Geochemistry of Carbonates on Mars: Implications for Climate History and Nature of Aqueous Environments

Ongoing research on martian meteorites and a new set of observations of carbonate minerals provided by an unprecedented series of robotic missions to Mars in the past 15 years help define new constraints on the history of martian climate with important crosscutting themes including: the CO₂ budget of Mars, the role of Mg-, Fe-rich fluids on Mars, and the interplay between carbonate formation and acidity. Carbonate minerals have now been identified in a wide range of localities on Mars as well as in several martian meteorites. The martian meteorites contain carbonates in low abundances (<1 vol.%) and with a wide range of chemistries. Carbonates have also been identified by remote sensing instruments on orbiting spacecraft in several surface locations as well as in low concentrations (2–5 wt.%) in the martian dust. The Spirit rover also identified an outcrop with 16 to 34 wt.% carbonate material in the Columbia Hills of Gusev Crater that strongly resembled the composition of carbonate found in martian meteorite ALH 84001. Finally, the Phoenix lander identified concentrations of 3–6 wt.% carbonate in the soils of the northern plains. The carbonates discovered to date do not clearly indicate the past presence of a dense Noachian atmosphere, but instead suggest localized hydrothermal aqueous environments with limited water availability that existed primarily in the early to mid-Noachian followed by low levels of carbonate formation from thin films of transient water from the late Noachian to the present. The prevalence of carbonate along with evidence for active carbonate precipitation suggests that a global acidic chemistry is unlikely and a more complex relationship between acidity and carbonate formation is present.     

Water in Extrasolar Planets and Implications for Habitability

Space Science Reviews - Exoplanet detection missions have found thousands of planets or planet candidates outside of the Solar System—some of which are in the habitable zone, where liquid...     

Near Surface Stratigraphy and Regolith Production in Southwestern Elysium Planitia,Mars: Implications for Hesperian-Amazonian Terrains and the InSight Lander Mission

The presence of rocks in the ejecta of craters at the InSight landing site in southwestern Elysium Planitia indicates a strong, rock-producing unit at depth. A finer regolith above is inferred by the lack of rocks in the ejecta of 10-m-scale craters. This regolith should be penetrable by the mole of the Heat Flow and Physical Properties Package (HP³). An analysis of the size-frequency distribution (SFD) of 7988 rocky ejecta craters (RECs) across four candidate landing ellipses reveals that all craters >200 m in diameter and \({<}750 \pm 30\ \mbox{Ma}\) in age have boulder-sized rocks in their ejecta. The frequency of RECs however decreases significantly below this diameter (\(D\)), represented by a roll-off in the SFD slope. At \(30\ \text{m} < D < 200\ \text{m}\), the slope of the cumulative SFD declines to near zero at \(D < 30\ \text{m}\). Surface modification, resolution limits, or human counting error cannot account for the magnitude of this roll-off. Rather, a significant population of <200 m diameter fresh non-rocky ejecta craters (NRECs) here indicates the presence of a relatively fine-grained regolith that prevents smaller craters from excavating the strong rock-producing unit. Depth to excavation relationships and the REC size thresholds indicate the region is capped by a regolith that is almost everywhere 3 m thick but may be as thick as 12 to 18 m. The lower bound of the thickness range is independently confirmed by the depth to the inner crater in concentric or nested craters. The data indicate that 85% of the InSight landing region is covered by a regolith that is at least 3 m thick. The probability of encountering rockier material at depths >3 m by the HP³ however increases significantly due to the increase in boulder-size rocks in the lower regolith column, near the interface of the bedrock.     

Water and Volatile Inventories of Mercury,Venus, the Moon,and Mars

We review the geochemical observations of water, \(\mbox{D}/\mbox{H}\) and volatile element abundances of the inner Solar System bodies, Mercury, Venus, the Moon, and Mars. We focus primarily on the inventories of water in these bodies, but also consider other volatiles when they can inform us about water. For Mercury, we have no data for internal water, but the reducing nature of the surface of Mercury would suggest that some hydrogen may be retained in its core. We evaluate the current knowledge and understanding of venusian water and volatiles and conclude that the venusian mantle was likely endowed with as much water as Earth of which it retains a small but non-negligible fraction. Estimates of the abundance of the Moon’s internal water vary from Earth-like to one to two orders of magnitude more depleted. Cl, K, and Zn isotope anomalies for lunar samples argue that the giant impact left a unique geochemical fingerprint on the Moon, but not the Earth. For Mars, an early magma ocean likely generated a thick crust; this combined with a lack of crustal recycling mechanisms would have led to early isolation of the Martian mantle from later delivery of water and volatiles from surface reservoirs or late accretion. The abundance estimates of Martian mantle water are similar to those of the terrestrial mantle, suggesting some similarities in the water and volatile inventories for the terrestrial planets and the Moon.     

Communication from Mars: Requirements and Limitations

The exploration of our nearest planets will require relaying large amounts of data to Earth for study and evaluation. However, our ability to communicate at interplanetary distances is limited. In this paper, an evaluation is made of our capability to communicate from the vicinity of Mars using the present S-band deep-space network, prospects for enhancing that performance, and limitations beyond which no additional improvement seems feasible. In addition, requirements for real-time television are evaluated and prospects for improving the communication rates by operating at higher microwave frequencies considered.     

物证DNA分析技术的过去与现在

使用DNA指纹鉴定技术不仅可得到可靠的否定结论,还可以得到可靠的认定结论.PCR技术极大地提高了检测生物检材的灵敏度.借助芯片技术可一次性对样品大量序列进行实时、灵敏、精确地检测和分析.从第一代分析方法应用于法庭科学开始,第二、第三代分析技术的诞生以及相继应用,使个人识别及亲子鉴定的结果愈来愈精确.     

Robot System to Search for Signs of Life on Mars

This describes a robot system that can be used to look for the tell-tale signs of life on Mars. Currently, NASA has satellites in orbit that can identify broad regions to explore in its search for life. NASA also has instruments that can examine samples of Martian soil to see if they contain any indications of biological activity. This leaves the problem of deciding specifically where to look for suitable samples in the large area around a landing site. This also describes a robot system that can rapidly search thousands of square meters around the landing position to find sources of biogenic gas samples that may harbor important clues in the search for extra-terrestrial life.     

An Approach to Searching for Life on Mars, Europa, and Enceladus

Near-term missions may be able to access samples of organic material from Mars, Europa, and Enceladus. The challenge for astrobiology will be to determine if this material is the remains of dead microorganisms or merely abiotic organic material. The remains of life that shares a common origin with life on Earth will be straightforward to detect using sophisticated methods such as DNA amplification. These methods are extremely sensitive but specific to Earth-like life. Detecting the remains of alien life—that does not have a genetic or biochemical commonality with Earth life—will be much more difficult. There is a general property of life that can be used to determine if organic material is of biological origin. This general property is the repeated use of a few specific organic molecules for the construction of biopolymers. For example, Earth-like life uses 20 amino acids to construct proteins, 5 nucleotide bases to construct DNA and RNA, and a few sugars to construct polysaccharides. This selectivity will result in a statistically anomalous distribution of organic molecules distinct from organic material of non-biological origin. Such a distinctive pattern, different from the pattern of Earth-like life, will be persuasive evidence for a second genesis of life.     

REMS: The Environmental Sensor Suite for the Mars Science Laboratory Rover

The Rover Environmental Monitoring Station (REMS) will investigate environmental factors directly tied to current habitability at the Martian surface during the Mars Science Laboratory (MSL) mission. Three major habitability factors are addressed by REMS: the thermal environment, ultraviolet irradiation, and water cycling. The thermal environment is determined by a mixture of processes, chief amongst these being the meteorological. Accordingly, the REMS sensors have been designed to record air and ground temperatures, pressure, relative humidity, wind speed in the horizontal and vertical directions, as well as ultraviolet radiation in different bands. These sensors are distributed over the rover in four places: two booms located on the MSL Remote Sensing Mast, the ultraviolet sensor on the rover deck, and the pressure sensor inside the rover body. Typical daily REMS observations will collect 180 minutes of data from all sensors simultaneously (arranged in 5 minute hourly samples plus 60 additional minutes taken at times to be decided during the course of the mission). REMS will add significantly to the environmental record collected by prior missions through the range of simultaneous observations including water vapor; the ability to take measurements routinely through the night; the intended minimum of one Martian year of observations; and the first measurement of surface UV irradiation. In this paper, we describe the scientific potential of REMS measurements and describe in detail the sensors that constitute REMS and the calibration procedures.     

Geochemical Reservoirs and Timing of Sulfur Cycling on Mars

Sulfate-dominated sedimentary deposits are widespread on the surface of Mars, which contrasts with the rarity of carbonate deposits, and indicates surface waters with chemical features drastically different from those on Earth. While the Earth’s surface chemistry and climate are intimately tied to the carbon cycle, it is the sulfur cycle that most strongly influences the Martian geosystems. The presence of sulfate minerals observed from orbit and in-situ via surface exploration within sedimentary rocks and unconsolidated regolith traces a history of post-Noachian aqueous processes mediated by sulfur. These materials likely formed in water-limited aqueous conditions compared to environments indicated by clay minerals and localized carbonates that formed in surface and subsurface settings on early Mars. Constraining the timing of sulfur delivery to the Martian exosphere, as well as volcanogenic H₂O is therefore central, as it combines with volcanogenic sulfur to produce acidic fluids and ice. Here, we reassess and review the Martian geochemical reservoirs of sulfur from the innermost core, to the mantle, crust, and surficial sediments. The recognized occurrences and the mineralogical features of sedimentary sulfate deposits are synthesized and summarized. Existing models of formation of sedimentary sulfate are discussed and related to weathering processes and chemical conditions of surface waters. We also review existing models of sulfur content in the Martian mantle and analyze how volcanic activities may have transferred igneous sulfur into the exosphere and evaluate the mass transfers and speciation relationships between volcanic sulfur and sedimentary sulfates. The sedimentary clay-sulfate succession can be reconciled with a continuous volcanic eruption rate throughout the Noachian-Hesperian, but a process occurring around the mid-Noachian must have profoundly changed the composition of volcanic degassing. A hypothetical increase in the oxidation state or in water content of Martian lavas or a decrease in atmospheric pressure is necessary to account for such a change in composition of volcanic gases. This would allow the pre mid-Noachian volcanic gases to be dominated by water and carbon-species but late Noachian and Hesperian volcanic gases to be sulfur-rich and characterized by high SO₂ content. Interruption of early dynamo and impact ejection of the atmosphere may have decreased the atmospheric pressure during the early Noachian whereas it remains unclear how the redox state or water content of lavas could have changed. Nevertheless, volcanic emission of SO₂ rich gases since the late Noachian can explain many features of Martian sulfate-rich regolith, including the mass of sulfate and the particular chemical features (i.e. acidity) of surface waters accompanying these deposits. How SO₂ impacted on Mars’s climate, with possible short time scale global warming and long time scale cooling effects, remains controversial. However, the ancient wet and warm era on Mars seems incompatible with elevated atmospheric sulfur dioxide because conditions favorable to volcanic SO₂ degassing were most likely not in place at this time.     

火星探测器气动外形/弹道一体化多目标优化

针对火星探测器概念设计阶段的需求,提出了融合气动外形、弹道和开伞条件的一体化多目标优化设计方法。首先建立了火星探测器进入段三自由度弹道运动方程,基于修正牛顿理论推导了适用于具有较大半锥角球锥外形的气动参数估算模型,采用Sutton-Graves公式计算了驻点热流密度。以开伞高度、总吸热量和容积率为目标函数建立了火星探测器气动外形/弹道一体化多目标优化模型,采用基于分解的多目标进化算法(MOEA/D)进行求解计算并与参考设计进行了对比。数值结果表明:多目标优化方法提供多个三目标均优于参考设计的Pareto最优解,为火星探测器的概念设计提供了一定的参考依据。     

Planetary Magnetic Fields and Solar Forcing: Implications for Atmospheric Evolution

The solar wind and the solar XUV/EUV radiation constitute a permanent forcing of the upper atmosphere of the planets in our solar system, thereby affecting the habitability and chances for life to emerge on a planet. The forcing is essentially inversely proportional to the square of the distance to the Sun and, therefore, is most important for the innermost planets in our solar system—the Earth-like planets. The effect of these two forcing terms is to ionize, heat, chemically modify, and slowly erode the upper atmosphere throughout the lifetime of a planet. The closer to the Sun, the more efficient are these process. Atmospheric erosion is due to thermal and non-thermal escape. Gravity constitutes the major protection mechanism for thermal escape, while the non-thermal escape caused by the ionizing X-rays and EUV radiation and the solar wind require other means of protection. Ionospheric plasma energization and ion pickup represent two categories of non-thermal escape processes that may bring matter up to high velocities, well beyond escape velocity. These energization processes have now been studied by a number of plasma instruments orbiting Earth, Mars, and Venus for decades. Plasma measurement results therefore constitute the most useful empirical data basis for the subject under discussion. This does not imply that ionospheric plasma energization and ion pickup are the main processes for the atmospheric escape, but they remain processes that can be most easily tested against empirical data. Shielding the upper atmosphere of a planet against solar XUV, EUV, and solar wind forcing requires strong gravity and a strong intrinsic dipole magnetic field. For instance, the strong dipole magnetic field of the Earth provides a “magnetic umbrella”, fending of the solar wind at a distance of 10 Earth radii. Conversely, the lack of a strong intrinsic magnetic field at Mars and Venus means that the solar wind has more direct access to their topside atmosphere, the reason that Mars and Venus, planets lacking strong intrinsic magnetic fields, have so much less water than the Earth? Climatologic and atmospheric loss process over evolutionary timescales of planetary atmospheres can only be understood if one considers the fact that the radiation and plasma environment of the Sun has changed substantially with time. Standard stellar evolutionary models indicate that the Sun after its arrival at the Zero-Age Main Sequence (ZAMS) 4.5 Gyr ago had a total luminosity of ≈70% of the present Sun. This should have led to a much cooler Earth in the past, while geological and fossil evidence indicate otherwise. In addition, observations by various satellites and studies of solar proxies (Sun-like stars with different age) indicate that the young Sun was rotating more than 10 times its present rate and had correspondingly strong dynamo-driven high-energy emissions which resulted in strong X-ray and extreme ultraviolet (XUV) emissions, up to several 100 times stronger than the present Sun. Further, evidence of a much denser early solar wind and the mass loss rate of the young Sun can be determined from collision of ionized stellar winds of the solar proxies, with the partially ionized gas in the interstellar medium. Empirical correlations of stellar mass loss rates with X-ray surface flux values allows one to estimate the solar wind mass flux at earlier times, when the solar wind may have been more than 1000 times more massive. The main conclusions drawn on basis of the Sun-in-time-, and a time-dependent model of plasma energization/escape is that:

1. Solar forcing is effective in removing volatiles, primarily water, from planets,
2. planets orbiting close to the early Sun were subject to a heavy loss of water, the effect being most profound for Venus and Mars, and
3. a persistent planetary magnetic field, like the Earth’s dipole field, provides a shield against solar wind scavenging.

     

Particle Acceleration in the Heliosphere: Implications for Astrophysics

There has been a remarkable discovery concerning particles that are accelerated in the solar wind. At low energies, in the region where the particles are being accelerated, the spectrum of the accelerated particles is always the same: when expressed as a distribution function, the spectrum is a power law in particle speed with a spectral index of ?5, and a rollover at higher particle speeds that can often be described as exponential. This common spectral shape cannot be accounted for by any conventional acceleration mechanism, such as diffusive shock acceleration or traditional stochastic acceleration. It has thus been necessary to invent a new acceleration mechanism to account for these observations, a pump mechanism in which particles are pumped up in energy through a series of adiabatic compressions and expansions. The conditions under which the pump acceleration is the dominant acceleration mechanism are quite general and are likely to occur in other astrophysical plasmas. In this paper, the most compelling observations of the ?5 spectra are reviewed; the governing equation of the pump acceleration mechanism is derived in detail; the pump acceleration mechanism is applied to acceleration at shocks; and, as an illustration of the potential applicability of the pump acceleration mechanism to other astrophysical plasmas, the pump mechanism is applied to the acceleration of galactic cosmic rays in the interstellar medium.     

Characterization and Calibration of the CheMin Mineralogical Instrument on Mars Science Laboratory

A principal goal of the Mars Science Laboratory (MSL) rover Curiosity is to identify and characterize past habitable environments on Mars. Determination of the mineralogical and chemical composition of Martian rocks and soils constrains their formation and alteration pathways, providing information on climate and habitability through time. The CheMin X-ray diffraction (XRD) and X-ray fluorescence (XRF) instrument on MSL will return accurate mineralogical identifications and quantitative phase abundances for scooped soil samples and drilled rock powders collected at Gale Crater during Curiosity’s 1-Mars-year nominal mission. The instrument has a Co X-ray source and a cooled charge-coupled device (CCD) detector arranged in transmission geometry with the sample. CheMin’s angular range of 5^° to 50^° 2θ with <0.35^° 2θ resolution is sufficient to identify and quantify virtually all minerals. CheMin’s XRF requirement was descoped for technical and budgetary reasons. However, X-ray energy discrimination is still required to separate Co?Kα from Co?Kβ and Fe?Kα photons. The X-ray energy-dispersive histograms (EDH) returned along with XRD for instrument evaluation should be useful in identifying elements Z>13 that are contained in the sample. The CheMin XRD is equipped with internal chemical and mineralogical standards and 27 reusable sample cells with either Mylar^? or Kapton^? windows to accommodate acidic-to-basic environmental conditions. The CheMin flight model (FM) instrument will be calibrated utilizing analyses of common samples against a demonstration-model (DM) instrument and CheMin-like laboratory instruments. The samples include phyllosilicate and sulfate minerals that are expected at Gale crater on the basis of remote sensing observations.