FeS/S/FeS(2) redox system and its oxidoreductase-like chemistry in the iron-sulfur world

The iron-sulfur world (ISW) theory is an intriguing prediction regarding the origin of life on early Earth. It hypothesizes that life arose as a geochemical process from inorganic starting materials on the surface of sulfide minerals in the vicinity of deep-sea hot springs. During the last two decades, many experimental studies have been carried out on this topic, and some interesting results have been achieved. Among them, however, the processes of carbon/nitrogen fixation and biomolecular assembly on the mineral surface have received an inordinate amount of attention. To the present, an abiotic model for the oxidation-reduction of intermediates participating in metabolic pathways has been ignored. We examined the oxidation-reduction effect of a prebiotic FeS/S/FeS(2) redox system on the interconversion between several pairs of α-hydroxy acids and α-keto acids (i.e., lactate/pyruvate, malate/oxaloacetate, and glycolate/glyoxylate). We found that, in the absence of FeS, elemental sulfur (S) oxidized α-hydroxy acids to form corresponding keto acids only at a temperature higher than its melting point (113°C); in the presence of FeS, such reactions occurred more efficiently through a coupled reaction mechanism, even at a temperature below the phase transition point of S. On the other hand, FeS was shown to have the capacity to reversibly reduce the keto acids. Such an oxidoreductase-like chemistry of the FeS/S/FeS(2) redox system suggests that it can determine the redox homeostasis of metabolic intermediates in the early evolutionary phase of life. The results provide a possible pathway for the development of primordial redox biochemistry in the iron-sulfur world. Key Words: Iron-sulfur world-FeS/S/FeS(2) redox system-Oxidoreductase-like chemistry. Astrobiology 11, 471-476.     

Terahertz circular dichroism spectroscopy: a potential approach to the in situ detection of life's metabolic and genetic machinery

We propose a terahertz (far-infrared) circular dichroism-based life-detection technology that may provide a universal and unequivocal spectroscopic signature of living systems regardless of their genesis. We argue that, irrespective of the specifics of their chemistry, all life forms will employ well-structured, chiral, stereochemically pure macromolecules (>500 atoms) as the catalysts with which they perform their metabolic and replicative functions. We also argue that nearly all such macromolecules will absorb strongly at terahertz frequencies and exhibit significant circular dichroism, and that this circular dichroism unambiguously distinguishes biological from abiological materials. Lastly, we describe several approaches to the fabrication of a terahertz circular dichroism spectrometer and provide preliminary experimental indications of their feasibility. Because terahertz circular dichroism signals arise from the molecular machinery necessary to carry out life's metabolic and genetic processes, this life-detection method differs fundamentally from more well-established approaches based on the detection of isotopic fractionation, "signature" carbon compounds, disequilibria, or other by-products of metabolism. Moreover, terahertz circular dichroism spectroscopy detects this machinery in a manner that makes few, if any, assumptions as to its chemical nature or the processes that it performs.     

Interaction of tryptophan and phenylalanine with metal ferrocyanides and its relevance in chemical evolution

The interaction of two naturally occurring aromatic alpha-amino acids, namely, tryptophan and phenylalanine, with zinc, nickel, cobalt, and copper ferrocyanides has been studied. Both amino acids showed a high adsorption affinity toward metal ferrocyanides at neutral pH (7.0). Adsorption trends followed the Langmuir adsorption isotherm. Values of the Langmuir constants K(L) and X(m) suggest tryptophan is a better adsorbate than phenylalanine. Zinc ferrocyanide showed the highest adsorption, while the minimum adsorption was found in the case of copper ferrocyanide. Infrared spectral studies of adsorbate, adsorbent, and adsorption adducts indicate that adsorption occurs because of the interaction of adsorbate molecules with outer divalent metal ions present in the lattice of metal ferrocyanides. The present investigation supports the hypothesis that metal ferrocyanides might have concentrated the biomonomers on their surface in primeval seas during the course of chemical evolution.     

Gypsum-permineralized microfossils and their relevance to the search for life on Mars

Abstract Orbital and in situ analyses establish that aerially extensive deposits of evaporitic sulfates, including gypsum, are present on the surface of Mars. Although comparable gypsiferous sediments on Earth have been largely ignored by paleontologists, we here report the finding of diverse fossil microscopic organisms permineralized in bottom-nucleated gypsums of seven deposits: two from the Permian (～260?Ma) of New Mexico, USA; one from the Miocene (～6?Ma) of Italy; and four from Recent lacustrine and saltern deposits of Australia, Mexico, and Peru. In addition to presenting the first report of the widespread occurrence of microscopic fossils in bottom-nucleated primary gypsum, we show the striking morphological similarity of the majority of the benthic filamentous fossils of these units to the microorganisms of a modern sulfuretum biocoenose. Based on such similarity, in morphology as well as habitat, these findings suggest that anaerobic sulfur-metabolizing microbial assemblages have changed relatively little over hundreds of millions of years. Their discovery as fossilized components of the seven gypsiferous units reported suggests that primary bottom-nucleated gypsum represents a promising target in the search for evidence of past life on Mars. Key Words: Confocal laser scanning microscopy-Gypsum fossils-Mars sample return missions-Raman spectroscopy-Sample Analysis at Mars (SAM) instrument-Sulfuretum. Astrobiology 12, 619-633.     

Subsurface filamentous fabrics: an evaluation of origins based on morphological and geochemical criteria, with implications for exopaleontology

The fossil record of the subsurface biosphere is sparse. Results obtained on subsurface filamentous fabrics (SFF) from >225 paleosubsurface sites in volcanics, oxidized ores, and paleokarst of subrecent to Proterozoic age are presented. SFF are mineral encrustations on filamentous or fibrous substrates that formed in subsurface environments. SFF occur in association with low-temperature aqueous mineral assemblages and consist of tubular, micron-thick (median 1.6 micron) filaments in high spatial density, which occur as irregular masses, matted fabrics, and vertically draped features that resemble stalactites. Micron-sized filamentous centers rule out a stalactitic origin. Morphometric analysis of SFF filamentous forms demonstrates that their shape more closely resembles microbial filaments than fibrous minerals. Abiogenic filament-like forms are considered unlikely precursors of most SFF, because abiogenic forms differ in the distribution of widths and have a lower degree of curvature and a lower number of direction changes. Elemental analyses of SFF show depletion in immobile elements (e.g., Al, Th) and a systematic enrichment in As and Sb, which demonstrates a relation to environments with high flows of water. Sulfur isotopic analyses are consistent with a biological origin of a SFF sample from a Mississippi Valley-Type deposit, which is consistent with data in the literature. Fe isotopes in SFF and active analogue systems, however, allow no discrimination between biogenic and abiogenic origins. The origin of most SFF is explained as permineralized remains of microbial filaments that possibly record rapid growth during phases of high water flow that released chemical energy. It is possible that some SFF formed due to encrustation of mineral fibers. SFF share similarities with Microcodium from soil environments. SFF are a logical target in the search for past life on Mars. The macroscopic nature of many SFF allows for their relatively easy in situ recognition and targeting for more detailed microstructural and geochemical analysis.     

Project Icarus: A review of local interstellar medium properties of relevance for space missions to the nearest stars

I review those properties of the interstellar medium within 15 light-years of the Sun, which will be relevant for the planning of future rapid (v≥0.1c) interstellar space missions to the nearest stars. As the detailed properties of the local interstellar medium (LISM) may only become apparent after interstellar probes have been able to make in situ measurements, the first such probes will have to be designed conservatively with respect to what can be learned about the LISM from the immediate environment of the Solar System. It follows that studies of interstellar vehicles should assume the lowest plausible density when considering braking devices, which rely on transferring momentum from the vehicle to the surrounding medium, but the highest plausible densities when considering possible damage caused by the impact of the vehicle with interstellar material. Some suggestions for working values of these parameters are provided. This paper is a submission of the Project Icarus Study Group.     

Space debris and the world community

In the early years of space flight the United Nations rapidly developed the principles which now govern outer space activities. In contrast, international agencies have during the 1980s proved reluctant to confront the escalating problem of space debris, presumbly for fear of the likely expense of remedial action. The author of this Viewpoint argues that not all the necessary measures need be expensive, and even the most unpalatable would be cost effective in the long run. But concerted action is urgently needed before the problem becomes unmanageable. International discussions must be initiated through the Committee on the peaceful Uses of Outer Space without delay.     

Recent advances in chemical evolution and the origins of life

This paper discusses the already 60 year old ideas of Oparin and Haldane, who suggested that the first forms of life were anaerobic, heterotrophic bacteria coming from chemical abiotic synthesis of organic compounds.     

对雷达区域增强技术的干扰及其效能评估

首先介绍了基于旋转电扫天线的区域增强技术的工作原理,并研究了灵巧噪声干扰的基本原理;然后利用噪声和雷达信号卷积调制产生干扰波形,从理论和仿真两方面验证了干扰的有效性和可行性;最后分析了压制干扰条件下,干扰机对雷达区域增强技术的干扰效果.     

A generalization of the rocket formula and its application to advanced space propulsion systems

A generalized rocket formula is derived from a first principles approach. The resulting expression of the thrust is applied to advanced space propulsion systems and a possible link between the asymptotic propellant velocity and the velocity at thruster exit is given. An estimation of the thrust modification due to spacecraft–plume interactions is also considered.     

Magnifying our world: Why we must extend civilization to the Moon

Since the completion of its original prehistoric migration some 10 000 years ago, humankind has had nowhere else on Earth to go. The Space Age has produced the wherewithal for a new off-Earth human migration to restart, with the Moon as the clear initial destination. As insurance against cataclysmic and human-induced natural disasters, as a means of creating new commercial industrial–financial opportunities at a time of fundamental change in the global economy, and as a way for the USA to regain some international political influence, it should pursue Moon settlement vigorously and soon. However, the developing US space exploration program being designed by NASA for such an undertaking is too narrowly confined to the pursuit of natural-science objectives. There must be fundamental involvement of the private sector and of a much wider range of professionals and federal departments therein.     

一种分形DGS单元结构设计及其在微带电路中的应用

文章设计出了一种新型的DGS单元——Minkowski分形哑铃DGS单元,并将其应用于微带电路的设计中。利用HFSS软件对相关电路模型进行仿真,结果表明,具有相同尺寸的一阶分形单元电路（缺口深度P=2／3）与普通的哑铃形DGS单元电路比较,谐振频率降低了1．1GHz。利用此分形单元设计电路,可以达到电路小型化的效果。     

导弹预警卫星对抗及其效能评估仿真研究

导弹预警卫星是导弹防御系统的重要组成部分,它的早期预警信息对成功拦截弹道导弹起着至关重要的作用.分析了导弹预警卫星的对抗手段并建立了相应的对抗效能评估模型,构建了预警卫星对抗仿真系统并描述了系统仿真流程.对于研究弹道导弹突防,具有比较重要的意义.     

Recognition of fossil prokaryotes in Cretaceous methane seep carbonates: relevance to astrobiology

Recovery of prokaryotic body fossils from methane seep carbonates such as those of the Cretaceous Tepee Buttes of Colorado serves as a model for sampling in future astrobiological missions. The fossils, found primarily at the interface between paragenetic fabrics, suggest a sharp physicochemical gradient. Evidence of these microbial fossils occurs at a variety of scales. In the field, microbialite is found as meter-scale thrombolitic zones and centimeterscale stromatolitic crusts lining voids inferred to be the sites of ancient methane seepage. Petrographic fabrics suggestive of microbialite include indistinct peloids (0.1-1 mm in diameter) and crusts of authigenic micrite. Primary evidence obtained from scanning electron microscopy coupled with energy-dispersive x-ray spectroscopy analysis comprises pinnate bacteria (0.3 microm in diameter and 1-1.5 microm long), sheaths (2-4 microm in diameter), coccoids (0.5-1 microm in diameter, up to 40 per cluster), and the presence of framboidal pyrite (6-8 microm in diameter). These results are in agreement with studies of other ancient and modern seeps and suggest a morphological conservatism of microbial form that can be incorporated into studies of extraterrestrial environments where it is presumed that reduced gases drive the metabolic activity of prokaryote-like organisms. Target areas that could serve as conduits for reduced gas seeps include tectonic or impact-driven faulting, zones of cryosphere melting, or other disruptions in crustal coherence. Ancient seeps, preserved as localized anomalous evaporite deposits in the sedimentary cover, could be detected by remote sensing.     

The militarization of space: A policy out of step with world events?

The onset of the Space Age had strong military overtones, but these were restrained by international agreement and the creation of civilian-led agencies such as NASA. Currently, however, a number of developments threaten to seriously undermine the concept of peaceful utilization of space, in particular the Strategic Defense Initiative, anti-satellite weapons research, and the routine intentional destruction of military satellites. There are nevertheless several factors mitigating military influence in space: the arrival of ‘non-superpowers’ as significant space explorers; greater ecological awareness; the virtual end of the Cold War; reaction against the cost and wastefulness of open-ended military expenditure; and the realization of the comparative efficiency of civil as opposed to military space expenditure in stimulating industry.     

Space technology in the third world : Commercialization and the spread of ballistic missiles

The recent enthusiastic initiatives in the USA to commercialize space activities are also likely to facilitate and accelerate Third World ventures in space. This article outlines the history of Third World space activities and points to the danger that these nations will use satellite launch technology for military applications. Competitive economic and political pressures are aiding the migration of older missile technology to Third World Nations. The author argues for the establishment of an International Missile Technology Regime, which would limit the transfer of space launch technology to nations which are in full compliance with the 1968 Nuclear Non-Proliferation Treaty.     

耐高温杂化有机硅树脂的合成及复合材料的高温力学性能

以一甲基三甲氧基硅烷(MTMS)和正硅酸乙酯(TEOS)为原料,甲醇为溶剂,通过溶胶—凝胶法制备出SiO2杂化有机硅树脂.借助傅立叶变换红外光谱(FT-IR)表征其高温结构变化,热失重分析(TG)研究SiO2杂化有基硅树脂的热稳定性和热降解机理.对TEOS改性甲基硅树脂/石英纤维复合材料在高温下的弯曲强度测试表明,TE...     

A socio-economic evaluation of the lunar environment and resources: II. Energy for the selenosphere

This first of several study papers, based on a fundamental paper presented in 1972, provides an independent conceptual analysis and evaluation of the lunar environment as industrial base and habitat. A selenosphere system strategy is outlined. The underlying concept is that of one or several lunar industrial zones for resource extraction and on-surface processing, integrated with a circumlunar zero-g processing capability, serving markets in geolunar space. A classification of lunar elements by utilization category is presented. Lunar oxygen is a prime candidate for being an initial economic “drawing card”, because of its value for fast transportation in geolunar space, requiring significantly fewer ships for equal transfer capability per unit time than electric transports which, however, have value, especially between geosynchronous and lunar orbit. The reduced development difficulties of controlled fusion outside the atmosphere and its advantages for extracting oxygen and other elements in quantity are summarized. Examples of lunar cycle management as fundamental exoindustrial requirement for economic resource enhancement are presented. The principal initial socio-economic value of lunar industry lies in the use of lunar resources for exoindustrial products and operations designed to accelerate, intensify and diversify Earth-related benefits. In the longer run, lunar settlements are a highly suitable proving ground for studying and testing the complex matrix of technological, biological, cultural, social and psychological aspects that must be understood and manageable before large settlements beyond Earth can have a realistic basis for viability. The lunar environment is more suitable for experimentation and comparatively more “forgiving” in case of failures than is orbital space.     

Comparison of motion de-blur algorithms and real world deployment

If a camera moves fast while taking a picture, motion blur is induced. There exist techniques to prevent this effect to occur, such as moving the lens system or the CCD chip electro-mechanically. Another approach is to remove the motion blur after the images have been taken, using signal processing algorithms as post-processing techniques. For more than 30 years, numerous researchers have developed theories and algorithms for this purpose, which work quite well when applied to artificially blurred images. If one attempts to use those techniques to real world scenarios, they mostly fail miserably. In order to study why the known algorithms have problems to de-blur naturally blurred images we have built an experimental setup, which produces real blurred images with defined parameters in a controlled environment. For this article we have studied the most important algorithms used for de-blurring, we have analyzed their properties when applied to artificially blurred images and to real images. We propose solutions to make the algorithms fit for purpose.