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1.
李松年 《推进技术》1992,13(4):83-84,56
通过储存五年多的乳液丁羧胶合成的推进剂与新生产的乳液丁羧胶用同一配方合成的推进剂在同等的环境条件下同时进行加速老化对比试验,结果是常温最大强度σ_m、最大强度时的延伸率ε_m、断裂延伸率ε_b和断裂功W_b的变化不同,并且在50℃加速老化的情况下,以同样规律随老化时间变化。  相似文献   

2.
丁羟推进剂新型偶联剂   总被引:2,自引:0,他引:2       下载免费PDF全文
吴文华 《推进技术》1990,11(2):59-61,80
阐述了丁羟推进剂高温偶联剂选择原则.评定了四类九种偶联剂,指出硼化合物具有提高高温力学性能的优异功能.尤其是硼酸酯化合物5527,能大幅度提高高温力学性能,是优异的丁羟推进剂新型偶联剂.  相似文献   

3.
宽使用温度范围的丁羟高燃速推进剂配方研究   总被引:1,自引:3,他引:1       下载免费PDF全文
鲁国林  尹瑞康  刘爚 《推进技术》2001,22(2):162-164
研究了细AP含量、增塑剂癸二酸二异辛酯(DOS)含量和键合剂LW1等因素对HTPB/IPDI高燃烧推进剂-55℃低温力学性能的影响,获得了一个使用范围广(-55℃-+70℃)、综合性能优良的丁羟高燃速推进剂配方。该推进剂除具有能量高、燃速高等特点外,还有优良的力学性能。70℃最大抗拉强度(σm)蒺、MPa,25℃,70℃最大伸长率(εm)大于45%,-55℃时的伸长率大于30%。  相似文献   

4.
贮存温度对丁羟推进剂老化性能影响的研究   总被引:3,自引:0,他引:3       下载免费PDF全文
贺南昌 《推进技术》1987,8(6):58-63,91
本文研究了贮存温度对丁羟推进剂老化性能的影响.实验是在空气中进行的,老化性能以推进剂强度、伸长率、硬度和失重%等参数为判据.实验结果表明:在同一贮存温度下,随着老化时间的延长,推进剂的强度增加,伸长率降低,硬度增加,失重%亦有所增长.提高贮存温度的影响是加速了这些性能的变化.根据伸长率的数据,表明在本文给定的贮存温度下,老化反应机理是相似的.本文还以Arr-henius图求得表观活化能为49.6kJ/mol,并进而用公式求得25℃下推进剂应变保留值(ε/ε_o)与贮存安全期的关系图.  相似文献   

5.
纳米碳酸盐对复合固体推进剂燃烧性能的影响   总被引:1,自引:0,他引:1       下载免费PDF全文
研究了纳米碳酸盐对丁羟三组元、丁羟四组元、低燃速NEPE推进剂燃烧性能的影响。结果表明:纳米碳酸盐使丁羟三组元推进剂在高压(10~18MPa)和低压(4~10MPa)段的压强指数降低到0.2以下,同时使燃速明显降低;使丁羟四组元推进剂在高压段(10~18MPa)的压强指数降低到0.26左右;使低燃速NEPE推进剂的的压强指数(4~9MPa)从0.77左右降至0.55以下。从研究结果可以看出,添加该纳米碳酸盐是降低复合推进剂压强指数行之有效的途径。  相似文献   

6.
复合固体推进剂的高能化   总被引:2,自引:1,他引:2       下载免费PDF全文
王文俊 《推进技术》1987,8(6):35-43,89
本文评述了国外固体推进剂近年来向高能化方向发展的三个主要动向:HTPB推进剂的高固体及硝胺化;丁羟之后的新品种——NEPE推进剂;Be、B、叠氮化物等高能组分的研究等.对我国固体推进剂的发展方向提出了建议.  相似文献   

7.
为了分析POM(共聚甲醛)降低无烟XLDB推进剂在1~5MPa内燃速的原因,分别测量和分析了含和不含POM的推进剂样品的PDSC(高压热分解)特征量,燃烧波及火焰结构的变化。通过实验发现POM在1~5MPa下使ΔH(推进剂的分解焓)减小265~214J/g;POM在1MPa,5MPa下使推进剂的燃面温度分别由481℃和628℃降至433℃和569℃;理论计算表明:POM在10MPa下使推进剂的爆热、燃温分别由4418.4J/g,3031K降至4397.4J/g,3015K。结果表明,POM对无烟XLDB推进剂的热分解及燃烧过程有明显的抑制作用,这一作用可能降低无烟XLDB推进剂在1~5MPa范围内的燃速。  相似文献   

8.
催化硝胺推进剂的高压热分解及燃烧性能   总被引:6,自引:0,他引:6       下载免费PDF全文
选择了一种典型硝胺推进剂,研究了加入不同的催化剂后燃烧性能的变化及样品高压DSC热分解行为。发现铅盐以及铜盐使硝胺推进剂在5MPa下的分解反应提前完成,热焓增加,碳黑的加入不产生该趋势,但三元复合催化剂加剧了此作用;三元复合催化剂使该硝胺推进剂在191.7℃到239.5℃的分解反应速度提高,这一区域放热的增加正是燃速提高的原因。参量ΔH与ΔT之比ΔH/ΔT与推进剂燃速之间有关联,ΔH/ΔT越大,燃  相似文献   

9.
苯乙烯对推进剂力学贮存性能的影响研究   总被引:1,自引:0,他引:1       下载免费PDF全文
唐汉祥 《推进技术》1988,9(3):50-54,75,76
本文用气液色谱法和25℃下单向拉伸,研究高固体含量HTPB推进剂在各种温度下的加速老化.结果表明:推进剂中残留苯乙烯含量与δm(δ表示应力)、εm的变化成对应关系;60℃下贮存外加4%苯乙烯的配方药块,三个月δm升高31.8%,εm下降18.5%;而无苯乙烯配方药块在同样条件下,八个月δm升高26.2%,εm基本不变.经研究找到了苯乙烯挥发是推进剂贮存前期力学性能变化的主要原因,取消苯乙烯的配方可显著改善推进剂的力学贮存性能;本文对苯乙烯在推进剂中的残留量、存在状态及作用机理也作了探讨.  相似文献   

10.
杜磊  肖金武  尹瑞康 《推进技术》2002,23(3):245-248
为了改善高燃速丁羟推进剂的低温力学性能,设计合成了AO系列 同助剂,并在丁羟高燃速实验配方中验让了它们的使用效能。结果表明AO助剂大幅度提高了高燃速实验配方的低温力学性能,在常温强度相当的条件下,-40℃下最大伸长率由40%左右提高到55%以上。实验结果也显示助剂与粘事剂的表面张力值越接近,工艺性能越好。文中还通过温反射红外光谱(DRIR)和动态热机械分析(DMA)对界面助剂的作用机理作了简要探讨。  相似文献   

11.
This paper discusses experimental results from two different build configurations of a heated multiple rotating cavity test rig.Measurements of heat transfer from the discs and tangential velocities are presented.The test rig is a 70% full scale version of a high pressure compressor stack of an axial gas turbine engine.Of particular interest are the internal cylindrical cavities formed by adjacent discs and the interaction of these with a central axial throughflow of cooling air.Tests were carried out for a range of non-dimensional parameters representative of high pressure compressor internal air system flows(Re up to 5×106 and Rez up to 2×105).Two different builds have been tested.The most significant difference between these two build configurations is the size of the annular gap between the(non-rotating) drive shaft and the bores of the discs.The heat transfer data were obtained from thermocouple measurements of surface temperature and a conduction solution method.The velocity measurements were made using a two component,LDA system.The heat transfer results from the discs show differences between the two builds.This is attributed to the wider annular gap allowing more of the throughflow to penetrate into the cavity.There are also significant differences between the radial distributions of tangential velocity in the two builds of the test rig.For the narrow annular gap,there is an increase of non-dimensional tangential velocity V/Ωr with radial location to solid body rotation V/Ωr=1.For the wider annular gap,the non-dimensional velocities show a decrease with radial location to solid body rotation.   相似文献   

12.
Aerospace relay is one kind of electronic components which is used widely in national defense system and aerospace system. The existence of remainder particles induces the reliability declining, which has become a severe problem in the development of aerospace relay. Traditional particle impact noise detection (PIND) method for remainder detection is ineffective for small particles, due to its low precision and involvement of subjective factors. An auto-detection method for PIND output signals is proposed in this paper, which is based on direct wavelet de-noising (DWD), cross-correlation analysis (CCA) and homo-filtering (HF), the method enhances the affectiv-ity of PIND test about the small particles. In the end, some practical PIND output signals are analysed, and the validity of this new method is proved.  相似文献   

13.
14.
Antimony-doped tin hydroxide colloid precipitates have been synthesized by hydrolysis of SnCl4 and SbCl3 using: (1) an ion-exchange hydrolysis to remove chlorine ions, and (2) isoamyl acetate as an azeotropic solvent to obviate water. The obtained dried powder is of high dispersivity without any need for further grinding. The size and dispersivity of the final particles are investigated with the aid of TG-DTA, BET, XRD and TEM. After having calcined, the antimony-doped tin oxide nanopowder possesses a tetragonal rutile structure with high dispersivity, uniform particles and low hard agglomeration.  相似文献   

15.
The effects of Mo on the microstructure evolution, porosity and hydrogen sorption properties of Ti-Mo getters are investigated in this work. The results show that the addition of Mo prolongs the densification process of Ti-Mo getters and results in a significant amount of sintered pores. With the Mo content increasing, the porosity of getters firstly increases reaching the maximum value as it at- tains about 7.5wt.%, and then drops. At the room temperature, the hydrogen sorption property of getters increases progressively with the Mo content increasing, but the tendency is not very clear before its content lies below 2.5wt.%. When the Mo content achieves about 7.5wt.%, the hydrogen sorption property proves to be the best. The discussion is made about the above mentioned phenomena inclusive of hydrogen sorption properties of getters under different activation conditions (from 500-750 ℃).  相似文献   

16.
超声速燃烧数值模拟中的湍流与化学反应相互作用模型   总被引:1,自引:0,他引:1  
杨越  游加平  孙明波 《航空学报》2015,36(1):261-273
高精度数值模拟有助于理解超声速湍流燃烧中湍流与化学反应的相互作用,可为发动机燃烧室等工程应用设计提供可靠的预测模型。除直接数值模拟外,目前在湍流燃烧应用中使用的大涡模拟和雷诺平均Navier-Stokes模拟均需要借助模型模化发生在湍流小尺度上的流动与化学反应过程对湍流大尺度运动的影响。现有的湍流与化学反应相互作用模型大致可分为:火焰面类模型和概率密度函数类模型,2类模型在不同的应用中各自具有优势和局限性。此外,现有模型大都基于低马赫数燃烧,而超声速燃烧中通常会伴随快速混合、局部熄火和再着火以及激波等复杂过程,这为发展其中的湍流与化学反应相互作用模型提出了更多的挑战。  相似文献   

17.
适于低轨卫星IP网络的单核共享树组播算法(英文)   总被引:1,自引:0,他引:1  
为了解决低轨卫星IP网络中现有典型源组播算法的信道资源浪费问题,本文提出了一套单核共享树组播算法,即核心群合并共享树(CCST)和加权核心群合并共享树(w-CCST)算法。CCST 算法包括动态近似中心(DAC)选核方法和核心群合并组播路径构建方法。DAC方法专为周期、规律运动的低轨卫星网络提出,不需要复杂的星上计算。在核心群合并方法中,以核节点作为初始核心群,通过核心群和剩余组成员的最短路径方法逐步扩展直至整棵组播树构建完成,从而使得组播树的树代价最小,大大提高了网络的带宽利用率和组播传输效率。w-CCST 算法中所提出的加权因子可以调整树代价和端到端传播时延之间的折衷程度,因此,可以通过调整加权因子来适度增大树代价、降低端到端传播时延以支持某些端到端时延要求苛刻的实时组播业务。最后,与低轨卫星 IP 网络中典型算法进行了性能比较,仿真结果说明,CCST 算法的平均树代价比其它算法显著降低,w-CCST 算法的平均端到端传播时延小于 CCST 算法。  相似文献   

18.
Jet Vectoring Control Using a Novel Synthetic Jet Actuator   总被引:3,自引:1,他引:2  
A primary air jet vectoring control system with a novel synthetic jet actuator (SJA) is presented and simulated numerically. The results show that, in comparison with an existing traditional synthetic jet actuator, which is able to perform the duty of either “push” or “pull”, one novel synthetic jet actuator can fulfill both “push” and “pull” functions to vector the primary jet by shifting a slide block inside it. Therefore, because the new actuator possesses greater efficiency, it has potentiality to replace the existing one in various appli- cations, such as thrust vectoring and the reduction of thermal signature. Moreover, as the novel actuator can fulfill those functions that the existing one can not, it may well be expected to popularize it into more flow control systems.  相似文献   

19.
The slewing motion control of a truss arm driven by a V-gimbaled control-moment-gyro (CMG) is a nonlinear control problem. The V-gimbaled CMG consists of a pair of gyros that must precess synchronously. The moment of inertia of the system, the angular momentum of the gyros and the external disturbances are not exactly known. With the help of feedback linearization and recursive Lyapunov design method, an adaptive nonlinear controller is designed to deal with the unknown items. Performance of the proposed controller is verified by simulation.  相似文献   

20.
A new time-accurate marching scheme for unsteady flow calculations is proposed in the present work. This method is the combination of classical Successive Over-Relaxation (SOR) iteration method and Jacobian matrix diagonally dominant splitting method of LUSGS. One advantage of this algorithm is the second-order accuracy because of no factorization error. Another advantage is the low computational cost because the Jacobian matrices and fluxes are only calculated once in each physical time step. And, the SOR algorithm has better convergence property than Gauss-Seidel. To investigate its accuracy and convergency, several unsteady flow computa- tional tests are carried out by using the proposed SOR algorithm. Roe’s FDS scheme is used to discritize the inviscid flux terms. Un- steady computational results of SOR are compared with the experiment results and those of Gauss-Seidel. Results reveal that the numerical results agree well with the experimental data and the second-order accuracy can be obtained as the Gauss-Seidel for unsteady flow computations. The impact of SOR factor is investigated for unsteady computations by using different SOR factors in this algorithm to simulate each computational test. Different numbers of inner iterations are needed to converge to the same criterion for different SOR factors and optimal choice of SOR factor can improve the computational efficiency greatly.  相似文献   

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