Photochemistry of planetary ionospheres

The basic photochemical processes in the upper atmospheres and ionospheres of the various bodies in our solar system (planets, moons and comets) are similar. However, there are many different factors (e.g. gas composition, energy input, gravity) which control/change the relative importance of these controlling processes. The photo-chemistry of the inner planets is reasonably well understood at this time, thus there is good agreement between model calculations and most of the observational data base. The extremely limited information that we have available on the ionospheres of the outer planets leads to significant uncertainties about some of the controlling processes. Some important questions (e.g. Is the charge exchange process H⁺ + H₂(v≥4) → H₂⁺ + H important? Is water vapor influx from the rings important?) remain unanswered at this time. In cometary atmospheres the freshly evaporated parent molecules are rapidly photodissociated and photoionized, therefore most of the chemical kinetics of cometary ionospheres involve these rapidly moving and highly reactive ions and radicals.     

Comparative neutral composition instrumentation and new results

Composition and gas density measurement at all altitudes in the atmospheres of earth and other planets are made by mass spectrometers. Because of the impartiality and large dynamic range they are particularly favored for exploratory missions. Measurements of trace constituents, inert gases and height profiles, especially below clouds, are objectives where mass spectrometry is most useful. Significant advances have been made in recent years in development of light weight automated instruments. Experiments conducted in rarified atmospheres have been more successful or results were less controversial than in attempts to analyze high pressure atmospheres. Gas sampling and conditioning techniques are highly specific because of measurement environments and engineering constraints on the mission, and are usually the most critical elements in the experiment. Chemical sample enrichment and scrubbing for noble gas enhancement are additional sample conditioning techniques now employed. Dynamic range of more than 10⁸ is achievable. Reliable measurements of complex organic or chemically active trace constituents with mixing ratios of less than 10^?9 still require significant instrument development particularly where weight, power and sampling time are severely restricted. Adaptation of familiar and proven laboratory techniques for flight instruments is usually not straightforward and practical.     

系外行星大气与宜居系外行星研究进展及发展趋势

探测系外行星的主要目的是研究生命和可供地球生命生存的行星是否普遍存在这一基本科学问题.近20年来已有超过3000颗系外行星被发现,还有几千颗候选系外行星有待确认,其中疑似宜居系外行星的数量近20颗.未来十年疑似宜居系外行星的数目将大为增加.尽管目前对宜居系外行星大气观测的能力和科学结果还很有限,但可以预期未来20年对这一类行星大气的观测将成为行星科学研究的重要领域.本文根据当前系外行星大气科学发展的状态和主要科学问题,在对中国未来系外行星科学发展方向进行分析的基础上,提出一种比较可行的建议,即在近1~2年内有针对性地开展系外行星大气普查和系外行星高层大气观测的可行性论证和预研,并在5~10年内择一予以实施.      

Search for organic molecules in the outer solar system

Recent developments of millimeter astronomy have led to the discovery of more and more complex molecules in the interstellar medium. In a similar way, attempts have been made to detect complex molecules in the atmospheres of the most primitive bodies of the Solar System, i.e. outer planets and comets, as well as in Titan's atmosphere. An important progress has been achieved thanks to the continuous development of infrared astronomy, from the ground and from space vehicles. In particular, an important contribution has come from the IRIS-Voyager infrared spectrometer with the detection of prebiotic molecules on Titan, and some complex organic molecules on Jupiter and Saturn. Another important result has been the observation of carbonaceous material in the immediate surroundings of Comet Halley's nucleus. In the near future, the search for organic molecules in the outer Solar System should benefit from the developments of large millimeter antennae, and in the next decade, from the operation of infrared Earth-orbiting spacecrafts (ISO, SIRTF).     

Comparison of methods for the determination of key reactions in chemical systems: Application to Titan’s atmosphere

A new paradigm is emerging in the field of photochemistry modeling in giant planets and Titan atmospheres. The emphasis is placed on the accurate predictions of the models and the quantification of their uncertainties. In order to improve photochemical models predictions, it is necessary to identify in chemical schemes the key reactions that should be studied in priority at conditions relevant to planetary atmospheres.     

Comparison of solar soft X-ray irradiance from broadband photometers to a high spectral resolution rocket observation

The solar soft X-ray (XUV; 1–30 nm) radiation is highly variable on all time scales and strongly affects the ionosphere and upper atmosphere of Earth, Mars, as well as the atmospheres and surfaces of other planets and moons in the solar system; consequently, the solar XUV irradiance is important for atmospheric studies and for space weather applications. While there have been several recent measurements of the solar XUV irradiance, detailed understanding of the solar XUV irradiance, especially its variability during flares, has been hampered by the lack of high spectral resolution measurements in this wavelength range. The conversion of the XUV photometer signal into irradiance requires the use of a solar spectral model, but there has not been direct validation of these spectral models for the XUV range. For example, the irradiance algorithm for the XUV Photometer System (XPS) measurements uses multiple CHIANTI spectral models, but validation has been limited to other solar broadband measurements or with comparisons of the atmospheric response to solar variations. A new rocket observation of the solar XUV irradiance with 0.1 nm resolution above 6 nm was obtained on 14 April 2008, and these new results provide a first direct validation of the spectral models used in the XPS data processing. The rocket observation indicates very large differences for the spectral model for many individual emission features, but the differences are significantly smaller at lower resolution, as expected since the spectral models are scaled to match the broadband measurements. While this rocket measurement can help improve a spectral model for quiet Sun conditions, many additional measurements over a wide range of solar activity are needed to fully address the spectral model variations. Such measurements are planned with a similar instrument included on NASA’s Solar Dynamics Observatory (SDO), whose launch is expected in 2009.     

Modification of planetary atmospheres by material from the rings

The atmospheres and ionospheres of ringed planets can be, and perhaps are, modified by the injection of gaseous neutral and ionized species, and dust of ring origin. Although no direct evidence for such interaction exists, many of the unresolved characteristics of planetary composition, thermal structure and ionosphere would be understood if the rings supplied certain materials to their parent planets.     

Ultraviolet emissions from the upper atmospheres of the planets

A large number of atoms and molecules have strong emission lines in the vacuum ultraviolet. As a result, this spectral region is particularly suited to studying the upper atmospheres of the planets. The observed emissions not only identify the constituents, but also provide information on the solar and magnetospheric excitation processes. Long term monitoring of these emissions, particularly with modest spatial resolution, can elucidate the effects of variations in the solar input as well as changes in magnetospheric conditions. Also, earth orbiting telescopes generally provide better spectral resolution than is available on flyby vehicles. A modest beginning in planetary upper atmospheric studies from earth orbit has been made using orbiting observatories designed primarily for stellar astronomy. As examples of the power of this technique, some recent results will be reviewed with an emphasis on Jupiter and the Io torus. The unusual scheduling requirements and the effects of scattered intense long wavelength radiation put demands on orbiting planetary observatories which are somewhat different from those of stellar astronomy. The implications of these demands for continued advances in this area are discussed.     

A study of chemical systems using signal flow graph theory.

Photochemistry of giant planets and their satellites is characterized by numerous reactions involving a lot of chemical species. In the present paper, chemical systems are modeled by signal flow graphs. Such a technique evaluates the transmission of any input into the system (solar flux, electrons ... ) and gives access to the identification of the most important mechanisms in the chemical system. This method is applied to the production of hydrocarbons in the atmospheres of giant planets. In particular, the production of C2H6 in the atmosphere of Neptune from the photodissociation of CH4 is investigated. Different pathways of dissociation of CH4 are possible from L alpha radiation. A chemical system containing 14 species and 30 reactions including these different pathways of dissociation is integrated. The main mechanism of production of C2H6 is identified and evaluated for each model of dissociation. The importance of various reaction pathways as a function of time is presented.     

Raman scattering as a probe of planetary atmospheres

The observable effects of Raman scattering on the spectra of the giant planets may provide new information on the composition and structure of these atmospheres. Satellite observations have already shown the influence of Raman scattering on the UV continuum albedo. A cross correlation technique is presented for detecting rotational and vibrational transitions of the Raman active gases in the atmosphere. This technique has been applied to ground-based visible spectra of Venus, Jupiter, Saturn and Uranus. Extension of this method into the UV would improve the detectability of the Raman lines because the ratio of Raman to Rayleigh cross section increases with decreasing wavelength. The technology currently exists to efficiently obtain high signal-to-noise ratio UV spectra through the use of silicon diode array detectors. Application of the cross-correlation technique to UV spectra obtained from space vehicles would give us a new important probe of the structure and composition of planetary atmospheres by enabling us to use the UV spectra of a planet to observe that would normally be an infrared molecular transition.     

Chemical evolution and the origin of life.

During the last three decades major advances have been made in our understanding of the formation of carbon compounds in the universe and of the occurence of processes of chemical evolution. 1) Carbon and other biogenic elements (C,H,N,O,S and P) are some of the most abundant in the universe. 2) The interstellar medium has been found to contain a diversity of molecules of these elements. 3) Some of these molecules have also been found in comets which are considered the most primordial bodies of the solar system. 4) The atmospheres of the outer planets and their satellites, for example, Titan, are actively involved in the formation of organic compounds which are the precursors of biochemical molecules. 5) Some of these biochemical molecules, such as amino acids, purines and pyrimidines, have been found in carbonaceous chondrites. 6) Laboratory experiments have shown that most of the monomers and oligomers necessary for life can be synthesized under hypothesized but plausible primitive Earth conditions from compounds found in the above cosmic bodies. 7) It appears that the primitive Earth had the necessary and sufficient conditions to allow the chemical synthesis of biomacromolecules and to permit the processes required for the emergence of life on our planet. 8) It is unlikely that the emergence of life occurred in any other body of the solar system, although the examination of the Jovian satellite Europa may provide important clues about the constraints of this evolutionary process. Some of the fundamental principles of chemical evolution are briefly discussed.     

Observational astrochemistry: recent results.

More than 80 molecular species have now been observed by astronomers in the dense interstellar clouds where stars and planets form or in the envelopes expelled by evolved stars. Elemental constituents of these compounds include all of the "biogenic" elements, hydrogen, carbon, nitrogen, oxygen, sulfur, and (most recently) phosphorus. In addition, silicon is found in several molecules, and a series of metal halides have recently been detected in the outflowing envelope of a nearby carbon star. Additions to the list of known interstellar molecules since the last COSPAR meeting are discussed individually. Recent measurements of the hydrogen isotopic fractionation for the cyclic molecule C3H2 are described; values up to 10,000 times the cosmic deuterium-to-hydrogen ratio are found. Knowledge of the chemical reservoirs for the major volatile elements and a comparison between observed molecular abundances and theoretical models are both discussed.     

New flare model using recent measurements of the solar ultraviolet irradiance

The solar photon output from the Sun, which was once thought to be constant, varies considerably over time scales from seconds during solar flares to years due to the solar cycle. This is especially true in the wavelengths shorter than 190 nm. These variations cause significant deviations in the Earth and space environment on similar time scales, which then affects many things including satellite drag, radio communications, atmospheric densities and composition of particular atoms, molecules, and ions of Earth and other planets, as well as the accuracy in the Global Positioning System (GPS). The Flare Irradiance Spectral Model (FISM) is an empirical model that estimates the solar irradiance at wavelengths from 0.1 to 190 nm at 1 nm resolution with a time cadence of 60 s. This is a high enough temporal resolution to model variations due to solar flares, for which few accurate measurements at these wavelengths exist. This model also captures variations on the longer time scales of solar rotation (days) and solar cycle (years). Daily average proxies used are the 0–4 nm irradiance, the Mg II c/w, F10.7, as well as the 1 nm bins centered at 30.5 nm, 121.5 (Lyman Alpha), and 36.5 nm. The GOES 0.1–0.8 nm irradiance is used as the flare proxy. The FISM algorithms are given, and results and comparisons are shown that demonstrate the FISM estimations agree within the stated uncertainties to the various measurements of the solar Vacuum Ultraviolet (VUV) irradiance.     

卫星光学敏感器视场有效性分析工具设计

为了提高分析的效率和准确性,基于SolidW orks平台开发了一个卫星光学敏感器视场有效性分析工具.该工具用于分析敏感器在卫星任务期间是否会因为视场问题而失效,以及何时失效.敏感器有效性分析所涉及的问题有:有效性判断的3个层次——敏感器系统、敏感器组和单敏感器的有效性判断;遮挡问题——敏感器会受到卫星部件或目标的遮挡;反光问题——敏感器会受到行星反光和卫星部件反光的干扰;运动问题——包括目标、卫星本体、卫星部件和敏感器的运动.给出了解决以上问题的软件设计方案.介绍了有效性分析功能的实现原理.给出了分析过程的5个步骤:定义时间,定义目标,定义部件运动,定义敏感器和执行分析.最后给出了一个实例演示,验证了该工具的功能.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

A differential measurement of the Lyman alpha emission from the giant planets using IUE

The intensity of the resonantly scattered Ly-α line of the gian planets depends on the scattering column length of atomic hydrogen above the methane layer and on the incident solar flux. We have obtained measurements of the Ly-α brightness of Jupiter and Saturn on December 19, 1979, with a time difference of 111 minutes, which is only slightly longer than the additional travel time for solar photons scattered at Saturn compared to those from Jupiter. This observational technique eliminates two major uncertainties — the use of different instruments and solar variability — affecting previous determinations of the relative brightness of the planets. The measured ratio of the brightness of the subsolar points is 3.0 ± 0.4 which agrees well with the ratio of the incident solar flux of 3.4. This implies approximately equal scattering column lengths of H on both planets.     

The problems of simulation of planetary systems accumulation processes

Evolution of a system consisting of a great number of bodies that are gravitationally interacting and aggregating in contacts is considered. Body motions take place in the gravitational field of a central massive body (Sun or planet) in the same plane and at the initial time of system evolution orbits of all bodies are circular. It is shown that during evolution of the protoplanetary cloud, ring zones of matter rarefaction and condensation develop. Development of the condensation zones leads to the formation of planets, the most part of which acquire a direct rotation about their axes. In the case under consideration, approximate agreement between the law of planetary distances and that of geometric progression takes place as it is observed in planetary and satellite systems. The formation of the terrestrial planets and Jovian planets has been simulated. The principal numerical results have been obtained through digital simulation of planetary accumulation.     

The use of mineral crystals as bio-markers in the search for life on Mars.

Photographs that depict presumed fluvial features on the martian surface have led geologists to hypothesize that water flowed across the early martian terrain. From this, it has been further hypothesized that the surface and atmospheric conditions on early Mars were similar to those on early Earth. Because the oldest fossil evidence of life on Earth dates back to this early period, at least 3.5 billion years ago, the possibility exists that the early Martian environment could have also been conducive to the origin of life. To investigate this possibility, universal signatures or bio-markers indicative of past (or present) biological activity must be identified for use in the search for life on Mars. Several potentially applicable biomarkers have been identified and include: organics (e.g., specific classes of lipids and hopanes), suites of specific inorganic and organic compounds, as well as the isotopic ratios of C, N, and S. Unfortunately, all of these bio-markers may be of biologic or abiotic origin; these origins are often difficult to distinguish. Thus, the discovery of any one of these compounds alone is not a bio-marker. Because minerals produced under biologic control have distinctive crystallographies, morphologies, and isotopic ratios that distinguishable from abiotically produced minerals with the same chemical composition, and are stable through geologic time, we propose the use of minerals resulting from biologically controlled mineralization processes as bio-markers.     

北斗导航卫星姿态与轨道控制技术发展与贡献

通过总结北斗一号卫星到北斗三号卫星的发展过程，梳理了北斗导航卫星姿态与轨道控制技术的发展变化，以及在引领卫星姿轨控技术进步和星载器部件自主可控方面取得的成就.同时，根据下一代北斗卫星导航系统的论证需求，分析给出了未来导航卫星姿轨控系统需要关注与研究的关键技术.     

New results on planetary lightning

We present the latest observations from spacecraft and ground-based instruments in search for lightning activity in the atmospheres of planets in the solar system, and put them in context of previous research. Since the comprehensive book on planetary atmospheric electricity compiled by Leblanc et al. (2008), advances in remote sensing technology and telescopic optics enable detection of additional and new electromagnetic and optical emissions, respectively. Orbiting spacecraft such as Mars Express, Venus Express and Cassini yield new results, and we highlight the giant storm on Saturn of 2010/2011 that was probably the single most powerful thunderstorm ever observed in the solar system. We also describe theoretical models, laboratory spark experiments simulating conditions in planetary mixtures and map open issues.