新型聚苯并噁嗪改性树脂的制备与性能

通过预聚反应制备了一种新型聚苯并噁嗪改性树脂.利用FTIR、GPC表征了改性树脂.利用旋转黏度计、DSC、DMA和TGA分别考察了树脂的流动性能、固化行为和改性树脂固化物的热性能.结果表明:制备的苯并噁嗪改性树脂在60～ 100℃,黏度小于500 mPa·s,恒温6h黏度不明显增大,具有良好的流动性能,适用于RTM成型工艺.改性树脂聚合温度较低,具有良好的固化工艺性.改性树脂固化物在氮气气氛下Td5在430℃以上,在900℃的残重高达73.71％,Ts为353.4℃,具有良好热性能.     

苯并噁嗪杂化树脂及其复合材料的制备与性能

为提高苯并噁嗪(BZ)的热稳定性,通过BZ 与聚硅氮烷制备了一种苯并噁嗪杂化树脂(BZ-H),
并采用模压工艺制备了玻璃布/ BZ-H 复合材料。制备的BZ-H 树脂在70 ~170℃有较低的黏度和聚合温度、
较少的放热量及良好的固化工艺性。其固化物的Tg 为354. 7℃。在N2 气氛下,T5
d 为460℃,900℃ 的残重
(W900℃ )为75. 68%。在空气气氛下, T5
d 为466℃,W900℃ 为16. 39%。玻璃布/ BZ-H 复合材料在室温下的弯曲
强度、模量和层间剪切强度分别为433 MPa、22 GPa 和24 MPa,在350℃下的保留率分别为40%、68%和54%。
SEM 微观形貌观察表明,BZ-H 树脂与纤维间具有良好的粘接作用,该特征赋予了复合材料优良的力学性能。     

可溶性改性双马来酰亚胺树脂基体的研究

在双马来酰亚胺/二元胺/改性剂A预聚体系中加入环氧丙烯酸树脂,制备了一种可用作耐热复合材料基体的改性双马来酰亚胺树脂。用DSC研究了该树脂基体的反应特性,并制定出了合适的固化工艺参数:改性树脂基体经140℃/1 h 160℃/1 h 180℃/2 h初固化,于220℃/8 h后固化处理,其热变形温度(HDT)为245℃;该树脂与玻璃纤维制备的单向复合材料层压板的室温拉伸强度、弯曲强度和层间剪切强度分别为1 030 MPa、1 600 MPa和92．1 MPa;180℃下测得弯曲强度保持率为67．8%,层间剪切强度保持率为63．2%,用DMA法测得T_g为273℃。     

空间光学结构用改性氰酸酯树脂及其复合材料性能

以空间光学结构应用为背景,对新研制改性氰酸酯树脂低温固化体系开展评价研究,包括树脂体系的固化特性、力学性能、耐湿热性以及工艺性能等;与HS40高模量碳纤维复合制备了复合材料,对其主要力学性能进行了研究。结果表明,改性氰酸酯树脂催化体系具有优异的固化反应特性,起始固化温度为101.2℃,较未催化的氰酸酯树脂降低了97.4℃;拉伸性能以及弯曲性能均有提高,同时其沸水饱和吸水率仅1.3%左右,明显低于双马（4%）和环氧树脂（5.8%）;树脂的工艺性良好,适合热熔法制备预浸料;应用热熔浸渍法制备的HS40碳纤维/氰酸酯树脂预浸料经层合固化后力学性能优异：纵向拉伸强度和模量分别为2 244.5 MPa和248.0 GPa。     

邻苯二甲腈基联苯型酚醛树脂的制备与性能

以碱为催化剂,通过联苯型酚醛树脂与4-硝基邻苯二甲腈之间的亲核取代反应,制备了邻苯二甲腈基联苯型酚醛树脂(PBN).流变性能测试结果表明,PBN树脂在180 ～ 300℃,黏度＜400 mPa·s,表明该树脂具有优良的加工性能.DSC测试结果表明,PBN树脂的固化温度为280～450℃,固化反应峰值温度为377℃,固化放热约为187 J/g.该树脂表现出优良的耐热性,其储能模量起始下降温度高于450℃,Td5约为529℃,氮气氛围、900℃残碳率约为78％.     

TiO2-SiO2复合薄膜亲水性能研究

采用溶胶一凝胶法,钛酸丁酯和正硅酸乙酯为前驱体,在玻璃载体上制备了具有光致亲水性能的复合型TiO2-S iO2薄膜。研究了试剂配比、试剂加入方式、凝胶时间、镀膜速度、焙烧升温速度等对薄膜性能的影响。通过对试剂配比和工艺参数的优化,提高了复合薄膜的亲水性能。     

一种低摩擦系数复合润滑膜的结构与性能研究

采用微弧氧化和喷涂二硫化钼基润滑材料并在150 ～200℃固化2h左右的工艺,在铝合金表面制备了低摩擦系数的复合润滑膜.研究了复合润滑膜的结构与性能对摩擦系数的影响.结果表明,去除微弧氧化膜的表面疏松层获得以γ-Al2O3为主的致密硬化层,使其表面硬度明显提高,并且显著降低复合润滑膜的摩擦系数.微弧氧化层的硬度与载荷大...     

苯并噁嗪/ BMI/ 环氧树脂的固化动力学

制备了苯并噁嗪树脂/BMI/环氧树脂三元体系,采用动态DSC分析了三元体系的固化反应过程。并用Kissinger和Ozawa方法分别求得三元体系的反应活化能为89.5 kJ/mol。由Crane理论计算得到该体系的固化反应级数n=0.93级反应;根据计算的动力学参数,建立了三元体系的固化动力学模型。利用所建立的固化动力学模型分别预测了等温和动态条件下,三元体系的固化反应特性。得到了三元体系的固化工艺为180℃/1 h+200℃/2 h+230℃/2 h,后处理工艺为250℃/2 h。     

RTM 用R801 树脂工艺及性能

对一种新型RTM用双马来酰亚胺树脂R801的固化反应特性、成型工艺及其制备的复合材料性能进行了研究,DSC曲线表明该树脂体系的固化温度为170～220℃;黏度随温度变化曲线表明在70～120℃,树脂黏度增长缓慢,具有不少于7 h的适用期;在90℃左右时,其初始黏度<100 mPa.s,工艺操作窗口时间≥10 h;该树脂制备的MT300碳纤维复合材料在300℃时的压缩、弯曲、层剪性能保持率均≥63%。     

低频振动对超疏水电热除冰方法的增益效果探究

飞机结冰会给飞行安全带来严重损害。针对除冰问题,本文提出了一种超疏水电热低频振动复合式除冰方案。通过热压合工艺制备了电热薄膜,以喷涂方式在薄膜上制备了超疏水表面,并在超疏水电热薄膜的基础上复合低频振动器件,完成了超疏水电热低频振动复合除冰装置的设计制备,同时进行了冰风洞验证试验。结果表明,超疏水电热低频振动复合方法能有效除冰。对试验结果进行了理论分析,认为微小功率的低频振动产生的机械剪切作用是促使冰脱落的主要原因。低频振动的添加对超疏水电热复合除冰方案有显著增益效果,在飞机除冰领域有一定的实际应用潜力。     

有翼高超声速再入飞行器气动设计难点问题

有翼高超声速再入飞行器是近年来的研究热点,气动设计是飞行器设计的关键。为了更清楚地认识有翼高超声速再入飞行器气动设计的难点问题,对有翼高超声速再入飞行器的发展、优势及总体任务剖面进行了介绍,从5个方面详细介绍了该类飞行器气动设计的难点问题,包括多约束复杂面对称气动布局设计、高温真实气体效应对气动特性影响、天地差异与天地换算方法、反作用控制系统(RCS)喷流干扰对气动特性的影响以及气动数据不确定度等,简要阐明了这些难点问题对总体设计的重要性以及初步的解决思路,为有翼高超声速再入飞行器气动设计提供了一些参考。     

Simulation and Analysis of Crashworthiness of Fuel Tank for Helicopters

Crashworthiness requirement of fuel tanks is one of the important requirements in helicopter designs. The relations among the protection frame, textile layer and rubber layer of the fuel tank are introduced. Two appropriate FE models are established, one is for an uncovered helicopter fuel tank without protection frame, and the other is for fuel tank with protection frame. The dynamic responses of the two types of fuel tanks impinging on the ground with velocities of 17.3 m/s are numerically simulated for the purpose of analyzing energy-absorbing capabilities of the textile layer and protection frame. The feasibility of the current crashworthiness design of the fuel tank is examined though comparing the dynamic response behaviors of the two fuel tanks.     

The effect of inlet conditions on the flow and heat transfer in multiple rotating cavity with axial throughflow

This paper discusses experimental results from two different build configurations of a heated multiple rotating cavity test rig.Measurements of heat transfer from the discs and tangential velocities are presented.The test rig is a 70% full scale version of a high pressure compressor stack of an axial gas turbine engine.Of particular interest are the internal cylindrical cavities formed by adjacent discs and the interaction of these with a central axial throughflow of cooling air.Tests were carried out for a range of non-dimensional parameters representative of high pressure compressor internal air system flows(Re up to 5×106 and Rez up to 2×105).Two different builds have been tested.The most significant difference between these two build configurations is the size of the annular gap between the(non-rotating) drive shaft and the bores of the discs.The heat transfer data were obtained from thermocouple measurements of surface temperature and a conduction solution method.The velocity measurements were made using a two component,LDA system.The heat transfer results from the discs show differences between the two builds.This is attributed to the wider annular gap allowing more of the throughflow to penetrate into the cavity.There are also significant differences between the radial distributions of tangential velocity in the two builds of the test rig.For the narrow annular gap,there is an increase of non-dimensional tangential velocity V/Ωr with radial location to solid body rotation V/Ωr=1.For the wider annular gap,the non-dimensional velocities show a decrease with radial location to solid body rotation.      

突破技术趋同，波音再现竞争优势

 波音公司面临着来自空客公司的巨大挑战,企业战略性创新才是公司成功的关键。为此波音公司的全部战略性研究集中在扩大产品的差异性上,体现在3个方面：电子化（e-Enabled）运营环境、整体复合材料机身部件的制造技术和支持波音787客机的全球协同环境（GCE）。     

临近空间飞行器测控与信息传输系统频段选择

 临近空间飞行器是高性能信息化武器平台,测控（TT&;C）与信息传输系统是其信息保障的核心,而选择合理、可行的频段是展开系统设计的前提和基础。频段选择影响到整个技术方案的制定,是一个需综合考虑、影响深远并具有战略意义的关键问题,从国际电联（ITU）国际标准、高速数传、接收信噪比（SNR）、“三抗”、超视距中继、黑障、雨衰以及设备研制成熟度8个方面全面、细致论证了近空间平台测控系统的频段选择问题,最终得出在视距链路中以Ka频段为宜,在超视距链路中以Ku/Ka双频段为宜的结论。     

基于弯曲激波压缩系统的高超声速进气道反设计研究进展

总结了近十年来弯曲激波压缩研究的主要成果。提出了弯曲激波压缩系统的新概念,即利用特殊设计的楔形弯曲压缩面或空间弯曲压缩面,产生一系列与前缘弱激波相互交汇或叠加的压缩波系,从而使前缘激波弯曲,形成特殊的弯曲激波,它与波后的等熵压缩波来共同完成对气流的压缩。在此基础上,实现了由给定出口气动参数的超声速内流道反设计,实现了由给定压缩面压力分布和给定压缩面马赫数分布要求的型面反设计,实现了由给定激波波面的压缩型面反设计。研究证明,弯曲压缩面-弯曲激波压缩系统具有良好的综合气动性能,为高性能高超声速进气系统的气动设计提供了一种全新的设计方法。     

Experimental Study on Effects of Fuel Injection on Scramjet Combustor Performance

In order to investigate the effects of fuel injection distribution on the scramjet combustor performance, there are conducted three sets of test on a hydrocarbon fueled direct-connect scramjet test facility. The results of Test A, whose fuel injection is carried out with injectors located on the top-wall and the bottom-wall, show that the fuel injection with an appropriate close-front and centralized distribution would be of much help to optimize combustor performances. The results of Test B, whose fuel injection is performed at the optimal injection locations found in Test A, with a given equivalence ratio and different injection proportions for each injector, show that this injection mode is of little benefit to improve combustor performances. The results of Test C with a circumferential fuel injection distribution displaies the possibility of ameliorating combustor performance. By analyzing the effects of injection location parameters on combustor performances on the base of the data of Test C, it is clear that the injector location has strong coupled influences on combus- tor performances. In addition, an inner-force synthesis specific impulse is used to reduce the errors caused by the disturbance of fuel supply and working state of air heater while assessing combustor performances.     

(高)超声速流动试验技术及研究进展

近年来,与高速飞行器相关的(高)超声速流动受到了极大的关注。这类流动所具有的非定常性、强梯度和可压缩性对试验方法和风洞设计技术提出了挑战。超声速纳米示踪平面激光散射(NPLS)技术是由作者所在团队研发的非接触光学测试技术。它能够以较高的空间分辨率来揭示超声速三维流场的一个瞬态剖面的时间解析的流动结构。介绍了NPLS技术以及基于NPLS开发的密度场测量、雷诺应力测量和气动光学波前测量等方法,并回顾了这些技术在超声速边界层、超声速混合层、超声速压缩拐角、激波/边界层相互作用和光学头罩绕流等流动中的应用,清晰地再现了边界层、混合层、激波等典型流场结构及其时空演化特性。另外,为了模拟和研究高空大气条件下边界层自然转捩和超声速混合层的转捩特性,介绍了高超声速静风洞、超-超混合层风洞的设计技术以及层流化喷管的设计方法。     

Research on Auto-detection for Remainder Particles of Aerospace Relay Based on Wavelet Analysis

Aerospace relay is one kind of electronic components which is used widely in national defense system and aerospace system. The existence of remainder particles induces the reliability declining, which has become a severe problem in the development of aerospace relay. Traditional particle impact noise detection (PIND) method for remainder detection is ineffective for small particles, due to its low precision and involvement of subjective factors. An auto-detection method for PIND output signals is proposed in this paper, which is based on direct wavelet de-noising (DWD), cross-correlation analysis (CCA) and homo-filtering (HF), the method enhances the affectiv-ity of PIND test about the small particles. In the end, some practical PIND output signals are analysed, and the validity of this new method is proved.