The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.     

Standard Solar Composition

We review the current status of our knowledge of the chemical composition of the Sun, essentially derived from the analysis of the solar photospheric spectrum. The comparison of solar and meteoritic abundances confirms that there is a very good agreement between the two sets of abundances. They are used to construct a Standard Abundance Distribution. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Local Interstellar Medium: Peculiar or Not?

The local Interstellar Medium (ISM) at the 500 pc scale is by many respects a typical place in our Galaxy made of hot and tenuous gas cavities blown by stellar winds and supernovae, that includes the 100 pc wide “Local Hot Bubble (LHB)”, dense and cold clouds forming the cavity “walls”, and finally diffuse and warm clouds embedded within the hot gas, such as the Local Interstellar Cloud (LIC) presently surrounding the Sun. A number of measurements however, including abundance data, have contradicted this “normality” of our interstellar environment. Some contradictions have been explained, some not. I review recent observations at different spatial scales and discuss those peculiarities. At all scales Johannes Geiss has played a major role. At the scale of the first hundred parsecs, there are at least three “anomalies”: (i) the peculiar Gould Belt (GB), (ii) the recently measured peculiar Deuterium abundance pattern, (iii) the low value of the local O, N and ³He gas phase abundances. I discuss here the possibility of a historical link between these three observations: the large scale phenomenon which has generated the Belt, a giant cloud impact or an explosive event could be the common origin. At the 50–100 parsec scale, some of the unexplained or contradictory measurements of the Local Bubble hot gas, including its EUV/soft X ray emissions, ion column-densities and gas pressure may at least partially be elucidated in the light of the newly discovered X-ray emission mechanism following charge transfer between solar wind high ions and solar system neutrals. The Local Bubble hot gas pressure and temperature may be lower than previously inferred. Finally, at the smaller scale of the local diffuse cloudlets (a few parsecs), the knowledge of their structures and physical states has constantly progressed by means of nearby star absorption spectroscopy. On the other hand, thanks to anomalous cosmic rays and pickup ions measurements, local abundances of ISM neutral species are now precisely derived and may be compared with the absorption data. Interestingly these comparisons are now accurate enough to reveal other (noninterstellar) sources of pickup ions. However the actual physical state of the ISM 10–20,000 A.U. ahead along the Sun trajectory, which will be the ambient interstellar medium in a few thousands years, remains unknown. Local Bubble hot gas or warm LIC-type gas? More EUV/UV spectroscopic data are needed to answer this question.     

Composition and Opacity in the Solar Interior

Detailed abundances of elements from hydrogen up to iron are necessary to perform a precise model of the solar structure. Most of them have been deduced from photospheric observed values, some others from the meteoritic composition. Nowadays, thanks to helioseismic constraints, they seem more and more under control. This revised version was published online in June 2006 with corrections to the Cover Date.     

Determination of Sulfur Abundance in the Solar Wind

Solar chemical abundances are determined by comparing solar photospheric spectra with synthetic ones obtained for different sets of abundances and physical conditions. Although such inferred results are reliable, they are model dependent. Therefore, one compares them with the values for the local interstellar medium (LISM). The argument is that they must be similar, but even for LISM abundance determinations models play a fundamental role (i.e., temperature fluctuations, clumpiness, photon leaks). There are still two possible comparisons—one with the meteoritic values and the second with solar wind abundances. In this work we derive a first estimation of the solar wind element ratios of sulfur relative to calcium and magnesium, two neighboring low-FIP elements, using 10 years of CELIAS/MTOF data. We compare the sulfur abundance with the abundance determined from spectroscopic observations and from solar energetic particles. Sulfur is a moderately volatile element, hence, meteoritic sulfur may be depleted relative to non-volatile elements, if compared to its original solar system value.     

An Update on Ultra-Heavy Elements in Solar Energetic Particles above 10 MeV/Nucleon

Measurements below several MeV/nucleon from Wind/LEMT and ACE/ULEIS show that elements heavier than Zn (Z=30) can be enhanced by factors of ∼100 to 1000, depending on species, in ³He-rich solar energetic particle (SEP) events. Using the Solar Isotope Spectrometer (SIS) on ACE we find that even large SEP (LSEP) shock-accelerated events at energies from ∼10 to >100 MeV/nucleon are often very iron rich and might contain admixtures of flare seed material. Studies of ultra-heavy (UH) SEPs (with Z>30) above 10 MeV/nucleon can be used to test models of acceleration and abundance enhancements in both LSEP and ³He-rich events. We find that the long-term average composition for elements from Z=30 to 40 is similar to standard solar system values, but there is considerable event-to-event variability. Although most of the UH fluence arrives during LSEP events, UH abundances are relatively more enhanced in ³He-rich events, with the (34<Z<40)/O ratio on average more than 50 times higher in ³He-rich events than in LSEP events. At energies >10 MeV/nucleon, the most extreme event in terms of UH composition detected so far took place on 23 July 2004 and had a (34<Z<40)/O enhancement of ∼250–300 times the standard solar value.     

The composition of heavy ions in solar energetic particle events

We review recent advances in determining the elemental, charge-state, and isotopic composition of 1 to 20 MeV per nucleon ions in solar energetic particle (SEP) events and outline our current understanding of the nature of solar and interplanetary processes which may explain the observations.The composition within individual SEP events may vary both with time and energy, and will in general be different from that in other SEP events. Average values of relative abundances measured in a large number of SEP events, however, are found to be roughly energy independent in the 1 to 20 MeV per nucleon range, and show a systematic deviation from photospheric abundances which seems to be organized in terms of the first ionization potential of the ion.Direct measurements of the charge states of SEPs have revealed the surprisingly common presence of energetic He⁺ along with heavy ions with typically coronal ionization states. High-resolution measurements of isotopic abundance ratios in a small number of SEP events show these to be consistent with the universal composition except for the puzzling overabundance of the SEP ²²Ne/²⁰Ne relative to this isotopes ratio in the solar wind. The broad spectrum of observed elemental abundance variations, which in their extreme result in composition anomalies characteristic of ³He-rich, heavy-ion rich and carbon-poor SEP events, along with direct measurements of the ionization states of SEPs provide essential information on the physical characteristics of, and conditions in the source regions, as well as important constraints to possible models for SEP production.It is concluded that SEP acceleration is a two-step process, beginning with plasma-wave heating of the ambient plasma in the lower corona, which may include pockets of cold material, and followed by acceleration to the observed energies by either flare-generated coronal shocks or Fermi-type processes in the corona. Interplanetary propagation as well as acceleration by interplanetary propagating shock will often further modify the composition of SEP events, especially at lower energies.     

Confronting Observations and Modeling: The Role of the Interstellar Magnetic Field in Voyager 1 and 2 Asymmetries

Magnetic effects are ubiquitous and known to be crucial in space physics and astrophysical media. We have now the opportunity to probe these effects in the outer heliosphere with the two spacecraft Voyager 1 and 2. Voyager 1 crossed, in December 2004, the termination shock and is now in the heliosheath. On August 30, 2007 Voyager 2 crossed the termination shock, providing us for the first time in-situ measurements of the subsonic solar wind in the heliosheath. With the recent in-situ data from Voyager 1 and 2 the numerical models are forced to confront their models with observational data. Our recent results indicate that magnetic effects, in particular the interstellar magnetic field, are very important in the interaction between the solar system and the interstellar medium. We summarize here our recent work that shows that the interstellar magnetic field affects the symmetry of the heliosphere that can be detected by different measurements. We combined radio emission and energetic particle streaming measurements from Voyager 1 and 2 with extensive state-of-the art 3D MHD modeling, to constrain the direction of the local interstellar magnetic field. The orientation derived is a plane ～60°–90° from the galactic plane. This indicates that the field orientation differs from that of a larger scale interstellar magnetic field, thought to parallel the galactic plane. Although it may take 7–12 years for Voyager 2 to leave the heliosheath and enter the pristine interstellar medium, the subsonic flows are immediately sensitive to the shape of the heliopause. The flows measured by Voyager 2 in the heliosheath indicate that the heliopause is being distorted by local interstellar magnetic field with the same orientation as derived previously. As a result of the interstellar magnetic field the solar system is asymmetric being pushed in the southern direction. The presence of hydrogen atoms tend to symmetrize the solutions. We show that with a strong interstellar magnetic field with our most current model that includes hydrogen atoms, the asymmetries are recovered. It remains a challenge for future works with a more complete model, to explain all the observed asymmetries by V1 and V2. We comment on these results and implications of other factors not included in our present model.     

Solar Wind Conditions and Composition During the Genesis Mission as Measured by in situ Spacecraft

We describe the Genesis mission solar-wind sample collection period and the solar wind conditions at the L1 point during this 2.3-year period. In order to relate the solar wind samples to solar composition, the conditions under which the samples were collected must be understood in the context of the long-term solar wind. We find that the state of the solar wind was typical of conditions over the past four solar cycles. However, Genesis spent a relatively large fraction of the time in coronal-hole flow as compared to what might have been expected for the declining phase of the solar cycle. Data from the Solar Wind Ion Composition Spectrometer (SWICS) on the Advanced Composition Explorer (ACE) are used to determine the effectiveness of the Genesis solar-wind regime selection algorithm. The data collected by SWICS confirm that the Genesis algorithm successfully separated and collected solar wind regimes having distinct solar origins, particularly in the case of the coronal hole sample. The SWICS data also demonstrate that the different regimes are elementally fractionated. When compared with Ulysses composition data from the previous solar cycle, we find a similar degree of fractionation between regimes as well as fractionation relative to the average photospheric composition. The Genesis solar wind samples are under long-term curation at NASA Johnson Space Center so that as sample analysis techniques evolve, pristine solar wind samples will be available to the scientific community in the decades to come. This article and a companion paper (Wiens et al. 2013, this issue) provide post-flight information necessary for the analysis of the Genesis array and foil solar wind samples and the Genesis solar wind ion concentrator samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

Elemental Abundances in the Solar Upper Atmosphere Derived by Spectroscopic Means

The composition of the solar photosphere is believed to be uniform. Indeed a quantity that does not vary with solar surface location or with a particular solar feature, i.e., no observational evidence is available to indicate that the photospheric composition near the solar equator is different from the photospheric composition near the solar poles or that the photospheric composition in quiet regions is different from the composition in active regions. In contrast, the composition of the solar upper atmosphere is not well defined. Solar composition work in recent decades has brought the recognition that there are systematic differences between the composition of the corona and the photosphere and revealed evidence for spatial and time variability in the composition of various coronal features. We review the spectroscopic techniques used and the progress that was made in recent years in deriving the plasma compositions of various solar upper atmosphere structures. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Seed Population for Energetic Particles Accelerated by CME-Driven Shocks

Understanding properties of solar energetic particle (SEP) events associated with coronal mass ejections has been identified as a key problem in solar-terrestrial physics. Although recent CME shock acceleration models are highly promising, detailed agreement between theoretical predictions and observations has remained elusive. Recent observations from ACE have shown substantial enrichments in the abundances of ³He and He⁺ ions which are extremely rare in the thermal solar wind plasma. Consequently, these ions act as tracers of their source material, i.e., ³He ions are flare suprathermals and He⁺ ions are interstellar pickup ions. The average heavy ion composition also exhibits unsystematic differences when compared with the solar wind values, but correlates significantly with the ambient suprathermal material abundances. Taken together these results provide compelling evidence that CME-driven shocks draw their source material from the ubiquitous but largely unexplored suprathermal tail rather than from the more abundant solar wind peak. However, the suprathermal energy regime has many more contributors and exhibits much larger variability than the solar wind, and as such needs to be investigated more thoroughly. Answers to fundamental new questions regarding the preferred injection of the suprathermal ions, the spatial and temporal dependence of the various sources, and the causes of their variability and their effects on the SEP properties are needed to improve agreement between the simulations and observations.     

Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.     

Composition of solar cosmic rays

Summary The general features of the solar particle composition now seem to be clear. The two most abundant components, protons and helium nuclei, have different velocity spectra, similar, but not exactly identical rigidity spectra, and varying relative abundances. The multiply charged nuclei, on the other hand, appear to have the same spectral shape and relative abundances each time measurements are made, at least in the region from 42 to 135 MeV/nucleon. Further, these relative abundances seem to reflect those of the solar atmosphere insofar as comparison can be made. Electrons are rare, but high energy electrons are not expected to be plentiful due to the probable high rate of energy loss caused by synchrotron radiation at the sun. Energetic neutrons were also not expected in large quantity and have not been observed. Finally, there is positive evidence that very small quantities of deuterons exist, probably in an amount which is about 10^-3 or less of the proton abundance.The experimental data indicate that the propagation phenomenon is not purely rigidity dependent. Although the propagation of solar particles is still not well understood, the development of theories which take into account both the general magnetic field and the inhomogeneities in the field seem to hold some promise of explaining the experimental results. The composition data have also established important restraints which any acceleration theory must satisfy, and thereby contributed greatly to the very difficult problem of determining the acceleration mechanism.The similarity of the relative abundance of the energetic solar particles and the nuclei in the sun's photosphere suggested the possibility of having a new means of estimating the solar neon and helium abundances. This very interesting possibility will have to be explored by further testing of the composition of future solar particle events. Finally, it was seen that the composition was a very strong argument against most stars being the principal source of high energy non-solar cosmic rays, and, therefore, special sources, such as supernovae or possibly quasistellar objects, should be considered as much more likely prospects for the origin of cosmic rays.The results which have been obtained thus far on the composition of solar cosmic rays have indicated that further research in this area of study should be very rewarding and of value to many fields of physics. Further data on the composition and relative, as well as absolute, energy spectra of the various components are needed throughout many events. More experiments also should be performed to determine the properties of the rare components, deuterons, tritons, He³ nuclei, electrons, neutrons, and the heavier nuclei. When these experiments are complete, the knowledge which is needed to aid in answering the solar and astrophysical problems discussed in this review should be at hand.     

Modeling the out-of-ecliptic interplanetary magnetic field in the declining phase of sunspot Cycle 22

We have developed a new model of the coronal and interplanetary magnetic field. The model includes the effects of large-scale horizontal electric currents flowing in the inner corona, of the warped heliospheric current sheet, and of heliospheric volume currents in the super-Alfvenic solar wind. The model determines the interplanetary magnetic field (IMF) strength as well as its polarity from measurements of the photospheric magnetic field. A detailed comparison between the observed and calculated in-ecliptic IMF Bx in Cycles 22, confirms the fitness of the optimal set of free parameters inferred using data in Cycle 21. We can predict the latitudinal gradient of Bx in the declining phase of Cycle 22 and the temporal variation of the amplitude of the radial component of the IMF at various latitudes. The calculated IMF polarity and Bx strength agree best with the in-ecliptic observations when the photospheric field (measured with a 5250Å magnetograph) is scaled up by a factor of two. Ulysses may provide the critical data to improve the model and check these inferences.     

Solar Gamma-Ray Spectroscopy

Interactions of ions accelerated in solar flares produce gamma-ray lines and continuum and neutrons. These emissions contain a rich set of observables that provides information about both the accelerated ions and the environment where the ions are transported and interact. Ion interactions with the various nuclei present in the ambient medium produce gamma-ray lines at unique energies. How abundance information is extracted from the measurements is discussed and results from analyses of a number of solar flares are presented. The analyses indicate that the composition of the ambient gas where the ions interact (typically at chromospheric densities) is different from that of the photosphere and more like the composition of the corona, exhibiting low-FIP elemental enhancements that may vary from flare to flare. Evidence for increased Ne/O and the photospheric ³He abundance is also discussed.     

Composition of Interstellar Neutrals and the Origin of Anomalous Cosmic Rays

Knowledge of the elemental composition of the interstellar gas is of fundamental importance for understanding galactic chemical evolution. In addition to spectroscopic determinations of certain element abundance ratios, measurements of the composition of interstellar pickup ions and Anomalous Cosmic Rays (ACRs) have provided the principal means to obtain this critical information. Recent advances in our understanding of particle acceleration processes in the heliosphere and measurements by the Voyagers of the energy spectra and composition of energetic particles in the heliosheath provide us with another means of determining the abundance of the neutral components of the local interstellar gas. Here we compare the composition at the termination shock of six elements obtained from measurements of (a) pickup ions at ～5 AU, (b) ACRs in the heliosphere at ～70 AU, and (c) energetic particles as well as (d) ACRs in the heliosheath at ～100 AU. We find consistency among these four sets of derived neutral abundances. The average interstellar neutral densities at the termination shock for H, N, O, Ne and Ar are found to be 0.055±0.021 cm^?3, (1.44±0.45)×10^?5 cm^?3, (6.46±1.89)×10^?5 cm^?3, (8.5±3.3)×10^?6 cm^?3, and (1.08±0.49)×10^?7 cm^?3, respectively, assuming the He density is 0.0148±0.002 cm^?3.     

Element Abundances and Isotope Ratios in the Giant Planets and Titan

This paper reviews our present knowledge about elemental and isotopic ratios in the Giant Planets and Titan. These parameters can provide key information about the formation and evolution of these objects. Element abundances, especially after the results of the Galileo Probe Mass Spectrometer in Jupiter, strongly support the formation model invoking an initial core formation (Mizuno, 1980; Pollack et al., 1996). They also suggest that solar composition icy planetesimals (SCIPs) brought the heavy elements to Jupiter. The Jupiter value of D/H appears to be representative of the protosolar value, while the D/H enrichment observed on Uranus and Neptune is consistent with the formation scenario of these planets. The ¹⁵N/¹⁴N measurement in Jupiter seems to be representative of its protosolar value. Future measurements are expected to come from the Cassini and Herschel space mission, as well as the ALMA submillimeter observatory. This revised version was published online in August 2006 with corrections to the Cover Date.