影响,并在多循环结构场基础上分析了冷却槽"狗窝"失效过程.结果表明可以通过选取热传导率差别小的内外壁材料、优化几何结构改善温度场及结构场;各向同性和随动硬化结构曲线变化趋势相似,但塑性应变有较大差别,残余应变相差约0.06%;多循环加载中每个循环的结构曲线形状相似并不断右移,硬化效应明显,低周疲劳损伤和蠕变损伤分别取决于循环载荷下的应变和应力值.     

A quantitative assay of biologically important compounds in simulated primitive Earth experiments.

A CH4-N2-H2OV gas mixture was subjected to a high voltage (20 kV), high frequency (0.3 MHz) electric discharge. The energy input in the electric discharge was varied from 0.016 to 3.048 MJ mol-1. The chemical yields (G), expressed as the number of molecules formed or destroyed per 100 eV of energy input were calculated for several products. The G values calculated at the lowest energy input were (-CH4) = 6.48; (-N2) = 2.51; (C2H2) = 1.16; (HCN) = 0.215; (CH3CHO) = 0.115; (CH3CH2CHO) = 0.00161; (CH3(CH2)2CHO) = 0.0165; ((CH2CO2H)2) = 0.0000339; (CH4 --> Solid material) = 0.196; (N2 --> Solid material) = 0.00355. This is the first report in prebiotic studies in which the G values of various products in electric discharge experiments are determined. This type of study is needed in order to get a better insight into the relative role of electric discharges on the primitive Earth.     

解JobShop问题的一种组合模拟算法

针对成批车间的作业排序(Job Shop Scheduling )问题设计了一种模拟退火与Tabu Search相组合的算法.首先用模拟退火算法求得一个初始解,再利用Tabu Search进行进一步的寻优.通过大量的算例分析表明,该算法具有良好的寻优特性与运算效率.