Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Exospheres and Energetic Neutral Atoms of Mars, Venus and Titan

Our understanding of the upper atmosphere of unmagnetized bodies such as Mars, Venus and Titan has improved significantly in this decade. Recent observations by in situ and remote sensing instruments on board Mars Express, Venus Express and Cassini have revealed characteristics of the neutral upper atmospheres (exospheres) and of energetic neutral atoms (ENAs). The ENA environment in the vicinity of the bodies is by itself a significant study field, but ENAs are also used as a diagnostic tool for the exosphere and the interaction with the upstream plasmas. Synergy between theoretical and modeling work has also improved considerably. In this review, we summarize the recent progress of our understanding of the neutral environment in the vicinity of unmagnetized planets.     

Atmospheric Escape and Evolution of Terrestrial Planets and Satellites

The origin and evolution of Venus’, Earth’s, Mars’ and Titan’s atmospheres are discussed from the time when the active young Sun arrived at the Zero-Age-Main-Sequence. We show that the high EUV flux of the young Sun, depending on the thermospheric composition, the amount of IR-coolers and the mass and size of the planet, could have been responsible that hydrostatic equilibrium was not always maintained and hydrodynamic flow and expansion of the upper atmosphere resulting in adiabatic cooling of the exobase temperature could develop. Furthermore, thermal and various nonthermal atmospheric escape processes influenced the evolution and isotope fractionation of the atmospheres and water inventories of the terrestrial planets and Saturn’s large satellite Titan efficiently.     

Upstream Ion Cyclotron Waves at Venus and Mars

The occurrence of waves generated by pick-up of planetary neutrals by the solar wind around unmagnetized planets is an important indicator for the composition and evolution of planetary atmospheres. For Venus and Mars, long-term observations of the upstream magnetic field are now available and proton cyclotron waves have been reported by several spacecraft. Observations of these left-hand polarized waves at the local proton cyclotron frequency in the spacecraft frame are reviewed for their specific properties, generation mechanisms and consequences for the planetary exosphere. Comparison of the reported observations leads to a similar general wave occurrence at both planets, at comparable locations with respect to the planet. However, the waves at Mars are observed more frequently and for long durations of several hours; the cyclotron wave properties are more pronounced, with larger amplitudes, stronger left-hand polarization and higher coherence than at Venus. The geometrical configuration of the interplanetary magnetic field with respect to the solar wind velocity and the relative density of upstream pick-up protons to the background plasma are important parameters for wave generation. At Venus, where the relative exospheric pick-up ion density is low, wave generation was found to mainly take place under stable and quasi-parallel conditions of the magnetic field and the solar wind velocity. This is in agreement with theory, which predicts fast wave growth from the ion/ion beam instability under quasi-parallel conditions already for low relative pick-up ion density. At Mars, where the relative exospheric pick-up ion density is higher, upstream wave generation may also take place under stable conditions when the solar wind velocity and magnetic field are quasi-perpendicular. At both planets, the altitudes where upstream proton cyclotron waves were observed (8 Venus and 11 Mars radii) are comparable in terms of the bow shock nose distance of the planet, i.e. in terms of the size of the solar wind-planetary atmosphere interaction region. In summary, the upstream proton cyclotron wave observations demonstrate the strong similarity in the interaction of the outer exosphere of these unmagnetized planets with the solar wind upstream of the planetary bow shock.     

Planetary Magnetic Fields and Solar Forcing: Implications for Atmospheric Evolution

The solar wind and the solar XUV/EUV radiation constitute a permanent forcing of the upper atmosphere of the planets in our solar system, thereby affecting the habitability and chances for life to emerge on a planet. The forcing is essentially inversely proportional to the square of the distance to the Sun and, therefore, is most important for the innermost planets in our solar system—the Earth-like planets. The effect of these two forcing terms is to ionize, heat, chemically modify, and slowly erode the upper atmosphere throughout the lifetime of a planet. The closer to the Sun, the more efficient are these process. Atmospheric erosion is due to thermal and non-thermal escape. Gravity constitutes the major protection mechanism for thermal escape, while the non-thermal escape caused by the ionizing X-rays and EUV radiation and the solar wind require other means of protection. Ionospheric plasma energization and ion pickup represent two categories of non-thermal escape processes that may bring matter up to high velocities, well beyond escape velocity. These energization processes have now been studied by a number of plasma instruments orbiting Earth, Mars, and Venus for decades. Plasma measurement results therefore constitute the most useful empirical data basis for the subject under discussion. This does not imply that ionospheric plasma energization and ion pickup are the main processes for the atmospheric escape, but they remain processes that can be most easily tested against empirical data. Shielding the upper atmosphere of a planet against solar XUV, EUV, and solar wind forcing requires strong gravity and a strong intrinsic dipole magnetic field. For instance, the strong dipole magnetic field of the Earth provides a “magnetic umbrella”, fending of the solar wind at a distance of 10 Earth radii. Conversely, the lack of a strong intrinsic magnetic field at Mars and Venus means that the solar wind has more direct access to their topside atmosphere, the reason that Mars and Venus, planets lacking strong intrinsic magnetic fields, have so much less water than the Earth? Climatologic and atmospheric loss process over evolutionary timescales of planetary atmospheres can only be understood if one considers the fact that the radiation and plasma environment of the Sun has changed substantially with time. Standard stellar evolutionary models indicate that the Sun after its arrival at the Zero-Age Main Sequence (ZAMS) 4.5 Gyr ago had a total luminosity of ≈70% of the present Sun. This should have led to a much cooler Earth in the past, while geological and fossil evidence indicate otherwise. In addition, observations by various satellites and studies of solar proxies (Sun-like stars with different age) indicate that the young Sun was rotating more than 10 times its present rate and had correspondingly strong dynamo-driven high-energy emissions which resulted in strong X-ray and extreme ultraviolet (XUV) emissions, up to several 100 times stronger than the present Sun. Further, evidence of a much denser early solar wind and the mass loss rate of the young Sun can be determined from collision of ionized stellar winds of the solar proxies, with the partially ionized gas in the interstellar medium. Empirical correlations of stellar mass loss rates with X-ray surface flux values allows one to estimate the solar wind mass flux at earlier times, when the solar wind may have been more than 1000 times more massive. The main conclusions drawn on basis of the Sun-in-time-, and a time-dependent model of plasma energization/escape is that:

1. Solar forcing is effective in removing volatiles, primarily water, from planets,
2. planets orbiting close to the early Sun were subject to a heavy loss of water, the effect being most profound for Venus and Mars, and
3. a persistent planetary magnetic field, like the Earth’s dipole field, provides a shield against solar wind scavenging.

     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Ion Energization and Escape on Mars and Venus

Mars and Venus do not have a global magnetic field and as a result solar wind interacts directly with their ionospheres and upper atmospheres. Neutral atoms ionized by solar UV, charge exchange and electron impact, are extracted and scavenged by solar wind providing a significant loss of planetary volatiles. There are different channels and routes through which the ionized planetary matter escapes from the planets. Processes of ion energization driven by direct solar wind forcing and their escape are intimately related. Forces responsible for ion energization in different channels are different and, correspondingly, the effectiveness of escape is also different. Classification of the energization processes and escape channels on Mars and Venus and also their variability with solar wind parameters is the main topic of our review. We will distinguish between classical pickup and ??mass-loaded?? pickup processes, energization in boundary layer and plasma sheet, polar winds on unmagnetized planets with magnetized ionospheres and enhanced escape flows from localized auroral regions in the regions filled by strong crustal magnetic fields.     

Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

The internal constitutions of the inner planets and the moon

The internal structures of the moon, Mars, Venus, and Mercury are examined in the light of what is known about the constitution of the earth. The gravitational figure of the earth as obtained from orbits of artificial satellites is used to estimate the possible deviations from hydrostatic equilibrium on other planets. Observations of the orbital and rotational motion of the moon are consistent with the hypothesis that the interior of the moon supports density inhomogeneities of the same order as those supported by the earth. The available data on the moon are insufficient to determine whether or not the moon is differentiated. The orbits of Phobos and Deimos yield an adequate value for the moment of inertia of Mars. The moment of inertia and the mass are consistent with a metallic core containing about 10 per cent of the mass of Mars. The observations of the possible magnetic field of Mars would be of importance both to the understanding of planetary magnetic fields and elucidating the internal structure of that planet. Seismic investigations on the earth yield an equation of state for silicates to pressures of about 1 × 10⁶ bars. This equation of state is used in determining density variation within Mars.The surface heat flow for the earth is consistent with the hypothesis that the concentration of radioactive elements is the same as that in chondritic meteorites. The observed ratio of potassium to uranium in surface and near-surface rocks is not consonant with the chondritic hypothesis. The moon can be of chondritic composition only if it is differentiated with the radioactivity concentrated in the upper few hundred kilometers. A chondritic composition for Mars would require a differentiation in excess of that consistent with its mass and moment of inertia. It is concluded that a chondritic composition is not a satisfactory chemical model for the inner planets.     

Thermal Evolution and Magnetic Field Generation in Terrestrial Planets and Satellites

Of the terrestrial planets, Earth and Mercury have self-sustained fields while Mars and Venus do not. Magnetic field data recorded at Ganymede have been interpreted as evidence of a self-generated magnetic field. The other icy Galilean satellites have magnetic fields induced in their subsurface oceans while Io and the Saturnian satellite Titan apparently are lacking magnetic fields of internal origin altogether. Parts of the lunar crust are remanently magnetized as are parts of the crust of Mars. While it is widely accepted that the magnetization of the Martian crust has been caused by an early magnetic field, for the Moon alternative explanations link the magnetization to plasma generated by large impacts. The necessary conditions for a dynamo in the terrestrial planets and satellites are the existence of an iron-rich core that is undergoing intense fluid motion. It is widely accepted that the fluid motion is caused by convection driven either by thermal buoyancy or by chemical buoyancy or by both. The chemical buoyancy is released upon the growth of an inner core. The latter requires a light alloying element in the core that is enriched in the outer core as the solid inner core grows. In most models, the light alloying element is assumed to be sulfur, but other elements such as, e.g., oxygen, silicon, and hydrogen are possible. The existence of cores in the terrestrial planets is either proven beyond reasonable doubt (Earth, Mars, and Mercury) or the case for a core is compelling as for Venus and the Moon. The Galilean satellites Io and Ganymede are likely to have cores judging from Galileo radio tracking data of the gravity fields of these satellites. The case is less clear cut for Europa. Callisto is widely taken as undifferentiated or only partially differentiated, thereby lacking an iron-rich core. Whether or not Titan has a core is not known at the present time. The terrestrial planets that do have magnetic fields either have a well-established inner core with known radius and density such as Earth or are widely agreed to have an inner core such as Mercury. The absence of an inner core in Venus, Mars, and the Moon (terrestrial bodies that lack fields) is not as well established although considered likely. The composition of the Martian core may be close to the Fe–FeS eutectic which would prevent an inner core to grow as long as the core has not cooled to temperatures around 1500 Kelvin. Venus may be on the verge of growing an inner core in which case a chemical dynamo may begin to operate in the geologically near future. The remanent magnetization of the Martian and the lunar crust is evidence for a dynamo in Mars’ and possibly the Moon’s early evolution and suggests that powerful thermally driven dynamos are possible. Both the thermally and the chemically driven dynamo require that the core is cooled at a sufficient rate by the mantle. For the thermally driven dynamo, the heat flow from the core into the mantle must by larger than the heat conducted along the core adiabat to allow a convecting core. This threshold is a few mW?m^?2 for small planets such as Mercury, Ganymede, and the Moon but can be as large as a few tens mW?m^?2 for Earth and Venus. The buoyancy for both dynamos must be sufficiently strong to overcome Ohmic dissipation. On Earth, plate tectonics and mantle convection cool the core efficiently. Stagnant lid convection on Mars and Venus are less efficient to cool the core but it is possible and has been suggested that Mars had plate tectonics in its early evolution and that Venus has experienced episodic resurfacing and mantle turnover. Both may have had profound implications for the evolution of the cores of these planets. It is even possible that inner cores started to grow in Mars and Venus but that the growth was frustrated as the mantles heated following the cessation of plate tectonics and resurfacing. The generation of Ganymede’s magnetic field is widely debated. Models range from magneto-hydrodynamic convection in which case the field will not be self-sustained to chemical and thermally-driven dynamos. The wide range of possible compositions for Ganymede’s core allows models with a completely liquid near eutectic Fe–FeS composition as well as models with Fe inner cores or cores in with iron snowfall.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

Effects of Low Energetic Neutral Atoms on Martian and Venusian Dayside Exospheric Temperature Estimations

The heating of the upper atmospheres and the formation of the ionospheres on Venus and Mars are mainly controlled by the solar X-ray and extreme ultraviolet (EUV) radiation (λ = 0.1–102.7 nm and can be characterized by the 10.7 cm solar radio flux). Previous estimations of the average Martian dayside exospheric temperature inferred from topside plasma scale heights, UV airglow and Lyman-α dayglow observations of up to ∼500 K imply a stronger dependence on solar activity than that found on Venus by the Pioneer Venus Orbiter (PVO) and Magellan spacecraft. However, this dependence appears to be inconsistent with exospheric temperatures (<250 K) inferred from aerobraking maneuvers of recent spacecraft like Mars Pathfinder, Mars Global Surveyor and Mars Odyssey during different solar activity periods and at different orbital locations of the planet. In a similar way, early Lyman-α dayglow and UV airglow observations by Venera 4, Mariner 5 and 10, and Venera 9–12 at Venus also suggested much higher exospheric temperatures of up to 1000 K as compared with the average dayside exospheric temperature of about 270 K inferred from neutral gas mass spectrometry data obtained by PVO. In order to compare Venus and Mars, we estimated the dayside exobase temperature of Venus by using electron density profiles obtained from the PVO radio science experiment during the solar cycle and found the Venusian temperature to vary between 250–300 K, being in reasonable agreement with the exospheric temperatures inferred from Magellan aerobraking data and PVO mass spectrometer measurements. The same method has been applied to Mars by studying the solar cycle variation of the ionospheric peak plasma density observed by Mars Global Surveyor during both solar minimum and maximum conditions, yielding a temperature range between 190–220 K. This result clearly indicates that the average Martian dayside temperature at the exobase does not exceed a value of about 240 K during high solar activity conditions and that the response of the upper atmosphere temperature on Mars to solar activity near the ionization maximum is essentially the same as on Venus. The reason for this discrepancy between exospheric temperature determinations from topside plasma scale heights and electron distributions near the ionospheric maximum seems to lie in the fact that thermal and photochemical equilibrium applies only at altitudes below 170 km, whereas topside scale heights are derived for much higher altitudes where they are modified by transport processes and where local thermodynamic equilibrium (LTE) conditions are violated. Moreover, from simulating the energy density distribution of photochemically produced moderately energetic H, C and O atoms, as well as CO molecules, we argue that exospheric temperatures inferred from Lyman-α dayglow and UV airglow observations result in too high values, because these particles, as well as energetic neutral atoms, transformed from solar wind protons into hydrogen atoms via charge exchange, may contribute to the observed planetary hot neutral gas coronae. Because the low exospheric temperatures inferred from neutral gas mass spectrometer and aerobraking data, as well as from CO⁺ ₂ UV doublet emissions near 180–260 nm obtained from the Mars Express SPICAM UV spectrograph suggest rather low heating efficiencies, some hitherto unidentified additional IR-cooling mechanism in the thermospheres of both Venus and Mars is likely to exist. An erratum to this article can be found at     

Planetary Atmospheres

The predominance of nitrogen in highly volatile forms and of carbon in solids set the abundance ratios of these elements in the inner planets, meteorites and comets. The absence of carbon compounds in an atmosphere then signals large deposits of carbon-bearing compounds in surface and/or subsurface deposits. In contrast, the icy planetesimals that contributed heavy elements to Jupiter must have had identical enrichments (relative to hydrogen) of both C and N, as well as other heavy elements that have been measured, compared to solar values. Capture of N and Ar suggests that the icy planetesimals that carried these elements must have formed at low temperatures, <40 K. New measurements of isotopes of nitrogen support this picture, but we must have more measurements in more atmospheres to be certain of this scenario.     

The Formation of Mars: Building Blocks and Accretion Time Scale

In this review paper I address the current knowledge of the formation of Mars, focusing on its primary constituents, its formation time scale and its small mass compared to Earth and Venus. I argue that the small mass of Mars requires the terrestrial planets to have formed from a narrow annulus of material, rather than a disc extending to Jupiter. The truncation of the outer edge of the disc was most likely the result of giant planet migration, which kept Mars’ mass small. From cosmochemical constraints it is argued that Mars formed in a couple of million years and is essentially a planetary embryo that never grew to a full-fledged planet. This is in agreement with the latest dynamical models. Most of Mars’ building blocks consists of material that formed in the 2 AU to 3 AU region, and is thus more water-rich than that accreted by Earth and Venus. The putative Mars could have consisted of 0.1 % to 0.2 % by mass of water.     

Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Planetary ionospheres

Experimental results on the ionospheres of Venus, Mars, Jupiter, Saturn, and Uranus are reviewed, especially from space missions like Pioneer Venus, Viking-1, and -2, Pioneer-10 and -11, and Voyager-1 and -2. Our emphasis has been on Venus, since most of the observational material pertains to it. On the outer planets, where the observations are rather modest, more emphasis is given on theoretical modelling.     

Below One Earth: The Detection, Formation, and Properties of Subterrestrial Worlds

The Solar System includes two planets—Mercury and Mars—significantly less massive than Earth, and all evidence indicates that planets of similar size orbit many stars. In fact, one of the first exoplanets to be discovered is a lunar-mass planet around a millisecond pulsar. Novel classes of exoplanets have inspired new ideas about planet formation and evolution, and these “sub-Earths” should be no exception: they include planets with masses between Mars and Venus for which there are no Solar System analogs. Advances in astronomical instrumentation and recent space missions have opened the sub-Earth frontier for exploration: the Kepler mission has discovered dozens of confirmed or candidate sub-Earths transiting their host stars. It can detect Mars-size planets around its smallest stellar targets, as well as exomoons of comparable size. Although the application of the Doppler method is currently limited by instrument stability, future spectrographs may detect equivalent planets orbiting close to nearby bright stars. Future space-based microlensing missions should be able to probe the sub-Earth population on much wider orbits. A census of sub-Earths will complete the reconnaissance of the exoplanet mass spectrum and test predictions of planet formation models, including whether low-mass M dwarf stars preferentially host the smallest planets. The properties of sub-Earths may reflect their low gravity, diverse origins, and environment, but they will be elusive: Observations of eclipsing systems by the James Webb Space Telescope may give us our first clues to the properties of these small worlds.     

Water and the Interior Structure of Terrestrial Planets and Icy Bodies

Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived ²⁶Al decay may govern the amount of hydrous silicates and leftover rock–ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors.     

Profiles of Ion and Aerosol Interactions in Planetary Atmospheres

In planetary atmospheres the nature of the aerosols varies, as does the relative importance of different sources of ion production. The nature of the aerosol and ion production is briefly reviewed here for the atmospheres of Venus, Mars, Jupiter and Titan using the concepts established for the terrestrial atmosphere. Interactions between the ions formed and aerosols present cause (1) charge exchange, which can lead to substantial aerosol charge and (2) ion removal. Consequences of (1) are that (a) charged aerosol are more effectively removed by conducting liquid droplets than uncharged aerosol and (b) particle–particle coagulation rates are modified, influencing particle residence times in the relevant atmosphere. Consequences of (2) are that ions are removed in regions with abundant aerosol, which may preclude charge flow in an atmosphere, such as that associated with an atmospheric electrical circuit. In general, charge should be included in microphysical modeling of the properties of planetary aerosols.     

Are There Chemical Gradients in the Inner Solar System?

The solar system is apparently stratified with regard to the contents of volatile constituents, as judged from the rocky, volatile-poor inner solar system planets and meteorites and the huge volatile-rich outer planets. However, beyond this gross structure there is no evidence for a systematic increase of the volatiles' abundances with distance from the Sun. Although meteorites show comparatively large differences in volatile element contents they also differ in many other respects, such as Mg/Si-ratios, bulk Fe and refractory element contents. These variations reflect variations in the nebular environment from which meteorites formed. The various conditions of meteorite formation cannot, however, be related in a simple way to heliocentric distances. There are also no systematic variations in the chemistry of the inner planets Mercury, Venus, Earth, Moon, Mars, and including the fourth largest asteroid Vesta, that could be interpreted as a relationship between volatility and composition. Although Mars (as judged from the composition of Martian meteorites) is more oxidized and contains more volatile elements than Earth, this trend cannot be extrapolated to the dry volatile poor Vesta (sampled by HED meteorites) in the asteroid belt. If the Earth-Mars trend reflects global inner solar system gradients then Vesta must have formed inside Earth's orbit and moved out later to its present location. The quality of Mercury and Venus composition data is not sufficient to allow reliable extrapolation to distances closer to the Sun. Recent nebula models predict small temperature gradients in the inner solar system supporting the view that no large variations in volatile element contents of inner solar system materials are expected. This revised version was published online in June 2006 with corrections to the Cover Date.