Aquatic animal research in space station and its issues--focus on support technology on nitrate toxicity.

We studied the effects of accumulated nitrate in water on the spawning, hatching and development of medaka using a simple nitrifying filter and a combined filter having both nitrifying and denitrifying capabilities. A nitrate concentration of 100 mg NO3(-)-N/L was clearly of lethal toxicity to fish when they were exposed to nitrate in both adult and the growing phases. A nitrate concentration of 75 mg NO3(-)-N/L reduced the fertilization rate, delayed the hatching time and reduced the hatching rate of the eggs laid by adults and decreased the growth rate of juveniles. In addition, nitrate accumulations as low as 50 mg NO3(-)-N/L remarkably retarded spawning and lowered the number of eggs laid by fish exposed in the juvenile phase. The effects on the reproduction system may be initiated by a low concentration, approximately 30 mg NO3(-)-N/L.     

A three-dimensional modelling study of the processes leading to mid latitude nitric oxide increases in the lower thermosphere following periods of high geomagnetic activity

The processes leading to enhancements in mid latitude nitric oxide (NO) densities following geomagnetic storms have been investigated using the University College London (UCL) Coupled Middle Atmosphere and Thermosphere (CMAT) general circulation model. A comparison of calculated storm time and quiet time NO densities at 110 km altitude reveals the presence of aurorally produced NO at both high and mid latitudes for several days after subsidence of activity. At 150 km, the NO enhancements are shorter lived and remain for up to approximately 2 days after the storm. By separating the contribution of chemical production and loss, horizontal and vertical advection, and molecular and eddy diffusion in the calculation of NO densities, we show that at 150 km altitude, horizontal transport must be taken into consideration if post-storm mid latitude enhancements are to be reproduced. Chemical production of NO at high latitudes continues for up to 2 days after subsidence of a storm at altitudes of around 150 km. We show that equatorward winds at this altitude are sufficiently strong to transport the aurorally produced NO to mid latitudes. Vertical diffusion transports NO from altitudes of 150 km and above, to lower altitudes where it is longer lived. At 110 km altitude, chemical, diffusive and advective terms must all be included in the calculation of NO density in order to simulate realistic mid latitude enhancements. We propose that it is the combined effects of increased chemical production, downward diffusion from altitudes of 150 km and above, and transport by winds that lead to increases in mid latitude NO density at altitudes of around 110 km. This is the first detailed study of the causes of post-storm mid latitude NO enhancements to use a three-dimensional general circulation model.     

Production of nitrogen oxides by lightning and coronae discharges in simulated early Earth, Venus and Mars environments.

We present measurements for the production of nitrogen oxides (NO and N2O) in CO2-N2 mixtures that simulate different stages of the evolution of the atmospheres of the Earth, Venus and Mars. The nitrogen fixation rates by two different types of electrical discharges, namely lightning and coronae, were studied over a wide range in CO2 and N2 mixing ratios. Nitric oxide (NO) is formed with a maximum energy yield estimated to be ~1.3 x 10(16) molecule J-1 at 80% CO2 and ~1.3 x 10(14) molecule J-1 at 50% CO2 for lightning and coronae discharges, respectively. Nitrous oxide (N2O) is only formed by coronae discharge with a maximum energy yield estimated to be ~1.2 x 10(13) molecule J-1 at 50% CO2. The pronounced difference in NO production in lightning and coronae discharges and the lack of formation of N2O in lightning indicate that the physics and chemistry involved in nitrogen fixation differs substantially in these two forms of electric energy.     

Involvement of nitric oxide in the mechanism of biochemical alterations induced by simulated microgravity in Microcystis aeruginosa

Simulated microgravity (SMG) can inhibit proliferation and enhance microcystin production of Microcystis aeruginosa. We investigated the role of nitric oxide (NO) in regulating the SMG induced changes of proliferation, photochemical system II photochemical activity, pigment, soluble protein and microcystin production in M. aeruginosa. M. aeruginosa was exposed to 0.1 mM sodium nitroprusside (SNP, NO donor) or 0.02 mM 2-(4-carboxyphenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide (c-PTIO, NO scavenger) alone or in combination with SMG for 48 h. SMG and SNP inhibited the growth of M. aeruginosa while c-PTIO had no effect on cell number. As to yield, the negative effect of SMG was augmented by SNP and suppressed by c-PTIO. The intracellular concentrations of chlorophyll a, carotenoid, phycocyanin, soluble protein and microcystin were increased by SMG after 48 h. The effects of SMG on these metabolic processes could be enhanced by SNP and be partly eliminated by c-PTIO. Moreover, SNP and c-PTIO only functioned in these biochemical processes under SMG, unlike in the regulation of cell proliferation and yield. These results showed that the effects of SMG could be enhanced by adding exogenous NO and be mitigated by scavenging endogenous NO, revealing the involvement of NO in the changes in biochemistry processes induced by SMG in M. aeruginosa.     

Aspects related to variability of radiative cooling by NO in lower thermosphere,TEC and O/N2 correlation,and diffusion of NO into mesosphere during the Halloween storms

Nitric Oxide is a very important trace species which plays a significant role acting as a natural thermostat in Earth’s thermosphere during strong geomagnetic activity. In this paper, we present various aspects related to the variation in the NO Infrared radiative flux (IRF) exiting the thermosphere by utilizing the TIMED/SABER (Thermosphere Ionosphere Mesosphere Energetics and Dynamics/ Sounding of the Atmosphere using Broadband Emission Radiometry) observational data during the Halloween storm which occurred in late October 2003. The Halloween storm comprised of three intense-geomagnetic storms. The variability of NO infrared flux during these storm events and its connection to the strength of the geomagnetic storms were found to be different in contrast to similar super storms. The connection between the quantum of energy outflux from the upper atmosphere into space in terms of NO IRF and the duration of storms is established. The NO radiative cooling, and the closely correlated depletion in O/N₂ ratio are controlled by the Joule heating intensity (proxied by AE-index). The collisional excitation rate of NO, calculated using the modelled datasets of WACCM-X (Whole Atmosphere Community Climate Model with thermosphere and ionosphere extension), correlates well with the observed pattern of radiative emission by NO. Observational datasets from TIMED/GUVI (Global Ultra-Violet Imager) and MIT Haystack observatory madrigal GNSS (Global navigation satellite system) total electron content (TEC) database shows that the TEC and O/N₂ enhancement in low-mid northern hemispheric latitudes are mainly controlled by the z-component of Interplanetary magnetic field (IMF-B_z). The penetration of eastward electric field during the storm events is found to be responsible for the overall enhancement of TEC. The contribution of enhanced day-side TEC in observed variation of O/N₂ ratio by GUVI is also reported. It is also seen that during substorms related events the night-time polar region experiences more cooling due to NO than the daytime polar region. The connections between the mid- and low-latitude enhancement in NO IRF with the propagation of LSTIDs (Large-scale traveling ionospheric disturbances) in combination with the O/N₂ variability, and the altitudinal variation in NO flux with the progression of the storm is also investigated. This study presents the evidence on the role of diffusion processes in the large scale enhancement of NO in the mesospheric altitudes.     

国内地面放射性测量模型标准装置的量值比对

核工业放射性勘查计量站于2015年组织西南、中南、华南和华东四家计量站实施了国内地面放射性测量模型标准装置的量值溯源比对,比对模型为核工业放射性勘查计量站的地面模型。从比对测量结果归一化偏差分析,仅有个别仪器在钾含量较低的YM1和钾含量存在争议的YM3模型的归一化偏差大于1,说明比对过程严谨、比对方法正确、结果可信。从比对测量结果与标称值比较分析,仍是YM1和YM3模型的钾含量相对偏差超过5%,其他均在8%不确定度之内,说明核工业放射性勘查计量站的地面模型量值稳定。     

A new non-LTE retrieval method for atmospheric parameters from mipas-envisat emission spectra

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a high-resolution limb sounder on board the European polar platform ENVISAT, scheduled to be launched in 2001. A large number of atmospheric trace gases relevant to stratospheric ozone chemistry and global change are expected to be retrieved from the IR spectra covering a wide spectral range. While operational data analysis under responsibility of the European Space Agency is limited to conditions of local thermodynamic equilibrium (LTE), the analysis of limb radiances affected by non-LTE is left to scientific institutions. In this paper we present an innovative non-LTE retrieval method as part of the MIPAS semi-operational data processor developed at the Institut für Meteorologie und Klimaforschung (IMK). The new approach enables the treatment of vibrational, rotational, and spin non-LTE as well as a dependence of the non-LTE state distribution on the retrieval target quantities. In a case study, the method has been tested for its application to the non-LTE analysis of 5.3 μm MIPAS radiances. The fundamental ro-vibrational band of nitric oxide emitting at 5.3 μm shows strong non-LTE effects arising from vibrational excitation of stratospheric NO and superposed thermospheric non-LTE emissions. A conventional non-LTE retrieval approach using ab initio vibrational temperatures of NO cannot be applied due to rotational and spin non-LTE in the thermosphere, and the dependence of stratospheric vibrational temperatures on the NO abundance itself. The ability of the developed non-LTE inversion tool to retrieve stratospheric NO abundances is demonstrated by retrieval simulations. The further application of this method to the simultaneous retrieval of NO and kinetic temperature in the thermosphere and the retrieval of important non-LTE process parameters has also been tested.     

差分吸收光谱法污染物连续监测系统

紫外—可见差分吸收光谱法 (DOAS)是一种新型在线式烟气排放污染物自动监测的可行方法 ,它在不改变被测试样成分的前提下 ,可以同时对多种气体进行连续测量。对获得的吸收光谱数据由计算机处理 ,可实时记录烟气中各种污染物的含量 ,并对未知成分的气体进行判断。介绍了基于这种测量方法的测试系统的构成、工作原理和测试结果     

地磁暴恢复相中间层低热层高纬温度响应

利用TIMEGCM模拟了2005年9月10日至20日由日冕物质抛射引起的地磁暴事件,研究了此地磁暴恢复相高纬度中间层低热层（MLT）区域温度的变化,揭示了磁暴恢复相时温度、垂直风、总加热项和NO辐射冷却的内在联系.结果表明:地磁暴恢复相刚开始时,温度对磁暴的响应在晨侧为负扰动（降温）,在其他地区都为正扰动（增温）;随着磁暴的恢复,整个北半球都变为正的温度扰动（增温）.这种高纬MLT区域的温度响应主要与垂直风密切相关.当垂直风为正时,总加热为负,增温减弱;当垂直风为负时,总加热为正,增温变强.辐射冷却特别是NO辐射冷却作用在热层被称为恒温器,降低了磁暴期间80%的热层增温.但是,在MLT区域NO辐射冷却作用不明显,一般比总加热项小一个量级,对温度响应造成的影响较小.      

一氧化氮对电离层电子密度的影响

本文利用电离层电子密度的理论计算模式,研究了一氧化氮对中、低纬度100-200km间电子密度的影响,发现电子密度与一氧化氮密度间存在着正、负相关。正相关,只有当这一光电离成为一氧化氮离子的主要生成源时才出现。      

氮氧化物羽烟在电离层局部的光热效应

在航天器羽烟一次性抛出和呈球状近似情况下,模拟了电离层E层NO羽烟与周围大气压力平衡时的最大亮度及其随时间的变化．在110km抛出的5molNO羽烟可使它获得瞬时夜间中等偏强极光那样的亮度,在140km抛出的同样数量的NO羽烟亮度却急剧地减弱．还模拟了白天夜间温度为1000K的NO2羽烟在190km和250km两个高度、50mol和500mol两种抛出总量所造成的局部大气温度短时间内的下降．在F层下部,夜间较大抛出量所造成的冷却效应是显著的．     

Search for ultraviolet shuttle glow

The Space Shuttle Columbia flown in January 1986 carried two ultraviolet experiments (UVX) designed to observe very weak diffuse emission from various astronomical sources at wavelengths below 3200 Å with moderate spectral resolution. Such observations are extremely sensitive to the presence of any shuttle induced ultraviolet glow, since the wavelength range, 1200–3200 Å, includes strong emission lines or bands of species such as O, NO, and OH which are predicted to radiate strongly by models of the shuttle glow. The UVX spectrometers are sensitive to emission features as faint as 0.1 Rayleighs. Emissions from O₂, O and NO are detected and shown to be consistent with an atmospheric origin.     

我国中低纬地区上空低电离层中的行星波

本文通过5年的电离层吸收观测资料与平流层增温事件对比及吸收资料的谱分析,得出以下几点初步结论:1)极区平流层增温事件的影响可能通过子午环流和行星波传播,经过5—9天后到达中低纬地区,从而引起那里的电离层吸收变化;2)冬季行星波沿子午方向的平均速度大约在10m/s到15m/s之间变化;3)全年均有周期为32天、18天、10天、8天和2天的行星波出现,它对大气湍流系数有明显影响。计算得出行星波扰动引起中层的NO浓度偏离未扰值可高达40%。      

加力燃烧室NOx排放生成规律试验分析

实现航空发动机大推力通常采用加力燃烧室设计,燃烧室进气温度升高会同步导致排放尾气中NO_x浓度提高.采用典型加力燃烧室主稳定器的V型结构试验件,测试加力燃烧前后(进口600 ℃,出口600~1 200 ℃)燃烧室排放断面的NO_x浓度分布,通过相同流场4种试验工况的NO_x生成浓度组分和氧含量变化分析,验证了加力燃烧室NO_x生成以热力型NO为主的"高温、富氧、贫油"燃烧特性.结果表明加力燃烧室燃烧过程中消耗的氧含量大多贡献于CO₂增量,在800~1 000 ℃燃气排放温度范围内,不完全燃烧产物CO对NO的热力生成有明显抑制作用.     

Long-term tropospheric variations of ozone content caused by galactic cosmic ray influence

Galactic cosmic ray (GCR) fluxes measured by balloons in the troposphere and stratosphere at several points in Russia, and total ozone (TO) records have been used to detect cosmic signal by linear regression analysis. It was shown that TO response is in phase with decadal variations of GCR in contrast to the assumption about ozone destruction by GCR due to the nitrogen catalytic cycle intensification. 1-D photochemical model was used to understand the situation. The results of calculations show positive ozone response in the troposphere caused by additional production of NO by GCRs.     

中国上空民航飞机NOx排放分布再探

对1998年旺季(4月~10月)的中国上空民航飞机的NOx排放量及其分布进行了评估,并结合国内外有关数据进行了分析和比较.结果表明,目前中国的商业飞行所造成的NOx排放主要集中在(大)城市上空,各城市上空的大气污染程度有很大的不同,且这些城市上空的NOx含量沿高度方向由地面向高空递减;就自身发展来看,目前的高空飞机NOx排放量已比6年前增加1倍多;从横向比较来看,目前中国几个大城市上空飞机的NOx排放量已达到并超过6年前全球空运发达地区的排放量,应引起有关部门的高度注意.      

利用太阳耀斑的电离层效应确定低纬度D层顶一氧化氮浓度

通过氧鎓离子化学计算了一次强太阳耀斑扰动期间低纬度(28°38′N)D层顶NO浓度。该方法适用于O+₂离子化学生存时间较短且负离子浓度与正离子相比可以忽略的80至87.5公里高度。计算结果表明,它相当好地符合Meira的实验观测剖面,只是85公里处的最小值特别弱。      

The Lyman-alpha absorption anomaly in satellite occulation measurements as a tracer for some thermospheric composition variations

The absorption anomaly of Lyman-alpha radiation in satellite occultation experiments is known as the fact that extinction above 100 km is much stronger than absorption by atmospheric O₂ alone would explain. Additional absorption by NO or H₂O has been suggested but none has been clearly identified so far. The additional absorption occurs predominantly in middle and high latitudes of the winter hemisphere, but has also been found in equatorial latitudes. Recent measurements of NO would explain the Lyman-alpha absorption anomaly. The high densities of the additional Lyman-alpha absorber at lower latitudes could be explained by transport processes through global circulation systems of the higher thermosphere. Structural variations of the neutral gas derived from occultation measurements seem to indicate that thermospheric low pressure systems in mid latitudes modulate the transport of tracer constituents and heat energy from higher latitudes to the equator.     

贫燃型汽车尾气NOx的催化净化

用溶胶-凝胶混合法制备了Al₂O₃,Ag/Al₂O₃,Sn/Al₂O₃,Ga/Al₂O₃,Co/Al₂O₃和Pt/Al₂O₃等催化剂.在相同实验条件下,比较了C₃H₆在这些催化剂上还原NO的活性,并考察了反应条件对C₃H₆和CH₃OH在Ag/Al₂O₃上还原NO性能的影响.结果表明,Ag/Al₂O₃的还原NO活性优于其它催化剂.H₂O对Ag/Al₂O₃催化剂的NO还原具有可逆抑制作用,SO₂降低C₃H₆在Ag/Al₂O₃上还原NO的活性,但会显著提高CH₃OH还原NO的活性.     

Diurnal and seasonal variations in long-term changes in the E-layer critical frequency

Long-term changes in the E-layer critical frequency, foE, at three stations of the European region (Juliusruh, Slough and Rome) and also at Moscow and Wakkanai stations are analyzed by the method developed by the authors and described in detail in the previous papers. It is found that Juliusruh and Slough stations demonstrate a well-pronounced change in foE (a trend) during two previous decades. At the same time, the same features of the behavior of the aforementioned trend k(foE) are obtained. The trend is positive and negative in the morning and evening hours, respectively. Similar diurnal behavior of k(foE) is found also for Moscow station but with lower absolute values of the trends. A well-pronounced seasonal behavior of k(foE) is detected at Juliusruh and Slough: the trend is minimal and maximal in the summer period and at the end of fall—beginning of winter, respectively. The maximal amplitude in the morning hours reaches +0.04?MHz per year, whereas the minimal amplitude in evening hours is ?0.06?MHz per year. No systematic changes exceeding by the magnitude 0.01?MHz per year are found for Rome and Wakkanai stations. It is assumed that the observed trends are related to changes (trends) in the meridional wind bringing NO molecules from the auroral oval to lower latitudes.