Validation of SAGE II data inversions by the European correlative experiments

An European program of correlative experiments has been organized in order to validate SAGE II data during three periods of observation over Europe (November 1984, April 1985, October 1985). About ten groups from France, Belgium, Germany and Italy were participating. The correlative data are lidar aerosol profiles, soundings of ozone profiles, and balloon observations, including limb photographies, polarimetric measurements of the aerosol scattered light and nitrogen dioxide extinction measurements. Results of the comparisons between SAGE II inverted data and correlative data are presented. The analysis of the aerosol correlative observations with the SAGE II four aerosol channel data, in term of profile and size distribution is perfectly consistent and provide a good indirect validatioin. The NO₂ comparison shows a good agreement between SAGE II and correlative data.     

The influence of the several very large solar proton events in years 2000–2003 on the neutral middle atmosphere

Solar proton events (SPEs) are known to have caused changes in constituents in the Earth’s polar neutral middle atmosphere. The past four years, 2000–2003, have been replete with SPEs. Huge fluxes of high energy protons entered the Earth’s atmosphere in periods lasting 2–3 days in July and November 2000, September and November 2001 and October 2003. The highly energetic protons produce ionizations, excitations, dissociations and dissociative ionizations of the background constituents, which lead to the production of HO_x (H, OH, HO₂) and NO_y (N, NO, NO₂, NO₃, N₂O₅, HNO₃, HO₂NO₂, ClONO₂, BrONO₂). The HO_x increases lead to short-lived ozone decreases in the polar mesosphere and upper stratosphere due to the short lifetimes of the HO_x constituents. Large mesospheric ozone depletions (>70%) due to the HO_x enhancements were observed and modeled as a result of the very large July 2000 SPE. The NO_y increases lead to long-lived stratospheric ozone changes because of the long lifetime of the NO_y family in this region. Polar total ozone depletions >1% were simulated in both hemispheres for extended periods of time (several months) as a result of the NO_y enhancements due to the very large SPEs.     

Comparison of ozone data derived from SBUV and SAGE with emphasis on longitudinal variations

Stratospheric ozone observations by the SAGE and SBUV satellite instruments in March and April, 1979 have been analyzed. All SAGE profiles have been smoothed vertically over 8 km to provide some compatibility with the SBUV vertical resolution. Comparing the zonal mean ozone mixing ratios against smoothed LIMS profiles, it is inferred that SAGE is systematically overestimating ozone by approximately 20% at tropical latitudes at pressures lower than 5 mb and that SBUV is underestimating ozone by approximately 15% at 50–70° latitude at 10 mb. A comparison of the longitudinal variations of ozone by SBUV and SAGE is made and the detectability of planetary waves in ozone is emphasized. The uncorrelated portion of the SAGE variances are found to be approximately consistent with the SAGE noise model. Based on the correlated variances, the amplitudes of the smoothed SAGE planetary waves in ozone are found to be the same, on average, as in the SBUV experiment at mid-latitudes between 1 and 10 mb. Planetary wave detectability is illustrated during two several day periods at mid-latitudes and a persistent and theoretically-consistent relationship between ozone and temperature is noted. These examples, however, indicate that differences between ozone planetary wave amplitudes derived from the two sensors may occur when there is a strong vertical gradient in wave amplitude.     

The variability of stratospheric nitrogen compounds observed by LIMS in the winter of 1978–1979

The LIMS experiment was launched on the Nimbus 7 satellite for the purpose of sounding the vertical structure of temperature and key upper atmosphere trace gases on a global scale. The technique of thermal infrared limb sounding was used to obtain measurements of O₃, H₂O, NO₂, and HNO₃. LIMS collected data almost continuously from late October to late May over the latitude range from 64°S to 84°N. Two of the gases, NO₂ and HNO₃, are important elements in the NO_x chain of chemical reactions leading to ozone destruction. We will describe results for these gases in terms of zonal mean profiles and latitudinal distributions. The period selected for study is January–May 1979, when a major stratospheric warming occurred.     

Statistical comparison of night-time NO2 observations in 2003–2006 from GOMOS and MIPAS instruments

GOMOS (Global Ozone Monitoring by Occultation of Stars) and MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) are remote sensing instruments on board the European Space Agency’s Envisat satellite. GOMOS and MIPAS have been designed for observations of stratospheric and mesospheric constituents, including ozone and nitrogen dioxide. Both instruments have a good global coverage of observations and can provide data also from the polar regions. In this paper, we compare night-time NO₂ data from GOMOS with those from MIPAS. We present statistics of selected sets of data spanning from the year 2003 to 2006. The results for low-to-mid latitudes show that the two instruments are in a good agreement in the middle stratosphere, the differences being typically less than 5%. In the upper stratosphere, GOMOS observations generally show 15% higher values than those from MIPAS. The bias is in virtually all cases smaller than the combined systematic error of the measurements, giving great confidence in the GOMOS and MIPAS data quality. The result for high mesospheric NO₂ mixing ratios observed in the polar regions during winter times indicate a good agreement between GOMOS and MIPAS. In the mesosphere, the difference is less than 35% and smaller than the systematic error. Due to the high mesospheric signal, MIPAS sensitivity decreases in the stratosphere which results in larger differences between the two instruments.     

Statistical global and regional atmospheric models of temperature and gas components over the northern hemisphere

Statistical mid-latitude models of altitude distribution of temperature, water vapor, ozone, carbon dioxide and trace gases (CO, CH₄, N₂O, NO, NO₂) are considered. The mean characteristics of altitude profiles of these parameters, as well as their time and space variability, have been taken into account. The statistical regional models were constructed using a temperature-humidy complex. The considered statistical mid-latitude models have been constructed as applied to solutions of the problems on remote sounding of the atmosphere and underlying surface from outer space.     

Study of atmospheric air pollutants during the partial solar eclipse on 15 January 2010 over Udaipur: A semi-arid location in Western India

The paper describes behavior of surface ozone, its precursor gases, BC along with TOCC, TWVC, AOT1020 nm as well as UV and IR radiation intensities observed during the partial solar eclipse of 15th January, 2010 over Udaipur, where 52% solar disc is obscured due to the moon’s shadow. During the beginning to main eclipse phase, the deviation values of several air pollutants concentrations from eclipse to control day values vary in a small range from −9 to −2 ppb in case of surface ozone and −180 to −80 ppb for CO. The corresponding change in the values of BC observed from −3.3 to −.5 μg/m³. No significant change is found in NO₂, NO or in ratio of NO₂/NO values during the partial eclipse time. TOCC values decrease from 3 to 5 DU along with a reduction in UV radiation intensity from 20 to 35% from starting to the main eclipse phase. The AOT1020 nm values are found to increase from .2 to 1.0 along with a reduction in IR radiation intensity order of 50%. However, TWVC values decrease from .22 to .1 cm during the eclipse hours. The low level of dilution in surface ozone in eclipse period may be attributed with change in local atmospheric boundary layer dynamic conditions or limited air pollutants dispersion, in term of decreases in planetary boundary layer height, wind speed and hence ventilation coefficient in the same eclipse hours. Thus, present studies support the argument for the leading roles of photochemical reactions with its precursor gases under presence of solar radiation in surface ozone variability. Other possible controlling factors are advection of air pollutants from the polluted region as evident from backward wind trajectories and altering the local meteorological conditions.     

The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O₃) over the 10-km to 65-km range and water vapor (H₂O), nitrogen dioxide (NO₂), and nitric acid (HNO₃) over the 10-km to ～50-km range. Latitude coverage extended from 64°S to 84°N. Several general features of the atmosphere have emerged from data analyses thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO₃ data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O₃, NO₂, and HNO₃ are strongly affected during a stratospheric warming. There is a persistently low water vapor mixing ratio in the tropical lower stratosphere (～2–3 ppmv), a poleward gradient at all times in the mission, and evidence of increasing mixing ratio with altitude at tropical and middle latitudes.     

Towards validation of SCIAMACHY lunar occultation NO2 vertical profiles

Vertical profiles of stratospheric nitrogen dioxide (NO₂) have been retrieved from moderate resolution lunar occultation transmission spectra measured by Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) on board the European Environmental Satellite (ENVISAT). These measurements were taken over the high southern latitude of 50°–90° during the period of 2003–2005. To assess the accuracy of the retrieved NO₂ profiles, the SCIAMACHY nighttime NO₂ profiles were compared with NO₂ profiles retrieved from sunrise solar occultation spectra measured by the Halogen Occultation Experiment (HALOE) and the Stratospheric Aerosol and Gas Experiments II (SAGE II) using a photochemical correction model. The validation results show good agreement of SCIAMACHY lunar occultation NO₂ with scaled HALOE and SAGE II profiles. The relative mean differences (rmd) with scaled HALOE profiles are within −13% to +5% and standard deviations (rms) of the relative differences are within 3–19% between 25 and 38 km. The rmd and rms with scaled SAGE II NO₂ profiles are in the range of −9 to +7 and 10–17% respectively between 22 and 39 km.     

Ozone variability related to several SEP events occurring during solar cycle no. 23

Data from geostationary operational environmental satellite (GOES) series were used to identify intense solar energetic particle (SEP) events occurred during the solar activity cycle no. 23. We retrieved O₃, NO, NO₂, HNO₃, OH, HCl and OHCl profiles coming from different satellite sensors (solar occultation and limb emission) and we looked for the mesospheric/stratospheric response to SEPs at high terrestrial latitudes. The chemistry of the minor atmospheric components is analysed to evaluate the associated odd nitrogen (NO_x) and odd hydrogen (HO_x) production, able to cause short (h) and medium (days) term ozone variations. We investigated the effects of SEPs on the polar atmosphere in three different seasons, i.e., January 2005, April 2002 and July 2000. The inter-hemispheric variability of the ozone, induced by the SEP series of January 2005, has been compared with the effects connected both to larger and quite similar events. We found that during SEP events: (i) solar illumination is the key factor driving SEP-induced effects on the chemistry of the polar atmosphere; (ii) even events with limited particle flux in the range 15–40 MeV are able to change the abundance of the minor constituents in the mesosphere and upper stratosphere.     

Rocket-borne measurements of atmospheric infrared emissions by spectrometric techniques

As part of the MAP/WINE Campaign 1983/84 a liquid helium cooled infrared grating spectrometer measured night zenith radiances of CO₂, O₃, and H₂O in the mesosphere and lower thermosphere. From a comparison of the measured spectral radiances with results from LTE radiative transfer calculations atmospheric temperatures and concentration profiles of H₂O and O₃ were determined, showing some interesting features. The ozone densities obtained appear to contradict model predictions based upon the assumption that ozone is in photochemical equilibrium at mesospheric heights. Since the ozone density distribution shows quite similar structures as the vertical wind profile, transport effects seem to play a major role in the mesospheric ozone formation.     

Mass spectrometry in the stratosphere

During the last few years a gas expansion system, combined with a mass spectrometer has been developed and successfully flown in the stratosphere. Neutral gas particles are formed into a molecular beam which traverses the ion source of the mass spectrometer without wall interactions. Vertical profiles of constituents such as H₂O, CO₂ and O₃ have been measured in the altitude range of 20 to 40 km during balloon descents. Isotopes of major atmospheric gases (N₂, O₂, Ar) provided in-flight calibration standards.Before each flight the mass spectrometer system was calibrated in the laboratory for many gases of interest, including ozone. Mixing ratios of ozone determined from recent flights have accuracies of better than 5%. The sensitivity of the system was sufficiently high to detect, in addition, the heavy isotope of ozone at mass 50. A pronounced enhancement of heavy ozone in the upper stratosphere has been found. The mass spectrometer system provides the unique opportunity to perform in the stratospherein-situ measurements combined with isotopic studies.     

Greenhouse gases and recovery of the Earth’s ozone layer

A numerical 2-D zonally averaged dynamical radiative-photochemical model of the ozonosphere including aerosol physics is used to examine the role of the greenhouse gases CO₂, CH₄, and N₂O in the recovery of the Earth’s ozone layer after reduction of anthropogenic discharges of chlorine and bromine compounds into the atmosphere. A weakness in efficiencies of all catalytic cycles of the ozone destruction due to cooling of the stratosphere caused by greenhouse gases is shown to be a dominant mechanism of the impact of the greenhouse gases on the ozone layer. Numerical experiments show that the total ozone changes caused by greenhouse gases will be comparable in absolute value with the changes due to chlorine and bromine species in the middle of the 21st century. Continuous anthropogenic growth of CO₂ will lead to a significantly faster recovery of the ozone layer. In this case, the global total ozone in the latitude range from 60°S to 60°N will reach its undisturbed level of 1980 by about 2040. If the CO₂ growth stops, the global total ozone will reach this level only by the end of the century.     

Prediction of clear-sky biologically effective erythematic radiation (EER) From global solar radiation (250–2800 nm) at Cairo,Egypt

The hourly and daily measured clear-sky global solar radiation (G) and biologically important effective erythematic radiation (EER) incident on a horizontal surface at Cairo, Egypt (latitude 30° 05′ N & Longitude 31° 15′ E), during the period from January 1995 to December 2005 are used in this paper. The relationship between daily integrated totals of EER and the daily totals of broadband global solar radiation (250–2800 nm) is established. The temporal variability of the percentage ratio of the total daily erythema to total daily broadband solar global irradiation (EER/G) is determined. The monthly and the seasonal averages of the extraterrestrial UVB solar radiation, Mesurad and estímated UVB solar radiation and clearness index K_tUVB of UVB radiation are discussed. The average monthly mean variation of slant ozone (Z) and UVB transmission (K_tUVB) at the present work are found. The two variables show an opposite seasonal behavior, and the average monthly of slant ozone column and UVB transmission values shows the relationship between them in a clearer way than those of daily values. The estimated values of UVB solar radiation a good agreement with the measured values of the UVB solar radiation, the difference between the estimated and measured values of UVB solar radiation varies from 1.2% to 2.8%. The effect of the annual cycles of solar zenith angle (SZA) and total column ozone (TCO) on the ratios (EER/G) are presented and the correction factors are determined for removal of the ozone cycle. The seasonal variability of EER/G is also discussed. The effect of the annual cycles of solar zenith angle (SZA) and total column ozone (TCO) on the ratios (EER/G) is presented and the correction factors are determined for removal of the ozone cycle.     

NO2 field observations in the stratosphere during Map/Globus campaign in 1983 and 1985

NO₂ has been measured from balloons, plane and ground during Map/Globus Campaign in Europe in 1983. The results have shown an agreement between in situ and remote sensing techniques in the lower stratosphere, but some divergence at higher altitude. Part of the differences might be due to unknown experimental systematic errors and part to real atmospheric variations as the observations were not performed on the same day. In order to improve the knowledge of the instruments performances and to evaluate the NO_x stratospheric budget a new field campaign has been set up in Europe in 1985. Simultaneous in situ and balloons, ground and satellites remote sensing observations of NO and NO₂ were obtained, covering a 24 H period.     

Derivation of OH concentrations from LIMS measurements

Stratospheric concentrations of OH have been derived from LIMS measurements of minor constituents. Two methods have been used. Assuming that HNO₃ and NO₂ are in photochemical steady state, LIMS measurements of these species, with knowledge of appropriate rate constants and a calculation of the HNO₃ photolysis rate, allow nearly global fields of OH to be derived. The derived profiles show satisfactory agreement with observations. As a check on our method, OH has also been derived by calculations of its sources and sinks using LIMS measurements of H₂O. The two methods agree extremely well in low latitudes. At higher latitudes the agreement is less satisfactory. This is discussed in terms of the diurnal behaviour of the species and the time constant of the HNO₃/NO₂ equilibrium.     

Verification of satellite observations of stratospheric minor constituents

The TIROS-N operational meteorological satellite observing system will have the capability of determining global ozone amounts from two instruments by 1985. The TIROS Operational Vertical Sounder (TOVS) yields total ozone amounts through measurements of atmospheric infrared radiances. The Solar Backscatter Ultraviolet (SBUV/2) spectrometer yields total ozone amounts and vertical ozone profiles through measurements of the solar ultraviolet radiation backscattered by the atmosphere. The current operations plan calls for single satellites containing both instruments system with local afternoon equator crossing times. They will be launched at approximately 18 month intervals.The satellite ozone products will require verification using commonly accepted references. For total ozone, Dobson spectrophotometer determinations are to be used. For vertical profiles, no clear choice now exists among balloon-launched chemical sondes, rocket-launched optical sondes or Dobson Umkehr measurements. The applicability and use of these measurement systems are discussed with emphasis on the need for the verification data consistent with the operational satellite lifetimes.Another major source of data for verification is other satellite systems. Comparisons of vertical ozone profiles from several concurrent satellites is discussed. This includes results from SAGE, LIMS and SBUV.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Seasonal and diurnal behavior of NO2 column density in Antarctica as observed by Mark IV,Brewer Ozone Spectrophotometer Number 153

The Meteorology Department of India has been measuring vertical column density of NO₂ at Maitri (70.7°S, 11.7°E), Antarctica since July 1999 using a Mark IV, Brewer Ozone Spectrophotometer. Maitri is situated at the south of the Antarctic circle. An analysis of 6 years of data shows that NO₂ column has seasonal variation with a maximum value during summer. It is also found that during the period when sun does not set, the NO₂ column exhibits a diurnal variation, with a peak around noon and lower values in the morning and afternoon hours. Using a simple steady-state chemical reaction scheme, an attempt has been made to explain these features.