Heusler合金M2CoA(M=Mn,Ti;A=Al,Si)的第一性原理

采用基于密度泛函理论(DFT)的第一性原理计算方法,研究了M₂CoA型Heusler合金Mn₂CoAl、Mn₂CoSi、Ti₂CoAl和Ti₂CoSi的电子结构和磁学性质。发现Heusler合金Mn₂CoAl是亚铁磁性自旋无带隙半导体,Mn₂CoSi与Ti₂CoAl是亚铁磁性自旋半金属,而Ti₂CoSi是铁磁性自旋半金属。它们的总自旋磁矩均为整数,符合Slater-Pauling规则。然后,在分析电子能带结构和态密度的基础上,探讨了自旋无带隙半导体与半金属性的根源。最后,声子谱和弹性常数计算结果表明所有M₂CoA型Heusler合金在晶格动力学和力学上均是稳定的。     

受控生态生保系统内红萍供氧特性研究

研究红萍载人供O₂特征, 为红萍生物部件进行系统总体地面模拟试验及空间应用奠定基础,构建了受控生态生保系统密闭试验舱和红萍栽培装置, 在“红萍-鱼-人”共存情况下, 测定密闭舱内O₂, CO₂浓度的变化. 试验结果显示, 单位重量的鱼耗O₂量. 0805～0.0831 L·kg-1·h-1, 排放CO₂量为0.0705～0.0736 L·kg-1·h-1; 试验志愿者耗O₂量19.71 L·h-1, 呼吸释放CO₂量18.90 L·h-1. 人工光照保持7000～8000 lx条件下, 红萍的光合作用与人和鱼的呼吸作用相辅相成, 舱内O₂, CO₂浓度趋于平衡. 密闭舱内CO₂浓度升高对促进红萍群体净光合效率有明显效果, 红萍光合放O₂能力很强, 能有效促使密闭舱内O₂, CO₂浓度朝着有利于人生存的环境方向平衡, 进而验证了红萍的空间应用前景.      

混合球磨对YAl_2颗粒形貌及表面改性的影响

采用扫描电镜、能谱分析、透射电镜等分析方法研究了球磨对YAl₂及YAl₂/Mg颗粒的组织形貌、YAl₂颗粒在YAl₂/Mg颗粒中的分散性及YAl₂/Mg界面结合状况的影响.结果表明:YAl₂颗粒经球磨20 h后,其平均粒径约为1.5 μm,颗粒边缘尖角数量明显减少,呈圆滑的近球形.加入Mg颗粒进行混合球磨20 h后,YAl₂颗粒在混合颗粒中呈弥散分布,且表面包裹一层单质Mg,YAl₂/Mg的界面为直接结合型,未发现有界面反应.     

VEGA three-channel spectrometer experiment: Spectroscopy of comet Halley in the visible and near-ultraviolet ranges

A total of 3600 spectra of Comet Halley in the 275–710 nm were obtained on March, 8, 9, 10 and 11, 1986, from the VEGA 2 spacecraft. The emissions of OH, NH, CN, C₃, CH, C₂, NH₂ and H₂O⁺ are identified. From the OH intensity in the (0,0) band: 1.1 Megarayleigh at 5400 km from the nucleus, it can be inferred that the OH production rate was (1.4 ± 0.5)×10³⁰ molecules s⁻¹. The NH, C₃, CH and NH₂ bands became comparatively more intense at distances from the nucleus shorter than 3000km. At 06:40 U.T. when the instrument field of view was 6000×4500 km, two jets were observed. Spectra from the jets show significant differences with other spectra. Inside a jet NH, C₃ and NH₂ are comparatively more intense and the rotational distributions of OH, CN and C₂ are strongly distorted. This shows that part of the observed emissions probably comes from radicals directly produced in the excited state during the initial process of photolysis of the parent molecules.     

八水氢氧化钡相变材料储热性能实验

采用八水氢氧化钡（Ba（OH）₂·8H₂O）作为相变储热材料,经过150次熔化-凝固热循环实验,发现随着热循环次数的增加,Ba（OH）₂·8H₂O的相变点温度变化很小,但是该相变材料结晶时存在严重的过冷现象.通过扫描电子显微镜获得50次热循环后Ba（OH）₂·8H₂O与铝合金和紫铜金属材料之间的腐蚀情况图像,图像分析表明,Ba（OH）₂·8H₂O与紫铜有良好的相容性.搭建了含/未含泡沫铜的相变储能装置的实验台,对比实验结果表明,泡沫铜填充不仅可以提高相变材料的传热效率,而且能够有效地降低Ba（OH）₂·8H₂O的过冷度.      

Atmospheric photochemistry above possible martian hot spots

Considering the possibility of outgassing from some localized sources on Mars, we have developed a one-dimensional photochemical model that includes methane (CH₄), sulfur dioxide (SO₂) and hydrogen sulfide (H₂S). Halogens were considered but were found to have no significant impact on the martian atmospheric chemistry. We find that the introduction of methane into the martian atmosphere results in the formation of mainly formaldehyde (CH₂O), methyl alcohol (CH₃OH) and ethane (C₂H₆), whereas the introduction of the sulfur species produces mainly sulfur monoxide (SO) and sulfuric acid (H₂SO₄). Depending upon the flux of the outgassed molecules from possible hot spots, some of these species and the resulting new molecules may be detectable locally, either by remote sensing (e.g., with the Planetary Fourier Spectrometer on Mars Express) or in situ measurements.     

Remote infrared observations of parent volatiles in comets: A window on the early solar system

Organic volatiles and water in Oort Cloud comets were investigated at infrared wavelengths. The detected species include H₂O, CO, CH₃OH, CH₄, C₂H₂, C₂H₆, OCS, HCN, NH₃, and H₂CO. Several daughter fragments (CN, OH, NH₂, etc.) are also measured, and OH prompt emission provides a proxy for water. Long-slit spectra are taken at high spectral dispersion and high spatial resolution, eliminating several sources of systematic error. The resulting parent volatile production rates are highly robust, permitting a sensitive search for compositional diversity among comets. Here, seven OC comets are compared. Six (including Halley) exhibit similar compositions (excepting CO and CH₄). Their low formation temperatures (30 K) suggest this group probably formed beyond 30 AU from the young sun. However, C/1999 S4 is severely depleted in hypervolatiles and also in methanol, and it likely formed near 5–10 AU. C/2001 A2 is discussed briefly to illustrate future prospects.     

释放不同化学物质对电离层扰动的比较

在电离层F区释放氢（H₂）、水（H₂O）、二氧化碳（CO₂）、六氟化硫（SF₆）、三氟溴甲烷（CF₃Br）、羰基镍（Ni（CO）₄）可以损耗局域等离子体电子密度,形成电子空洞,电离层电子密度的改变主要取决于释放物质的气态分子与电离层之间的离子化学反应.在电离层人工主动扰动实验中,应根据发射成本和扰动效果对释放物质进行选择.通过热力学原理和有限元模拟方法计算比较了上述6种物质对电离层的扰动影响.计算结果表明,6种物质中水的气化率最低,约为19%,其余5种物质都在60%以上,选择密度小的物质,例如H₂和CO₂,可以有效降低发射成本.另外,扩散较慢且化学反应较快的物质,例如SF₆和Ni（CO）₄,能够使得电离层电子密度减少得更多,并且受扰动区域更广、持续时间更长.     

氧化物涂层对航天器材料原子氧剥蚀的防护

采用磁控溅射方法在航天器常用材料聚酰亚胺(Kapton)表面沉积无机氧化物涂层(TiO₂和SiO₂),来提高材料的抗原子氧剥蚀性能.通过选择试验材料和参数,优化了沉积涂层的工艺,以克服容易产生裂纹的缺点.对材料进行了原子氧效应地面模拟试验,结果表明,在Kapton上沉积涂层后,质量损失下降了2个数量级.另外,有涂层的Kapton表面基本没有变化并且没有出现裂纹.其中,TiO₂由于热膨胀系数更接近Kapton,比SiO₂的防护效果更好.     

On the adjust of minor constituents density in middle atmosphere during solar proton events

Profiles of O₃ partial pressure and of other minor atmospheric constituents (NO, NO₂, HCL, HF and H₂O), observed in the middle atmosphere during Solar proton events (20.04.1998; 05.04.2000), were analysed. Conclusions were drawn that under SCR impact a short-term O₃ partial pressure increase and destruction of some freon constituents took place.     

Comparison of ion composition from the goddard comprehensive ionosphere database with the international reference ionosphere model

We compared the IRI values of T_e, N_e, T_i, O⁺, H⁺, He⁺, O₂₊, and NO⁺ with AE-C values, obtained from the Goddard Comprehensive Ionosphere Database (GCID), composed of data from the satellites, AE-B, OGO-6, ISIS-2, AE-C, AE-D, and AE-E. O⁺ - H⁺ transition levels were derived from the IRI and AE-C altitude profiles. Some discrepancies were found between IRI and the AE-C data. The IRI electron density was found to be about a factor of 2 higher than the data. The H⁺ composition agreed best among the IRI ions, with an average AE-C/IRI ratio of 1.05. The temperatures of both electrons and ions agreed quite well: the average ratios of AE-C/IRI was found to be .99 for electrons and 1.17 for ions.     

电离层电场对磁层活动响应时延的模式研究

本文用极盖边界上电离层驱动电位φ₀随时间变化的不同模式计算了场向电流J_∥2及电离层对流电场E的演化过程。计算表明,当φ₀(t)先升后降有极大值时,J_∥2(t)和E(t)也表现出类似的趋势。但它们的极值滞后于φ_0max出现的时刻,即在一段时间内,φ₀虽已开始下降,J_∥2及高纬E却继续增大。一般说,E先于J_∥2达到极值,但相差甚小。φ₀变化形式不同时,滞后时间亦不同。当φ₀陡升缓降时,E、J_∥2的极值相对于φ_0max的时延可超过一小时。这与持续时间较长的磁暴期间所观测到的电离层场强响应时延量级是一致的。时延大小还受电离层电导率的制约。低纬电离层场强的响应与高纬不同,其升降趋势与φ₀同步。      

中国空间站燃烧科学实验系统PIV单元地面试验

中国空间站燃烧科学实验系统是用于开展微重力燃烧实验研究的综合性科学实验平台，可以实现燃烧流场测量。为了验证燃烧科学实验系统粒子图像测速(PIV)单元对燃烧流场测量的功能与可行性，本文基于与在轨状态一致的连续激光器和相机的空间布局，搭建了地面层流圆孔射流试验平台，选取Al₂O_3，TiO_2，ZrO₂三种示踪粒子进行冷态试验与热态试验。试验结果表明，自主研制Nd∶YVO₄泵浦连续激光器偏光角度合适，能照亮被测流场主流区域，燃烧科学实验系统PIV单元可用于低速燃烧流场测量；相同工况下，Al₂O₃粒子在冷态试验测量的速度值更接近于理论值，速度幅值比更接近1，更适用于低速流体测量。      

密闭空间内氢气和二氧化碳甲醇化系统的非均相模型及反应特性

在载人密闭空间内通过电解水方式为乘员供氧会产生副产物氢气（H₂）。此外,乘员还呼出二氧化碳（CO₂）。将H₂和CO₂催化合成甲醇（CH₃OH）是消除载人密闭空间内富余H₂和CO₂的最优方式之一。对其开展反应过程建模及反应特性研究有助于进行反应过程的控制,更好地维持载人密闭空间内的大气平衡。本文采用微元法建立了H₂和CO₂催化合成甲醇的物料计算模型和温度一维非均相模型,研究了不同反应压力、冷却介质温度以及入口反应气体中CO₂与CO比值等反应条件下的反应特性变化规律。结果显示,反应压力的增加、冷却介质的温升以及入口气体中CO₂与CO比值的减小均能促进各反应速率增加,进而使得H₂和CO₂消除量增加、甲醇合成率上升以及催化剂和反应气体最高温度上升。在保证反应速率增加且催化剂最高温度不超过合理反应温度区间的最大值573.15 K时需维持反应压力不大于8 MPa,冷却介质温度不高于538.15 K以及CO₂与CO比值不小于1。      

多舱段载人航天器CO2去除系统性能仿真分析

多舱段载人航天器通常由主控舱段利用舱间通风对组合体空气环境参数进行集中控制.利用Ecosimpro建立了一种多舱段载人航天器CO₂去除系统性能仿真分析模型,包括舱体模块、乘员模块、CO₂净化模块、舱间通风模块,并对三舱段载人航天器CO₂去除系统性能进行了计算分析.结果表明,当净化装置进风量为0.007 2 kg/s,非主控舱段驻留人数达到6人时,会造成非主控舱段CO₂分压超出700 Pa的指标上限.此时增大舱间通风量对降低非主控舱段CO₂分压的效果并不明显,有效的控制方式是增大净化装置进风量.当净化装置进风量增加至0.011 3 kg/s时,非主控舱段CO₂分压可降至700 Pa以下.该工作有助于加快载人航天器空气环境控制系统的设计和改进流程.     

Effect of track structure and radioprotectors on the induction of oncogenic transformation in murine fibroblasts by heavy ions

The oncogenic potential of high-energy ⁵⁶Fe particles (1 GeV/nucleon) accelerated with the Alternating Gradient Synchrotron at the Brookhaven National Laboratory was examined utilizing the mouse C3H 10T1/2 cell model. The dose-averaged LET for high-energy ⁵⁶Fe is estimated to be 143 keV/μm with the exposure conditions used in this study. For ⁵⁶Fe ions, the maximum relative biological effectiveness (RBE_max) values for cell survival and oncogenic transformation were 7.71 and 16.5 respectively. Compared to 150 keV/μm ⁴He nuclei, high-energy ⁵⁶Fe nuclei were significantly less effective in cell killing and oncogenic induction. The prostaglandin E₁ analog misoprostol, an effective oncoprotector of C3H 10T1/2 cells exposed to X rays, was evaluated for its potential as a radioprotector of oncogenic transformation with high-energy ⁵⁶Fe. Exposure of cells to misoprostol did not alter ⁵⁶Fe cytotoxicity or the rate of ⁵⁶Fe-induced oncogenic transformation.     

量子点与TiO2电极参数对光阳极电子寿命及性能影响

通过对P25Ti O2光阳极薄膜厚度、敏化的量子点种类及量子点敏化方法研究,探讨了使用连续离子层吸附反应法的敏化方法(SILAR)时,P25Ti O2薄膜厚度与光阳极电子寿命的关系,以及量子点种类、共敏化工艺对光阳极光电性能的影响.采用电化学阻抗(EIS)、开路电压衰减(OCVD)及紫外-可见吸收方法,对影响光阳极光电性能的Ti O2薄膜厚度、量子点种类及共敏化工艺因素进行测试分析.实验结果表明:当光阳极薄膜厚度为12μm时,电子复合几率最小,光阳极的电子寿命相对最长;采用连续离子层吸附反应法(SILAR)对多种量子点共敏化的光阳极(Ti O2/Cd S/Cd Se/Zn S)与单一量子点敏化的光阳极(Ti O2/Cd S)相比,短路电流提高了34%,光转换效率提高了42%;合适的共敏化工艺也有助于提高光阳极的电子寿命、光谱吸收范围和吸收强度.     

无碰撞低β磁流管中的非线性波

对无碰撞低β磁流管中柱对称状态下等离子体非线性静电波的存在进行了研究, 其结果表明: (1)若参数满足0<|(a/M2-1)E₀|<1, 存在着非线性周期波;(2)若|(a/M2-1)E₀|=1, 存在着隆起和下凹的孤立波, 也存在着激波;(3)若|(a/M2-1)E₀|>1, 存在着周期波, 也存在着隆起的孤立波。还对波的某些特性进行了研究。      

电离对高超声速热化学非平衡气动热环境的影响

高超声速飞行,激波后高温气体会发生电离,飞行器气动热环境复杂。5组元（N₂,O₂,NO,O,N）、7组元（N₂,O₂,NO,O,N,NO+,e-）和11组元（N₂,O₂,NO,O,N,N₂+,O₂+,NO+,O+,N+,e-）热化学反应采用Gupta化学反应模型,分别数值研究电离作用对高超声速热化学非平衡气动热环境影响。本文分析了不同催化壁面条件下,高超声速热化学非平衡电离流场气动热环境特性。电离作用对激波离体距离和气动力载荷的影响很小。5组元热化学非平衡不考虑电离作用,流场温度和壁面热流密度偏大。11组元热化学平衡强电离流场温度最低;7组元热化学非平衡弱电离流场NO+和e-生成量过低;11组元热化学反应能对热化学非平衡电离流场气动力和热流密度载荷可靠预测。壁面催化作用会增大壁面热流密度,但它对高超声速热化学非平衡电离流场温度和气动力载荷的影响很小。