D/H and Nearby Interstellar Cloud Structures

Analysis of UV spectra obtained with the HST, FUSE and other satellites provides a new understanding of the deuterium abundance in the local region of the galactic disk. The wide range of gas-phase D/H measurements obtained outside of the Local Bubble can now be explained as due to different amounts of deuterium depletion on carbonaceous grains. The total D/H ratio including deuterium in the gas and dust phases is at least 23 parts per million of hydrogen, which is providing a challenge to models of galactic chemical evolution. Analysis of HST and ground-based spectra of many lines of sight to stars within the Local Bubble have identified interstellar velocity components that are consistent with more than 15 velocity vectors. We have identified the structures of 15 nearby warm interstellar clouds on the basis of these velocity vectors and common temperatures and depletions. We estimate the distances and masses of these clouds and compare their locations with cold interstellar clouds.     

The Composition of Interstellar Molecular Clouds

We consider four aspects of interstellar chemistry for comparison with comets: molecular abundances in general, relative abundances of isomers (specifically, HCN and HNC), ortho/para ratios for molecules, and isotopic fractionation, particularly for the ratio hydrogen/deuterium. Since the environment in which the solar system formed is not well constrained, we consider both isolated dark clouds where low mass stars may form and the "hot cores" that are the sites of high mass star formation. Attention is concentrated on the gas phase, since the grains are considered elsewhere in this volume. This revised version was published online in June 2006 with corrections to the Cover Date.     

Deuterium Fractionation in Interstellar Clouds

This paper reviews the chemical processes responsible for fractionating deuterium in interstellar molecules. I show that this process is intrinsically a low temperature phenomenon and discuss how the degree of enhancement of the deuterium content of molecules is related to the physical conditions, particularly abundances, in molecular clouds. If significant amounts of abundant species, such as CO, are frozen out on to interstellar dust grains, the resulting enhancement in H₂D⁺ can result in its abundance being greater than that of H ₃ ⁺ at 10K. Transfer of the deuteron from H₂D⁺ can then lead to the efficient formation of multiply deuterated species, such as NHD₂ and ND₃. Fractionation can also occur in grain surface reactions and some simple models are discussed. This revised version was published online in August 2006 with corrections to the Cover Date.     

Isotopic Fractionation by Ion-Molecule Reactions

Isotopic fractionation in interstellar clouds can occur by ion-molecule reactions at low temperatures. The major effect is not kinetic but thermodynamic in origin in that it arises from the difference in rate coefficients between forward and backward directions in reactions which exchange isotopic atoms. In this article, we concentrate on deuterium fractionation in interstellar clouds; this effect enhances the relative abundances of deuterated isotopomers to their normal counterparts by up to four orders of magnitude as compared with the basic D/H elemental abundance ratio. We also discuss the fractionation of ¹⁵N and ¹³C. This revised version was published online in August 2006 with corrections to the Cover Date.     

Recent progress in astrochemistry

Models of the four currently recognized regimes of astrochemistry are compared with observations. Ion-Molecule Gas Phase Chemistry is fundamental throughout all interstellar and circumstellar molecular clouds, and by itself explains fairly well the simpler molecular species in diffuse and cold quiescent dense interstellar clouds, as well as in the outer envelopes of circumstellar clouds. Dust-Grain Chemistry may modify ion-molecule chemistry noticeably in regions containing UV radiation, shocks, or other heating agents which can serve to promote surface reactions and to desorb molecules frozen on grains; it likely plays no role in cold quiescent clouds except to adsorb gas phase molecules. Shock Chemistry occurs in regions of star formation and appears important in explaining certain molecular species and in disrupting grains. Circumstellar envelopes combine several chemistries, including those of thermochemical equilibrium in the dense inner regions, and ion-molecule in the outer regions, with grain processes also likely. The limitations of all current models are lack of knowledge of reaction rates, of detailed physical conditions (interstellar clouds), and of the relative depletions (onto grains) of the chemical elements, as well as grain surface chemistry in general. In both interstellar and circumstellar objects, ion-molecule gas phase models are now quite successful in explaining, semi-quantitatively, observed species with up to 4 atoms, but difficulties remain for larger species, as well as the state of carbon, and the models are not yet very predictive.NRAO is operated by Associated Universities Inc. under contract with NSF.     

Spectroscopy Between the Stars

The emission and absorption spectra of interstellar molecules are reviewed with special consideration of recent observational and technical advances in the shorter submillimeter wave region of the electromagnetic spectrum. Single-dish observations have contributed in the past probably most of the information about the structure of interstellar molecular clouds. At present about 120 interstellar molecules have been identified in interstellar clouds and circumstellar envelopes, evidence of a rich and diversified chemistry. CO, the most abundant interstellar molecule and other diatomic molecules and radicals are found throughout molecular clouds, whereas the more complex molecules are found in high-density cores, which are often the sites of active star formation. These locations represent prime targets for the search for larger molecules, such as glycine. The ignition of young stars is accompanied by strong heating of the surrounding material by radiation and/or shocks, leading to photoevaporation of molecules depleted on dust grains driving a "hot core" chemistry, traceable by its rich organic chemistry and its prevailing high excitation conditions (up to about 2000 cm^-1). However, in the list of detected interstellar molecules many simple hydrides are still missing, e.g. SH, PH, PH₂, etc., which constitute the building blocks for larger molecules. With the technological opening of the terahertz region (ν ∼1 THz corresponds to λ ∼0.3 mm) to both laboratory and interstellar spectroscopy, great scientific advances are to be expected. Amongst these will be the direct detection of the lowest rotational transitions of the light hydrides, the low energy bending vibrations of larger (linear) molecules, and possibly the ring-puckering motion of larger ring molecules such as the polycyclic (multiring) aromatic hydrocarbons. This revised version was published online in June 2006 with corrections to the Cover Date.     

Big Bang Nucleosynthesis and the Density of Baryons in the Universe

Now that extragalactic deuterium observations are being made, Big Bang Nucleosynthesis (BBN) is on the verge of undergoing a transformation. Previously, the emphasis was on demonstrating the concordance of the Big Bang Nucleosynthesis model with the abundances of the light isotopes extrapolated back to their primordial values using stellar and Galactic evolution theories. Once the primordial deuterium abundance is converged upon, the nature of the field will shift to using the much more precise primordial D/H to constrain the more flexible stellar and Galactic evolution models (although the question of potential systematic error in 4He abundance determinations remains open). The remarkable success of the theory to date in establishing the concordance has led to the very robust conclusion of BBN regarding the baryon density. The BBN constraints on the cosmological baryon density are reviewed and demonstrate that the bulk of the baryons are dark and also that the bulk of the matter in the universe is non-baryonic. Comparison of baryonic density arguments from Lyman- clouds, x-ray gas in clusters, and the microwave anisotropy are made and shown to be consistent with the BBN value.     

Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Reaction Networks for Interstellar Chemical Modelling: Improvements and Challenges

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes—ion-neutral reactions, neutral-neutral reactions, radiative association, and dissociative recombination—is reviewed. Emphasis is placed on those key reactions that have been identified, by sensitivity analyses, as ‘crucial’ in determining the predicted abundances of the species observed in the interstellar medium. These sensitivity analyses have been carried out for gas-phase models of three representative, molecule-rich, astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the expanding circumstellar envelope IRC +10216. Our review has led to the proposal of new values and uncertainties for the rate coefficients of many of the key reactions. The impact of these new data on the predicted abundances in TMC-1 and L134N is reported. Interstellar dust particles also influence the observed abundances of molecules in the interstellar medium. Their role is included in gas-grain, as distinct from gas-phase only, models. We review the methods for incorporating both accretion onto, and reactions on, the surfaces of grains in such models, as well as describing some recent experimental efforts to simulate and examine relevant processes in the laboratory. These efforts include experiments on the surface-catalyzed recombination of hydrogen atoms, on chemical processing on and in the ices that are known to exist on the surface of interstellar grains, and on desorption processes, which may enable species formed on grains to return to the gas-phase.     

The D/H Ratio in Chondrites

The statistical distribution of all available published D/H ratios of carbonaceous chondrites is presented. The possible interpretations of this distribution are reviewed at the global scale of the solar system planetary objects and at the scale defined by the carbonaceous meteorites. New issues concerning the chemical origin of the deuterium enrichment in solar system water and organic molecules are put into light by this exercise. This distribution is a robust constraint on the origin of water on Earth. This revised version was published online in August 2006 with corrections to the Cover Date.     

Coupled Clouds and Chemistry of the Giant Planets— A Case for Multiprobes

In seeking to understand the formation of the giant planets and the origin of their atmospheres, the heavy element abundance in well-mixed atmosphere is key. However, clouds come in the way. Thus, composition and condensation are intimately intertwined with the mystery of planetary formation and atmospheric origin. Clouds also provide important clues to dynamical processes in the atmosphere. In this chapter we discuss the thermochemical processes that determine the composition, structure, and characteristics of the Jovian clouds. We also discuss the significance of clouds in the big picture of the formation of giant planets and their atmospheres. We recommend multiprobes at all four giant planets in order to break new ground.     

模拟存在运动激波流场的无网格自适应算法

将无网格自适应算法发展用于求解存在运动激波的非定常流动问题。为了降低初始布点要求,同时提高对运动激波的分辨率,提出了一种结合点云加密和点云粗化的动态点云技术。采用该技术,在非定常计算的每一个时间步,首先通过基于压强梯度的流场探针识别出激波所在位置,然后对激波附近点云进行加密,从而提高对激波的分辨率,同时对远离激波的点云进行粗化,尽可能减少冗余节点,提高计算效率。采用所提出的无网格自适应算法求解了N-S方程,首先对一维运动激波问题进行了数值模拟,通过将数值模拟结果与精确解比较,验证了所提算法求解存在运动激波的非定常流动的可行性,在此基础上,将方法推广用于二维非定常流动问题的求解,分别对瞬时激波碰撞圆柱以及双弧翼型激波振荡流动进行了数值模拟,计算结果表明,方法可以显著提高对激波的分辨率,同时相对于直接采用较密布点的非自适应算法,自适应算法在计算效率上具有优势。     

The Cassini Ultraviolet Imaging Spectrograph Investigation

The Cassini Ultraviolet Imaging Spectrograph (UVIS) is part of the remote sensing payload of the Cassini orbiter spacecraft. UVIS has two spectrographic channels that provide images and spectra covering the ranges from 56 to 118 nm and 110 to 190 nm. A third optical path with a solar blind CsI photocathode is used for high signal-to-noise-ratio stellar occultations by rings and atmospheres. A separate Hydrogen Deuterium Absorption Cell measures the relative abundance of deuterium and hydrogen from their Lyman-α emission. The UVIS science objectives include investigation of the chemistry, aerosols, clouds, and energy balance of the Titan and Saturn atmospheres; neutrals in the Saturn magnetosphere; the deuterium-to-hydrogen (D/H) ratio for Titan and Saturn; icy satellite surface properties; and the structure and evolution of Saturn’s rings.This revised version was published online in July 2005 with a corrected cover date.     

A spectroscopic method for measuring turbulence in QSO Lyα forest clouds

The effects of a finite correlation length of a turbulent velocity field on the line formation process are considered for hydrogen absorption lines observed in quasar spectra. It is shown that both thermal and large-scale stochastic motions with a finite correlation length (0<l<) lead in general tosmaller equivalent widths of hydrogen lines than in the case when macroscopic motions are assumed to be completely uncorrelated (l0). Different influence of this effect on optically thin and thick absorption lines allows us to measure eventually turbulent characteristics of the gas in the Ly forest clouds. It is emphasized that possible measurements of the deuterium abundance in the early Universe could yield systematically higher ratios of D/H if the finite-correlation-length effects are ignored.     

Deuterium Observations in the Galaxy

An accurate measurement of the primordial value of D/H would provide one of the best tests of nucleosynthesis models for the early Universe and the baryon density. Such evaluations have been traditionally made using present estimations of the deuterium abundance in the interstellar medium, extrapolated backwards in time with the use of galactic evolution models. Direct estimations of the primordial deuterium abundance have been carried out only recently in QSOs absorbers at high redshift.We will summarize galactic observations of deuterium and suggest that, perhaps, a single D/H value for the interstellar medium is not representative. These evaluations mainly came from observations completed in the far UV with first the Copernicus satellite over the Lyman lines series followed then by H and D Lyman-alpha lines observations with both the IUE and the GHRS on the Hubble Space Telescope. We discuss different known systematics and show that the situation is not yet clear. It is not possible today to claim that we know "the" D/H value in the interstellar medium, if any.Overall and in the context of additional D observations made in the solar system, we conclude that the actual evolution of deuterium from Big-Bang nucleosynthesis to now is not yet understood. More observations, recently made with IMAPS (the Interstellar Medium Absorption Profile Spectrograph) and hopefully to be made with FUSE (the Far Ultraviolet Spectroscopic Explorer to be launched in the fall of 1998), at higher spectral resolution or in many different galactic sites are certainly needed to help us reach a better global view of the evolution of that key element, and thus better constrain any evaluation of its primordial abundance.     

A point cloud deep neural network metamodel method for aerodynamic prediction

Aiming to reduce the high expense of 3-Dimensional (3D) aerodynamics numerical simulations and overcome the limitations of the traditional parametric learning methods, a point cloud deep learning non-parametric metamodel method is proposed in this paper. The 3D geometric data, corresponding to the object boundaries, are chosen as point clouds and a deep learning neural network metamodel fed by the point clouds is further established based on the PointNet architecture. This network can learn an end-to-end mapping between spatial positions of the object surface and CFD numerical quantities. With the proposed aerodynamic metamodel approach, the point clouds are constructed by collecting the coordinates of grid vertices on the object surface in a CFD domain, which can maintain the boundary smoothness and allow the network to detect small changes between geometries. Moreover, the point clouds are easily accessible from 3D sensors. The point cloud deep learning neural network, which employs re-sampling technique, the spatial transformer network and the fully connected layer, is developed to predict the aerodynamic characteristics of 3D geometry. The effectiveness of the proposed metamodel method is further verified by aerodynamic prediction and robust shape optimization of the ONERA M6 wing. The results show that the proposed method can achieve more satisfactory agreement with the experimental measurements compared to the parametric-learning-based deep neural network.     

Collisionless Shocks in Partly Ionized Plasma with Cosmic Rays: Microphysics of Non-thermal Components

In this review we discuss some observational aspects and theoretical models of astrophysical collisionless shocks in partly ionized plasma with the presence of non-thermal components. A specific feature of fast strong collisionless shocks is their ability to accelerate energetic particles that can modify the shock upstream flow and form the shock precursors. We discuss the effects of energetic particle acceleration and associated magnetic field amplification and decay in the extended shock precursors on the line and continuum multi-wavelength emission spectra of the shocks. Both Balmer-type and radiative astrophysical shocks are discussed in connection to supernova remnants interacting with partially neutral clouds. Quantitative models described in the review predict a number of observable line-like emission features that can be used to reveal the physical state of the matter in the shock precursors and the character of nonthermal processes in the shocks. Implications of recent progress of gamma-ray observations of supernova remnants in molecular clouds are highlighted.     

铝颗粒云燃烧研究进展

为探究铝颗粒云燃烧特性,把握其研究进展,并为后续研究工作提供参考,本文首先简述了铝颗粒点火、燃烧过程,总结了铝颗粒燃烧机理;其次,综述了铝颗粒云燃烧的实验、理论和模拟研究进展,从不同维度分析了影响颗粒云火焰速度的关键参数,并提出颗粒云燃烧的研究方向,包括提升颗粒云燃烧实验颗粒分散均匀性与表征精度、降低火焰传播速度等实验结果散差、改善颗粒云燃烧理论预测模型精度及构建实用的颗粒云燃烧模拟CFD模型。     

Charge Structure and Dynamics in Thunderstorms

The electrical structure inside thunderstorm clouds and the changes with time of this structure are fundamental parameters for atmospheric electricity studies on Earth. This paper gives a review of the current state of knowledge about thunderstorm charge structure based primarily on in-cloud vertical profiles through different types of deep convective clouds, cirriform anvil clouds, and stratiform precipitation regions associated with mid-latitude mesoscale convective systems. Results on the dynamical evolution of the vertical charge structure during the early and decay stages from series of balloon soundings through small thunderstorms are described, along with recent findings regarding the importance of the charge structure in determining the current contribution of small and large thunderstorms to the Earth’s global electrical circuit.