Hydrogen cyanide polymers from the impact of comet P/Shoemaker-Levy 9 on Jupiter.

Hydrogen cyanide polymers--heterogeneous solids ranging in color from yellow to orange to brown to black--may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orange-brown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to alpha-amino acids. Other polymers and multimers with ladder structures derived from HCN would also be present and might well be the source of the many nitrogen heterocycles, adenine included, detected by thermochemolytic analysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter could therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized from freshly formed HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.     

Thermomechanical stresses on comets

Thermal stresses due to temperature differences between the cometary surface and the core have been calculated for different models of cometary nuclei. It is shown, that for comets on P/Halley-type orbits thermomechanical stresses exceed the (cohesive) strength of water ice near to the cometary surface. Consequently, there should be cracks on cometary surfaces. The existence of line structures on the surface of P/Halley, which might be due to thermomechanical cracks, is demonstrated on the basis of VEGA-images from the surface of P/Halley.     

Thermal model and thermo-mechanical stresses in cometary nuclei

Spherically symmetric radial temperature profiles of cometary nuclei have been determined numerically (and for simplified models analytically) in dependence on the orbital position of the periodic comet Halley. These temperature fields in the nucleus are connected with thermal stress fields which have been calculated with the assumption of elastic properties of cometary matter. The remarkable result is the possible existence of stresses, strong enough to cause internal cracking of the nucleus and break-ups of the cometary surface. This may be essential understanding normal cometary activity as well as outbursts and splits.     

Organic analysis of hydrogen cyanide polymers: prebiotic and extraterrestrial chemistry.

Hydrogen cyanide polymerizes readily to a black solid from which a yellow-brown powder can be extracted by water and further hydrolyzed to alpha-amino acids. These macromolecules could be major components of the dark matter observed on many bodies in the outer solar system, including comets and asteroids. Primitive Earth might therefore have been covered with HCN polymers through bolide bombardment or be terrestrial synthesis. Several instrumental methods were used for the separation and identification of these intriguing polymeric materials, including photoacoustic Fourier transform infrared spectroscopy, supercritical fluid extraction chromatography and pyrolysis mass spectrometry. Our integrated analytical approach revealed fragmentation patterns and chemical functionalities consistent with the presence of polymeric peptide precursors both in HCN polymers and in the Murchison meteorite.     

彗星穿越过境对磁层的影响及其分析讨论

对哈雷、百武和海尔-波普三颗慧星在不同时间、不同位置的情况下5次过近地点可能引起对地球磁层影响进行了资料分析和统计研究，指出，根据等离子体彗尾的特征，完全可以对磁层引起扰动，但是这种扰动有严格的制约条件，不是每次彗星过境都很容易对地球电磁环境产生影响。     

Optical observations of ion tail structures and velocity flows in comet Halley during the period of the five spacecraft encounters

Observations of the distribution and evolution of a number of the major constituents of the neutral coma (CN, C₂, CH, O, H, Na) of Comet Halley were made during two observing periods, each of 3 weeks duration, from the Table Mountain Observatory, California. The first period was pre-perihelion, in late November/December 1985. The second period, from Feb 28 to March 22 1986, covered the five close spacecraft encounters with Halley, and when ICE flew some 20 M Km upstream of Halley. Sodium emission was recorded in early Dec 1985 from the near-nuclear region at a heliocentric distance of 1.4 AU, an observation confirmed with the UCL Doppler Imaging system. The CN coma could be detected to an outer diameter of more than 4M Km in Dec 1985, and 5 – 6M Km in early March 1986, allowing the production of heavy cometary pick-up ions to be estimated. Observations of the cometary ion coma (H₂O⁺ and CO⁺ ions) showed considerable variability from day to day, particularly during the period of the spacecraft encounters. These observations have been used, in conjuction with the neutral coma data, to map the flow field of cometary ions. In early Dec. 1985, Halley developed a traditional “type I” ion tail, which persisted until late April 1986. It has also been possible to evaluate the ion flow fields within the narrow core of the ion tail, and in the surrounding diffuse, low density, regions populated by pick-up and extracted cometary ions, and by slowed solar wind ions. Tail disconnection events were observed on several occasions, particularly between the VEGA 2 and GIOTTO encounters, and with a highly spectacular event on March 19 1986.     

Imaging of comet Halley from Catania observatory using a CCD and Schmidt plates

Observations of comet Halley through CCD and Schmidt plates have been performed at Catania Observatory (Italy) from October 1985 through April 1986. Preliminary results are presented concerning the spatial structures for different spectral ranges of cometary light.     

Ion formation by high- and medium-velocities dust impacts from laboratory measurements and Halley results

The ion formation processes by dust impacts have been studied qualitatively as well as quantitatively by dust accelerator laboratory measurements. Iron, carbon and metallized glass particles in the femto- to nano-gram mass range had been impacted on various metal targets in a velocity regime of v = 2 - 64 km/s. In the high velocity regime as relevant for the (retrograde) Halley encounter more than 99% of the ions produced are singly charged atomic, the rest molecular ones. The ion/atom ratios are apparently modified SIMS yields, the modification parameter being impact velocity dependent. A semiempirical formula was deduced for the determination of mass and density of the impacting particle from target and projectile ion yields. When evaluating the Halley encounter results, the elemental distribution of p/Halley dust appeared nearly to be solar; the organic fraction (CHON) could be characterized in a rough manner as fairly unsaturated. Oligomers of the monomers C₂H₂ (65%), CH₂O (25%), and HCN (10%) are probable.

With medium velocities (for prograde comet encounter), i.e. v = 15-30 km/s molecular ion types govern the mass spectra. Consequently, more chemical information of the projectile can be expected in this case, additional to the elemental distribution. Mass and density of the impinging dust particles can be determined as well.     

Radio occultation experiments with Comet Halley

Previous radio occultation investigations on cometary comae and tails have included refraction measurements and intensity scintillations of natural radio sources used to derive the density and structure of the cometary plasma. Significant improvements in the coverage and sensitivity of these measurements will be achieved during the present apparition of Comet Halley. The comet missions GIOTTO and VEGA will also feature passive radio science expeirments designed to measure comet-induced Doppler shifts of the dual-frequency spacecraft signals during Halley flyby. A brief survey of these radio occultation measurement techniques and their application in the specific case of Comet Halley are presented.     

Hydrogen coma of comet P/Halley

The main molecular processes to produce the hydrogen comae of comets are now well known: Water, the main constituent of cometary atmospheres, is photodissociated by the solar ultraviolet radiation to form the high (20 km s⁻¹) and low (8 km s⁻¹) velocity components of the atomic hydrogen. The hydrogen clouds of various fresh comets have been observed in 1216Å by a number of spacecrafts. Ultraviolet observations of short period comets are, however, rather rare. Consequently Comet P/Halley in this apparition is a good object to obtain new physics of the hydrogen coma. Strong breathing of the hydrogen coma of this comet found by “Suisei” provides just such an example. The rotational period of Comet Halley's nucleus, its activity in the form of outbursts alone, and the position of jet sources etc. are determined from the breathing phenomena. Atomic hydrogen from organic compounds with a velocity of 11 km s⁻¹ play an important role in that analysis. The time variations of the water production rate of Comet Halley during this apparition observed by various spacecrafts appear to be in agreement with each other and are about 1.5–2 times larger than the standard model. The difficulty of the calibration problem was emphasized.     

Planet-A mission to Halley

Looking at the chance of the next apparition of the Halley comet in 1986, ISAS decided to send a first Japasanese interplanetary spacecraft for the study of cometary hydrogen coma and solar wind. The Planet-A spacecraft which carries VUV imaging camera and solar wind plasma analyser will be launched in August 1985 and flyby the Halley comet in early March 1986 with the distance of several million kilometers from the comet nucleus. This mission is not only self-consistent but collaborative with other space mission as well as earth-bound observations. In the present paper, the Planet-A mission to Halley is described with brief explanation of the spacecraft.     

Dust optical properties: A comparison between cometary and interplanetary grains

A better understanding of cometary dust optical properties has been derived from extensive observations of comet Halley, complemented by other cometary observations at large phase angles and/or in the infrared. Also, further analysis of IRAS observations and improvements in inversion techniques for zodiacal light have led to some progress in our knowledge of interplanetary dust.

Synthetic curves for phase angle dependence of intensity and polarization are presented, together with typical albedo values. The results obtained for interplanetary dust are quite reminiscent of those found for comets. However, the heterogeneity of the interplanetary dust cloud is demonstrated by the radial dependence of its local polarization and albedo; these parameters are also found to vary with inclination of the dust grains' orbits with respect to the ecliptic. Such results suggest drastic alterations with temperature in the texture of cometary dust, and would favor an important asteroidal component in the zodiacal cloud.     

Mass-spectrometric in situ studies of cometary organics for p/Halley and options for the future.

When the VEGA and GIOTTO spacecrafts flew by comet p/Halley in 1986 the mass-spectrometers Puma and PIA measured the composition of cometary dust particles impacting at speeds of well above 65 km/s. Ion formation upon impact lead to mostly atomic ions. However, a small fraction of the ions measured could be related to molecules. A sophisticated analysis allowed for the first time to point to the chemical nature of cometary organics based on actual mass spectra. With the instrument CoMA for the NASA-BMFT mission CRAF much higher mass-resolution and molecule masses become accessible for in situ measurement, and will yield complementary information to the gas chromatograph CIDEX also onboard CRAF.     

Comet-solar wind interactions: A dusty point of view

Anticipating the new results from the space missions to Comet Halley and Comet Giacobini-Zinner, we make a brief review of recent theoretical and observational studies of dust-plasma environment. In order to relate different disciplines in cometary research in the context of comet-solar wind interaction, two separate issues: (a) surface processes and (b) plasma processes are considered to indicate how various kinds of observations of cometary dust comas and tails may be used to infer the conditions of solar wind - comet interaction and the corresponding plasma processes in the cometary ionospheres and ion tails (and vice-versa). In particular, it is suggested that the narrow sunward-pointing dust streamers emitted from the cometary nuclei could be related to the electrostatic transport of sub-micron dust over the nuclear surfaces at large heliocentric distances; and the striae sometimes observed in cometary dust tails at smaller heliocentric distances could be the consequence of electrostatic fragmentation of fluffy dust particles in the ion tails.     

Cometary ephemerides for spacecraft flyby missions

For spacecraft without on-board navigation capability, their ability to fly close to target comets is limited primarily by the comet's ephemeris uncertainty. Factors contributing to cometary ephemeris uncertainties include measurement errors, star catalog errors, and offsets between the comet's center of mass and its observed center of light. The situation is further complicated by nongravitational forces acting upon a comet's nucleus and the paucity of observers currently making astrometric observations of comets. For comet Halley, the nongravitational forces affecting this comet's motion are consistent with the rocket effect of an outgassing water ice nucleus; the nucleus is apparently rotating in a direct sense about a stable spin axis. Accurate comet Halley ephemerides for close spacecraft flybys will require continued efforts to refine the existing nongravitational force model. In addition, the various flyby missions to comet Halley will require a well organized network of astrometric observers. These observers must rapidly reduce their observations in early 1986, thus allowing continuous updates to the comet's ephemeris just prior to the spacecraft flybys in March 1986.     

Cometary magnetospheres: a tutorial

The nucleus of an active comet, such as comet Halley near its perihelion, produces large quantities of gas and dust. The resulting cometary atmosphere, or coma, extends more than a million kilometers into space, where it interacts with the solar wind. An “induced” cometary magnetosphere is a consequence of this interaction. Cometary ion pick-up and mass loading of the solar wind starts to take place at very large cometocentric distances. Eventually this mass loading leads to the formation of a weak cometary bow shock. Even closer to the nucleus, collisional processes, such as ion-neutral chemistry, become important. Other features of the magnetosphere of an active comet include a magnetic barrier, a magnetotail, and a diamagnetic cavity near the nucleus. X-ray emission from comets is produced by the interaction of the solar wind with cometary neutrals and this topic is also discussed. A broad review of the cometary magnetosphere will be given in this paper.     

Physical properties of dust grains deduced by optical probing techniques

In-situ space observations of dust in the solar system are seldom possible. On the opposite, remote observations of solar light scattered by dust are relatively easy to perform from Earth- or satellite-based observatories; the evolution of the polarization of light scattered by dust particles as a function of the phase angle may provide information on the physical properties of these particles. Unfortunately, since remote observations are integrated along the line-of-sight of the observer, they can hardly be used to determine local physical properties. We have precisely developed Optical Probe techniques to forge the link between the numerous remote observations and the unique in-situ measurements. A short review of the remote observations of light scattered by cometary dust is first presented. Then, the Optical Probe concept is analyzed. Finally, the OPE instrument, which had been designed to optically probe the inner coma of comet Halley is described; its limitations and its achievements during Halley and Grigg-Skjellerup encounters are discussed.     

Solar wind interaction with comet Halley

In March 6 and 9, 1986 the spacecrafts ‘Vega-1’ and ‘Vega-2’ have flown through the coma of comet Halley and have carried measurements of plasma, energetic particles, magnetic field and plasma waves along its trajectory. A short review of these measurements and its comparison with theoretical models of solar wind interaction with comets are given.

The spacecrafts ‘Vega-1’ and ‘Vega-2’ have studied the solar wind loading by cometary ions, the structure of cometary bow shock and the processes in the inner coma of comet Halley. Exactly in this sequence we discuss the results of measurements and compare them with the theory.     

Modelling the neutral gas environment of comets with special application to P/Halley

A technique has been developed which allows relatively accurate modelling of cometary gas production from nothing more than a visible light curve. Application to P/Halley suggests the production rate of parent molecules will be about 2.6 × 10²⁹ per second on March 10, 1986, for example. The uncertainties and intrinsic limitations in this approach are outlined. The theory is then extended to predictions of abundance of other gaseous species, and a photometric model of these gases provided. Combined with the dust model of N. Divine, preliminary predictions of the luminance of P/Halley as seen in any direction from inside the coma or outside can be provided for λλ3000–7000.     

Trapping of gases by water ice and implications for icy bodies.

The trapping of various gases by water ice at low temperatures (20-80K) and their release from the ice upon warming, was studied experimentally. The results of these experiments, together with a computation of the thermal evolution of a cometary nucleus, can explain the gas and dust jets which were observed to emanate from the nucleus of P/Halley. The experimental results are important also to the gas content of Titan.