局部拉弯应力对民机蒙皮2024-T3铝合金剥蚀行为的影响

 根据弯梁法自制简易加载装置,结合电化学阻抗谱(EIS)测试方法,研究了民机蒙皮2024-T3铝合金在局部拉弯应力作用下浸泡于剥落腐蚀(EXCO)溶液中的剥蚀行为。结果表明,合金在发生剥蚀时,EIS中将出现2个时间常数。2024-T3铝合金加载试样的EIS在12 h时出现2个时间常数,而未加载试样的EIS在12~24 h之间才出现2个时间常数,且通过对比剥蚀过程中2种试样EIS的拟合数据,说明局部拉弯应力对2024-T3铝合金剥蚀的发生及发展具有促进作用。     

Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy

For a long time, chromate incorporated conversion coatings have been drawn special attention in corrosion protection of air-craft-used aluminum alloys. However,ever-increasing environmental pressures requires that non-chromate conversion coatings be developed because of the detrimental carcinogenic effects of the chromate compounds. In recent years, the sol-gel coatings doped with inhibitors were developed to replace chromate conversion coatings, and showed real promise. A sol-gel coating was prepared and its anti-corrosion behavior was investigated using the potentiodynamic scanning (PDS) and the electrochemical impedance spectroscopy (EIS). It is found that the sol-gel coating obtained by the hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane (TMOS) is prone to form defects if cured at the room temperature, whereas if cured at a higher temperature (100 ℃), these flaws can be avoided. Furthermore, it can be seen that addition of anti-foam agents and surfactants will reduce the faults if cured at the room temperature. Effects of the corrosion inhibitors, CeCl3 and mercaptobenzothiazole (MBT), in the sol-gel coatings on 2024-T3 aluminum alloy were also investigated. Results show that the corrosion resistance of the sol-gel coatings containing CeCl3 proves to be better than that of the pure and MBT added sol-gel coatings by the electrochemical methods.     

腐蚀/疲劳交替作用下飞机金属材料疲劳寿命计算方法

 使用环境下飞机金属结构剩余寿命评定是确定飞机结构疲劳寿命与日历寿命关系的关键。为此,本文模拟飞机结构经历的"地面腐蚀+空中疲劳"过程,提出了腐蚀/疲劳交替作用下飞机金属材料的疲劳寿命计算方法。首先,通过分析2A12-T4铝合金试样预腐蚀/疲劳试验结果,发现其在模拟腐蚀/疲劳交替作用时计算得到的疲劳寿命偏于保守。随后,根据2A12-T4铝合金试样真实的交替试验结果,采用回归算法,建立了基于均匀分布耦合损伤形式的腐蚀/疲劳交替寿命计算模型;并分别采用BP、Elman神经网络对上述模型的计算结果进行验证。结果表明,本文提出的均匀分布耦合损伤模型计算结果与真实试验结果吻合较好;通过进一步的计算与试验对比发现,该模型也可以用于加载循环与腐蚀周期组合发生变化时的疲劳寿命预测,具有较好的适用性。     

模拟沿海大气环境腐蚀对2A12-T4 铝合金板件疲劳行为的影响

对航空材料服役的大气环境开展实验室加速模拟试验以获得其长期腐蚀行为和寿命退化情况是相关材料和装备设计、制造、维修以及寿命评定和寿命控制的重要内容和基础。通过开展针对2A12-T4 铝合金板件的模拟铝合金沿海大气腐蚀的实验室加速腐蚀试验，模拟研究从初期点蚀到后期剥蚀的整个沿海大气腐蚀过程中，腐蚀对铝合金板件疲劳特性的影响；基于疲劳寿命退化相当的原则，建立2A12-T4 铝合金板件加速腐蚀与大气腐蚀之间的加速等效关系。结果表明：2A12-T4 铝合金实验室加速预腐蚀后疲劳寿命退化规律与大气预腐蚀疲劳寿命退化规律一致，均呈现为“快速下降期”+“平台期”的特征。     

温度与氯离子浓度对H62铜合金腐蚀的影响

H62铜合金应用广泛。分析不同环境因素对 H62铜合金腐蚀的影响,对腐蚀防护具有重要意义。设计二因素的全面试验,通过电化学工作站测得 H62铜合金在温度、氯离子浓度 2个因素 3个水平下的极化曲线,利用方差分析评估温度与氯离子浓度对 H62铜合金腐蚀的影响。试验说明,随着温度的升高以及氯离子浓度的增大, H62铜合金的腐蚀情况加重。温度与氯离子浓度有交互作用,在氯离子参与的情况下,温度对 H62铜合金腐蚀作用增强,氯离子浓度对 H62铜合金腐蚀的影响大于温度对 H62铜合金腐蚀的影响。