The limb infrared monitor of the stratosphere (LIMS) experiment: Temperature and nitrogen dioxide results

The Limb Infrared Monitor of the Stratosphere (LIMS) is a 6 channel scanning radiometer which measures the infrared emission by the earth's limb. These measurements are inverted to yield distributions of temperature, ozone, water vapor, nitric acid and nitrogen dioxide. The instrumentation and its orbital performance are briefly described. Retrievals of temperature and nitrogen dioxide are presented, with a discussion of their precision. Comparisons to in-situ rocket and balloon measurements are used to assess their accuracy. Special mention is made of the temperature data supplied for the FGGE II-b data sets. Results for ozone, water vapor and nitric acid are presented in companion papers.     

Changes in surface UV solar irradiance and ozone over the balkans during the eclipse of August 11, 1999

Intensive measurements of UV solar irradiance, total ozone and surface ozone were carried out during the solar eclipse of 11 August 1999 at Thessaloniki, Greece and Stara Zagora, Bulgaria, located very close to the footprint of the moon's shadow during the solar eclipse with the maximum coverage of the solar disk reaching about 90% and 96% respectively. It is shown that during the eclipse the diffuse component is reduced less compared to the decline of the direct solar irradiance at the shorter wavelengths. A 20-minute oscillation of erythemal UV-B solar irradiance was observed before and after the time of the eclipse maximum under clear skies, indicating a possible 20-minute fluctuation in total ozone presumably caused by the eclipse induced gravity waves. The surface ozone measurements at Thessaloniki display a decrease of around 10–15 ppbv during the solar eclipse. Similarly, ozone profile measurements with a lidar system indicate a decrease of ozone up to 2 km during the solar eclipse. The eclipse offered the opportunity to test our understanding of tropospheric ozone chemistry. The use of a chemical box model suggested that photochemistry can account for a significant portion of the observed surface ozone decrease.     

Towards validation of SCIAMACHY lunar occultation NO2 vertical profiles

Vertical profiles of stratospheric nitrogen dioxide (NO₂) have been retrieved from moderate resolution lunar occultation transmission spectra measured by Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) on board the European Environmental Satellite (ENVISAT). These measurements were taken over the high southern latitude of 50°–90° during the period of 2003–2005. To assess the accuracy of the retrieved NO₂ profiles, the SCIAMACHY nighttime NO₂ profiles were compared with NO₂ profiles retrieved from sunrise solar occultation spectra measured by the Halogen Occultation Experiment (HALOE) and the Stratospheric Aerosol and Gas Experiments II (SAGE II) using a photochemical correction model. The validation results show good agreement of SCIAMACHY lunar occultation NO₂ with scaled HALOE and SAGE II profiles. The relative mean differences (rmd) with scaled HALOE profiles are within −13% to +5% and standard deviations (rms) of the relative differences are within 3–19% between 25 and 38 km. The rmd and rms with scaled SAGE II NO₂ profiles are in the range of −9 to +7 and 10–17% respectively between 22 and 39 km.     

Vega project — Three channel spectrophotometer for the Halley''s comet investigation

A spectrometer for the Halley's Comet Investigation after the VEGA Project is described in the present work. It consists of a telescope and three spectral channels: UV (120 – 290 nm), resolution Δ λ / λ = 170; VIS (280 – 710 nm), resolution Δ λ / λ = 170; IR (950 – 1900 nm), resolution Δ λ / λ = 70.

With the help of two-coordinate scanner, the secondary mirror of the telescope allows spatial scanning of the Comet with a frame 2°×1,5° with 105 different pixels.     

Comparison of OClO nadir measurements from SCIAMACHY and GOME

The scanning imaging absorption spectrometer for atmospheric chartography was launched successfully onboard ENVISAT on March 1, 2002. It observes the solar radiation transmitted and backscattered from the atmosphere and reflected from the ground in nadir, limb and occultation viewing modes. Chlorine dioxide (OClO), an important indicator for stratospheric chlorine activation, can be measured in the UV spectral range by differential optical absorption spectroscopy (DOAS).

First results of the DOAS retrieval of OClO slant column densities from the SCIAMACHY nadir measurements are presented and compared to measurements of the global ozone monitoring experiment (GOME), which has successfully measured OClO since 1995. While SCIAMACHY operates in the same orbit, it measures ≈30 min earlier than GOME and has an increased spatial resolution (30 × 60 km² compared to 40 × 320 km² for GOME).     

A study of the solar cycle signal on total ozone over low-latitude Brazilian observation stations

Observations of total ozone at low latitudes in Brazil have been made using Dobson spectrophotometers since 1974 for Cachoeira Paulista (23.1° S, 45° W) and since 1978 for Natal (5.8° S, 35.2° W). Annual averages, 12 months and 36 months running averages have been analyzed. Spectral analyses of the data revealed that the most important periods found (confidence level> 90%) were: for Natal, 2.5 years (93.1%, quasi-biennial oscillation-QBO) and 10 years (98,2%, possibly the solar cycle signal); for Cachoeira Paulista, 2.4 years (96.8%, QBO) and 8 years (99.6%). The difference in total ozone between maximum and minimum solar cycles were estimated, using yearly averages of total ozone. For solar cycle 21, 1.16% and 1.26% for Natal and Cachoeira Paulista were found; for solar cycle 22, a larger difference of 3.8% for Natal and 4.1% for Cachoeira Paulista were found. The corresponding variation in UV-B at 300 nm, using Beer's law, is 8–10% for C. Paulista and 4–5% for Natal, with maxima occurring during the minimum of the solar cycle.     

Mesospheric nitric oxide and ozone measurements in polar winter at 69°N

Two rocket experiments were carried out just before and after the polar night at Andoya (69°N), Norway to investigate transport of nitric oxide produced by auroral processes into the middle atmosphere and its influence on the ozone chemistry. Nitric oxide densities of (2–5) × 10⁸cm⁻³ found in the 70–90 km region are one to two orders of magnitude larger than those at middle latitudes. The influence on ozone densities in the 70–90 km region due to such enhanced nitric oxide abundance is found to be insignificant as compared to that due to transport in the middle of February. The larger ozone densities found in February (in spite of longer sunlit duration) than in November in the 40–60 km region again support predominance of transport over photochemical loss.     

Air depression over south pole during Antarctic spring and its possible influence on ozone content in this region

Air depression during Antarctic spring, its long-term behaviour and connection with ozone content has been investigated on base of rocket data for polar regions and total ozone data sets for South pole (TOMS data) for 1979–1990. It was shown, that air pressure depression near South polar region in September in the lower stratosphere has a visible (about 5% per decade) negative trend similar to the tendency which total ozone records reveal. Rather high correlation (+0.82) between air pressure in the stratosphere and total ozone content for spring in Antarctica was found.     

Validation of SAGE II data inversions by the European correlative experiments

An European program of correlative experiments has been organized in order to validate SAGE II data during three periods of observation over Europe (November 1984, April 1985, October 1985). About ten groups from France, Belgium, Germany and Italy were participating. The correlative data are lidar aerosol profiles, soundings of ozone profiles, and balloon observations, including limb photographies, polarimetric measurements of the aerosol scattered light and nitrogen dioxide extinction measurements. Results of the comparisons between SAGE II inverted data and correlative data are presented. The analysis of the aerosol correlative observations with the SAGE II four aerosol channel data, in term of profile and size distribution is perfectly consistent and provide a good indirect validatioin. The NO₂ comparison shows a good agreement between SAGE II and correlative data.     

Solar UV irradiance variation during cycles 22 and 23

The Solar Ultraviolet Spectral Irradiance Monitor (SUSIM) aboard the Upper Atmosphere Research Satellite (UARS) has been measuring solar UV irradiances since October 1991, a period which includes the decline of solar cycle 22 followed by the rise of cycle 23. Daily solar measurements include scans over the wavelength range 115–410 nm at 1.1 nm resolution. As expected, the measured time series of UV irradiances exhibit strong periodicities in solar cycle and solar rotation. For all wavelengths, the UV irradiance time series are similar to that of the Mg II core-to-wing ratio. During solar cycle 22, the irradiance of the strong Ly- line varied by more than a factor of two. The peak-to-peak irradiance variation declined with increasing wavelength, reaching 10% just below the Al edge at 208 nm. Between the Al edge and 250 nm the variation was 6–7%. Above 250 nm, the variation declines further until none is observed above 290 nm. Preliminary results for the first portion of cycle 23 indicate that the far UV below the Al edge is rising at about the same rate as the Mg II index while the irradiances in the Ly- emission line and for wavelengths longer than the Al edge are rising more slowly — even after accounting for the lower level of activity of cycle 23.     

Variability in the solar constant from irradiances shortward of Lyman-Alpha

The variation in the solar constant, S(t), is reproduced by the SOLAR2000 Research Grade v1.05 empirical solar irradiance model and is described for 5 solar cycles between cycles 18 and 23 (February 14, 1947 through May 31, 2000). This solar constant variation is dependent upon the derivation data sets and the formulation of SOLAR2000 which are described in more detail. The S(t) temporal variability in SOLAR2000 is shown for the solar spectrum between 1–122 nm. The variability is consistent with previous discussions in the literature and a new result is shown where the 1–122 nm wavelength range accounts for about 5–14% of the standard deviation reported in the ASTM E-490 standard. The minimum-maximum range of S(t) variation due to 1–122 nm variability is between 1367.2768 Wm⁻² on 1986-152 and 1367.2877 Wm⁻² on 1957-340. The mean S(t) in these data is 1367.2796 Wm⁻².     

Stratospheric ozone loss, ulraviolet effects and action spectroscopy

The major effect of stratospheric ozone loss will be an increase in the amount of ultraviolet radiation reaching the ground. This increase will be entirely contained within the UV-B (290–320nm). How this will impact life on Earth will be determined by the UV-B photobiology of exposed organisms, including humans. One of the analytical methods useful in estimating these effects is Action Spectroscopy (biological effect as a function of wavelength). Carefully constructed action spectra will allow us to partially predict the increase in bio-effect due to additional UV exposure. What effect this has on the organism and the system in which the organism resides is of paramount importance. Suitable action spectra already exist for human skin cancer, human cell mutation and killing, and for one immune response. Comprehensive and widely applicable action spectra for terrestrial and aquatic plant responses are being generated but are not yet suitable for extensive analysis. There is little data available for animals, other than those experiments completed in the laboratory as model systems for human studies. Some polychromatic action spectra have proven useful in determining the possible impact of ozone loss on biological systems. The pitfalls and limits of this approach will be addressed.     

Quasi-biennial oscillation (QBO) of tropical total ozone under alternative QBO scenarios of equatorial stratospheric wind

Equatorial total column ozone variations with quasi-biennial periodicity are described by paying attention to their coupling with the quasi-biennial oscillation (QBO) of zonal wind in equatorial stratosphere. Analysis is made for the 35-year time interval from 1978 to 2013 using the zonal mean total ozone (TOZ) data in latitude band from 5° S to 5° N derived from satellite measurements by means of Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI). The study was performed using strong seasonal regularities of the wind QBO and the discrete variation of the QBO-period revealed earlier. The forecast of the wind QBO evolution made in Gabis (2012) is fully justified. The comparison between predicted and actually observed changes of the height wind structure shows the prominent accordance, which confirms the forecast validity. It is shown that variations of deseasonalized TOZ are in strong coupling with changes of equatorial wind QBO that coincides with the numerous previous researches. However our results contradict the assumption about quite complicated ozone response in the equatorial region due to continuously varying with time relationship between annual and quasi-biennial cycles and irregularly variable wind QBO-period. The total ozone changes actually observed clearly corresponds to the mean ozone variations calculated for different QBO scenarios and aligned according to the sequence of QBO scenarios already occurred in fact. This close association indicates the possibility of forecasting the equatorial total ozone QBO based on the predicted wind QBO.     

Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model,and model calculations

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago (Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O₃ and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.     

Numerical simulations of the radiance from the comet 46P/Wirtanen in the various configurations of the measurements during “Rosetta” mission

The work we present deals with the spectrometric measurements of VIRTIS instrument of the Comet P/Wirtanen planned for the Rosetta mission. This spectrometer can monitor (VIRTIS M channel: 0.250μm – 0.980μm; Δκ=20cm⁻¹; 0.980 – 5.0 μm; Δκ = 5cm⁻¹; VIRTIS H channel: 2.0 μm – 5.0 μm; Δκ=2cm⁻¹) the nucleus and the coma in order to provide a general picture of coma's composition, the production of gas and dust, the relationship of coma production to surface composition and the structure and variation of mineralogy of the nucleus surface. During the mission the observation conditions of the spectroscopic investigation change due to different relative positions spacecraft/comet, and to the different illumination conditions of the surface at various distances of the comet to the Sun. The nucleus surface is continuously modified by the ice sublimation accompanied by gas and dust emission. Consequently the surface also its spectrophotometric properties changes and their monitoring can give a new insight. The important role of simulations is to predict the results of measurements in various experimental condition what, in the future, can help in interpretation of the measured data.

In this paper the first results of our simulation the radiance from the comet in the 0.25–5.0μm spectral range at two distances from the Sun (1AU and 3AU) are shown. The distance between the Rosetta orbiter and the nucleus surface as well as the sun zenith angles are taken into account according to the Rosetta mission phases. In fact the surface and coma properties vary along the comet orbit, and should be taken into account in our calculations. The optical parameters of the dust on the surface (e.g. reflectance) and in the coma (e.g. Q_ext) were calculated from optical constants of possible comet analogues. The thermodynamic parameters of the comet are taken from the models of comet evolution. Through this kind of modelling it is possible to identify the surface characteristics in spectra of the radiation from the surface of nucleus transmitted through the coma loaded with dust and gases.

Even if the “Rosetta mission” is postponed, with the consequence of a target change, we think that our idea and the method used for the simulations can be useful also for the new Rosetta target - the comet 67P/Churyumov Gerasimenko.     

First estimations of the aerosol optical thickness using Langley Method at Southern Brazil (29.4°S, 53.8°W)

The first estimations of the aerosol optical thickness (AOT) using Langley Method at Southern Space Observatory (SSO) at Southern Brazil (29.4°S, 53.8°W) are presented. In addition to ozone and sulphur dioxide columns, AOT can be obtained using Brewer Spectrophotometer at specific wavelengths: 306.3, 310.1, 313.5, 316.8 and 320.1 nm. The AOT was obtained for the period from November/2002 to May/2003. Very low AOT averages were obtained, whose values were about 0.21 ± 0.03 at 306.3 nm, 0.21 ± 0.02 at 310.1 nm, 0.19 ± 0.02 at 313.5 nm, 0.20 ± 0.02 at 316.8 nm and 0.20 ± 0.02 at 320.0 nm for all period analysed. Different behaviour of AOT were obtained at two daily specific periods of aerosol accumulation, one in the afternoons from November/2002 to February/2003, caused mainly by a mild biomass burning season’s in the region and other in the mornings from March to May/2003, due the high relative humidity presented in the region studied.     

Solar radiation variability in the last 1400 years recorded in the carbon isotope ratio of a mediterranean sea core

We present measurements and data analysis of the carbon stable isotopes (δ¹³C) in the planktonic Globigerinoides ruber extracted from the GT90/3 shallow water Ionian sea core, dated with high precision. It is commonly accepted that δ¹³C variations in symbiontic foraminifera mainly record the effects of productivity and of photosynthetic activity, varying with the ambient light level. Therefore from this time series we can deduce information on the sea surface illumination at the time of the planktonic foraminifera growth. The profile (359 points) covers the period 590–1979 AD, with a resolution of 3.87 years and it is an extension of the time series (215 points) previously published in this journal. The spectral analysis of the longer time series confirms the presence of the 11 y signal, with amplitude 0.08‰ (peak-to-trough), found in the shorter time series in phase with the sunspot solar cycle; furthermore it shows the presence of two centennial cycles of 100 and 200 years, with amplitude 0.08‰ and 0.02‰ respectively. These components are identified at high significance level by Monte Carlo singular spectrum analysis (MC-SSA). A comparison between the δ¹³C profile and the historical aurorae series (600–1500 AD) shows that the long-term δ¹³C variations are at least partially generated by the solar activity modulation and in phase with the solar output, as represented by the solar wind interaction with the magnetosphere.     

MEMORIS: a wide angle camera for the BepiColombo mission

MEMORIS (MErcury Moderate Resolution Imaging System) is a wide angle camera (WAC) concept for the ESA mission BepiColombo. The main scientific objectives consist of observing the whole surface of Mercury in the spectral range of 400–1000 nm, with a spatial resolution of 50 m per pixel at peri-Herm (400 km) and 190 m at apo-Herm (1500 km). It will obtain a map of Mercury in stereo mode allowing the determination of a digital elevation model with a panchromatic filter through two different channels. The camera will also perform multispectral imaging of the surface with a set of 8–12 different broad band filters. A third channel dedicated to limb observations will provide images of the atmosphere. MEMORIS will thus monitor the surface and the atmosphere during the entire mission, providing a unique opportunity to study the relationship between surface regions and the atmosphere, as suggested by ground-based observations and theory.     

The potential for radiometric retrievals of halocarbon concentrations from the MIPAS-E instrument

Halocarbons, such as CFC-11, CFC-12 and HCFC-22, are important trace gases in the atmosphere through their role as greenhouse gases and their influence on stratospheric ozone chemistry. This paper focuses on an initial study using integration of spectral radiance measurements from a spaceborne limb sounding Fourier Transform Spectrometer (FTS) to retrieve these compounds in the upper troposphere and lower stratosphere (UTLS). The instrument employed in this study is the Michelson Interferometer for Passive Atmospheric Sounding onboard ENVISAT (MIPAS-E) which obtains spectral data in the altitude range of 6–68 km at an unapodized spectral resolution of 0.025 cm⁻¹. We have used optimal estimation techniques to retrieve vertical information for these compounds using a radiometric approach.

It is shown that significant retrieval information is obtained at up to five measured levels in the UTLS for CFC-11, up to six for CFC-12 and up to two levels for HCFC-22. An initial error analysis indicates significant sensitivity of our retrievals to variability in operationally retrieved pressure and temperature data. For each halocarbon, gain, offset and spectroscopic uncertainties generally each contribute less than 10% to the total error. Finally, tracer correlations are used to compare the datasets to equivalent relationships derived here from version 2 ATMOS data with very good agreements for CFC-12 but with more variability in the CFC-11 comparisons.