Rotational constants of linear and/or bent Cn+1H and CnN(n = 1–6): A DFT study

The geometries, dipole moments, and rotational constants for the linear and/or bent cations, C_n+1H⁺ and C_nN⁺(n = 1–6), were studied by the B3LYP method with the modest basis sets. For C_nH⁺(n = odd; 3, 5, 7) and C_nN⁺(n = even; 2, 4, 6), the theoretical rotational constants (B_es) of closed-shell singlet C₃H⁺, C₅H⁺, C₇H⁺, CCN⁺, C₄N⁺, and C₆N⁺ were calculated to be about 11,244, 2420, 885.2, 11,970, 2439, and 880.8 MHz, respectively. By contrast, the triplets are stable than the corresponding singlets for C_nH⁺(n = odd; 2, 4, 6) and C_nN⁺(n = even; 3, 5) except CN⁺.     

Longitudinal behaviors of the IRI-B parameters of the equatorial electron density profiles retrieved from FORMOSAT-3/COSMIC radio occultation measurements

The electron density profiles in the bottomside F₂-layer ionosphere are described by the thickness parameter B0 and the shape parameter B1 in the International Reference Ionosphere (IRI) model. We collected the ionospheric electron density (N_e) profiles from the FORMOSAT-3/COSMIC (F3/C) radio occultation measurements from DoY (day number of year) 194, 2006 to DoY 293, 2008 to investigate the daytime behaviors of IRI-B parameters (B0 and B1) in the equatorial regions. Our fittings confirm that the IRI bottomside profile function can well describe the averaged profiles in the bottomside ionosphere. Analysis of the equatorial electron density profile datasets provides unprecedented detail of the behaviors of B0 and B1 parameters in equatorial regions at low solar activity. The longitudinal averaged B1 has values comparable with IRI-2007 while it shows little seasonal variation. In contrast, the observed B0 presents semiannual variation with maxima in solstice months and minima in equinox months, which is not reproduced by IRI-2007. Moreover, there are complicated longitudinal variations of B0 with patterns varying with seasons. Peaks are distinct in the wave-like longitudinal structure of B0 in equinox months. An outstanding feature is that a stable peak appears around 100°E in four seasons. The significant longitudinal variation of B0 provides challenges for further improving the presentations of the bottomside ionosphere in IRI.     

Model calculations of the dayside ionosphere of Venus

Model calculations of the dayside ionosphere of Venus are presented. The coupled continuity and momentum equations were solved for O₂⁺, O⁺, CO₂⁺, C⁺, N⁺, He⁺, and H⁺ density distributions, which are compared with measurements from the Pioneer Venus ion mass spectrometer. The agreement between the model results and the measurements is good for some species, such as O⁺, and rather poor for others, such as N⁺, indicating that our understanding of the dayside ion composition of Venus is incomplete. The coupled heat conduction equations for ions and electrons were solved and the calculated temperatures compared with Pioneer Venus measurements. It is shown that fluctuations in the magnetic field have a significant effect on the energy balance of the ionosphere.     

Studies of electron and ion temperatures at 500 km altitude during sunrise using Indian SROSS C2 satellite

Solar dependence of electron and ion temperatures (T_e and T_i) in the ionosphere is studied using RPA data onboard SROSS C2 at an altitude of ∼500 km and 77°E longitude during early morning hours (04:00–07:00 LT) for three solar activities: solar minimum, moderate and maximum during winter, summer and equinox months in 10°S–20°N geomagnetic latitude. In winter the morning overshoot phenomenon is observed around 06:00 LT (T_e enhances to ∼4000 K) during low-solar activity and to T_e ∼ 3800 K, during higher solar activity. In summer, it is observed around 05:30 LT, but the rate of T_e enhancement is higher during moderate solar activity (∼2700 K/hr) than the low-solar activity (∼1700 K/hr). During equinox, this phenomenon is delayed and is observed around 06:00 LT (∼4200 K) during all three activities.     

Response of low latitude D-region ionosphere to the total solar eclipse of 22 July 2009 deduced from ELF/VLF analysis

Response of the D-region of the ionosphere to the total solar eclipse of 22 July 2009 at low latitude, Varanasi (Geog. lat., 25.27° N; Geog. long., 82.98° E; Geomag. lat. = 14° 55’ N) was investigated using ELF/VLF radio signal. Tweeks, a naturally occurring VLF signal and radio signals from various VLF navigational transmitters are first time used simultaneously to study the effect of total solar eclipse (TSE). Tweeks occurrence is a nighttime phenomena but the obscuration of solar disc during TSE in early morning leads to tweek occurrence. The changes in D-region ionospheric VLF reflection heights (h) and electron density (n_e: 22.6–24.6 cm⁻³) during eclipse have been estimated from tweek analysis. The reflection height increased from ∼89 km from the first occurrence of tweek to about ∼93 km at the totality and then decreased to ∼88 km at the end of the eclipse, suggesting significant increase in tweek reflection height of about 5.5 km during the eclipse. The reflection heights at the time of totality during TSE are found to be less by 2–3 km as compared to the usual nighttime tweek reflection heights. This is due to partial nighttime condition created by TSE. A significant increase of 3 dB in the strength of the amplitude of VLF signal of 22.2 kHz transmitted from JJI-Japan is observed around the time of the total solar eclipse (TSE) as compared to a normal day. The modeled electron density height profile of the lower ionosphere depicts linear variation in the electron density with respect to solar radiation as observed by tweek analysis also. These low latitude ionospheric perturbations on the eclipse day are discussed and compared with other normal days.     

Imaging Global Electron Content backwards in time more than 160 years ago

The Global Electron Content, GEC, represents the total number of electrons in the spherical layer over the Earth restricted by orbit of Global Positioning Satellite system (20,200 km). GEC is produced from Global Ionospheric Map of Total Electron Content, GIM-TEC, transformed to the electron density varying with height using the International Reference Ionosphere and Plasmasphere model, IRI-Plas. The climatologic GEC model is developed from GIM-TEC maps for a period 1999–2012 including the solar activity, annual and semiannual cycles as the most important factors affecting daily GEC variation. The proxy R_zp of the international sunspot numbers, R_i, is used as a measure of solar activity composed of 3 day smoothed R_i, 7 day and 81 day backwards mean of R_i scaled to the range of 1–40 proxy units, p.u. The root mean square error of the GEC climatologic model is found to vary from 8% to 13% of GEC. Taking advantage of a long history of sunspot numbers, the climatologic GEC model is applied for GEC reconstruction backwards in time for more than 160 years ago since 1850. The extended set of GEC values provides the numerical representation of the ionosphere and plasmasphere electron content coherent with variations of solar activity as a potential proxy index driving the ionosphere models.     

XMM-Newton observations across the Cygnus Loop from northeastern rim to southwestern rim

We have observed the Cygnus Loop from the northeast (NE) to the southwest (SW) with XMM-Newton. We extracted spectra from 3′-spaced annular regions across the Loop and fitted them either with a one-kT_e-component non-equilibrium ionization (NEI) model or with two-kT_e-component NEI model. We found that the two-kT_e-component model yields significantly better fits in almost all the spectra than the one-kT_e-component model. Judging from the abundances, the high-kT_e-component in the two-temperature model must be fossil ejecta while the low-kT_e-component comes from the swept-up interstellar medium (ISM). The distributions of Ne, Mg, Si, and S for fossil ejecta appear to retain the onion-skin structure at the time of a supernova explosion, suggesting that significant overturning of the ejecta has not occurred yet. Comparing the relative abundances of fossil ejecta estimated for the entire Cygnus Loop with those from theoretical calculations for Type-II SN, the mass of the progenitor star is likely to be ∼13 M_⊙. The trends of the radial profiles of kT_e and emission integral for the swept-up ISM are adequately described by the Sedov model, suggesting that the swept-up ISM is concentrated in a shell-like structure. Comparing our data with the Sedov model, we found the ambient medium density to be ∼0.7 cm⁻³. Then, we estimated the total mass of the swept-up ISM and the age of the remnant to be ∼130 M_⊙ and 13,000 years, respectively. Note that if the explosion occurred within a stellar wind cavity, then the density in the cavity, the total swept-up mass in the cavity, and the age of the remnant are estimated to be ∼0.14 cm⁻³, ∼25 M_⊙, and ∼10,000 years, respectively.     

Solar cycle effect on temporal and spatial variation of topside ion density measured by SROSS C2 and ROCSAT 1 over the Indian longitude sector

We investigated the diurnal, seasonal and latitudinal variations of ion density Ni over the Indian low and equatorial topside ionosphere within 17.5°S to 17.5°N magnetic latitudes by combining the data from SROSS C2 and ROCSAT 1 for the 9 year period from 1995 to 2003 during solar cycle 23. The diurnal maximum density is found in the local noon or in the afternoon hours and the minimum occurs in the pre sunrise hours. The density is higher during the equinoxes as compared to that in the June and December solstice. The local time spread of the daytime maximum ion density increases with increase in solar activity. A north south asymmetry with higher ion density over northern hemisphere in the June solstice and over southern hemisphere in December solstice has been observed in moderate and high solar activity years. The crest to crest distance increases with increase in solar flux. Ion density bears a nonlinear relationship with F_10.7 cm solar flux and EUV flux in general. The density increases linearly with solar flux up to ∼150 sfu (1 sfu = 10⁻²²Wm⁻²Hz⁻¹) and EUV flux up to ∼50 units (10⁹ photons cm⁻² s⁻¹). But beyond this the density saturates. Inverse saturation and linear relationship have been observed in some season or latitude also. Inter-comparison of the three solar activity indices F_10.7 cm flux, EUV flux and F_10.7P (= (F_10.7 + F_10.7A)/2, where F_10.7A is the 81 day running average value of F_10.7) shows that the ion density correlates better with F_10.7P and F_10.7 cm fluxes. The annual average daytime total ion density from 1995 to 2003 follows a hysteresis loop as the solar cycle reverses. The ion density at 500 km over the Indian longitude sector as obtained by the international reference ionosphere is in general lower than the measured densities during moderate and high solar activity years. In low solar activity years the model densities are equal or higher than measured densities. The IRI EIA peaks are symmetric (±10°) in equinox while densities are higher at 10°N in June solstice and at 10°S in the December solstice. The model density follows F_10.7 linearly up to about F_10.7 > ∼150 sfu and then saturates.     

Latitudinal variation of the topside electron temperature at different levels of solar activity

A database of electron temperature (T_e) measurements comprising of most of the available satellite measurements in the topside ionosphere is used for studying the solar activity variations of the electron temperature T_e at different latitudes, altitudes, local times and seasons. The T_e data are grouped into three levels of solar activity (low, medium, high) at four altitude ranges, for day and night, and for equinox and solstices. We find that in general T_e changes with solar activity are small and comparable in magnitude with seasonal changes but much smaller than the changes with altitude, latitude, and from day to night. In all cases, except at low altitude during daytime, T_e increases with increasing solar activity. But this increase is not linear as assumed in most empirical T_e models but requires at least a parabolic approximation. At 550 km during daytime negative as well as positive correlation is found with solar activity. Our global data base allows to quantify the latitude range and seasonal conditions for which these correlations occur. A negative correlation with solar activity is found in the invdip latitude range from 20 to 55 degrees during equinox and from 20 degrees onward during winter. In the low latitude (20 to −20 degrees invdip) F-region there is almost no change with solar activity during solstice and a positive correlation during equinox. A positive correlation is also observed during summer from 30 degrees onward.     

Response of the mid-latitude D-region ionosphere to the total solar eclipse of 22 July 2009 studied using VLF signals in South Korean peninsula

In this paper, we analyze VLF signals received at Busan to study the the D-region changes linked with the solar eclipse event of 22 July 2009 for very short (∼390 km) transmitter–receiver great circle path (TRGCP) during local noon time 00:36–03:13 UT (09:36–12:13 KST). The eclipse crossed south of Busan with a maximum obscuration of ∼84%. Observations clearly show a reduction of ∼6.2 dB in the VLF signal strength at the time of maximum solar obscuration (84% at 01:53 UT) as compared to those observed on the control days. Estimated values of change in Wait ionospheric parameters: reflection height (h′) in km and inverse scale height parameter (β) in km⁻¹ from Long Wave Propagation Capability (LWPC) model during the maximum eclipse phase as compared to unperturbed ionosphere are 7 km and 0.055 km⁻¹, respectively. Moreover, the D-region electron density estimated from model computation shows 95% depletion in electron density at the height of ∼71 km. The reflection height is found to increase by ∼7 km in the D-region during the eclipse as compared to those on the control days, implying a depletion in the Lyman-α flux by a factor of ∼7. The present observations are discussed in the light of current understanding on the solar eclipse induced D-region dynamics.     

An alternative Shell inversion technique - Analysis and validation based on COSMIC and ionosonde data

Multi-channel Global Positioning System (GPS) carrier phase signals, received by the six low Earth orbiting (LEO) satellites from the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) program, were used to undertake active limb sounding of the Earth’s atmosphere and ionosphere via radio occultation. In the ionospheric radio occultation (IRO) data processing, the standard Shell inversion technique (SIT), transformed from the traditional Abel inversion technique (AIT), is widely used, and can retrieve good electron density profiles. In this paper, an alternative SIT method is proposed. The comparison between different inversion techniques will be discussed, taking advantage of the availability of COSMIC datasets. Moreover, the occultation results obtained from the SIT and alternative SIT at 500 km and 800 km, are compared with ionosonde measurements. The electron densities from the alternative SIT show excellent consistency to those from the SIT, with strong correlations over 0.996 and 0.999 at altitudes of 500 km and 800 km, respectively, and the peak electron densities (N_mF₂) from the alternative SIT are equivalent to the SIT, with 0.839 vs. 0.844, and 0.907 vs. 0.909 correlation coefficients when comparing to those by the ionosondes. These results show that: (1) the N_mF₂ and h_mF₂ retrieved from the SIT and alternative SIT are highly consistent, and in a good agreement with those measured by ionosondes, (2) no matter which inversion technique is used, the occultation results at the higher orbits (∼800 km) are better than those at the lower orbits (∼500 km).     

Equatorial M(3000)F2 estimation of F2-layer models peak heights during low solar activity

M(3000)F2 estimation of h_mF2 based on four different formulated models viz: (1) Shimazaki (1955) (2) Bradley and Dudeney (1973), (3) Dudeney (1974) and (4) Bilitza et al. (1979) at an equatorial station in West Africa during low solar activity period (1995) are used to validate its conformity with observed and International Reference Ionosphere (IRI) model. Local time analyses of data from fifteen (15) selected days during the January and July solstices and April and October equinoxes are used. The results obtained show that the M(3000)F2 estimation of h_mF2 from the ionosonde-measured values using the Ionospheric Prediction Service (IPS-42) sounder compared to the observed values which were deduced using an algorithm from scaled virtual heights of quiet day ionograms are highly correlated with Bilitza model. International Reference Ionosphere (IRI 2007) model for the equatorial region also agrees with the formulation developed by Bilitza et al. (1979) for the four different seasons of the year. h_mF2 is highest (425 km) in summer (June solstice) season and lowest (386 km) in autumn (September equinox) season with daytimes peaks occurring at 1100–1200 LT during the solstices and at 1000 LT during the equinoxes respectively. Also, the post-sunset peaks are highest (362 km) at the spring (March equinox) and lowest (308 km) at the summer (June solstice) both occurring between 1800 and 2000 LT.     

The O2+ vibrational distribution in the Venusian ionosphere

Calculations are presented of the vibrational distribution of O₂⁺ in the Venusian ionosphere for a model atmosphere based on Pioneer Venus data. At 100 km, quenching precludes the survival of vibrationally excited O₂⁺. At the exobase, near 200 km, more than half are vibrationally excited. The effects of vibrationally excited O₂⁺ on the hot oxygen corona and the airglow are discussed.     

An empirical model of electron density in low latitude at 600 km obtained by Hinotori satellite

An empirical model of electron density (Ne) was constructed by using the data obtained with an impedance probe on board Japanese Hinotori satellite. The satellite was in circular orbit of the height of 600 km with the inclination of 31 degrees from February 1981 to June 1982. The constructed model gives Ne at any local time with the time resolution of 90 min and between −25 and 25 degrees in magnetic latitude with its resolution of 5 degrees in the range of F_10.7 from 150 to 250 under the condition of K_p < 4. Spline interpolations are applied to the functions of day of year, geomagnetic latitude and solar local time, and linear interpolation is applied to the function of F_10.7. Longitude dependence of Ne is not taken into account. Our density model can reproduce solar local time variation of electron density at 600 km altitude better than current International Reference Ionosphere (IRI2001) model which overestimates Ne in night time and underestimates Ne in day time. Our density model together with electron temperature model which has been constructed before will enable more understanding of upper ionospheric phenomenon in the equatorial region.     

Spectral analysis of time-integrated Konus–Wind GRBs: Implication on radiative mechanisms

We have analysed a sample of 328 time-integrated GRB prompt emission spectra taken via the Konus instrument on board the US GGS-Wind spacecraft between 2002 and 2004 using a couple of two-components models, Cut-off Power Law (CPL) + Power Law (PL) and blackbody (BB) + PL. The spectra show clear deviation from the Band function. The PL term is interpreted as the low energy tail of a nonthermal emission mechanism. The distributions of corresponding index β give values β < −2/3 consistent with synchrotron and synchrotron self-Compton mechanisms. The distribution of low energy index α associated with the CPL term shows clear discordance with synchrotron models for 31.4% of the analysed GRBs with values exceeding that for the line of death, α = −2/3. Then, a set of nonthermal radiation mechanisms producing harder slopes, i.e., α > −2/3, are presented and discussed. For the remaining majority (68.6%) of GRBs with CPL index α < −2/3, we show that optically thin synchrotron produced by a power law electron distribution of type, N(γ) ∼ γ^−p, γ₁ < γ < γ₂, for finite energy range (γ₂ ≠ ∞) is a likely emission mechanism with α ∼−(p + 1)/2 in the frequency range ν₁ ? ν ? ν₂ (where ν₂ = η²ν₁ with η = γ₂/γ₁), such that for p > 1/3, one gets α < −2/3. We also show that corresponding spectra in terms of F_ν and νF_ν functions are peaked around frequency ν₂ instead of ν₁, respectively for p < 1 and p < 3. Besides, thermal emission is examined taking a single Planck function for fitting the low energy range. It can be interpreted as an early emission from the GRB fireball photosphere with observed mean temperature, kT′ ∼ 16.8 keV. Furthermore, we have performed a statistical comparison between the CPL + PL and BB + PL models finding comparable χ²-values for an important fraction of GRBs, which makes it difficult to distinguish which model and specific radiation mechanism (possible thermal or nonthermal γ-ray emissions) are best suitable for describing the reported data. Therefore, additional information for those bursts, such as γ-ray polarization, would be highly desirable in future determinations of GRBs observational data.     

Use of principal component analysis in the identification of the spatial pattern of an ionospheric total electron content anomalies after China’s May 12, 2008, M = 7.9 Wenchuan earthquake

This paper uses principal component analysis (PCA) to determine the spatial pattern of total electron content (TEC) anomalies in the ionosphere post the China’s Wenchuan Earthquake of 12 May, 2008 (UTC) (M_w = 7.9). PCA and image processing are applied to the global ionospheric map (GIM) with transforms conducted for the time period 08:00–10:00 UT on 12 May 2008. Results show that at a height of approximately 200 km the anomaly is widespread and less intense; however, it becomes more localized with height reaching maximum intensity and localization at an altitude of 300 km. The spatial distribution is remarkably similar to that reported for a TEC anomaly previously identified as a precursor anomaly on May 9, 2008 for the same time period. Potential causes of the results are discussed with emphasis given to vertical acoustic gravity waves based on the spatial pattern identified.     

F-Region ion composition modeling

Measurements of the principal ion species of the F₁- and F₂- regions have been used to develop an empirical model of the ion composition for altitudes between 150 and 500 km. The species measured by the S3-1 satellite include N⁺, O⁺, N₂⁺, NO⁺ and O₂⁺. The data were obtained near the minimum of the solar cycle, thus limited information on the ionospheric variation with solar flux is available. However, the range of latitude, altitude, local time and geomagnetic activity does provide a useful basis for modeling the F-region. The ion composition measurements have been used to provide a model for relative ion composition which is compatible with the total ion density from the International Reference Ionosphere model.