PS-PVD用CeO2掺杂8YSZ团聚粉末及其涂层

在纳米ZrO₂-8%Y₂O₃(摩尔分数)(8YSZ)粉末中掺杂20%(质量分数)微米级CeO₂粉末,并通过喷雾干燥合成CeO₂-8YSZ(CYSZ)复合团聚粉体。借助激光粒度仪和扫描电镜(SEM)及附带能谱仪(EDS)考察羧甲基纤维素黏结剂(carboxymethyl cellulose,CMC)质量分数对复合团聚粉体性能影响。采用PS-PVD制备具有柱状结构的CYSZ热障涂层,对涂层截面和表面进行EDS分析。采用X射线衍射(XRD)和X射线光电子能谱(XPS)分析涂层物相。结果表明:黏结剂质量分数达到2%时可获得球形度高、粒度分布均匀的团聚粉体;制备的涂层中Ce元素呈均匀分布;涂层物相基本为t-相结构,其中Ce⁴⁺取代Zr⁴⁺进入ZrO₂晶格形成类质同象的固溶体结构,显示出CeO₂掺杂对t-相向m-相转变的抑制作用;所制备CYSZ涂层在1100℃,水冷循环100次后仍保持完整,展现出较高的抗热冲击性能。     

High-temperature oxidation behavior and analysis of impedance spectroscopy of 7YSZ thermal barrier coating prepared by plasma spray-physical vapor deposition

Quasi-columnar structure 7YSZ(yttria stabilized zirconia) thermal barrier coatings(TBCs) are prepared by plasma spray-physical vapor deposition(PS-PVD) onto pretreated and un-pretreated bond coating, respectively. An isothermal oxidation experiment of 7YSZ TBCs is carried out in the atmosphere of 950 °C in order to simulate the high-temperature oxidation process of engine blades. The isothermal oxidation process of 7YSZ thermal barrier coatings is investigated systematically by impedance spectroscopy. The electrochemical physical model and equivalent circuit of columnar 7YSZ coatings are established. Results show that the isothermal oxidation kinetic curve of columnar 7YSZ thermal barrier coatings appears to follow the parabolic law. A pretreatment of bond coating can reduce the growth rate of the thermally grown oxide(TGO) layer, restraining the initiation and propagation of microcracks between YSZ and TGO layers. The oxidation rate constants of 7YSZ coatings with pretreated and un-pretreated bond coating are 0.101×10~(-12) cm~2·s~(-1) and 0.115 × 10~(-13) cm~2 ·s~(-1), respectively. Impedance analysis shows that the content of oxygen vacancies decreases and the density increases after the TGO layer is oxidized for 150 h. In addition, shrinkage microcracks formed by sintering during the oxidation process is the main reason for an increase of the capacitance and a decrease of the resistance in the grain boundary of YSZ.     

Coating deposition regularity depended on orientation difference in PS-PVD plasma jet

The YSZ coatings are prepared by the plasma spray-physical vapor deposition(PS-PVD)technology based on a specific experimental design. The structure, thickness and growth angle of YSZ coatings on the entire circumferential surface of the cylindrical sample are studied. The results indicated that the structure, thickness and deflection growth angle of YSZ coatings are related to the orientation of deposition location. The numerical simulation of the multiphase mixed fluid near the substrate is ca...     

基于成核理论的水温对结冰黏附强度影响研究

飞机结冰会影响飞行安全,甚至导致严重的飞行事故。研究积冰与基底的黏附强度,可以为飞机防除冰系统的设计提供具体的指标要求。设计剪切黏附力测量实验平台,并利用该平台测量基底在不同冻结用水初始温度下的结冰黏附力;采集水/冰在冻结过程中的温度变化,并通过成核理论分析实验现象,着重研究冻结用水的初始温度对黏附强度的影响。结果表明：冻结水温初始温度的增加会促进冰晶成核,进而提高黏附强度。     

喷枪空间行进速率对等离子喷涂Mo/8YSZ复合涂层温度场的影响

为了突破传统金属/陶瓷双层热防护涂层高温环境易剥离的技术瓶颈,研究喷枪空间行进速率变化对等离子喷涂Mo/8YSZ复合涂层时间域及空间域温度场分布的影响规律。利用ANSYS有限元分析软件,建立等离子喷涂Mo/8YSZ功能梯度热障涂层的数值模型,考虑材料不同温度下的热物性参数和材料的相变潜热,通过分析不同喷枪空间行进速率下喷涂构件的温度与温度梯度发现:在喷涂过程的同一时刻,喷枪行进速率越大,单位长度内喷枪与构件相互作用的时间越少,构件的最大温度值越小,构件上表面温度分布的均匀性越高,构件的最大温度梯度值越小;先沉积的涂层对后沉积的涂层存在预热作用,基体的最大温度值呈台阶式升高的变化趋势;随着涂层厚度的增加,涂层的热阻增加,基体温度的波动幅度逐渐减小;通过调控各涂层的喷枪行进速率,可进一步减小构件的温度梯度,按照黏结层最大、过渡层次之、陶瓷层最小的顺序进行喷涂时,喷涂构件的温度梯度最小。     

Distributed coordinated control scheme of UAV swarm based on heterogeneous roles

This paper proposes a new distributed coordinated control scheme based on heterogeneous roles for Unmanned Aerial Vehicle(UAV) swarm to achieve formation control. First, the framework of the distributed coordinated control scheme is designed on the basis of Distributed Model Predictive Control(DMPC). Then, the effect of heterogeneous roles including leader, coordinator and follower is discussed, and the role-based cost functions are developed to improve the performance of coordinated control for...