Composition of the Martian atmosphere

Data on the composition of the Martian atmosphere obtained by instruments aboard the Viking spacecraft are not of sufficient accuracy to address important questions regarding the composition and history of Mars. Laboratory analyses of gases trapped in glassy phases of shergottite meteorite EETA 79001 yield precise data, but it remains to be ascertained that these gases constitute unfractionated Martian atmosphere. Return from Mars of a gas sample for laboratory analysis appears preferable to another in situ measurement, especially if rocks of documented origin will become available for gas analysis as well.     

The morphology of the Martian surface

Most of the southern hemisphere of Mars is densely cratered and stands 1–3 km above the topographic datum. The northern hemisphere is more sparsely cratered and elevations are generally below the datum. A broad rise, the Tharsis bulge, centered at 14° S, 101° W, is 8000 km across and 10 km above the datum at its summit. The densely cratered terrain has two main components; very ancient crust, nearly saturated with large craters, and younger intercrater plains. In many areas the older unit is fractured and extensively dissected by small channels. The younger intercrater plains are distinctly layered in places and less dissected, less fractured, and less cratered. Both units probably date from very early in the planet's history. Cratered plains cover much of the northern hemisphere and are highly variegated. Those around the large volcanoes are covered with numerous volcanic flows whereas in other areas the plains are featureless except for craters and lunar mare-like ridges. Between 40° N and 60° N the plains are complex with various kinds of striped and patterned ground, low escarpments, and isolated irregularly shaped mesas. Their peculiar morphology has been attributed, in part, to the repeated deposition and removal of volatile-rich debris layers. Along the boundary between the northern plains and the densely cratered terrain to the south, the plains and cratered terrain complexly inter-finger. The old terrain forms the high ground and appears to have undergone mass wasting on a large scale. In several areas, particularly south of Chryse Planitia, the old, cratered surface has collapsed to form chaotic terrain. Large channels, tens of kilometers wide and hundreds of kilometers long, with numerous characteristics suggestive of catastrophic flooding, commonly emerge from the chaotic areas. Much of the area between 50° W and 180° W and 50° N and 50° S is cut by fractures radial to the center of the Tharsis bulge. The equatorial canyon system, Valles Marineris, is radial to the bulge and appears to have formed largely by faulting along the radial fractures, although it has also been extensively modified by various mass wasting and fluvial processes. Most but not all volcanoes are in the Tharsis and Elysium regions. The largest resemble terrestrial shield volcanoes except for scale; the edifices, flow features and calderas are all far larger than their terrestrial counterparts. Most impact craters on Mars are surrounded by layers of ejecta, each with a distil ridge. This unique morphology coupled with other surface characteristics suggests large amounts of ground ice. Layered deposits at both poles appear to be relatively young, volatile-rich, aeolian deposits. The north pole is also surrounded by a continuous belt of dunes several tens of kilometers across. In most other places, aeolian modification of the surface at a scale of several tens of meters appears slight despite annual global dust storms.     

Long-Term Evolution of the Martian Crust-Mantle System

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K?Gyr^?1 were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K?Gyr^?1. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet’s initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (H₂O, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two.     

The Martian Surface Composition

Mars is unique to have undergone all planetary evolutionary steps, without global resets, till its geological death: this is reflected in the variety of its surface features. The determination of Mars surface composition has thus the potential to identify the processes responsible for the entire Mars evolution, from geological timescales to seasonal variations. Due to technical challenges, only few investigations have been performed so far. They are summarized in this paper, and their interpretation is discussed in terms of surface materials (minerals, ices and frosts).     

Observations of the Martian Subsolar ENA Jet Oscillations

The Neutral Particle Detector (NPD) of the ASPERA-3 experiment (Analyser of Space Plasmas and Energetic Atoms) on board the Mars Express (MEX) spacecraft observed an intense flux of H ENAs (energetic neutral atoms) with average energy of about 1.5 keV emitted anisotropically from the subsolar region of Mars. The NPD detected the ENA jet near the bow shock at radial distances of about 1 R _M from the Martian surface as the spacecraft moved outbound, while the NPD continuously pointed towards the subsolar region. The jet intensity shows oscillative behavior. These intensity variations occur on two clearly distinguishable time scales. The majority of the identified events have an average oscillation period of about 50 sec. The second group consists of events with long-scale variations with a time scale of approximately 300 sec. The fast oscillations of the first group exhibit a periodic structure and are detected in every orbit, while the slow variations of the second group are identified in ∼40% of orbits. The intensity of the fast oscillations have a peak-to-valley ratio about 20 to 30% of the peak intensity. One of the possible mechanisms to explain fast oscillations is the formation of the low frequency ion waves at the subsolar region of Mars. Slow variations may be explained by either temporal variations in the ENA generation source or by a specific structure of the ENA generation source, in which hair-like ENA subjets can be present.     

Observations of Vertical Reflections from the Topside Martian Ionosphere

The Martian ionosphere has for the first time been probed by a low frequency topside radio wave sounder experiment (MARSIS) (Gurnett et al., 2005). The density profiles in the Martian ionosphere have for the first time been observed for solar zenith angles less than 48 degrees. The sounder spectrograms typically have a single trace of echoes, which are controlled by reflections from the ionosphere in the direction of nadir. With the local density at the spacecraft derived from the sounder measurements and using the lamination technique the spectrograms are inverted to electron density profiles. The measurements yield electron density profiles from the sub-solar region to past the terminator. The maximum density varies in time with the solar rotation period, indicating control of the densities by solar ionizing radiation. Electron density increases associated with solar flares were observed. The maximum electron density varies with solar zenith angle as predicted by theory. The altitude profile of electron densities between the maximum density and about 170m altitude is well approximated by a classic Chapman layer. The neutral scale height is close to 10 to 13 km. At altitudes above 180 km the densities deviate from and are larger than inferred by the Chapman layer. At altitudes above the exobase the density decrease was approximated by an exponential function with scale heights between 24 and 65 km. The densities in the top side ionosphere above the exobase tends to be larger than the densities extrapolated from the Chapman layer fitted to the measurements at lower altitudes, implying more efficient upward diffusion above the collision dominated photo equilibrium region.     

Volatile Trapping in Martian Clathrates

Thermodynamic conditions suggest that clathrates might exist on Mars. Despite observations which show that the dominant condensed phases on the surface of Mars are solid carbon dioxide and water ice, clathrates have been repeatedly proposed to play an important role in the distribution and total inventory of the planet’s volatiles. Here we review the potential consequences of the presence of clathrates on Mars. We investigate how clathrates could be a potential source for the claimed existence of atmospheric methane. In this context, plausible clathrate formation processes, either in the close subsurface or at the base of the cryosphere, are reviewed. Mechanisms that would allow for methane release into the atmosphere from an existing clathrate layer are addressed as well. We also discuss the proposed relationship between clathrate formation/dissociation cycles and how potential seasonal variations influence the atmospheric abundances of argon, krypton and xenon. Moreover, we examine several Martian geomorphologic features that could have been generated by the dissociation of extended subsurface clathrate layers. Finally we investigate the future in situ measurements, as well as the theoretical and experimental improvements that will be needed to better understand the influence of clathrates on the evolution of Mars and its atmosphere.     

Ages and Geologic Histories of Martian Meteorites

We review the radiometric ages of the 16 currently known Martian meteorites, classified as 11 shergottites (8 basaltic and 3 lherzolitic), 3 nakhlites (clinopyroxenites), Chassigny (a dunite), and the orthopyroxenite ALH84001. The basaltic shergottites represent surface lava flows, the others magmas that solidified at depth. Shock effects correlate with these compositional types, and, in each case, they can be attributed to a single shock event, most likely the meteorite's ejection from Mars. Peak pressures in the range 15 – 45 GPa appear to be a "launch window": shergottites experienced ～30 – 45 GPa, nakhlites ～20 ± 5 GPa, Chassigny ～35 GPa, and ALH84001 ～35 – 40 GPa. Two meteorites, lherzolitic shergottite Y-793605 and orthopyroxenite ALH84001, are monomict breccias, indicating a two-phase shock history in toto: monomict brecciation at depth in a first impact and later shock metamorphism in a second impact, probably the ejection event. Crystallization ages of shergottites show only two pronounced groups designated S₁ (～175 Myr), including 4 of 6 dated basalts and all 3 lherzolites, and S₂ (330 – 475 Myr), including two basaltic shergottites and probably a third according to preliminary data. Ejection ages of shergottites, defined as the sum of their cosmic ray exposure ages and their terrestrial residence ages, range from the oldest (～20 Myr) to the youngest (～0.7 Myr) values for Martian meteorites. Five groups are distinguished and designated S_Dho (one basalt, ～20 Myr), S_L (two lherzolites of overlapping ejection ages, 3.94 ± 0.40 Myr and 4.70 ± 0.50 Myr), S (four basalts and one lherzolite, ～2.7 – 3.1 Myr), S_DaG (two basalts, ～1.25 Myr), and S_E (the youngest basalt, 0.73 ± 0.15 Myr). Consequently, crystallization age group S₁ includes ejection age groups S_L, S_E and 4 of the 5 members of S, whereas S₂ includes the remaining member of S and one of the two members of S_DaG. Shock effects are different for basalts and lherzolites in group S/S₁. Similarities to the dated meteorite DaG476 suggest that the two shergottites that are not dated yet belong to group S₂. Whether or not S₂ is a single group is unclear at present. If crystallization age group S₁ represents a single ejection event, pre-exposure on the Martian surface is required to account for ejection ages of S_L that are greater than ejection ages of S, whereas secondary breakup in space is required to account for ejection ages of S_E less than those of S. Because one member of crystallization age group S₂ belongs to ejection group S, the maximum number of shergottite ejection events is 6, whereas the minimum number is 2. Crystallization ages of nakhlites and Chassigny are concordant at ～1.3 Gyr. These meteorites also have concordant ejection ages, i.e., they were ejected together in a single event (NC). Shock effects vary within group NC between the nakhlites and Chassigny. The orthopyroxenite ALH84001 is characterized by the oldest crystallization age of ～4.5 Gyr. Its secondary carbonates are ～3.9 Gyr old, an age corresponding to the time of Ar-outgassing from silicates. Carbonate formation appears to have coincided with impact metamorphism, either directly, or indirectly, perhaps via precipitation from a transient impact crater lake. The crystallization age and the ejection age of ALH84001, the second oldest ejection age at 15.0 ± 0.8 Myr, give evidence for another ejection event (O). Consequently, the total number of ejection events for the 16 Martian meteorites lies in the range 4 – 8. The Martian meteorites indicate that Martian magmatism has been active over most of Martian geologic history, in agreement with the inferred very young ages of flood basalt flows observed in Elysium and Amazonis Planitia with the Mars Orbital Camera (MOC) on the Mars Global Surveyor (MGS). The provenance of the youngest meteorites must be found among the youngest volcanic surfaces on Mars, i.e., in the Tharsis, Amazonis, and Elysium regions.     

Mars Global Surveyor Measurements of the Martian Solar Wind Interaction

The solar wind at Mars interacts with the extended atmosphere and small-scale crustal magnetic fields. This interaction shares elements with a variety of solar system bodies, and has direct bearing on studies of the long-term evolution of the Martian atmosphere, the structure of the upper atmosphere, and fundamental plasma processes. The magnetometer (MAG) and electron reflectometer (ER) on Mars Global Surveyor (MGS) continue to make many contributions toward understanding the plasma environment, thanks in large part to a spacecraft orbit that had low periapsis, had good coverage of the interaction region, and has been long-lived in its mapping orbit. The crustal magnetic fields discovered using MGS data perturb plasma boundaries on timescales associated with Mars' rotation and enable a complex magnetic field topology near the planet. Every portion of the plasma environment has been sampled by MGS, confirming previous measurements and making new discoveries in each region. The entire system is highly variable, and responds to changes in solar EUV flux, upstream pressure, IMF direction, and the orientation of Mars with respect to the Sun and solar wind flow. New insights from MGS should come from future analysis of new and existing data, as well as multi-spacecraft observations.     

An analysis of Martian photometry and polarimetry

The physical parameters that influence the photometric and polarimetric properties of a solid are enumerated and used to guide a comparison of laboratory measurements with observations of Mars. Both the bright and dark areas of Mars are found to be covered by a fine powder. Furthermore, they appear to have a very similar chemical composition. It is argued that goethite is a major constituent of both regions. The particles on the bright areas are characterized by an average particle radius of 25 , while those on the dark areas have a mean size of 100 outside of the period of seasonal darkening and about 200 near the peak of the darkening. The seasonal darkening of the dark areas is the result of a change in the average particle dimension without an accompanying chemical change.The Martian atmosphere has much less of an influence on the photometric and polarimetric observations than was previously supposed. The observed lack of contrast in the blue appears to be largely the result of an intrinsic loss of surface contrast, and not an effect of a hypothetical atmospheric blue haze.

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Résumé Les paramètres physiques qui influencent les propriétés photométriques et polarimétriques d'un solide sont énumérés et utilisés pour conduire une comparaison entre des mesures de laboratoire et des observations de Mars. On trouve que les régions brillantes et les régions sombres de Mars sont couvertes d'une fine poudre. En outre, elles paraissent avoir des compositions chimiques très semblables. Il est soutenu que la goethite est un constituant majeur des deux régions. Les particules des régions brillantes sont caractérisées par un rayon moyen de 25 , tandis que celles des régions sombres ont une taille moyenne de 100 en dehors de la période d'assombrissement saisonnier, et d'environ 200 près du maximum d'assombrissement. L'assombrissement saisonnier des régions sombres est le résultat d'une variation de la dimension moyenne des particules, non accompagné d'un changement chimique.L'influence de l'atmosphère Martienne sur les observations photométriques et polarimétriques est bien inférieure à ce qui était supposé antérieurement. Le manque de contraste que l'on observe dans le bleu, parait être principalement une conséquencede la perte de contraste de surface, et non pas un effet d'un hypothétique halo atmosphérique bleu.

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This work was supported in part by grants NGR-09-015-023 and NGR-33-010-082 from the National Aeronautics and Space Administration. A preliminary account was published as Smithsonian Astrophysical Observatory Special Report 258 (1967). This paper is dedicated to the memory of V. V. Sharonov.     

Magnetic Flux Ropes in the Martian Atmosphere: Global Characteristics

We report observations of magnetic fields amplitude, which consist of a series of individual spikes in the Martian atmosphere. A minimum variance analysis shows that these spikes form twisted cylindrical filaments. These small diameter magnetic filaments are commonly called magnetic flux ropes. We examine the global characteristics of magnetic flux ropes, which are observed on 5% of the elliptical orbits of Mars Global Surveyor. Flux ropes are more often observed in Venus' atmosphere (70% of the orbits). In this paper we report some of the global characteristics of the flux ropes identified in the Martian atmosphere. No flux ropes are observed in the southern hemisphere of Mars. Most of them occur at high solar zenith angles, close to the terminator plane, and at high latitude with altitudes below 400 km. The orientation of the flux ropes appears random while in the case of Venus the orientation is more horizontal near the terminator for altitudes greater than 200 km. We have identified fewer flux ropes for SZA between 40 to 60 deg and for SZA lower than 20 deg, like in the case of Venus (Elphic and Russell, 1983b). Statistically, Mars' ionosphere with SZA range between 40^circ to 60^circ is less magnetized than near the subsolar point. As the Martian ionosphere is quite often magnetized by the magnetic components of the crustal field, this crustal magnetic field seems to inhibit the flux ropes formation in the southern hemisphere. However, some orbits without crustal magnetic field, called magnetic cavities, were observed without flux ropes. So the flux ropes formation process seems to be uppressed by another factor, like the solar wind dynamic pressure for Venus (Krymskii and Breus, 1988).     

The Solar Wind Interaction With the Martian Ionosphere/Atmosphere

The interaction of the solar wind with the Martian exosphere and ionosphere leads to significant loss of atmosphere from the planet. Spacecraft data confirm that this is the case. However, the issue is how much is actually lost. Given that spacecraft coverage is sparse, simulation is one of the few ways for these estimates to be made. In this paper the evolution of our attempts to place bounds on this loss rate will be addressed. Using a hybrid particle code the loss rate with respect to solar EUV flux is addressed as well as a variety of numerical and chemical issues. The progress made has been of an evolutionary nature, with one approach tried and tested followed by another as the simulations are improved and better estimates are produced. The results to be reported suggest that the ion loss rates are high enough to explain the loss of water from Mars during earlier solar epochs.     

Martian Radiation EnvIronment Experiment (MARIE)

Measurements of radiation levels at Mars including the contributions of protons, neutrons, and heavy ions, are pre-requisites for human exploration. The MARIE experiment on the Mars-01 Odyssey spacecraft consists of a spectrometer to make such measurements in Mars orbit. MARIE is measuring the galactic cosmic ray energy spectra during the maximum of the 24^th solar cycle, and studying the dynamics of solar particle events and their radial dependence in orbit of Mars. The MARIE spectrometer is designed to measure the energy spectrum from 15 to 500 MeV/n, and when combined other space based instruments, such as the Advanced Composition Explorer (ACE), would provide accurate GCR spectra. Similarly, observations of solar energetic particles can be combined with observations at different points in the inner heliosphere from, for example, the Solar Heliospheric Observatory (SOHO), to gain information on the propagation and radial dependence in the Earth-Mars space. Measurements can be compared with the best available radiation environment and transport models in order to improve these models for subsequent use, and to provide key inputs for the engineering of spacecraft to better protect the human crews exploring Mars.     

Outgassing History and Escape of the Martian Atmosphere and Water Inventory

The evolution and escape of the martian atmosphere and the planet’s water inventory can be separated into an early and late evolutionary epoch. The first epoch started from the planet’s origin and lasted ～500 Myr. Because of the high EUV flux of the young Sun and Mars’ low gravity it was accompanied by hydrodynamic blow-off of hydrogen and strong thermal escape rates of dragged heavier species such as O and C atoms. After the main part of the protoatmosphere was lost, impact-related volatiles and mantle outgassing may have resulted in accumulation of a secondary CO₂ atmosphere of a few tens to a few hundred mbar around ～4–4.3 Gyr ago. The evolution of the atmospheric surface pressure and water inventory of such a secondary atmosphere during the second epoch which lasted from the end of the Noachian until today was most likely determined by a complex interplay of various nonthermal atmospheric escape processes, impacts, carbonate precipitation, and serpentinization during the Hesperian and Amazonian epochs which led to the present day surface pressure.     

Auroral Plasma Acceleration Above Martian Magnetic Anomalies

Aurora is caused by the precipitation of energetic particles into a planetary atmosphere, the light intensity being roughly proportional to the precipitating particle energy flux. From auroral research in the terrestrial magnetosphere it is known that bright auroral displays, discrete aurora, result from an enhanced energy deposition caused by downward accelerated electrons. The process is commonly referred to as the auroral acceleration process. Discrete aurora is the visual manifestation of the structuring inherent in a highly magnetized plasma. A strong magnetic field limits the transverse (to the magnetic field) mobility of charged particles, effectively guiding the particle energy flux along magnetic field lines. The typical, slanted arc structure of the Earth’s discrete aurora not only visualizes the inclination of the Earth’s magnetic field, but also illustrates the confinement of the auroral acceleration process. The terrestrial magnetic field guides and confines the acceleration processes such that the preferred acceleration of particles is frequently along the magnetic field lines. Field-aligned plasma acceleration is therefore also the signature of strongly magnetized plasma. This paper discusses plasma acceleration characteristics in the night-side cavity of Mars. The acceleration is typical for strongly magnetized plasmas – field-aligned acceleration of ions and electrons. The observations map to regions at Mars of what appears to be sufficient magnetization to support magnetic field-aligned plasma acceleration – the localized crustal magnetizations at Mars (Acuña et al., 1999). Our findings are based on data from the ASPERA-3 experiment on ESA’s Mars Express, covering 57 orbits traversing the night-side/eclipse of Mars. There are indeed strong similarities between Mars and the Earth regarding the accelerated electron and ion distributions. Specifically acceleration above Mars near local midnight and acceleration above discrete aurora at the Earth – characterized by nearly monoenergetic downgoing electrons in conjunction with nearly monoenergetic upgoing ions. We describe a number of characteristic features in the accelerated plasma: The “inverted V” energy-time distribution, beam vs temperature distribution, altitude distribution, local time distribution and connection with magnetic anomalies. We also compute the electron energy flux and find that the energy flux is sufficient to cause weak to medium strong (up to several tens of kR 557.7 nm emissions) aurora at Mars. Monoenergetic counterstreaming accelerated ions and electrons is the signature of field-aligned electric currents and electric field acceleration. The topic is reasonably well understood in terrestrial magnetospheric physics, although some controversy still remains on details and the cause-effect relationships. We present a potential cause-effect relationship leading to auroral plasma acceleration in the nightside cavity of Mars – the downward acceleration of electrons supposedly manifesting itself as discrete aurora above Mars.     

The Martian stratigraphy — Short review and perspectives

The main aspects of the Martian stratigraphy have been determined from the detailed study of Mariner 9 and Viking Orbiter images. Three major stratigraphic systems, the Noachian System, the Hesperian System, and the Amazonian System, are inferred from these studies. The global geological evolution of Mars is essentially derived from its stratigraphy. It reveals that tectonism and volcanism were widespread during two major periods (Noachian and Lower Hesperian) and became more localized during the Upper Hesperian and Amazonian periods. The transition between these two major periods occurred about 2 Ga ago, and significant geologic activity could still be present. However, a number of geologic features and processes remain little understood. Future investigations, including complete high resolution imaging and detailed mapping, geochemical mapping, in situ chemical analyses, etc., will be necessary in order to improve our knowledge of the Martian stratigraphy and geologic evolution and are essential to prepare any future Mars Sample Return mission and the Human Exploration of this planet.