An Oxygen Isotope Mixing Model for the Accretion and Composition of Rocky Planets

The oxygen isotope systematics in planetary and nebular matter are used to constrain the types of nebular material accreted to form a planet. The basic assumption of this model is that the mean oxygen isotopic composition of a planet is determined by the weighted mean oxygen isotopic composition of nebular matter accreted by the planet. Chondrites are taken as representatives of nebular matter. The chemical composition (which determines core size, mantle oxidation state, density, moment of inertia) of a planet results from the weighted mean compositions of the accreted nebular material, once the mass fractions of the different types of accreting matter are known. Here some results for Earth, Moon, Mars, and Vesta are discussed. The model implies that loss of volatile elements, such as alkalis and halogens, occurs during accretion and early planetary differentiation (e. g., by catastrophic impacts). The possible depletion mechanisms of moderately volatile elements are discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Induced Magnetospheres of Mars, Venus, and Titan

This article summarizes and aims at comparing the main features of the induced magnetospheres of Mars, Venus and Titan. All three objects form a well-defined induced magnetosphere (IM) and magnetotail as a consequence of the interaction of an external wind of plasma with the ionosphere and the exosphere of these objects. In all three, photoionization seems to be the most important ionization process. In all three, the IM displays a clear outer boundary characterized by an enhancement of magnetic field draping and massloading, along with a change in the plasma composition, a decrease in the plasma temperature, a deflection of the external flow, and, at least for Mars and Titan, an increase of the total density. Also, their magnetotail geometries follow the orientation of the upstream magnetic field and flow velocity under quasi-steady conditions. Exceptions to this are fossil fields observed at Titan and the near Mars regions where crustal fields dominate the magnetic topology. Magnetotails also concentrate the escaping plasma flux from these three objects and similar acceleration mechanisms are thought to be at work. In the case of Mars and Titan, global reconfiguration of the magnetic field topology (reconnection with the crustal sources and exits into Saturn??s magnetosheath, respectively) may lead to important losses of plasma. Finally, an ionospheric boundary related to local photoelectron signals may be, in the absence of other sources of pressure (crustal fields) a signature of the ultimate boundary to the external flow.     

Paleomagnetic Records of Meteorites and Early Planetesimal Differentiation

The large-scale compositional structures of planets are primarily established during early global differentiation. Advances in analytical geochemistry, the increasing diversity of extraterrestrial samples, and new paleomagnetic data are driving major changes in our understanding of the nature and timing of these early melting processes. In particular, paleomagnetic studies of chondritic and small-body achondritic meteorites have revealed a diversity of magnetic field records. New, more sensitive and highly automated paleomagnetic instrumentation and an improved understanding of meteorite magnetic properties and the effects of shock, weathering, and other secondary processes are permitting primary and secondary magnetization components to be distinguished with increasing confidence. New constraints on the post-accretional histories of meteorite parent bodies now suggest that, contrary to early expectations, few if any meteorites have been definitively shown to retain records of early solar and protoplanetary nebula magnetic fields. However, recent studies of pristine samples coupled with new theoretical insights into the possibility of dynamo generation on small bodies indicate that some meteorites retain records of internally generated fields. These results indicate that some planetesimals formed metallic cores and early dynamos within just a few million years of solar system formation.     

Chemistry,accretion, and evolution of Mars

The high FeO concentrations measured by VIKING for the Martian soils correspond to all probability to a FeO-rich mantle. In general, the VIKING XRF-data indicate a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust.In recent years evidence has been collected which points towards Mars being the parent body of SNC-meteorites and, hence, these meteorites have become a valuable source of information about the chemistry of Mars. Using element correlations observed in SNC-meteorites and general cosmochemical constraints, it is possible to estimated the bulk composition of Mars. Normalized to Si and Cl, the mean abundance value for the elements Ga, Fe, Na, P, K, F, and Rb in the Martian mantle is found to be 0.35 and thus exceeds the terrestrial value by about a factor of two. Aside pressure effects and the H₂O poverty, the high P and K content of the Martian mantle may lead to magmatic processes different from those on Earth.The composition of the Earth's mantle can successfully be described by a two component model. Component A: highly reduced and almost free of all elements more volatile than Na; component B: oxidized and containing all elements in Cl-abundances including volatile elements. The same two components can be used as building blocks for Mars, if one assumes that, contrary to the inhomogeneous accretion of the Earth, Mars accreted almost homogeneously. The striking depletion of all elements with chalcophile character indicates that chemical equilibrium between component A and B was achieved on Mars which lead to the formation of significant amounts of FeS which, on segregation, extracted the elements according to their sulphide-silicate partition coefficients. While for the Earth a mixing ratio AB = 8515 was derived, the Mars ratio of 6040 reflects the higher concentrations of moderately volatile elements like Na, K, and sulphur on Mars. A homogeneous accretion of Mars could also explain the obvious low abundances of water and primordial rare gases.     

Modeling of Venus, Mars, and Titan

Increased computer capacity has made it possible to model the global plasma and neutral dynamics near Venus, Mars and Saturn??s moon Titan. The plasma interactions at Venus, Mars, and Titan are similar because each possess a substantial atmosphere but lacks a global internally generated magnetic field. In this article three self-consistent plasma models are described: the magnetohydrodynamic (MHD) model, the hybrid model and the fully kinetic plasma model. Chamberlain and Monte Carlo models of the Martian exosphere are also described. In particular, we describe the pros and cons of each model approach. Results from simulations are presented to demonstrate the ability of the models to capture the known plasma and neutral dynamics near the three objects.     

Lee Hartmann,Accretion Processes in Star Formation

Space Science Reviews -     

The plasma Environment of Mars

Space Science Reviews -     

Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

The seasonal cycle of water on Mars

A review of the behavior of water in the Mars atmosphere and subsurface is appropriate now that data from the Mariner and Viking spacecraft have been analyzed and discussed for several years following completion of those missions. Observations and analyses pertinent to the seasonal cycle of water vapor in the atmosphere of Mars are reviewed, with attention toward transport of water and the seasonal exchange of water between the atmosphere and various non-atmospheric reservoirs. Possible seasonally-accessible sources and sinks for water include water ice on or within the seasonal and residual polar caps; surface or subsurface ice in the high-latitude regions of the planet; adsorbed or chemically-bound water within the near-surface regolith; or surface or subsurface liquid water. The stability of water within each of these reservoirs is discussed, as are the mechanisms for driving exchange of the water with the atmosphere and the timescales for exchange. Specific conclusions are reached about the distribution of water and the viability of each mechanism as a seasonal reservoir. Discussion is also included of the behaviour of water on longer timescales, driven by the variations in solar forcing due to the quasi-periodic variations of the orbital obliquity. Finally, specific suggestions are made for future observations from spacecraft which would further define or constrain the seasonal cycle of water.     

Water and Volatile Inventories of Mercury,Venus, the Moon,and Mars

We review the geochemical observations of water, \(\mbox{D}/\mbox{H}\) and volatile element abundances of the inner Solar System bodies, Mercury, Venus, the Moon, and Mars. We focus primarily on the inventories of water in these bodies, but also consider other volatiles when they can inform us about water. For Mercury, we have no data for internal water, but the reducing nature of the surface of Mercury would suggest that some hydrogen may be retained in its core. We evaluate the current knowledge and understanding of venusian water and volatiles and conclude that the venusian mantle was likely endowed with as much water as Earth of which it retains a small but non-negligible fraction. Estimates of the abundance of the Moon’s internal water vary from Earth-like to one to two orders of magnitude more depleted. Cl, K, and Zn isotope anomalies for lunar samples argue that the giant impact left a unique geochemical fingerprint on the Moon, but not the Earth. For Mars, an early magma ocean likely generated a thick crust; this combined with a lack of crustal recycling mechanisms would have led to early isolation of the Martian mantle from later delivery of water and volatiles from surface reservoirs or late accretion. The abundance estimates of Martian mantle water are similar to those of the terrestrial mantle, suggesting some similarities in the water and volatile inventories for the terrestrial planets and the Moon.     

Exospheres and Energetic Neutral Atoms of Mars, Venus and Titan

Our understanding of the upper atmosphere of unmagnetized bodies such as Mars, Venus and Titan has improved significantly in this decade. Recent observations by in situ and remote sensing instruments on board Mars Express, Venus Express and Cassini have revealed characteristics of the neutral upper atmospheres (exospheres) and of energetic neutral atoms (ENAs). The ENA environment in the vicinity of the bodies is by itself a significant study field, but ENAs are also used as a diagnostic tool for the exosphere and the interaction with the upstream plasmas. Synergy between theoretical and modeling work has also improved considerably. In this review, we summarize the recent progress of our understanding of the neutral environment in the vicinity of unmagnetized planets.     

The Emirates Mars Mission (EMM) Emirates Mars InfraRed Spectrometer (EMIRS) Instrument

Space Science Reviews - Modern observatories have revealed the ubiquitous presence of magnetohydrodynamic waves in the solar corona. The propagating waves (in contrast to the standing waves) are...     

The Mars Science Laboratory Organic Check Material

Mars Science Laboratory’s Curiosity rover carries a set of five external verification standards in hermetically sealed containers that can be sampled as would be a Martian rock, by drilling and then portioning into the solid sample inlet of the Sample Analysis at Mars (SAM) suite. Each organic check material (OCM) canister contains a porous ceramic solid, which has been doped with a fluorinated hydrocarbon marker that can be detected by SAM. The purpose of the OCM is to serve as a verification tool for the organic cleanliness of those parts of the sample chain that cannot be cleaned other than by dilution, i.e., repeated sampling of Martian rock. SAM possesses internal calibrants for verification of both its performance and its internal cleanliness, and the OCM is not used for that purpose. Each OCM unit is designed for one use only, and the choice to do so will be made by the project science group (PSG).     

The Mars Odyssey Gamma-Ray Spectrometer Instrument Suite

The Mars Odyssey Gamma-Ray Spectrometer is a suite of three different instruments, a gamma subsystem (GS), a neutron spectrometer, and a high-energy neutron detector, working together to collect data that will permit the mapping of elemental concentrations on the surface of Mars. The instruments are complimentary in that the neutron instruments have greater sensitivity to low amounts of hydrogen, but their signals saturate as the hydrogen content gets high. The hydrogen signal in the GS, on the other hand, does not saturate at high hydrogen contents and is sensitive to small differences in hydrogen content even when hydrogen is very abundant. The hydrogen signal in the neutron instruments and the GS have a different dependence on depth, and thus by combining both data sets we can infer not only the amount of hydrogen, but constrain its distribution with depth. In addition to hydrogen, the GS determines the abundances of several other elements. The instruments, the basis of the technique, and the data processing requirements are described as are some expected applications of the data to scientific problems.     

The Orbital Forcing of Climate Changes on Mars

Solar variability influences the climate of a planet by radiatively forcing changes over a certain timescale; orbital variations of a planet, which yield similar solar forcing modulations, can be studied within the same scientific context. It is known for Earth that obliquity changes have played a critical role in pacing glacial and interglacial eras. For Mars, such orbital changes have been far greater and have generated extreme variations in insolation. Signatures associated with the presence of water ice reservoirs at various positions across the surface of Mars during periods of different orbital configurations have been identified. For this reason, it has been proposed that Mars is currently evolving between ice ages. The advent of climate tools has given a theoretical frame to the study of orbitally-induced climate changes on Mars. These models have provided an explanation to many puzzling observations, which when put together have permitted reconstruction of almost the entire history of Mars in the last 10 million years. This paper proposes to give an overview of the scientific work dedicated to this topic.