Production and evolution of carbonaceous material by ion irradiation in space.

We review recent experimental studies concerning the evolution, driven by ion irradiation, of carbonaceous material from frozen gas to a refractory molecular solid. Under further irradiation the latter changes to a polymer-like material and ultimately to amorphous carbon. Most of the results have been obtained by "in situ" and remote IR and Raman spectroscopy. The results have been applied to demonstrate that molecular solids may be easily formed by irradiation of frozen mantles in dense interstellar clouds. Polymer-like material and amorphous carbons may result by further irradiation of organic mantles on grains in the diffuse interstellar medium. Those grains, during the aggregation to form extended bodies like comets (T-Tau phase of the Sun), are further modified. These latter are also irradiated, after the comet formation, during their long stay in the Oort cloud. In particular it has been suggested that comet may develop an ion-produced cometary organic crust that laboratory evidences show to be stable against temperature increases experienced during passages near the Sun. The comparison between the Raman spectra of some IDP (Interplanetary Dust Particles) and the Raman spectra of some ion-produced amorphous carbons, is also discussed.     

Polarization imaging of dust cloud particles: Improvements and applications of the PROGRA2 instrument

The imaging system of the -PROGRA2 instrument allows to obtain maps of polarization and brightness of levitating dust clouds with a theoretical resolution of 10 μm per pixel. The measurements are conducted in microgravity during parabolic flights and on the ground by air-draught. It is then possible to measure the contribution of individual particles (grains, aggregates and agglomerates.) The size distribution can be retrieved, as well as the variation of polarization for a given phase angle with size for particles larger than 10 microns. Two different kinds of particles are considered: compact grains and (aggregates and agglomerates of) fluffy particles. Opposite results are obtained for these two kinds of particles, concerning the dependence of polarization with size and color in the visible domain for gray materials. These results, coupled with such remote sensing observations in the solar system, can then help to better understand the physical properties of solid particles and their variation in cometary comae, as well as in the Earth's atmosphere.     

A comparison of the dust properties in recent periodic comets

Measurements of the thermal emission from the cometary dust coma can be used to derive the rate of dust production from the nucleus as well as the size distribution of absorbing grains. More than ten short-period comets have now been observed in the infrared over a wide range in heliocentric distance. Dust production rates are derived for these comets based on theoretical models of the thermal emission from small absorbing grains and calculations of dust grain velocities. The mean size and albedo of the dust grains is similar in these comets, with the exception of Comet Crommelin, which seems to have had larger, darker grains.     

Spectroscopic observations of comet Giacobini-Zinner during the ice encounter

A set of 5 sequential spectra of Comet Giacobini-Zinner was obtained during the encounter of the ICE spacecraft with that comet on September 11, 1985. The observations were initiated 20 min before the encounter and were conducted in 10 min-long intervals until approximately 40 min after the event. The spectra were taken along a direction nearly coincident to the axis of the cometary tail and cover a distance of approximately 74 000 km at the comet. The preliminary analysis of the data indicates that the measured brightness intensity of CN at 3884 Å and that of the continuum at 5215 Å was nearly constant throughout the period of observation.     

On the conditions for fluidisation in cometary mantles

In our current understanding, active cometary nuclei comprise a volatile-depleted outer crust covering a mixture of dust and ices. During each perihelion passage the thermal wave penetrates the crust and sublimates a portion of these ices, which then escape the nucleus, dragging with them dust particles that replenish the coma and dust tail. The flux of released gases is likely to vary as a complex function of solar distance, nucleus structure, spin rate, etc. It has been previously hypothesised that at some point a fluidised state could occur, in which the gas drag is approximately equal to the weight of overlying dust and ice grains. This state is well understood and used in industrial processes where extensive mixing of the gas and solid components is desired. The literature on fluidisation under reduced gravity and pressure conditions is here reviewed and published relations used to predict the conditions under which fluidisation could occur in the near-surface of a cometary nucleus.     

Entry of dust particles into planetary magnetospheres

While interplanetary dust constitutes a primary source of cosmic particulate matter in planetary magnetospheres, the debris produced by its impact with small satellites and ring material provides an important secondary source. Internal processes, such as volcanic activity, particularly in the smaller satellites, could result in a third source. In the case of the terrestrial magnetosphere there are also artificial (internal) sources: 1–10μ sized A?₂O₃ particles injected by solid rocket mortar burns between near earth and geosynchronous orbit constitute one such source, while the fragments of larger bodies (artificial satellites) due to explosions (e.g., “killer satellites”) and collisions constitute another. Finally, if we include the purely induced cometary magnetosphere among planetary magnetospheres, the injection of cometary dust into it due to entrainment by the outflowing gases constitutes another source.As a result of being immersed in a radiative and plasma environment these dust grains get electrically charged up to some potential (positive or negative). Particularly in those regions where the magnetospheric plasma is hot and dense and their own spatial density is low, the dust grains could get charged to numerically large negative potentials.While this charging may have physical consequences for the larger grains, such as electrostatic erosion (“chipping”) and disruption, it also can effect the dynamics of the smaller grains. Indeed, the small but finite capacitance of these grains, which leads to a phase lag in the gyrophase oscillation of the grain potential, could even lead to the permanent magneto-gravitational capture of interplanetary grains within planetary magnetospheres in certain situations. Here we will review the sources of dust in planetary magnetospheres and discuss their physics and their dynamics under the combined action of both planetary gravitational and magnetospheric electromagnetic forces.     

Mass-spectrometric in situ studies of cometary organics for p/Halley and options for the future.

When the VEGA and GIOTTO spacecrafts flew by comet p/Halley in 1986 the mass-spectrometers Puma and PIA measured the composition of cometary dust particles impacting at speeds of well above 65 km/s. Ion formation upon impact lead to mostly atomic ions. However, a small fraction of the ions measured could be related to molecules. A sophisticated analysis allowed for the first time to point to the chemical nature of cometary organics based on actual mass spectra. With the instrument CoMA for the NASA-BMFT mission CRAF much higher mass-resolution and molecule masses become accessible for in situ measurement, and will yield complementary information to the gas chromatograph CIDEX also onboard CRAF.     

Models of P/Borrelly: Activity and dust mantle formation

Comet 19P/Borrelly was observed by Deep Space One spacecraft on September 22, 2001 (Soderblom et al., 2002).The DS1 images show a very dark and elongate nucleus with a complex topography; the IR spectra show a strong red-ward slope consistent with a very hot and dry surface (345K to 300K). During DS1 encounter the comet coma was dominated by a prominent jet but most of the comet was inactive, confirming the Earth-based observations that <10% of the surface is actively sublimating. We have developed a thermal evolution model of comet PBorrelly, using a numerical code that is able to solve the heat conduction and gas diffusion equations at the same time across an idealized spherical nucleus ( De Sanctis et al., 1999, 2000; Capria et al., 2000; Coradini et al., 1997a,b). The comet nucleus is composed by water, volatiles ices and dust in different proportions. The refractory component is made by grains that are embedded in the icy matrix. The code is able to account for the dust release, contributing to the dust flux, and the formation of dust mantles on the comet surface. The model was applied to a cometary nucleus with the estimated physical and dynamical characteristics of P/Borrelly in order to infer the status and activity level of a body on such an orbit during the DS1 observation. The comet gas flux, differentiation and thermal behavior were simulated and reproduced. The model results are in good agreement with the DS1 flyby results and the ground based observations, in terms of activity, dust coverage and temperatures of the surface.     

The detection of energetic cometary and solar particles by the EPONA instrument on the Giotto mission

EPONA is an energetic particle detector system incorporating totally depleted silicon surface barrier layer detectors. Active and passive background shielding will be employed and, by applying various techniques, particles of different species, including electrons, protons, alpha particles and pick-up ions of cometary origin may be detected over a wide spectrum of energies extending from the tens of KeV into the MeV range.

The instrument can operate in two modes namely (a) in a cruise phase or storage mode and (b) in a real time mode. During the real time mode, observations at high spatial (octosectoring) and temporal (0.5s) resolution in the cometary environment permit studies to be made of accelerated particles at the bow shock and/or in the tail of the comet. In conjunction with magnetic field measurements on board Giotto, observations of energetic electrons and their anisotropies can determine whether the magnetic field lines in the cometary tail are open or closed. Further, the absorption of low energy solar particles in the cometary atmosphere can be measured and such data would provide an integral value of the pertaining gas and dust distribution. Solar particle background measurements during encounter may also be used to correct the measurements of other spacecraft borne instruments potentially vulnerable to such radiation.

Solar particle flux measurements, obtained during the cruise phase will, when combined with simultaneous observations made by other spacecraft at different heliographic longitudes, provide information concerning solar particle propagation in the corona and in interplanetary space.     

Interplanetary dust interaction with comets: Production of x-rays

Recent results of theoretical investigations related to generation of high-energy (0.1-1 keV) photons in comets due to production of high-temperature (3×10⁵-10⁷ K) plasma clots from collisions of cometary and interplanetary grains at high relative velocities (70-700 km s⁻¹ at heliocentric distances R=0.01-1 AU) are summarized and main features of the process are marked.     

The plasma regime at comet Giacobini-Zinner

This review of the plasma regime sampled by the encounter of the International Cometary Explorer spacecraft (ICE) with the comet Giacobini-Zinner, discusses the shock, or bow wave, ion pickup, ionization mechanisms, and the cometary plasma tail.

The observations are consistent with the existence of a weak shock, which may be pulsating, but do not exclude the suggestion by Wallis and Dryer that the shock, though present around the sub-solar point, is in process of decaying to a wave on the flanks.

Pickup of cometary ions provokes, by means of several mechanisms, ion cyclotron, mirror, beam and electrostatic instabilities which cause strong turbulence in the inner coma, as indicated in the power spectra of the magnetic field in the coma and the surrounding volume. Heavy mass loading and consequent slowing down of the solar wind is observed. Acceleration of ions by a stochastic mechanism is indicated.

Ionization of cometary neutrals occurs principally by photoionization and charge exchange. Alfvens critical velocity mechanism, likely operates only in the inner coma not visited by ICE. A steep increase of nearly two orders of magnitude in electron density occurs in the tail, where electron velocity distributions show evidence of entry of electrons from the solar wind. The turbulence there is damped by the high ion density and low temperature.

In general, the vicinity of the comet is filled with plasma phenomena and a rich variety of corresponding atomic and molecular processes can be studied there. Comparison between the ICE, Giotto, and Vega observations forms a most valuable future study.     

Theory and observations of cometary ionospheres

The physical and chemical processes responsible for cometary ionospheres are now beginning to be understood, due to comparisons between theoretical results and recently obtained in situ observations of the ionospheric plasma and magnetic field of comet Halley. The contact surface which separates outflowing cometary plasma from solar wind controlled cometary plasma can be explained in terms of a balance between the magnetic pressure gradient force and ion-neutral drag. An analytic expression for the magnetic field in the vicinity of the contact surface is given in this paper.     

Cometary kilometric radio waves and plasma waves correlated with ion pick-up effect at comet Halley

From the discrete spectra of the emissions from the comet in the frequency range from 30 to 195 kHz named CKR (Cometary Kilometric Radiation), movements of the bow shock at comet Halley are concluded, i.e., the observed CKR emissions can be interpreted as being generated and propagating from the moving shock. The motion of the shocks are possibly associated with time variation of the solar wind and of the cometary outgassings. By in-situ plasma waves observations using PWP (Plasma Wave Probe) onboard the Sakigake spacecraft, the characteristic spectra of the electrostatic electron plasma waves, the electron cyclotron harmonic waves, and the ion sound waves have been detected during the interval of the Halley's comet fly-by. Compared with the results of a Faraday cup observation and a magnetometer, it is concluded that these plasma wave phenomena are the manifestation of the ion pick-up processes. The ion pick-up processes are taking place even in the remote region within a distance range from 7×10⁶ to 10⁷ km from the cometary nucleus.     

Dirty ice grains in comets

Based on the computed equilibrium temperature of evaporating dirty water-ice grains, dirty water-ice halo is examined, taking into account of a size dependence of terminal velocity of dust at P/Halley. It is found that due to an enhanced grain's temperature caused by dirtiness, icy halo cannot extend over 100 km from the nucleus when comet approaches inside a solar distance r of 1 AU. Therefore, it is unlikely that the ice bands in the near infrared wavelengths could be detected in the cometary coma at r<1 AU.     

Interpretation of the measurements of secondary electron currents induced by impacts during the flyby of comet Halley

The Giotto, Vega-1 and Vega-2 spacecraft flew through the environment of comet Halley at a relatively close range with velocities of the order of 70–80 km/s. The fore sections of their surface were bombarded by neutral molecules and dust grains which caused the emission of secondary electrons and sputtered ions. This paper makes use of the secondary electron current measurements performed on Vega-1 to infer some characteristic features of the cometary atmosphere. The total gas production rate is estimated to be of the order of 10³⁰ molecules/s and is found to vary with time; the presence of a major jet is also detected at closest approach.     

Conception of the 'Chirality-Experiment' on ESA's mission ROSETTA to comet P46/Wirtanen.

In the last years extraterrestrial scenarios for the origin of homochirality in biological structures received considerable attention in the topical literature: Rubenstein and Bonner postulated a rapidly rotating neutron star emitting circularly polarised synchrotron radiation responsible for the first asymmetric synthesis; the group of Bailey published the observation of circular polarisation caused by Mie scattering from aligned dust grains in the Orion OMC-1 star-formation region that might provide an enantioselective effect on prochiral or racemic organic molecules. Rikken and Raupach observed a magnetochiral effect and considered extraterrestrial magnetic fields of sufficient strengths to introduce biomoleculars parity violation. With the aim to investigate these hypotheses among other theories describing the origin of biological asymmetry, our laboratory participates in the conception and development of ROSETTA's COSAC Experiment, that is designed to identify organic molecules in the cometary matter in situ. Within COSAC's 'Chirality Module' enantiomers will be separated gas chromatographically with the help of capillary columns coated with chirally active liquid films. This technique will allow the separation of specific chiral organic compounds out of the analysed cometary matter into their enantiomeric constituents. Both thermo conductivity and mass spectrometric detectors will be used to determine each enantiomer's amount and therefore the corresponding enantiomeric excesses. As a consequence of COSAC's 'Chirality-Experiment' far-reaching results are expected to investigate the various hypotheses about the first asymmetric synthesis.     

Dust emission phenomena of cometary analogues

Experiments with cometary analogues are reported, which were performed at DLR - Köln in a small vacuum chamber and in the Space Simulator. The results apply to the emission processes of ice-dust grains from the surface of mineral-ice mixtures during insolation. The emission phenomena were observed with CCD-video-cameras. The camera used at the small chamber was equipped with a magnifying (10x) macro-lens. The magnified pictures show that the ice-dust agglomerates carry tiny ice particles on their surfaces. These may play the role of interlinking bonds between one grain and its neighbors. In the enlarged view it can be seen that the ice-dust grains do not erupt with high velocity out of the surface. The upstreaming gas jet originating from the sublimation of the volatile components first erodes the interlinking bonds between the particles. When the drag force exerted on the particles exceeds the force of gravity, the particles lift off. In most of the observed cases this initial lift off velocity is very small e.g. a few cm/s.

During a comet-simulation experiment in the Space-Simulator in November 1989 the trajectories of emitted dust particles were recorded for the first time with a high speed shutter video system 60 cm from the model comet. The video tapes were evaluated with a computerized image processing system. Unique insights in the gas-dust-interaction immediately at and above the insolated icy body were obtained. The trajectories differ markedly in all cases from the the ballistic parabolas calculated from the measured starting conditions: elevation angle and speed. The trajectory is mainly dominated by the momentum transfer from the gas jet to the dust particles. Many of the particles have millimeter sizes. The observed velocities at the end of the visible trajectory are in the order of a few meters per second.     

Organic chemistry by irradiation in space

The irradiation of grains and/or ices by particles from solar or stellar winds, as well as cosmic rays, induces the synthesis of molecular species. We have shown by in-situ infrared spectroscopy of irradiated samples that this chemistry may be responsible for the presence of organic compounds in a large variety of astrophysical sites such as: lunar and asteroidal regoliths, cometary nucleus, rings and satellites of outer planets, circumstellar shells, interstellar clouds. We present our experimental results concerning the nature and efficiency of C and N irradiation chemistries, and give plausible astrophysical implications.     

Giotto/Cometary dust interaction event near the comet Halley ionopause

Plasma and magnetic field disturbances accompanying dust particle impacts are explained by means of creation of a secondary cloud around the spacecraft. Cold cometary ions impinging upon the cloud are scattered by atoms of the cloud. This scattering changes initial angular distribution of cometary ions. Magnetic field perturbation is created by the friction between the electron component of the cometary plasma flow and the cloud.