Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

Temporal and spatial variations observed in the ionospheric composition of Venus: Implications for empirical modelling

In situ measurements of the thermal ion composition of the ionosphere of Venus have been obtained for a period of two Venus years from the Bennett rf ion mass spectrometer on the Pioneer Venus Orbiter. Ion measurements within an altitude interval of 160 to 300 kilometers, corresponding to an overall latitude interval of about ?4° to 34°N, are assembled from the interval December 1978 to March 1980. This time interval corresponds to two revolutions of Venus about the Sun, designated as two “diurnal cycles”. The distributions of several ion species in this data base have been sorted to identify temporal and spatial variations, and to determine the feasibility of an analytical representation of the experimental results. The first results from the sorting of several prominent ions including O⁺, O₂⁺, and H⁺ and several minor ions including CO₂⁺, C⁺, and H₂⁺ reveal significant diurnal variations, with superimposed modulation associated with solar activity and solar wind variations. The diurnal variation consists of strong day to night contrast in the ion concentrations, with differences of one to two orders of magnitude, depending upon ion mass and altitude. The concentrations of O₂⁺, O⁺, CO₂⁺ and C⁺ peak throughout the dayside decreasing sharply at the terminators to nightside levels, lower by one to two orders of magnitude relative to the dayside. The diurnal variations of the light ions H⁺ and H₂⁺ peak during the night, exhibiting asymmetric nightside bulges favoring the pre-dawn sector, near 0400 solar hour angle. Superimposed upon the diurnal distributions are modulation signatures which correlate well with modulation in the F_10.7 index, indicating a strong influence of solar variability on the ion production and distribution. The influence of solar wind perturbations upon the ion distributions are also indicated, by a significant increase in the scatter of the observations with increasing altitude as higher altitudes, approaching 300 kilometers, are sampled. Together, these temporal and spatial variations make the task of modelling the ionosphere of Venus both very interesting and challenging.     

Circulation of energetic ions of terrestrial origin in the magnetosphere

Energetic ion composition measurements have now been performed from earth orbiting satellites for more than a decade. As early as 1972 we knew that energetic (keV) ions of terrestrial origin represented a non-negligible component of the storm time ring current. We have now assembled a significant body of knowledge concerning energetic ion composition throughout much of the earth's magnetosphere. We know that terrestrial ions are a common component of the hot equatorial magnetospheric plasma in the ring current and the plasma sheet out to ? 23 R_E. During periods of enhanced geomagnetic activity this component may become dominant. There is also clear evidence that the terrestrial component (specifically O⁺) is strongly dependent on solar cycle. Terrestrial ion source, transport, and acceleration regions have been identified in the polar auroral region, over the polar caps, in the magnetospheric boundary layers, and within the magnetotail lobes and plasma sheet boundary layer. Combining our present knowledge of these various magnetospheric ion populations, it is concluded that the primary terrestrial ion circulation pattern associated with enhanced geomagnetic activity involves direct injection from the auroral ion acceleration region into the plasma sheet boundary layer and central plasma sheet. The observed terrestrial component of the magnetospheric boundary layer and magnetotail lobes are inadequate to provide the required influx. They may, however, contribute significantly to the maintenence of the plasma sheet terrestrial ion population, particularly during periods of reduced geomagnetic activity. It is further concluded, on the basis of the relative energy distributions of H⁺ and O⁺ in the plasma sheet, that O⁺ probably contributes significantly to the ring current population at energies inaccessible to present ion composition instrumentation (? 30 keV).     

Model calculations of the dayside ionosphere of Venus

Model calculations of the dayside ionosphere of Venus are presented. The coupled continuity and momentum equations were solved for O₂⁺, O⁺, CO₂⁺, C⁺, N⁺, He⁺, and H⁺ density distributions, which are compared with measurements from the Pioneer Venus ion mass spectrometer. The agreement between the model results and the measurements is good for some species, such as O⁺, and rather poor for others, such as N⁺, indicating that our understanding of the dayside ion composition of Venus is incomplete. The coupled heat conduction equations for ions and electrons were solved and the calculated temperatures compared with Pioneer Venus measurements. It is shown that fluctuations in the magnetic field have a significant effect on the energy balance of the ionosphere.     

Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Positive ion distributions in the morning auroral zone: Local acceleration and drift effects

We report on the typical structure of the large scale ion precipitation in the morning sector of the auroral zone and associated low frequency electromagnetic waves. Data obtained during near radial passes of the AUREOL-3 satellite point to a distinction between two main precipitation regions: 1) In the poleward part of the auroral zone the latitudinal variation of the average energy (or temperature) of the precipitated ions (mainly H⁺) indicate that they are adiabatically accelerated in the outer magnetosphere. This “high energy” (? 3 to > 20 keV) precipitation is usually associated with a low energy (E < 110 eV) upward flowing 0⁺ and H⁺ component, and 2) near the boundary between discrete and diffuse electron aurorae a drastic change in the ion characteristics is observed. The flux of energetic precipitated H⁺ ions is sharply reduced, which suggests the formation of an Alfvén layer. However, intense fluxes of precipitated H⁺, O⁺, and He⁺ ions with energies < 3 keV are observed equatorward of the Alfvén layer, in coincidence with the diffuse aurora and in association with quasi-monochromatic electromagnetic waves with frequencies around the proton gyrofrequency. As the characteristic convection and bounce times of the low energy upward flowing ion component are comparable (τ > 3 hours) we suggest that the precipitation of ionospheric ions inside the diffuse aurora results from convection and corotation of the ions accelerated to suprathermal energies at higher latitudes.     

The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O₃) over the 10-km to 65-km range and water vapor (H₂O), nitrogen dioxide (NO₂), and nitric acid (HNO₃) over the 10-km to ～50-km range. Latitude coverage extended from 64°S to 84°N. Several general features of the atmosphere have emerged from data analyses thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO₃ data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O₃, NO₂, and HNO₃ are strongly affected during a stratospheric warming. There is a persistently low water vapor mixing ratio in the tropical lower stratosphere (～2–3 ppmv), a poleward gradient at all times in the mission, and evidence of increasing mixing ratio with altitude at tropical and middle latitudes.     

Measurements of H I and O VI velocity distributions in the extended solar corona with UVCS/SOHO and UVCS/Spartan 201

The Ultraviolet Coronagraph Spectrometer on the Solar and Heliospheric Observatory, UVCS/SOHO, and the Ultraviolet Coronal Spectrometer on the Spartan 201 satellite, UVCS/Spartan, have been used to measure H I 1215.67 Å line profiles in polar coronal holes of the Sun at projected heliocentric heights between 1.5 and 3.0 R_⊙. UVCS/SOHO also measured line profiles for H I 1025.72 Å, O VI 1032/1037 Å, and Mg X 625 Å. The reported UVCS/SOHO observations were made between 5 April and 21 June 1996 and the UVCS/Spartan observations were made between 11 and 12 April 1993. Both sets of measurements indicate that a significant fraction of the protons along the line of sight in coronal holes have velocities larger than those for a Maxwellian velocity distribution at the expected electron temperature. Most probable speeds for O⁵⁺ velocity distributions along the lines of sight are smaller than those of H⁰ at 1.5 R_⊙, are comparable at about 1.7 R_⊙ and become significantly larger than the H⁰ velocities above 2 R_⊙. There is a tendency for the O⁵⁺ line of sight velocity distribution in concentrations of polar plumes to be more narrow than those in regions away from such concentrations. UVCS/SOHO has identified 31 spectral lines in the extended solar corona.     

Global comparison of the model results of GSM TIP with IRI for summer conditions

This paper presents the results of the numerical calculations thermosphere/ionosphere parameters which were executed with using of the Global Self-consistent Model of the Thermosphere, Ionosphere and Protonosphere (GSM TIP)and comparison of these results with empirically-based model IRI-2001. Model GSM TIP was developed in West Department of IZMIRAN and solves self-consistently the time-dependent, 3-D coupled equations of the momentum, energy and continuity for neutral particles (O₂, N₂, O), ions (O⁺, H⁺), molecular ions (M⁺) and electrons and largescale eletric field of the dynamo and magnetospheric origin in the range of height from 80 km to 15 Earth’s radii. The empirically derived IRI model describes the E and F regions of the ionosphere in terms of location, time, solar activity and season. Its output provides a global specification not only of N_e but also on the ion and electron temperatures and the ion composition. These two models represent a unique set of capabilities that reflect major differences in along with a substantial approaches of the first-principles model and global database model for the mapping ionosphere parameters. We focus on global distribution of the N_e, T_i, T_e and TEC for the one moment UT and fixed altitudes: 110 km, h_mF2, 300 km and 1000 km. The calculations were executed with using of GSM TIP and IRI models for August 1999, moderate solar activity and quiet geomagnetic conditions. Results present as the global differences between the IRI and GSM TIP models predictions. The discrepancies between model results are discussed.     

Transport of ions in presence of induced electric field and electrostatic turbulence: Source of ions injected into ring current

The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O⁺ flux of 2.8 × 10⁸ cm^?2 s^?1 (w > 10 eV) and an H⁺ flux of 5.5 × 10⁸ cm^?2 s^?1 (w > .63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O⁺ flux and a large part of the H⁺ flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.     

Field-aligned plasmaspheric flows at moderate latitudes

In a model of the plasmasphere, coupled time-dependent continuity, momentum and energy equations are solved for thermal O⁺, H⁺ and electrons. The field-aligned mass flow coupling and thermal coupling of conjugate ionsopheres via the protonosphere are studied. For solstice conditions, thermal coupling between conjugate hemispheres gives rise to very strong upward flows of O⁺ in the topside ionosphere of the summer hemisphere at the time of sunrise in the conjugate (winter) ionosphere; a less marked effect (but with downward flow) occurs in the summer ionosphere at winter sunset. In addition, there are strong upward and downward flows of O⁺ at local sunrise and sunset, respectively, in both hemispheres. At both L = 1.5 and L = 3, the 24-hour time-integrated interhemispheric H⁺ flux is in the summer - winter direction. At L = 1.5 its magnitude is in good agreement with the magnitude of the time- integrated field-aligned plasma (O⁺ + H⁺) flux at 1000 km altitude; there is no such agreement at L = 3.     

Ion precipitation into the ionosphere during geomagnetic storms

This review presents numerous recent examples of interesting variations in the composition and intensity of the hot ion flux (10 eV - 15 keV/e) provided by the AUREOL-3 satellite as a function of latitude and local time during periods of magnetic activity. In particular, these results reveal that although H⁺ is the most abundant ion during magnetically quiet periods, the ion composition of hot plasma at ionospheric altitudes is quite variable, and depends strongly on magnetic activity; results obtained during main and recovery phases of several magnetic storms demonstrate clearly (below 15 keV/Q) the great importance of the low altitude ionospheric source (H⁺, O⁺, and to a lesser degree He⁺) particularly at low latitudes (L ～ 3 - 4) where the flux of O⁺ ions becomes very large and even dominates. The results of the AUREOL-3 ion spectrometers establish the fact that upflowing suprathermal ionospheric ions (E_i < 100 eV/e) appear over large regions of the auroral ionosphere, the polar caps, and the polar cusp, as well as in or at the boundary of the plasmasphere during magnetospheric substorms or magnetic storms, and may consequently contribute significantly to the plasma sheet and to the inner storm time ring current. Most of the properties of the storm time ring current found by the GEOS, SCATHA, and ISEE satellites apply to lower altitudes, although the role of the ionospheric and/or plasmaspheric source appears accentuated.     

Occurrence features of simultaneous H+- and He+-band EMIC emissions in the outer radiation belt

As an important loss mechanism of radiation belt electrons, electromagnetic ion cyclotron (EMIC) waves show up as three distinct frequency bands below the hydrogen (H⁺), helium (He⁺), and oxygen (O⁺) ion gyrofrequencies. Compared to O⁺-band EMIC waves, H⁺- and He⁺-band emissions generally occur more frequently and result in more efficient scattering removal of <～5?MeV relativistic electrons. Therefore, knowledge about the occurrence of these two bands is important for understanding the evolution of the relativistic electron population. To evaluate the occurrence pattern and wave properties of H⁺- and He⁺-band EMIC waves when they occur concurrently, we investigate 64 events of multi-band EMIC emissions identified from high quality Van Allen Probes wave data. Our quantitative results demonstrate a strong occurrence dependence of the multi-band EMIC emissions on magnetic local time (MLT) and L-shell to mainly concentrate on the dayside region of L?=?～4–6. We also find that the average magnetic field amplitude of H⁺-band waves is larger than that of He⁺-band waves only when L?<?4.5 and AE¹?<?300?nT, and He⁺-band emissions are more intense under all other conditions. In contrast to 5 events that have average H⁺-band amplitude over 2 nT, 19 events exhibit >2 nT He⁺-band amplitude, indicating that the He⁺-band waves can be more easily amplified than the H⁺-band waves under the same circumstances. For simultaneous occurrences of the two EMIC wave bands, their frequencies vary with L-shell and geomagnetic activity: the peak wave frequency of H⁺-band emissions varies between 0.25 and 0.8 f_cp with the average between 0.25 and 0.6 f_cp, while that of He⁺-band emissions varies between 0.03 and 0.23 f_cp with the average between 0.05 and 0.15 f_cp. These newly observed occurrence features of simultaneous H⁺- and He⁺-band EMIC emissions provide improved information to quantify the overall contribution of multi-band EMIC waves to the loss processes of radiation belt electrons.     

On the progress in Odin’s hunt for molecules

Glimpses of new results from Odin’s fourth to sixth years of operation are presented: the first detection of interstellar O₂; the high water abundance in the M 42/Orion KL interface region; new results from the Orion KL spectral scan, including considerably improved knowledge of source physics and chemistry; the constant H₂O/HCO⁺ abundance ratio observed in diffuse, spiral arm clouds; mapping of shock-enhanced water emission in some nearby bipolar outflows; meaningful upper limits to the water abundance in nearby starburst galaxies; new mapping of the water emissions and absorptions in the Galactic Centre region – Sgr A; abundant self-absorbing water observed in the circumstellar envelope of R Doradus; very successful observations of many comets – including Tempel 1 (the target of Deep Impact) and recent observations of an outburst in the disintegrating Comet 73P/Schwassmann–Wachmann 3; and finally a note on our Odin searches for primordial molecules – potential structure probes during the dark ages of the evolution of the Universe.     

Rocket-borne measurements of atmospheric infrared emissions by spectrometric techniques

As part of the MAP/WINE Campaign 1983/84 a liquid helium cooled infrared grating spectrometer measured night zenith radiances of CO₂, O₃, and H₂O in the mesosphere and lower thermosphere. From a comparison of the measured spectral radiances with results from LTE radiative transfer calculations atmospheric temperatures and concentration profiles of H₂O and O₃ were determined, showing some interesting features. The ozone densities obtained appear to contradict model predictions based upon the assumption that ozone is in photochemical equilibrium at mesospheric heights. Since the ozone density distribution shows quite similar structures as the vertical wind profile, transport effects seem to play a major role in the mesospheric ozone formation.     

Relative contributions of terrestrial and solar wind ions in the plasma sheet

A major uncertainty concerning the origins of plasma sheet ions is due to the fact that terrestrial H⁺ can have similar fluxes and energies as H⁺ from the solar wind. The situation is especially ambiguous during magnetically quiet conditions (AE < 60γ) when H⁺ typically contributes more than 90% of the plasma sheet ion population. In this study we examine that problem using a large data set obtained by the ISEE-1 Plasma Composition Experiment. The data suggest that one component of the H⁺ increases in energy with increasing activity, roughly in proportion to $\text{1}\text{4}$ the energy of the He⁺⁺, whereas the other H⁺ component has about the same energy at all activity levels, as do the O⁺ and the He⁺. If we can assume that the H⁺ of solar wind origin on the average has about the same energy-per-nucleon as the He⁺⁺, which is presumably almost entirely from the solar wind, then the data imply that as much as 20–30% of the H⁺ can be of terrestrial origin even during quiet conditions.     

The glow of the night ionosphere due to energetic ion beams

This paper discusses photometric measurements made of the ionospheric excitation of the line $\text{λ = 5577}\text{A}\text{?}$ at the time of electron beam injection from a rocket into the Earth's ionosphere. The gradual increase of the glow intensity per impulse occurs due to accumulation of the energy of excited states of N₂(A³Σ⁺_u) and O(′S) during their lifetimes. The large disturbed zone in the near-rocket environment (size >500 m) is connected via the interaction of ions accelerated in the rocket potential field with ionospheric components. The glow intensity modulation is observed at a height of ～98 km during the electron beam injection simultaneously with the ignition of the beam-plasma discharge (BPD). The intensity minima are explained by a decrease of the energy of accelerated ions due to effective neutralization of the rocket body by the BPD plasma. The height profile of the glow intensity revealed two maxima at heights of ～103 km and ～115 km. The second maximum (at ～115 km) indicates that, at these heights, both collision and collision-free mechanisms of accelerated ion energy transport to ionospheric components exist.