Cratering Chronology and the Evolution of Mars

Results by Neukum et al. (2001) and Ivanov (2001) are combined with crater counts to estimate ages of Martian surfaces. These results are combined with studies of Martian meteorites (Nyquist et al., 2001) to establish a rough chronology of Martian history. High crater densities in some areas, together with the existence of a 4.5 Gyr rock from Mars (ALH84001), which was weathered at about 4.0 Gyr, affirm that some of the oldest surfaces involve primordial crustal materials, degraded by various processes including megaregolith formation and cementing of debris. Small craters have been lost by these processes, as shown by comparison with Phobos and with the production function, and by crater morphology distributions. Crater loss rates and survival lifetimes are estimated as a measure of average depositional/erosional rate of activity.We use our results to date the Martian epochs defined by Tanaka (1986). The high crater densities of the Noachian confine the entire Noachian Period to before about 3.5 Gyr. The Hesperian/Amazonian boundary is estimated to be about 2.9 to 3.3 Gyr ago, but with less probability could range from 2.0 to 3.4 Gyr. Mid-age dates are less well constrained due to uncertainties in the Martian cratering rate. Comparison of our ages with resurfacing data of Tanaka et al. (1987) gives a strong indication that volcanic, fluvial, and periglacial resurfacing rates were all much higher in approximately the first third of Martian history. We estimate that the Late Amazonian Epoch began a few hundred Myr ago (formal solutions 300 to 600 Myr ago). Our work supports Mariner 9 era suggestions of very young lavas on Mars, and is consistent with meteorite evidence for Martian igneous rocks 1.3 and 0.2 – 0.3 Gyr old. The youngest detected Martian lava flows give formal crater retention ages of the order 10 Myr or less. We note also that certain Martian meteorites indicate fluvial activity younger than the rock themselves, 700 Myr in one case, and this is supported by evidence of youthful water seeps. The evidence of youthful volcanic and aqueous activity, from both crater-count and meteorite evidence, places important constraints on Martian geological evolution and suggests a more active, complex Mars than has been visualized by some researchers.     

X-Rays From Mars

X-rays from Mars were first detected in July 2001 with the satellite Chandra. The main source of this radiation was fluorescent scattering of solar X-rays in its upper atmosphere. In addition, the presence of an extended X-ray halo was indicated, probably resulting from charge exchange interactions between highly charged heavy ions in the solar wind and neutrals in the Martian exosphere. The statistical significance of the X-ray halo, however, was very low. In November 2003, Mars was observed again in X-rays, this time with the satellite XMM-Newton. This observation, characterized by a considerably higher sensitivity, confirmed the presence of the X-ray halo and proved that charge exchange is indeed the origin of the emission. This was the first definite detection of charge exchange induced X-ray emission from the exosphere of another planet. Previously, this kind of emission had been detected from comets (which are largely exospheres) and from the terrestrial exosphere. Because charge exchange interactions between atmospheric constituents and solar wind ions are considered as an important nonthermal escape mechanism, probably responsible for a significant loss of the Martian atmosphere, X-ray observations may lead to a better understanding of the present state of the Martian atmosphere and its evolution. X-ray images of the Martian exosphere in specific emission lines exhibited a highly anisotropic morphology, varying with individual ions and ionization states. With its capability to trace the X-ray emission out to at least 8 Mars radii, XMM-Newton can explore exospheric regions far beyond those that have been observationally explored to date. Thus, X-ray observations provide a novel method for studying processes in the Martian exosphere on a global scale.     

The Hydrogen Exospheric Density Profile Measured with ASPERA-3/NPD

We have evaluated the Lyman-α limb emission from the exospheric hydrogen of Mars measured by the neutral particle detector of the ASPERA-3 instrument on Mars Express in 2004 at low solar activity (solar activity index = 42, F_10.7=100). We derive estimates for the hydrogen exobase density, n _H = 10¹⁰ m^?3, and for the apparent temperature, T > 600 K. We conclude that the limb emission measurement is dominated by a hydrogen component that is considerably hotter than the bulk temperature at the exobase. The derived values for the exosphere density and temperature are compared with similar measurements done by the Mariner space probes in the 1969. The values found with Mars Express and Mariner data are brought in a broader context of exosphere models including the possibility of having two hydrogen components in the Martian exosphere. The present observation of the Martian hydrogen exosphere is the first one at high altitudes during low solar activity, and shows that for low solar activity exospheric densities are not higher than for high solar activity.     

Geophysical Constraints on the Evolution of Mars

The evolution of Mars is discussed using results from the recent Mars Global Surveyor (MGS) and Mars Pathfinder missions together with results from mantle convection and thermal history models and the chemistry of Martian meteorites. The new MGS topography and gravity data and the data on the rotation of Mars from Mars Pathfinder constrain models of the present interior structure and allow estimates of present crust thickness and thickness variations. The data also allow estimates of lithosphere thickness variation and heat flow assuming that the base of the lithosphere is an isotherm. Although the interpretation is not unambiguous, it can be concluded that Mars has a substantial crust. It may be about 50 km thick on average with thickness variations of another ±50 km. Alternatively, the crust may be substantially thicker with smaller thickness variations. The former estimate of crust thickness can be shown to be in agreement with estimates of volcanic production rates from geologic mapping using data from the camera on MGS and previous missions. According to these estimates most of the crust was produced in the Noachian, roughly the first Gyr of evolution. A substantial part of the lava generated during this time apparently poured onto the surface to produce the Tharsis bulge, the largest tectonic unit in the solar system and the major volcanic center of Mars. Models of crust growth that couple crust growth to mantle convection and thermal evolution are consistent with an early 1 Gyr long phase of vigorous volcanic activity. The simplest explanation for the remnant magnetization of crustal units of mostly the southern hemisphere calls for an active dynamo in the Noachian, again consistent with thermal history calculations that predict the core to become stably stratified after some hundred Myr of convective cooling and dynamo action. The isotope record of the Martian meteorites suggest that the core formed early and rapidly within a few tens of Myr. These data also suggest that the silicate rock component of the planet was partially molten during that time. The isotope data suggest that heterogeneity resulted from core formation and early differentiation and persisted to the recent past. This is often taken as evidence against vigorous mantle convection and early plate tectonics on Mars although the latter assumption can most easily explain the early magnetic field. The physics of mantle convection suggests that there may be a few hundred km thick stagnant, near surface layer in the mantle that would have formed rapidly and may have provided the reservoirs required to explain the isotope data. The relation between the planform of mantle convection and the tectonic features on the surface is difficult to entangle. Models call for long wavelength forms of flow and possibly a few strong plumes in the very early evolution. These plumes may have dissolved with time as the core cooled and may have died off by the end of the Noachian.     

Geochemical Consequences of Widespread Clay Mineral Formation in Mars’ Ancient Crust

Clays form on Earth by near-surface weathering, precipitation in water bodies within basins, hydrothermal alteration (volcanic- or impact-induced), diagenesis, metamorphism, and magmatic precipitation. Diverse clay minerals have been detected from orbital investigation of terrains on Mars and are globally distributed, indicating geographically widespread aqueous alteration. Clay assemblages within deep stratigraphic units in the Martian crust include Fe/Mg smectites, chlorites and higher temperature hydrated silicates. Sedimentary clay mineral assemblages include Fe/Mg smectites, kaolinite, and sulfate, carbonate, and chloride salts. Stratigraphic sequences with multiple clay-bearing units have an upper unit with Al-clays and a lower unit with Fe/Mg-clays. The typical restriction of clay minerals to the oldest, Noachian terrains indicates a distinctive set of processes involving water-rock interaction that was prevalent early in Mars history and may have profoundly influenced the evolution of Martian geochemical systems. Current analyses of orbital data have led to the proposition of multiple clay-formation mechanisms, varying in space and time in their relative importance. These include near-surface weathering, formation in ice-dominated near-surface groundwaters, and formation by subsurface hydrothermal fluids. Near-surface, open system formation of clays would lead to fractionation of Mars’ crustal reservoir into an altered crustal reservoir and a sedimentary reservoir, potentially involving changes in the composition of Mars’ atmosphere. In contrast, formation of clays in the subsurface by either aqueous alteration or magmatic cooling would result in comparatively little geochemical fractionation or interaction of Mars’ atmospheric, crustal, and magmatic reservoirs, with the exception of long-term sequestration of water. Formation of clays within ice would have geochemical consequences intermediate between these endmembers. We outline the future analyses of orbital data, in situ measurements acquired within clay-bearing terrains, and analyses of Mars samples that are needed to more fully elucidate the mechanisms of martian clay formation and to determine the consequences for the geochemical evolution of the planet.     

Geochemistry of Carbonates on Mars: Implications for Climate History and Nature of Aqueous Environments

Ongoing research on martian meteorites and a new set of observations of carbonate minerals provided by an unprecedented series of robotic missions to Mars in the past 15 years help define new constraints on the history of martian climate with important crosscutting themes including: the CO₂ budget of Mars, the role of Mg-, Fe-rich fluids on Mars, and the interplay between carbonate formation and acidity. Carbonate minerals have now been identified in a wide range of localities on Mars as well as in several martian meteorites. The martian meteorites contain carbonates in low abundances (<1 vol.%) and with a wide range of chemistries. Carbonates have also been identified by remote sensing instruments on orbiting spacecraft in several surface locations as well as in low concentrations (2–5 wt.%) in the martian dust. The Spirit rover also identified an outcrop with 16 to 34 wt.% carbonate material in the Columbia Hills of Gusev Crater that strongly resembled the composition of carbonate found in martian meteorite ALH 84001. Finally, the Phoenix lander identified concentrations of 3–6 wt.% carbonate in the soils of the northern plains. The carbonates discovered to date do not clearly indicate the past presence of a dense Noachian atmosphere, but instead suggest localized hydrothermal aqueous environments with limited water availability that existed primarily in the early to mid-Noachian followed by low levels of carbonate formation from thin films of transient water from the late Noachian to the present. The prevalence of carbonate along with evidence for active carbonate precipitation suggests that a global acidic chemistry is unlikely and a more complex relationship between acidity and carbonate formation is present.     

The Modern Near-Surface Martian Climate: A Review of In-situ Meteorological Data from Viking to Curiosity

We analyze the complete set of in-situ meteorological data obtained from the Viking landers in the 1970s to today’s Curiosity rover to review our understanding of the modern near-surface climate of Mars, with focus on the dust, CO₂ and H₂O cycles and their impact on the radiative and thermodynamic conditions near the surface. In particular, we provide values of the highest confidence possible for atmospheric opacity, atmospheric pressure, near-surface air temperature, ground temperature, near-surface wind speed and direction, and near-surface air relative humidity and water vapor content. Then, we study the diurnal, seasonal and interannual variability of these quantities over a span of more than twenty Martian years. Finally, we propose measurements to improve our understanding of the Martian dust and H₂O cycles, and discuss the potential for liquid water formation under Mars’ present day conditions and its implications for future Mars missions. Understanding the modern Martian climate is important to determine if Mars could have the conditions to support life and to prepare for future human exploration.     

The Martian stratigraphy — Short review and perspectives

The main aspects of the Martian stratigraphy have been determined from the detailed study of Mariner 9 and Viking Orbiter images. Three major stratigraphic systems, the Noachian System, the Hesperian System, and the Amazonian System, are inferred from these studies. The global geological evolution of Mars is essentially derived from its stratigraphy. It reveals that tectonism and volcanism were widespread during two major periods (Noachian and Lower Hesperian) and became more localized during the Upper Hesperian and Amazonian periods. The transition between these two major periods occurred about 2 Ga ago, and significant geologic activity could still be present. However, a number of geologic features and processes remain little understood. Future investigations, including complete high resolution imaging and detailed mapping, geochemical mapping, in situ chemical analyses, etc., will be necessary in order to improve our knowledge of the Martian stratigraphy and geologic evolution and are essential to prepare any future Mars Sample Return mission and the Human Exploration of this planet.     

Global Response of Martian Plasma Environment to an Interplanetary Structure: From Ena and Plasma Observations at Mars

As a part of the global plasma environment study of Mars and its response to the solar wind, we have analyzed a peculiar case of the subsolar energetic neutral atom (ENA) jet observed on June 7, 2004 by the Neutral Particle Detector (NPD) on board the Mars Express satellite. The “subsolar ENA jet” is generated by the interaction between the solar wind and the Martian exosphere, and is one of the most intense sources of ENA flux observed in the vicinity of Mars. On June 7, 2004 (orbit 485 of Mars Express), the NPD observed a very intense subsolar ENA jet, which then abruptly decreased within ∼10 sec followed by quasi-periodic (∼1 min) flux variations. Simultaneously, the plasma sensors detected a solar wind structure, which was most likely an interplanetary shock surface. The abrupt decrease of the ENA flux and the quasi-periodic flux variations can be understood in the framework of the global response of the Martian plasma obstacle to the interplanetary shock. The generation region of the subsolar ENA jet was pushed towards the planet by the interplanetary shock; and therefore, Mars Express went out of the ENA jet region. Associated global vibrations of the Martian plasma obstacle may have been the cause of the quasi-periodic flux variations of the ENA flux at the spacecraft location.     

Potential Effects of Surface Temperature Variations and Disturbances and Thermal Convection on the Mars InSight HP<Superscript>3</Superscript> Heat-Flow Determination

The HP³ instrument on the InSight lander mission will measure subsurface temperatures and thermal conductivities from which heat flow in the upper few meters of the regolith at the landing site will be calculated. The parameter to be determined is steady-state conductive heat flow, but temperatures may have transient perturbations resulting from surface temperature changes and there could be a component of thermal convection associated with heat transport by vertical flow of atmospheric gases over the depth interval of measurement. The experiment is designed so that it should penetrate to a depth below which surface temperature perturbations are smaller than the required measurement precision by the time the measurements are made. However, if the measurements are delayed after landing, and/or the probe does not penetrate to the desired depth, corrections may be necessary for the transient perturbations. Thermal convection is calculated to be negligible, but these calculations are based on unknown physical properties of the Mars regolith. The effects of thermal convection should be apparent at shallow depths where transient thermal perturbations would be observed to deviate from conductive theory. These calculations were required during proposal review and their probability of predicting a successful measurement a prerequisite for mission approval. However, their uncertainties lies in unmeasured physical parameters of the Mars regolith.     

Experimental Investigation of InSight HP<Superscript>3</Superscript> Mole Interaction with Martian Regolith Simulant

The InSight mission launches in 2018 to characterize several geophysical quantities on Mars, including the heat flow from the planetary interior. This quantity will be calculated by utilizing measurements of the thermal conductivity and the thermal gradient down to 5 meters below the Martian surface. One of the components of InSight is the Mole, which hammers into the Martian regolith to facilitate these thermal property measurements. In this paper, we experimentally investigated the effect of the Mole’s penetrating action on regolith compaction and mechanical properties. Quasi-static and dynamic experiments were run with a 2D model of the 3D cylindrical mole. Force resistance data was captured with load cells. Deformation information was captured in images and analyzed using Digitial Image Correlation (DIC). Additionally, we used existing approximations of Martian regolith thermal conductivity to estimate the change in the surrounding granular material’s thermal conductivity due to the Mole’s penetration. We found that the Mole has the potential to cause a high degree of densification, especially if the initial granular material is relatively loose. The effect on the thermal conductivity from this densification was found to be relatively small in first-order calculations though more complete thermal models incorporating this densification should be a subject of further investigation. The results obtained provide an initial estimate of the Mole’s impact on Martian regolith thermal properties.     

Geological Processes and Evolution

Geological mapping and establishment of stratigraphic relationships provides an overview of geological processes operating on Mars and how they have varied in time and space. Impact craters and basins shaped the crust in earliest history and as their importance declined, evidence of extensive regional volcanism emerged during the Late Noachian. Regional volcanism characterized the Early Hesperian and subsequent to that time, volcanism was largely centered at Tharsis and Elysium, continuing until the recent geological past. The Tharsis region appears to have been largely constructed by the Late Noachian, and represents a series of tectonic and volcanic centers. Globally distributed structural features representing contraction characterize the middle Hesperian. Water-related processes involve the formation of valley networks in the Late Noachian and into the Hesperian, an ice sheet at the south pole in the middle Hesperian, and outflow channels and possible standing bodies of water in the northern lowlands in the Late Hesperian and into the Amazonian. A significant part of the present water budget occurs in the present geologically young polar layered terrains. In order to establish more firmly rates of processes, we stress the need to improve the calibration of the absolute timescale, which today is based on crater count systems with substantial uncertainties, along with a sampling of rocks of unknown provenance. Sample return from carefully chosen stratigraphic units could calibrate the existing timescale and vastly improve our knowledge of Martian evolution.     

Composition of the Martian atmosphere

Data on the composition of the Martian atmosphere obtained by instruments aboard the Viking spacecraft are not of sufficient accuracy to address important questions regarding the composition and history of Mars. Laboratory analyses of gases trapped in glassy phases of shergottite meteorite EETA 79001 yield precise data, but it remains to be ascertained that these gases constitute unfractionated Martian atmosphere. Return from Mars of a gas sample for laboratory analysis appears preferable to another in situ measurement, especially if rocks of documented origin will become available for gas analysis as well.     

2001 Mars Odyssey Mission Summary

The 2001 Mars Odyssey spacecraft, now in orbit at Mars, will observe the Martian surface at infrared and visible wavelengths to determine surface mineralogy and morphology, acquire global gamma ray and neutron observations for a full Martian year, and study the Mars radiation environment from orbit. The science objectives of this mission are to: (1) globally map the elemental composition of the surface, (2) determine the abundance of hydrogen in the shallow subsurface, (3) acquire high spatial and spectral resolution images of the surface mineralogy, (4) provide information on the morphology of the surface, and (5) characterize the Martian near-space radiation environment as related to radiation-induced risk to human explorers. To accomplish these objectives, the 2001 Mars Odyssey science payload includes a Gamma Ray Spectrometer (GRS), a multi-spectral Thermal Emission Imaging System (THEMIS), and a radiation detector, the Martian Radiation Environment Experiment (MARIE). THEMIS and MARIE are mounted on the spacecraft with THEMIS pointed at nadir. GRS is a suite of three instruments: a Gamma Subsystem (GSS), a Neutron Spectrometer (NS) and a High-Energy Neutron Detector (HEND). The HEND and NS instruments are mounted on the spacecraft body while the GSS is on a 6-m boom. Some science data were collected during the cruise and aerobraking phases of the mission before the prime mission started. THEMIS acquired infrared and visible images of the Earth-Moon system and of the southern hemisphere of Mars. MARIE monitored the radiation environment during cruise. The GRS collected calibration data during cruise and aerobraking. Early GRS observations in Mars orbit indicated a hydrogen-rich layer in the upper meter of the subsurface in the Southern Hemisphere. Also, atmospheric densities, scale heights, temperatures, and pressures were observed by spacecraft accelerometers during aerobraking as the spacecraft skimmed the upper portions of the Martian atmosphere. This provided the first in-situ evidence of winter polar warming in the Mars upper atmosphere. The prime mission for 2001 Mars Odyssey began in February 2002 and will continue until August 2004. During this prime mission, the 2001 Mars Odyssey spacecraft will also provide radio relays for the National Aeronautics and Space Administration (NASA) and European landers in early 2004. Science data from 2001 Mars Odyssey instruments will be provided to the science community via NASA’s Planetary Data System (PDS). The first PDS release of Odyssey data was in October 2002; subsequent releases occur every 3 months.     

Long-Term Evolution of the Martian Crust-Mantle System

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K?Gyr^?1 were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K?Gyr^?1. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet’s initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (H₂O, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two.     

Electrical Charging of Volcanic Plumes

Many explosive terrestrial volcanic eruptions are accompanied by lightning and other atmospheric electrical phenomena. The plumes produced generate large perturbations in the surface atmospheric electric potential gradient and high charge densities have been measured on falling volcanic ash particles. The complex nature of volcanic plumes (which contain gases, solid particles, and liquid drops) provides several possible charging mechanisms. For plumes rich in solid silicate particles, fractoemission (the ejection of ions and atomic particles during fracture events) is probably the dominant source of charge generation. In other plumes, such as those created when lava enters the sea, different mechanisms, such as boiling, may be important. Further charging mechanisms may also subsequently operate, downwind of the vent. Other solar system bodies also show evidence for volcanism, with activity ongoing on Io. Consequently, volcanic electrification under different planetary scenarios (on Venus, Mars, Io, Moon, Enceladus, Tethys, Dione and Triton) is also discussed.     

Outgassing History and Escape of the Martian Atmosphere and Water Inventory

The evolution and escape of the martian atmosphere and the planet’s water inventory can be separated into an early and late evolutionary epoch. The first epoch started from the planet’s origin and lasted ～500 Myr. Because of the high EUV flux of the young Sun and Mars’ low gravity it was accompanied by hydrodynamic blow-off of hydrogen and strong thermal escape rates of dragged heavier species such as O and C atoms. After the main part of the protoatmosphere was lost, impact-related volatiles and mantle outgassing may have resulted in accumulation of a secondary CO₂ atmosphere of a few tens to a few hundred mbar around ～4–4.3 Gyr ago. The evolution of the atmospheric surface pressure and water inventory of such a secondary atmosphere during the second epoch which lasted from the end of the Noachian until today was most likely determined by a complex interplay of various nonthermal atmospheric escape processes, impacts, carbonate precipitation, and serpentinization during the Hesperian and Amazonian epochs which led to the present day surface pressure.     

Collecting Samples in Gale Crater, Mars; an Overview of the Mars Science Laboratory Sample Acquisition, Sample Processing and Handling System

The Mars Science Laboratory Mission (MSL), scheduled to land on Mars in the summer of 2012, consists of a rover and a scientific payload designed to identify and assess the habitability, geological, and environmental histories of Gale crater. Unraveling the geologic history of the region and providing an assessment of present and past habitability requires an evaluation of the physical and chemical characteristics of the landing site; this includes providing an in-depth examination of the chemical and physical properties of Martian regolith and rocks. The MSL Sample Acquisition, Processing, and Handling (SA/SPaH) subsystem will be the first in-situ system designed to acquire interior rock and soil samples from Martian surface materials. These samples are processed and separated into fine particles and distributed to two onboard analytical science instruments SAM (Sample Analysis at Mars Instrument Suite) and CheMin (Chemistry and Mineralogy) or to a sample analysis tray for visual inspection. The SA/SPaH subsystem is also responsible for the placement of the two contact instruments, Alpha Particle X-Ray Spectrometer (APXS), and the Mars Hand Lens Imager (MAHLI), on rock and soil targets. Finally, there is a Dust Removal Tool (DRT) to remove dust particles from rock surfaces for subsequent analysis by the contact and or mast mounted instruments (e.g. Mast Cameras (MastCam) and the Chemistry and Micro-Imaging instruments (ChemCam)).     

Water and Brines on Mars: Current Evidence and Implications for MSL

Liquid water is a basic ingredient for life as we know it. Therefore, in order to understand the habitability of other planets we must first understand the behavior of water on them. Mars is the most Earth-like planet in the solar system and it has large reservoirs of H₂O. Here, we review the current evidence for pure liquid water and brines on Mars, and discuss their implications for future and current missions such as the Mars Science Laboratory. Neither liquid water nor liquid brines are currently stable on the surface of Mars, but they could be present temporarily in a few areas of the planet. Pure liquid water is unlikely to be present, even temporarily, on the surface of Mars because evaporation into the extremely dry atmosphere would inhibit the formation of the liquid phase, where the temperature and pressure are high enough so that water would neither freeze nor boil. The exception to this is that monolayers of liquid water, referred to as undercooled liquid interfacial water, could exist on most of the Martian surface. In a few places liquid brines could exist temporarily on the surface because they could form at cryogenic temperatures, near ice or frost deposits where sublimation could be inhibited by the presence of nearly saturated air. Both liquid water and liquid brines might exist in the shallow subsurface because even a thin layer of soil forms an effective barrier against sublimation allowing pure liquid water to form sporadically in a few places, or liquid brines to form over longer periods of time in large portions of the planet. At greater depths, ice deposits could melt where the soil conductivity is low enough to blanket the deeper subsurface effectively. This could cause the formation of aquifers if the deeper soil is sufficiently permeable and an impermeable layer exists below the source of water. The fact that liquid brines and groundwater are likely to exist on Mars has important implications for geochemistry, glaciology, mineralogy, weathering and the habitability of Mars.