Core Formation and Mantle Differentiation on Mars

Geochemical investigation of Martian meteorites (SNC meteorites) yields important constraints on the chemical and geodynamical evolution of Mars. These samples may not be representative of the whole of Mars; however, they provide constraints on the early differentiation processes on Mars. The bulk composition of Martian samples implies the presence of a metallic core that formed concurrently as the planet accreted. The strong depletion of highly siderophile elements in the Martian mantle is only possible if Mars had a large scale magma ocean early in its history allowing efficient separation of a metallic melt from molten silicate. The solidification of the magma ocean created chemical heterogeneities whose ancient origin is manifested in the heterogeneous ¹⁴²Nd and ¹⁸²W abundances observed in different meteorite groups derived from Mars. The isotope anomalies measured in SNC meteorites imply major chemical fractionation within the Martian mantle during the life time of the short-lived isotopes ¹⁴⁶Sm and ¹⁸²Hf. The Hf-W data are consistent with very rapid accretion of Mars within a few million years or, alternatively, a more protracted accretion history involving several large impacts and incomplete metal-silicate equilibration during core formation. In contrast to Earth early-formed chemical heterogeneities are still preserved on Mars, albeit slightly modified by mixing processes. The preservation of such ancient chemical differences is only possible if Mars did not undergo efficient whole mantle convection or vigorous plate tectonic style processes after the first few tens of millions of years of its history.     

Chronology of SNC meteorites

In this paper a model is presented for the geochemical evolution of Mars which is constrained by the isotope systematics of Pb, Nd, and Sr determined for SNC meteorites (SNCs). The young magmatic crystallization ages (internal or mineral ages) of SNCs may indicate that these meteorites indeed stem from Mars. Internal ages and U-Pb and Pb-Pb systematics strongly suggest that they are the result of two magmatic processes. In addition, shock metamorphism is implied from observed petrographic shock features. For ALHA 77009 a shock-age < 15 Ma is obtained which is within uncertainty identical to the independently determined cosmic ray exposure age. It is therefore plausible that shock and exposure ages are identical for all SNCs. The Rb/Sr data of all common (non-SNC) meteorites form a 4.55 Ga isochron as do the Pb-Pb data (geochron). The SNC data fall close to these two isochrons. The Sr and Pb isotopic compositions in SNCs suggest that they formed in a recent (1.3-0.15 Ga) melting event from reservoirs which had been magmatically differentiated 4.3 ± 0.2 Ga ago. In a concordia diagram (U-Pb evolution plot) the SNC data reflect recent increase of the U/Pb ratio and the same two stage magmatic history as suggested by the other isotopic systems. The oxygen isotopic composition as well as the Nd isotopic systematics strongly suggest that the SNCs stem from one common reservoir which chemically differentiated 4.3 ± 0.2 Ga ago and then formed sub-reservoirs. In contrast to common meteorites, SNCs experienced an early magmatic differentiation where the Sm/Nd, U/Pb and Rb/Sr ratios have been strongly fractionated. In the recent magmatic process (1.3-0.15 Ga ago), in which the SNCs were formed as rocks, Sm/Nd and U/Pb were fractionated, while Rb/Sr remained similar to that of the source from which the magmas originated. During these melting events, mixing of components from different sub-reservoirs might have had occurred. At least three subreservoirs are necessary to explain the isotopic variations observed in SNCs. In contrast to the isotopic evolution of the Earth, Mars conserved remnants of the primary differentiation, a fact, which places important constraints on the tectonic evolution of Mars.     

The carbonaceous chondrites

The carbonaceous chondrites are a group of stony meteorites characterized by the presence of an appreciable amount of carbonaceous material other than free carbon (diamond and graphite). They have been divided into three subgroups known respectively as Type I, Type II, and Type III. Analyses of Type I meteorites show about 3–5% of carbon and 20% of combined water; they consist largely of hydrated magnesium-iron silicate, magnetite, and magnesium sulfate, contain no chondrules, and have a density about 2.2. Analyses of Type II meteorites show about 2–3% of carbon and 10–15% of combined water; they consist of a groundmass of hydrated magnesium-iron silicate enclosing chondrules of olivine and pyroxene which are almost iron-free, and have a density of 2.6–2.9. Analyses of Type III meteorites show about 0.5–2% of carbon and 2% combined water; they consist largely of olivine (often variable in composition, but averaging 30–40 mole per cent Fe₂SiO₄), with accessory pigeonite and sulfide minerals, and have a density about 3.4.The carbonaceous material and combined water in these meteorites are clearly of extraterrestrial origin, but their significance is not well understood. A biological origin has been claimed for some of the organic compounds on the basis of their composition, but this claim is the subject of considerable dispute. Microscopic objects with regular outline (organized elements) have been recognized in some of these meteorites; some investigators have claimed these to be extraterrestrial fossils, others have ascribed them to terrestrial contamination or considered them to be crystals or crystal aggregates of non-biological origin.     

Elemental and Isotopic Abundances of Carbon and Nitrogen in Meteorites

We have taken an inventory of the elemental and isotopic abundances of major carbon- and nitrogen-bearing components in different groups of meteorites. Primary phases, inherited from the solar nebula, are frequently isotopically heterogeneous, and surprisingly resistant to modification through parent body processing. Even melted and recrystallised meteorites retain primordial carbon and nitrogen isotopic signatures. This revised version was published online in August 2006 with corrections to the Cover Date.     

Long-Term Evolution of the Martian Crust-Mantle System

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K?Gyr^?1 were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K?Gyr^?1. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet’s initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (H₂O, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two.     

Hydrocarbons in terrestrial samples and the Orgueil meteorite

Meteorites contain extraterrestrial carbonaceous materials. The Alais, Orgueil, Tonk, and Ivuna meteorites resemble in their carbon, free sulfur, and non-metamorphosed mineral contents, densities, and general appearances certain organic-rich terrestrial sediments. Structural and isotopic determinations of carbon compounds in the Orgueil chondrite indicate that these compounds are primarily indigenous. Physically and chemically the benzene extractable carbonaceous materials from the Orgueil and certain near-surface terrestrial sediments are similar. Mass spectrometric type analyses of the alkanes from an Orgueil fragment, terrestrial sediments and organisms are statistically indistinguishable at the 95 per cent confidence level. Theoretical considerations and experimental data are presented, and these permit an assessment of the potential and reliability of hydrocarbons as biological indicators. Based on the production and preservation or organic substances in terrestrial environments, alkanes in the Alais, Orgueil, Tonk, and Ivuna (Type I) carbonaceous chondrites could retain the best evidence of organisms that may have lived on a parent body of meteorites.A portion of the research reported in this article was supported by the National Aeronautics and Space Administration under Contract No. NASw 508.     

Organic matter in meteorites and comets: Possible origins

At least 6 extraterrestrial environments may have contributed organic compounds to meteorites and comets: solar nebula, giant-planet subnebulae, asteroid interiors containing liquid water, carbon star atmospheres, and diffuse or dark interstellar clouds. The record in meteorites is partly obscured by pervasive reheating that transformed much of the organic matter to kerogen; nonetheless, it seems that all 6 formation sites contributed. For comets, the large abundance of HCHO, HCN, and unsaturated hydrocarbons suggests an interstellar component of 50%, but the contributions of various interstellar processes, and of a solar-nebula component, are hard to quantify. A research program is outlined that may help reduce these uncertainties.     

Isotopic Criteria for Identification of Organic Carbon on Earth and Meteorites

Contrary to the often stated view, an enrichment of organic material in the light isotope is not a conclusive evidence of its life-related origin. The β¹³C - σ¹³C correlation is a special feature of biological systems. Therefore it can be used as a criterion for identification of organic carbon. A survey of the available isotopic data for organic compounds in meteorites shows that they do not comply with the β¹³C - σ¹³C correlation. The prevalence of amino and hydroxy acids in purines and sugars found in carbonaceous meteorites indicates that condensation of HCN and HCHO passed through cyanohydrin reaction, while biological evolution proceeds through formation of adenosine triphosphate (ATP). This, in addition to the isotope criterion, indicates that the organic compounds in carbonaceous chondrites are not life-related substances. This revised version was published online in August 2006 with corrections to the Cover Date.     

Origin,age, and composition of meteorites

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites.The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstätten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstätten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe₄C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four.The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. Hybrid meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt.Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one.The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body.As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with 10¹⁷ protons/cm² at a very early stage of its history.There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Öpik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites.The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km).Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.     

Planetary Atmospheres

The predominance of nitrogen in highly volatile forms and of carbon in solids set the abundance ratios of these elements in the inner planets, meteorites and comets. The absence of carbon compounds in an atmosphere then signals large deposits of carbon-bearing compounds in surface and/or subsurface deposits. In contrast, the icy planetesimals that contributed heavy elements to Jupiter must have had identical enrichments (relative to hydrogen) of both C and N, as well as other heavy elements that have been measured, compared to solar values. Capture of N and Ar suggests that the icy planetesimals that carried these elements must have formed at low temperatures, <40 K. New measurements of isotopes of nitrogen support this picture, but we must have more measurements in more atmospheres to be certain of this scenario.     

On the Isotopic Composition of Primordial Xenon in Terrestrial Planet Atmospheres

Xenon plays a crucial role in models of atmospheric evolution in which noble gases are fractionated from their initial compositions to isotopically heavier distributions by early hydrodynamic escape of primordial planetary atmospheres. With the assumption that nonradiogenic Xe isotope ratios in present-day atmospheres were generated in this way, backward modeling from these ratios through the fractionating process can in principle identify likely parental Xe compositions and thus the probable sources of noble gases in pre-escape atmospheres. Applied to Earth, this approach simultaneously establishes the presence of an atmospheric Xe component due principally to fission of extinct ²⁴⁴Pu and identifies a composition called U-Xe as primordial Xe. Pu-Xe comprises 4.65±0.30% of atmospheric ¹³⁶Xe, and 6.8±0.5% of the present abundance of ¹²⁹Xe derives from decay of extinct ¹²⁹I. U-Xe is identical to the measured composition of solar-wind Xe except for deficits of the two heaviest isotopes – an unexpected difference since the modeling otherwise points to solar wind compositions for the lighter noble gases in the primordial terrestrial atmosphere. Evidence for the presence of U-Xe is not restricted to the early Earth; modeling based on a purely meteoritic data set defines a parental component in chondrites and achondrites with the same isotopic distribution. Results of experimental efforts to measure this composition directly in meteorites are promising but not yet conclusive. U-Xe also appears as a possible base component in interstellar silicon carbide, here with superimposed excesses of ¹³⁴Xe and ¹³⁶Xe six-fold larger than those in the solar wind. These compositional differences imply mixing of U-Xe with a nucleogenetic heavy-isotope component whose relative abundance in the solar accretion disk and in pre-solar environments varied both spatially and temporally. In contrast to Earth, the U-Xe signature on Mars was apparently overwhelmed by local accretion of materials rich in either chondritic Xe or solar-wind Xe. Data currently in hand from SNC meteorites on the composition of the present atmosphere are insufficiently precise to constrain a modeling choice between these two candidates for primordial martian Xe. They likewise do not permit definitive resolution of a ²⁴⁴Pu component in the atmosphere although its presence is allowed within current measurement uncertainties. This revised version was published online in June 2006 with corrections to the Cover Date.     

Organic constituents of the carbonaceous chondrites

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers.Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded that most of the organic constituents are indigenous to the meteorites and are extra terrestial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin.A brief review on studies of organized elements contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some micro-structures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.Contribution from the Chemistry Section, Space Science Division of Jet Propulsion Laboratory.     

On The 53Mn Heterogeneity In The Early Solar System

It is well established that the prolonged and thorough mixing of numerous nucleosynthetic components that constitutes the matter in the solar nebula resulted in an essential isotopic homogeneity of the solar system material. This may or may not be true for the short-lived radionuclides which were injected into or formed within the solar nebula just prior to or during solar system formation. Distinguishing between their heterogeneous or homogeneous distribution is important because the short- lived radionuclides are now widely used for the relative chronology of various objects and processes in the early solar system and as constraints for models of nucleosynthesis. The recent studies of the ⁵³Mn-⁵³Cr isotope system (half life of ⁵³Mn is 3.7 Ma) in various solar system objects have shown that the relative abundance of radiogenic ⁵³Cr is consistent with essentially homogeneous distribution of ⁵³Mn in the asteroid belt. Thus, the relative ⁵³Mn-⁵³Cr chronometer can be directly used for dating samples which originated in the asteroid belt. Importantly, however, all meteorite groups studied so far indicate a clear excess of ⁵³Cr as compared to Earth and to a lunar sample, which exhibits also a terrestrial ⁵³Cr/⁵²Cr ratio. The results from the Martian (SNC) meteorites show that their ⁵³Cr excesses are less than half of those found in the asteroid belt bodies. Thus, the characteristic ⁵³Cr/⁵²Cr ratio of Mars is intermediate between that of the Earth-Moon system and those of the other meteorites. If these ⁵³Cr variations are viewed as a function of the heliocentric distance, the radial dependence of the relative abundances of radiogenic ⁵³Cr is indicated. This observed gradient can be explained by either an early, volatility controlled, Mn/Cr fractionation within the nebula or by an initial radial heterogeneous distribution of ⁵³Mn. Although model calculations of the Mn/Cr ratios in the bulk terrestrial planets seem to be inconsistent with the volatility driven scenario, the precision of these calculations is inadequate for eliminating this possibility. In contrast, recent studies of the ⁵³Mn-⁵³Cr system in the enstatite chondrites indicate that, while their bulk Mn/Cr ratios are essentially the same as in ordinary chondrites, the ⁵³Cr excess in bulk enstatite chondrites is three times lower than that in the bulk ordinary chondrites. This difference cannot be explained by a Mn/Cr fractionation and, thus, strongly suggests that a radial heterogeneous distribution of ⁵³Mn must have existed in at least the early inner solar system. Using the observed gradient and the ⁵³Cr/⁵²Cr ratio of the bulk enstatite chondrites, their parent body(ies) formed at ∼1.4 AU or somewhat closer to the Sun. This revised version was published online in June 2006 with corrections to the Cover Date.     

Protostellar Winds and Chondritic Meteorites

We discuss the interaction between the magnetosphere of a young star and its surrounding accretion disk. We consider how an X-wind can be driven magnetocentrifugally from the inner edge of the disk where accreting gas is diverted onto stellar field lines either to flow onto the Sun or to be flung outwards with the wind. The X-wind satisfies many observational tests concerning optical jets, Herbig-Haro objects, and molecular outflows. Connections may exist between primitive solar system materials and X-winds. Chondrules and calcium-aluminum-rich inclusions (CAIs) experienced short melting events uncharacteristic of the asteroid belt where meteorites originate. The inner edge of the solar nebula has the shortest orbital timescale available to the system, a few days. Protosolar flares introduce another timescale, tens of minutes to hours. CAIs may form when solids are lifted from shaded portions of the disk close to the Sun and are exposed to its intense light for a day or so before they are flung by the X-wind to much larger distances. Chondrules were melted, perhaps many times, by flares at larger distances from the Sun before being launched and annealed, but not remelted, in the X-wind. Aerodynamic sorting explains the narrow range of sizes with which CAIs and chondrules are found in chondritic meteorites. Flare-generated cosmic-rays may induce spallation reactions that produce some of the short-lived radioactivities associated with primitive solar system rocks. This revised version was published online in June 2006 with corrections to the Cover Date.     

Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Paleomagnetic Records of Meteorites and Early Planetesimal Differentiation

The large-scale compositional structures of planets are primarily established during early global differentiation. Advances in analytical geochemistry, the increasing diversity of extraterrestrial samples, and new paleomagnetic data are driving major changes in our understanding of the nature and timing of these early melting processes. In particular, paleomagnetic studies of chondritic and small-body achondritic meteorites have revealed a diversity of magnetic field records. New, more sensitive and highly automated paleomagnetic instrumentation and an improved understanding of meteorite magnetic properties and the effects of shock, weathering, and other secondary processes are permitting primary and secondary magnetization components to be distinguished with increasing confidence. New constraints on the post-accretional histories of meteorite parent bodies now suggest that, contrary to early expectations, few if any meteorites have been definitively shown to retain records of early solar and protoplanetary nebula magnetic fields. However, recent studies of pristine samples coupled with new theoretical insights into the possibility of dynamo generation on small bodies indicate that some meteorites retain records of internally generated fields. These results indicate that some planetesimals formed metallic cores and early dynamos within just a few million years of solar system formation.     

Gas-rich meteorites: Probes for particle environment and dynamical processes in the inner solar system

The discovery in the early sixties of precompaction solar wind irradiation records in the gas-rich meteorites opened up the possibility of studying the solar activity at different epochs in the distant past. Subsequent studies in several meteorites have led to the discovery of the precompaction records of irradiation of constituent grains by solar wind, solar flare and galactic cosmic ray particles. There are also microcraters resulting from their collisions with interplanetary dust grains. Analyses of these records and their observed similarity with those found in the lunar samples led to the hypothesis that the precompaction records in individual components of these meteorites were imprinted while they were residing in the near surface region of their parent bodies, most probably the asteroids. Although the asteroids are the most plausible candidates for the parent bodies of gas-rich meteorites, there exist certain dynamical arguments which tend to favor a cometary origin in certain cases. Also, recent studies indicate that in the case of gas-rich carbonaceous chondrites solar flare irradiation of grains may have occurred prior to formation of the parent bodies.In this review we summarize the significant advances that have taken place in the multi-disciplinary studies (petrography, chemistry, and radiation effects) of the gas-rich meteorites and critically evaluate the present state of our knowledge regarding the origin and evolution of the gas-rich meteorites. The information on the spatial and temporal variations in the interplanetary radiation and particle fluxes, obtained from the analysis of precompaction irradiation records in these meteorites is presented and further studies in certain specific topics are suggested for resolving some of the unsolved problems.     

The Origin and Evolution of the Asteroid Belt��Implications for Vesta and Ceres

Vesta and Ceres are the largest members of the asteroid belt, surviving from the earliest phases of Solar System history. They formed at a time when the asteroid belt was much more massive than it is today and were witness to its dramatic evolution, where planetary embryos were formed and lost, where the collisional environment shifted from accretional to destructive, and where the current size distribution of asteroids was sculpted by mutual collisions and most of the asteroids originally present were lost by dynamical processes. Since these early times, the environment of the asteroid belt has become relatively quiescent, though over the long history of the Solar System the surfaces of Vesta and Ceres continue to record and be influenced by impacts, most notably the south polar cratering event on Vesta. As a consequence of such impacts, Vesta has contributed a significant family of asteroids to the main belt, which is the likely source of the HED meteorites on Earth. No similar contribution to the main belt (or meteorites) is evident for Ceres. Through studies of craters, the surfaces of these asteroids will offer an opportunity for Dawn to probe the modern population of small asteroids in a size regime not directly observable from Earth.     

Are There Chemical Gradients in the Inner Solar System?

The solar system is apparently stratified with regard to the contents of volatile constituents, as judged from the rocky, volatile-poor inner solar system planets and meteorites and the huge volatile-rich outer planets. However, beyond this gross structure there is no evidence for a systematic increase of the volatiles' abundances with distance from the Sun. Although meteorites show comparatively large differences in volatile element contents they also differ in many other respects, such as Mg/Si-ratios, bulk Fe and refractory element contents. These variations reflect variations in the nebular environment from which meteorites formed. The various conditions of meteorite formation cannot, however, be related in a simple way to heliocentric distances. There are also no systematic variations in the chemistry of the inner planets Mercury, Venus, Earth, Moon, Mars, and including the fourth largest asteroid Vesta, that could be interpreted as a relationship between volatility and composition. Although Mars (as judged from the composition of Martian meteorites) is more oxidized and contains more volatile elements than Earth, this trend cannot be extrapolated to the dry volatile poor Vesta (sampled by HED meteorites) in the asteroid belt. If the Earth-Mars trend reflects global inner solar system gradients then Vesta must have formed inside Earth's orbit and moved out later to its present location. The quality of Mercury and Venus composition data is not sufficient to allow reliable extrapolation to distances closer to the Sun. Recent nebula models predict small temperature gradients in the inner solar system supporting the view that no large variations in volatile element contents of inner solar system materials are expected. This revised version was published online in June 2006 with corrections to the Cover Date.     

Ureilites

Ureilites are a rare group of five stony meteorites — feldsparless achondrites containing diamonds of preterrestrial origin the total weight of them being 315 carats. The whole carbon content in ureilites makes up 1.5–4.1%. Ureilites substantially differ from the other stony meteorites. In comparison with chondrites they are enriched in Mg but depleted in metal, troilite, alkaline elements. All ureilites are very similar by their structure. They contain elongated cavities generally stretched in the same direction. The structure of ureilites is an achondritic porphyric one. These meteorites consist of large olivine grains, there is less clinopyroxene (pigeonite). They contain kamacite (Ni content being 1.5–4%), troilite FeS, chromite. Carbon material is represented by diamond, graphite and organic material being present in a disequilibrium state. Two ureilites (North Haig and Dingo Pup Donga) were considerably oxidized during terrestrial weathering and contain secondary iron oxides.Diamonds are present in ureilites in thin intergrowths with graphite being disposed between silicate grains more or less evenly in the meteorite. The sizes of such black diamond-graphite aggregates are 0.3–0.9 mm. The sizes of the micromonocrystals of diamond and graphite are less than 1. The diamond-graphite aggregates contain dispersed particles of kamacite, troilite, chromite, nickelchrome, being present in very thin intergrowths with one another. Besides the usual diamond there is an admixture of lonsdaleite in the aggregates representing a hexagonal diamond with a würtzite-like structure. Lonsdaleite has been identified in the ureilites Novo Urei, Goalpara, North Haig. The diamonds of ureilites are characterized by inhomogeneities in the crystalline structure which are at least partly caused by the presence of donor nitrogen. According to the isotopic carbon composition the diamond in the meteorite Novo Urei has the value C¹³ = -5.7.The structure peculiarities of ureilites bear witness of the fact that these meteorites had been subject to the action of dynamic pressure about 300–600 kbar. The impact had taken place in cosmic space. All ureilites subdivide into two types: the first type are Novo Urei, Dyalpur, Dingo Pup Donga, the second type are Goalpara, North Haig according to the following signs: (1) olivine grains are finer in ureilites of the second type; (2) twinning is more typical of clinopyroxenes of ureilites belonging to the first type; (3) in ureilites of the first type a net-like iron distribution is observed, in ureilites of the second type kamacite plates are chiefly present between silicate grains; (4) the size of diamondgraphite intergrowths in ureilites of the first type does not exceed 0.3 mm, in ureilites of the second type it reaches 0.9 mm. Ureilites of the first type have undergone a less intensive impact than ureilites of the second type. Certain similarity of the material composition of ureilites and of the material composition of carbonaceous chondrites, the distinction of these two groups of meteorites from all other meteorites bear witness of the fact that ureilites have formed from carbonaceous chondrites during a collision of asteroid bodies in cosmic space, diamonds having been formed from the carbon material of carbonaceous chondrites.