Solid organic matter in the atmosphere and on the surface of outer Solar System bodies.

Many bodies in the outer Solar System display the presence of low albedo materials. These materials, evident on the surface of asteroids, comets, Kuiper Belt objects and their intermediate evolutionary step, Centaurs, are related to macromolecular carbon bearing materials such as polycyclic aromatic hydrocarbons and organic materials such as methanol and related light hydrocarbons, embedded in a dark, refractory, photoprocessed matrix. Many planetary rings and satellites around the outer gaseous planets display such component materials. One example, Saturn's largest satellite, Titan, whose atmosphere is comprised of around 90% molecular nitrogen N2 and less than 10% methane CH4, displays this kind of low reflectivity material in its atmospheric haze. These materials were first recorded during the Voyager 1 and 2 flybys of Titan and showed up as an optically thick pinkish orange haze layer. These materials are broadly classified into a chemical group whose laboratory analogs are termed "tholins", after the Greek word for "muddy". Their analogs are produced in the laboratory via the irradiation of gas mixtures and ice mixtures by radiation simulating Solar ultraviolet (UV) photons or keV charged particles simulating particles trapped in Saturn's magnetosphere. Fair analogs of Titan tholin are produced by bombarding a 9:1 mixture of N2:CH4 with charged particles and its match to observations of both the spectrum and scattering properties of the Titan haze is very good over a wide range of wavelengths. In this paper, we describe the historical background of laboratory research on this kind of organic matter and how our laboratory investigations of Titan tholin compare. We comment on the probable existence of polycyclic aromatic hydrocarbons in the Titan Haze and how biological and nonbiological racemic amino acids produced from the acid hydrolysis of Titan tholins make these complex organic compounds prime candidates in the evolution of terrestrial life and extraterrestrial life in our own Solar System and beyond. Finally, we also compare the spectrum and scattering properties of our resulting tholin mixtures with those observed on Centaur 5145 Pholus and the dark hemisphere of Saturn's satellite Iapetus in order to demonstrate the widespread distribution of similar organics throughout the Solar System.     

Organic chemistry in Titan's atmosphere: new data from laboratory simulations at low temperature.

Many experiments have already been carried out to simulate organic chemistry on Titan, the largest satellite of Saturn. They can provide fruitful information on the nature of minor organic constituents likely to be present in Titan's atmosphere, both in gas and aerosol phases. Indeed, all the organic compounds but one already detected in Titan's atmosphere have been identified in simulation experiments. The exception, C4N2, as well as other compounds expected in Titan from theoretical modeling, such as other N-organics, and polyynes, first of all C6H2, have never been detected in experimental simulation thus far. All these compounds are thermally unstable, and the temperature conditions used during the simulation experiments were not appropriate. We have recently started a new program of simulation experiments with temperature conditions close to that of Titan's environment. It also uses dedicated analytical techniques and procedures compatible with the analysis of organics only stable at low temperatures, as well solid products of low stability in the presence of O2 and H2O. Spark discharge of N2-CH4 gas mixtures was carried out at low temperature in the range 100-150 K. Products were analysed by FTIR, GC and GC-MS techniques. GC-peaks were identified by their mass spectrum, and, in most cases, by comparison of the retention time and mass spectrum with standard ones. We report here the first detection in Titan simulation experiments of C6H2 and HC5N. Their abundance is a few percent relative to C4H2 and HC3N, respectively. Preliminary data on the solid products indicate an elemental composition corresponding to (H11C11N)n. These results open new prospects in the modeling of Titan's haze making.     

Formation of Saturn's spokes

The scattering properties of the spokes in Saturn's rings suggest that they consist of micron-sized dust particles. We suggest that these grains are elevated above the ring plane by electrostatic charging. We show that electrostatic levitation requires a sufficiently large plasma density near the rings. If the plasma density near the rings exceeds a few 10² cm^?3 levitation may occur at significant rates in the strong electric fields which exist in the wall-sheaths at the ring. Once the dust particles are elevated they drift relative to the plasma (except at synchronous orbit). This relative motion constitutes a current which causes a polarization electric field if the plasma is azimuthally inhomogeneous. The dense plasma will drift radially in response to this electric field and cause levitation of more dust particles as it moves along. It leaves a radially aligned trail of elevated dust particles—the spokes. One way of producing dense plasma is by meteor impact on the rings. We discuss the mechanisms of ring charging, electrostatic levitation and the currents in the plasma-dust mixture. We show that for reasonable conditions spokes of more than 10,000 km radial length can be formed in less than five minutes. We also show that under the same conditions the electrostatic levitation model predicts a dust grain population which peaks at a size of 0.6 microns and can reach optical depths of 0.1.     

The physical nature of Titan's aerosols: laboratory simulations.

The atmosphere of Titan is known to contain aerosols, as evidenced by the Voyager observations of at least three haze layers. Such aerosols can have significant effects on the reflection spectrum of Titan and on the chemistry and thermal structure of its atmosphere. To investigate some of these effects, laboratory simulations of the chemistry of Titan's atmosphere have been done. The results of these studies show that photolysis of acetylene, ethylene, and hydrogen cyanide, known constituents of Titan's atmosphere, yields sub-micron sized spheres, with mean diameters ranging from 0.4 to 0.8 microns, depending on the pressures of the reactant gases. Most of the spheres are contained in near-linear aggregates. The formation of the aggregates is consistent with models of Titan's reflection spectrum and polarization, which are best fit with non-spherical particles. At room temperature, the particles are very sticky, but their properties at low temperatures on Titan are presently not known.     

月球受光面上月尘静电浮扬特性分析

基于单粒子轨道理论及空间尘埃等离子体充电方程,建立了月球受光面上尘埃微粒的静态荷电模型.基于光电子能量Maxiwellian分布假设,确定了月面垂直空间电场强度和光电子鞘层内带电粒子密度的函数表达式.利用牛顿运动定律和静电场力表达式,构建了月球受光面上尘埃微粒的静电浮扬动力学模型,并进行月尘静态浮扬特性的数值计算.研究结果显示:太阳高度角与颗粒粒径是控制月尘静电浮扬发生及动力学特性的两个基本参量;月尘静电浮扬发生在月球的黎明和黄昏;随着粒径的减少,月尘颗粒的最大浮扬高度不断增加.     

IR and UV spectroscopic data for polyynes: predictions for long carbon chain compounds in Titan's atmosphere.

A better understanding of the complex organic chemistry occurring in the methane rich atmosphere of Titan can be achieved via the comparison of observations with results obtained by theoretical models. Available observations are still few but their analysis requires the knowledge of a large set of data, namely frequencies and absolute band intensities. Cross sections are also needed to develop the chemical schemes of photochemical models, in particular the schemes leading to the formation of haze particles visible on Titan. Unfortunately, some of these parameters are not well known, especially if one takes into account the extreme physical conditions of the studied object. This lack of data is particularly enhanced for polyynes because these compounds are highly unstable at the usual pressure and temperature conditions of a laboratory and therefore are very difficult to study. We have developed UV and IR studies, coupling experimental and theoretical approaches, in order to extrapolate the parameters available for short polyynes to longer carbon chains. In the mid-UV range, when the length of the chain increases, the absorption system of polyynes is shifted to longer wavelength and its oscillator strength increases linearly. In the IR range, with the increase of the number of carbon bonds, the positions of the CCC and CCH bending modes shift to lower energy, the latest converging rapidly to a fixed value of 620.5 cm-1 for an infinite length polyyne. Implications for detection and evolution of polyynes in Titan's atmosphere are emphasised.     

Formation of bioorganic compounds in simulated planetary atmospheres by high energy particles or photons.

Various types of organic compounds have been detected in Jupiter, Titan, and cometary coma. It is probable that organic compounds were formed in primitive Earth and Mars atmospheres. Cosmic rays and solar UV are believed to be two major energy sources for organic formation in space. We examined energetics of organic formation in simulated planetary atmospheres. Gas mixtures including a C-source (carbon monoxide or methane) and a N-source (nitrogen or ammonia) was irradiated with the followings: High energy protons or electrons from accelerators, gamma-rays from 60Co, UV light from a deuterium lamp, and soft X-rays or UV light from an electron synchrotron. Amino acids were detected in the products of particles, gamma-rays and soft X-rays irradiation from each gas mixture examined. UV light gave, however, no amino acid precursors in the gas mixture of carbon monoxide, nitrogen and nitrogen. It gave only a trace of them in the gas mixture of carbon monoxide, ammonia and water or that of methane, nitrogen and water. Yield of amino acid precursors by photons greatly depended on their wavelength. These results suggest that nitrogen-containing organic compounds like amino acid precursors were formed chiefly with high energy particles, not UV photons, in Titan or primitive Earth/Mars atmospheres where ammonia is not available as a predominant N-source.     

The low temperature organic chemistry of Titan's geofluid.

Organic chemistry on Titan and prebiotic chemistry on Earth involve the same N-containing organics: nitriles and their oligomers. Couplings of their chemistry in the three parts of Titan's geofluid (atmosphere, aerosols and surface) seem to play a key role in the organic chemical evolution of the planet. If liquid water was present on Titan, then a prebiotic chemistry, involving eutectics, similar to that of the early Earth, may have occurred. However, liquid water is currently absent and a prebiotic chemistry based only on N-organics may be evolving now on Titan. The other consequence of the low temperatures of Titan is the possible formation of organics unstable at room temperature and very reactive. So far, these compounds have not been systematically searched for in experimental studies of Titan's organic chemistry. C4N2 has already been detected on Titan. Powerful reactants in organic chemistry, CH2N2, and CH3N3, may be also present. They exhibit spectral signatures in the mid-IR strong enough to allow their detection at the 10-100 ppb level. They may be detectable on future IR spectra (ISO and Cassini) of Titan.     

Voyager photopolarimeter observations of Saturn and Titan

The Voyager 2 photopolarimeter experiment observed the intensity and polarization of scattered sunlight from the atmospheres of Saturn and Titan in the near-UV at 2640 Å and in the near-IR at 7500 Å. Measurements of Saturn's limb brightening and polarization at several phase angles up to 70° indicate that a significant optical depth of UV absorbers are present in the top 100 mbar of Saturn's atmosphere in the Equatorial Zone and north polar region, and possibly at other latitudes as well. UV absorbers are prominent in polar regions, suggesting that charged particle precipitation from the magnetosphere may be important in their formation.The whole-body polarization of Titan is strongly positive in both the UV and near IR. If spherical particles are responsible for the polarization, no single size distribution or refractive index can account for the polarization at both wavelengths. The model atmosphere proposed by Tomasko and Smith [1], characterized by a gradient in particle size with altitude, seems capable of explaining the Voyager observations. If non-spherical particles predominate, the Voyager observations place important constraints on their scattering properties.     

Saturn's equatorial haze

We have measured the amount of Raman scattering in Saturn's equatorial zone and polar regions near the central meridian at the wavelengths of the H and K Ca II solar lines, 3934 Å and 3969 Å. Approximately 2.1% of the sunlight in this wavelength range is Raman scattered out of this range in Saturn's equatorial zone. Modeling the aerosol particle distribution as a clear, Rayleigh- and Raman-scattering gas over a dense haze yields an H₂ column abundance of about 40 km-Amagats. Comparison with results obtained by Pioneer 11 suggests that either the equatorial haze was 2.5 times deeper at the time of these observations (May, 1981) than at the time of the Pioneer 11 flyby (Sept., 1979); or the haze particles are much more strongly polarizing in blue light than they are in red light.     

月尘静电迁移研究进展

月尘的静电悬浮和迁移是Apollo时期留下的最有争议的问题之一. 其既是研 究月球表面物质演化历史的重要线索, 也是探月工程必须考虑的重要因素. 月尘在月表环境下易因电子附着、光电效应、二次电子发射等过程带电, 并 在月球全球性静电场作用下发生迁移运动. 但目前对月尘静电迁移过程的认 识还不全面, 其主要原因在于对月尘静电特性的了解不够准确, 对静电迁移 过程的地面模拟不够充分以及对月球尘埃环境的探测较为缺乏. 未来需进一 步开展模拟月尘的研制, 月尘静电特性的分析, 静电迁移过程模拟以及尘埃 环境的探测等工作.      

Stability and mass flow in Saturn's rings

Besides gravitational effects, interesting electrodynamical processes could also take place in the vicinity of the rings of Saturn. In part, this is because of the electrostatic charging of the ring particles by the magnetospheric and ionospheric plasma, and in part, the generation of impact plasma by meteoroid bombardment at the ring plane could lead to strong coupling between the rings and the ionosphere via a variety of current systems. The mass transport and angular momentum transfer in association with the ring-ionosphere coupling may cause quite large changes in the ring configuration over the age of the solar system. The presence of the sharp boundary between the B and the C rings perhaps is a good example. To highlight these new developments, we describe several of the electrodynamical mechanisms (with emphasis on their corresponding electric fields and current systems) which have been postulated to be of importance in determining the mass transport of the ring system. Further points are made that, besides mass exchange between the rings and the planetary atmosphere, the mass injection from the rings could also have significant effect on the mass and energy budget of the magnetosphere, maintenance of the E ring, the Titan hydrogen torus as well as aeronomic process in the upper atmosphere of Titan.     

Corona discharge of Titan's troposphere.

The atmosphere of Titan is constantly bombarded by galactic cosmic rays and Saturnian magnetospheric electrons causing the formation of free electrons and primary ions, which are then stabilized by ion cluster formation and charging of aerosols. These charged particles accumulate in drops in cloud regions of the troposphere. Their abundance can substantially increase by friction, fragmentation or collisions during convective activity. Charge separation occurs with help of convection and gravitational settling leading to development of electric fields within the cloud and between the cloud and the ground. Neutralization of these charge particles leads to corona discharges which are characterized by low current densities. These electric discharges could induce a number of chemical reactions in the troposphere and hence it is of interest to explore such effects. We have therefore, experimentally studied the corona discharge of a simulated Titan's atmosphere (10% methane and 2% argon in nitrogen) at 500 Torr and 298 K by GC-FTIR-MS techniques. The main products have been identified as hydrocarbons (ethane, ethyne, ethene, propane, propene + propyne, cyclopropane, butane, 2-methylpropane, 2-methylpropene, n-butene, 2-butene, 2,2-dimethylpropane, 2-methylbutane, 2-methylbutene, n-pentane, 2,2-dimethylbutane, 2-methylpentane, 3-methylpentane, n-hexane, 2,2-dimethylhexane, 2,2-dimethylpentane, 2,2,3-trimethylbutane, 2,3-dimethylpentane and n-heptane), nitriles (hydrogen cyanide, cyanogen, ethanenitrile, propanenitrile, 2-methylpropanenitrile and butanenitrile) and an uncharacterized film deposit. We present their trends of formation as a function of discharge time in an ample interval and have derived their initial yields of formation. These results clearly demonstrate that a complex organic chemistry can be initiated by corona processes in the lower atmosphere. Although photochemistry and charged particle chemistry occurring in the stratosphere can account for many of the observed hydrocarbon species in Titan, the predicted abundance of ethene is to low by a factor of 10 to 40. While some ethene will be produced by charged-particle chemistry, its production by corona processes and subsequent diffusion into the stratosphere appears to be an adequate source. Because little UV penetrates to the lower atmosphere to destroy the molecules formed there, the corona-produced species may be long-lived and contribute significantly to the composition of the lower atmosphere and surface.     

Surface-atmosphere interactions on Titan compared with those on the pre-biotic Earth.

The surface and atmosphere of Titan constitute a system which is potentially as complex as that of the Earth, with the possibility of precipitation, surface erosion due to liquids, chemistry in large surface or subsurface hydrocarbon reservoirs, surface expressions of internal activity, and occasional major impacts leading to crustal melting. While none of the above have been observed as yet, the composition, density and thermal properties of Titan's atmosphere make it uniquely suited in the outer solar system as a place where such processes may occur. The one attribute of the Earth not expected on Titan is biological activity, which has had a profound effect on the evolution of the Earth's surface-atmosphere system. The earliest environment of Titan could have been warm enough for liquid ammonia-water solutions to exist on or near surface; pre-biotic organic processes may have taken place in such an environment. After a few hundred million years surface ammonia-water would have disappeared. Therefore, study of Titan through the Cassini-Huygens mission, planned for launch in 1997, primarily affords the opportunity to understand planet-wide surface-atmosphere interactions in the presence of fluids but in the absence of life. More speculative is the possibility that endogenic and exogenic heating continue to provide short-lived environments on Titan wherein pre-biotic organic processes in the presence of water happen.     

静电悬浮位置控制系统设计与实现

静电悬浮位置控制技术是静电悬浮材料实验装置中的关键技术. 以静电悬浮位置控制系统为研究对象, 分析了稳定悬浮样品的基本条件, 并以两组不同波段正交平行光作为光源, 位置测量传感器(PSD)作为位置信号接收器来组成样品的三维位置测量装置. 将PSD的位置输出信号作为输入、模拟电压信号作为输出构建PID位置反馈控制系统, 再利用PID反馈控制系统的输出来驱动高压放大器, 从而按照样品的实时位置变化调整电场强度. 通过选择合理的PID参数, 最终很好地实现了静电悬浮系统中样品位置的稳定控制.      

Experiments in materials science on the ground and in reduced gravity using electrostatic levitators

To counter residual accelerations, dedicated levitators or positioners are necessary to support a host of materials science experiments on the ground and in microgravity. All levitators (e.g., aerodynamic, acoustic, electromagnetic, electrostatic, optical) have their own merits and limitations but the electrostatic scheme offers the combined advantages of processing millimeter-size objects, independent heating, quasi-spherical shape of molten materials, handling of materials under extreme temperatures for hours, virtually convection-free samples, and wide view around the samples for diagnostic. These attributes provide unique research opportunities in materials science on the ground as well as under reduced gravity. In particular, electrostatic levitators are very attractive to measure the physical and structural properties of equilibrium and non-equilibrium liquids, to synthesize multi-function materials, and to understand metastable phase formation, vitrification, and diffusion. In this paper, research and development carried out by the Japan Aerospace Exploration Agency over the years in the field of electrostatic levitation are summarized and the main results obtained in materials science are presented.     

Experimental results for Titan aerobot thermo-mechanical subsystem development

This paper describes experimental results from a development program focused on maturing Titan aerobot technology in the areas of mechanical and thermal subsystems. Results from four key activities are described: first, a cryogenic balloon materials development program involving coupon and cylinder tests and culminating in the fabrication and testing of an inflated 4.6 m long prototype blimp at 93 K; second, a combined lab experiment and numerical simulation effort to assess potential problems resulting from radioisotope power source waste heat generation near an inflated blimp; third, an aerial deployment and inflation development program consisting of laboratory and helicopter drop tests on a near full scale (11 m long) prototype blimp; and fourth, a proof of concept experiment demonstrating the viability of using a mechanically steerable high gain antenna on a floating blimp to perform direct to Earth telecommunications from Titan. The paper provides details on all of these successful activities and discusses their impact on the overall effort to produce mature systems technology for future Titan aerobot missions.     

New insights into Titan's organic chemistry in the gas and aerosol phases.

Titan, the largest satellite of Saturn, with a dense atmosphere very rich in organics, and many couplings in the various parts of its "geofluid", is a reference for studying prebiotic chemistry on a planetary scale. New data have been obtained from experiments simulating this organic chemistry (gas and aerosol phases), within the right ranges of temperature and a careful avoiding of any chemical contamination. They show a very good agreement with the observational data, demonstrating for the first time the formation of all the organic species already detected in Titan atmosphere including, at last, C4N2, together with many other species not yet detected in Titan. This strongly suggests the presence of more complex organics in Titan's atmosphere and surface, including high molecular weight polyynes and cyanopolyynes. The NASA-ESA Cassini-Huygens mission has been successfully launched in October 1997. The Cassini spacecraft will reach the Saturn system in 2004 and become an orbiter around Saturn, while the Huygens probe will penetrate into Titan's atmosphere. In situ measurements, in particular from Huygens GC-MS and ACP instruments, will provide a detailed analysis of the organics present in the air, aerosols, and surface. This very ambitious mission should yield much information of crucial importance for our knowledge of the complexity of Titan's chemistry, and, more generally for the field of exobiology.     

悬浮月尘的遮挡模型

探月活动中,月表的尘埃会对太阳翼等光电器件的工作效率造成严重影响.基于附着月尘的遮挡模型,从立体空间的角度分析了悬浮月尘对工作器件的遮挡,提出了悬浮月尘的单粒度遮挡模型,利用月尘的平均粒度可计算在指定立体空间内,定量月尘造成的遮挡量;引入月尘的粒度分布函数,提出了悬浮月尘的多粒度遮挡模型,能够计算已知粒度分布函数的月尘在指定立体空间内造成的遮挡量;通过设计悬浮月尘遮挡的仿真实验,分别利用3种不同粒度大小的月尘进行实验,实验数据与悬浮月尘的单粒度、多粒度遮挡模型的理论计算值都较好吻合,实验结果证实了悬浮月尘遮挡模型的正确性与可靠性.      

Microgravity particle research on the space station: the Gas-Grain Simulation Facility.

In the gravitational field on Earth, the large settling rate of micron-sized particles and the effects of gravity-induced convection prohibit many interesting studies of phenomena such as coagulation, collisions, and mutual interactions of droplets, dust grains and other particles. Examples of exobiology experiments involving these phenomena are the simulation of organic aerosol formation in Titan's atmosphere, studies of the role of comets in prebiotic chemical evolution, and simulations of carbon grain interactions in various astrophysical environments. The Gas-Grain Simulation Facility (GGSF) is a proposed Earth-orbital laboratory that will allow present ground-based experimental programs which study processes involving small particles and weak interactions to be extended to a new domain. Physics issues that scientists wishing to propose GGSF experiments must consider are reviewed in this paper. Specifically, coagulation, motion in gases and vacua, and wall deposition of particles in a microgravity environment are discussed.