Comparison of ozone data derived from SBUV and SAGE with emphasis on longitudinal variations

Stratospheric ozone observations by the SAGE and SBUV satellite instruments in March and April, 1979 have been analyzed. All SAGE profiles have been smoothed vertically over 8 km to provide some compatibility with the SBUV vertical resolution. Comparing the zonal mean ozone mixing ratios against smoothed LIMS profiles, it is inferred that SAGE is systematically overestimating ozone by approximately 20% at tropical latitudes at pressures lower than 5 mb and that SBUV is underestimating ozone by approximately 15% at 50–70° latitude at 10 mb. A comparison of the longitudinal variations of ozone by SBUV and SAGE is made and the detectability of planetary waves in ozone is emphasized. The uncorrelated portion of the SAGE variances are found to be approximately consistent with the SAGE noise model. Based on the correlated variances, the amplitudes of the smoothed SAGE planetary waves in ozone are found to be the same, on average, as in the SBUV experiment at mid-latitudes between 1 and 10 mb. Planetary wave detectability is illustrated during two several day periods at mid-latitudes and a persistent and theoretically-consistent relationship between ozone and temperature is noted. These examples, however, indicate that differences between ozone planetary wave amplitudes derived from the two sensors may occur when there is a strong vertical gradient in wave amplitude.     

A mesospheric ozone profile at sunset

An altitude profile of the ozone concentration from 55 to 95 km was measured at sunset in January by simultaneous measurements of the 1.27 μm radiation and the solar UV radiation using rocket-borne radiometers at Uchinoura, Japan (31°N). The ozone profiles deduced by two different methods agree with each other at approximately 70 km. The profile was consistent with our previous results obtained at the same station in September, and with the sunset profile obtained at Wallops Island (38°N) during the WMO/FAA/NASA international ozone rocketsonde intercomparison. Our data show no seasonal variation of ozone in the 55 – 95 km region at Uchinoura.     

The potential for radiometric retrievals of halocarbon concentrations from the MIPAS-E instrument

Halocarbons, such as CFC-11, CFC-12 and HCFC-22, are important trace gases in the atmosphere through their role as greenhouse gases and their influence on stratospheric ozone chemistry. This paper focuses on an initial study using integration of spectral radiance measurements from a spaceborne limb sounding Fourier Transform Spectrometer (FTS) to retrieve these compounds in the upper troposphere and lower stratosphere (UTLS). The instrument employed in this study is the Michelson Interferometer for Passive Atmospheric Sounding onboard ENVISAT (MIPAS-E) which obtains spectral data in the altitude range of 6–68 km at an unapodized spectral resolution of 0.025 cm⁻¹. We have used optimal estimation techniques to retrieve vertical information for these compounds using a radiometric approach.

It is shown that significant retrieval information is obtained at up to five measured levels in the UTLS for CFC-11, up to six for CFC-12 and up to two levels for HCFC-22. An initial error analysis indicates significant sensitivity of our retrievals to variability in operationally retrieved pressure and temperature data. For each halocarbon, gain, offset and spectroscopic uncertainties generally each contribute less than 10% to the total error. Finally, tracer correlations are used to compare the datasets to equivalent relationships derived here from version 2 ATMOS data with very good agreements for CFC-12 but with more variability in the CFC-11 comparisons.     

Mesospheric ozone densities deduced from solar occultation measurements

Quartz-UV occultation measurements by the satellite Interkosmos-16 have been used to calculate ozone densities at altitudes between 50 and 90 km for the period August to October 1976. Below 65 km densities agree well with the Krueger-Minzner-model. Mesopause densities have been studied in some detail. A certain percentage of the profiles show close correlation with the model of Shimazaki and Laird (with a pronounced minimum below the mesopause) while others fit better to the Park and London model (no minimum). This variability of the ozone density may be caused by different processes in the photo-chemistry of ozone. Two possible causes, the temperature dependent rate coefficients and the odd hydrogen processes are discussed in greater detail.     

Hemispheric asymmetry of chemical species and its effect on stratospheric ozone: Emphasis on halogen loading

Differences between the dynamical characteristics of the northern hemisphere (NH) and southern hemisphere (SH) stratosphere (e.g., the temperature, the strength of polar vortex, and the mean meridional circulation) produce hemispherically asymmetrical distributions of chemical species. In this paper, we use global models to briefly discuss various effects on chemical species caused by this asymmetrical distribution, especially on stratospheric ozone. The role of hemispheric asymmetries in chlorine and bromine loadings on mid- and high latitude ozone depletion is particularly discussed.     

Solar UV and ozone balloon measurements

Absolute solar UV spectra were obtained with a $\text{1}\text{4}$m spectrometer on a balloon flight from Palestine, Texas on September 23, 1981. This balloon reached a float altitude of 39 km at solar noon. The ozone density profiles derived from these spectra are discussed. The measurements are compared with data obtained from the same calibrated instrument flown in 1976 at solar minimum.     

Validation of 9.6 μm ozone transmittances by spectral radiance satellite measurements

The accuracy of atmospheric transmittances is important in remote sensing applications. In this paper the atmospheric ozone transmittances in the 1042 cm^?1 ozone band were calculated for different temperatures and ozone profiles using line-by-line integration method. The absorption line parameters were taken from McClatchey's line parameter compilation. The transmittances were used to derive the main characteristics of the atmospheric ozone profile and the total ozone amount from radiance measurements of Meteor satellites.     

Vertical wavenumber spectra of atmospheric ozone measured from ozonesonde observations

Vertical profiles of ozone have been measured at balloon altitudes. Our purpose is to examine the character of vertical wavenumber spectra of ozone fluctuations, to assess the possible roles of gravity wave field in ozone fluctuations, and to determine dominant vertical wavelengths of ozone spectra. Vertical wavenumber spectra of 12 ozone fluctuations obtained during June–August 2003 are presented. Results indicate that mean spectral slopes in the wavenumber range from 4.69 × 10⁻⁴ to 2.50 × 10⁻³ cyc/m are about −2.91 in the troposphere and −2.87 in the lower stratosphere, which is close to the slope of −3 predicted by current gravity wave saturation models. The consistency of the observed spectral slopes with the value of −3 predicted by current gravity wave saturation models suggests that the observed ozone fluctuations are due primarily to atmospheric gravity waves. At m = 1/(1000 m) the mean spectral amplitude is over 30 times larger in the lower stratosphere than in the troposphere. Mean vertical wavenumber spectra in area-preserving form reveal dominant vertical wavelengths of ∼2.6 km in the troposphere and ∼2.7 km in the lower stratosphere, which is consistent with the values varying between 1.5 and 3.0 km estimated from the velocity field and temperature field at these heights.     

Precision measurements of stratospheric ozone profiles by rocket-borne optical ozonesondes

Sunset observations of the upper stratospheric and mesospheric ozone were made at Uchinoura (31.25°N, 131.08°E) with rocket-borne optical ozonesondes, which consist of multi-color solar ultraviolet radiometers and sun tracking devices. Three ozone density profiles were obtained in this study. A comparison with the 30°N zonal and monthly average of the interim reference ozone model shows a variability that our present ozone mixing ratios below −50 km are larger in January and February and smaller in September than those of the model.     

Measurement of middle atmospheric ozone density profile by rocket-borne radiometer onboard KSR-II

KSR-II, a two-stage sounding rocket of KARI was launched successfully at the Korean Peninsula on June 11, 1998. The apogee of the rocket was 137 km. For the ozone measurement, 8-channel UV and visible radiometers were onboard the rocket. The rocket measured an in situ stratospheric and mesospheric ozone density profile over Korea during its ascending phase using the radiometer and transmitted the data to ground station in real time. The maximum ozone density occurs near 25 km. Retrieved profile has a random error (1σ) of approximately 15% for altitude below 20km, 7% between 20-50 km and 10% greater than 50 km. The retrieved data were compared with Dobson spectrophotometer, ozonesonde, and HALOE onboard the UARS. Our results are in reasonable agreements with others.     

Global pictures of the ozone field,from high altitudes,from DE-I

Using the imaging instrumentation aboard the Dynamics Explorer spacecraft (DE-I), total column ozone densities are obtained in the sunlit hemisphere by measuring the intensities of backscattered solar ultraviolet radiation with multiple filters and multiple photometers. The high apogee altitude (23,000 km) of the eccentric polar orbit allows high resolution global-scale images of the terrestrial ozone field to be obtained within 12 minutes. Previous ozone-monitoring spacecraft have required much longer time periods for comparable spatial coverage because of their lower altitudes (<1200 km). The much higher altitude of DE-I also provides hours of continuous imaging of features compared to minutes or seconds with previous spacecraft. Near perigee, high resolution images can be gained with pixel size as small as 3 km to view mesoscale atmospheric variations. Utilizing these data, the effects of planetary-scale, synoptic-scale, and mesoscale dynamical processes, which control the distribution of ozone near the tropopause, can be studied. Preliminary results show short-term (less than one day) variations in the synoptic ozone field and these variations appear to be in accord with meteorological data. Spatial variations in the ozone field are found to be highly negatively correlated with tropopause altitude.     

Periodic and aperiodic ozone variations in the middle and upper stratosphere

Umkehr, ozonesonde and satellite observations were used to determine the height/latitude distribution of the amplitude and phase of the periodic components of the variation of the ozone mixing ratio in the middle and upper stratosphere. The amplitude of the first (annual) harmonic is small in the subtropics and increases to a maximum at polar latitudes. It also increases with height in the mid and upper stratosphere to an apparent maximum just below the stratopause. The second (semi-annual) harmonic has an amplitude that is largest in tropical regions and in subpolar regions at a level of about 40 km. There seems to be very little ozone variation above 30 km with dominant periods close to the quasi-biennial period of total ozone observed in the tropics. The percent of the total variance of the ozone mixing ratio accounted for by the first harmonic is larger than 60 percent at all heights from 20° – 60° latitude in both hemispheres (except near 40 km in the Northern Hemisphere). The percent of the total variance accounted for by the second harmonic is maximum at a height of about 40 km in the tropics and at subpolar latitudes where, as mentioned, its amplitude is also largest.The phase of the first harmonic shows a marked transition from a winter/spring maximum below 30 km to a summer maximum at 30 km, changing rapidly to a maximum in winter in both hemispheres. The regions of minimum amplitude of the annual variation and the marked phase shifts with height both indicate the separation by levels of the dominant physical control mechanisms on the periodic changes of the ozone mixing ratio in the middle and upper stratosphere. Changes below 30 km respond primarily to dynamic influences in the lower stratosphere while above 30 km the periodic variations result mainly from photochemical processes. Above 40 km these variations are strongly temperature dependent.     

Changes in surface UV solar irradiance and ozone over the balkans during the eclipse of August 11, 1999

Intensive measurements of UV solar irradiance, total ozone and surface ozone were carried out during the solar eclipse of 11 August 1999 at Thessaloniki, Greece and Stara Zagora, Bulgaria, located very close to the footprint of the moon's shadow during the solar eclipse with the maximum coverage of the solar disk reaching about 90% and 96% respectively. It is shown that during the eclipse the diffuse component is reduced less compared to the decline of the direct solar irradiance at the shorter wavelengths. A 20-minute oscillation of erythemal UV-B solar irradiance was observed before and after the time of the eclipse maximum under clear skies, indicating a possible 20-minute fluctuation in total ozone presumably caused by the eclipse induced gravity waves. The surface ozone measurements at Thessaloniki display a decrease of around 10–15 ppbv during the solar eclipse. Similarly, ozone profile measurements with a lidar system indicate a decrease of ozone up to 2 km during the solar eclipse. The eclipse offered the opportunity to test our understanding of tropospheric ozone chemistry. The use of a chemical box model suggested that photochemistry can account for a significant portion of the observed surface ozone decrease.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model,and model calculations

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago (Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O₃ and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.     

Seasonal-latitudinal variations of the mesospheric ozone density

Quartz-UV occultation measurements by the satellite Interkosmos-16 have been used to calculate ozone densities at altitudes between 55 and 75 km for the period July 27 – October 28 of 1976. Although the densities agree quite well with the Krueger-Minzner-model below 65 km distinct seasonal-latitudinal variations have been found. During July and August latitudinal variations are more pronounced than in September and October with a slight maximum shifting from 5° S in July to 30 – 40° S in September. A comparison of different height levels shows a decreasing latitudinal variation for increasing altitude during July and August and rather modest variations for September and October.     

Mesospheric nitric oxide and ozone measurements in polar winter at 69°N

Two rocket experiments were carried out just before and after the polar night at Andoya (69°N), Norway to investigate transport of nitric oxide produced by auroral processes into the middle atmosphere and its influence on the ozone chemistry. Nitric oxide densities of (2–5) × 10⁸cm⁻³ found in the 70–90 km region are one to two orders of magnitude larger than those at middle latitudes. The influence on ozone densities in the 70–90 km region due to such enhanced nitric oxide abundance is found to be insignificant as compared to that due to transport in the middle of February. The larger ozone densities found in February (in spite of longer sunlit duration) than in November in the 40–60 km region again support predominance of transport over photochemical loss.     

Radiative and dynamical impacts of Arctic and Antarctic ozone holes: General circulation model experiments

Radiative and dynamical impacts of Arctic and Antarctic ozone holes on the general circulation are investigated with the aid of a general circulation model developed at Kyushu University. The model includes a simplified ozone photochemistry interactively coupled with radiation and dynamics. Resultant temperature structure consisting of a cooling in the polar lower stratosphere and a warming in the polar upper stratosphere brings about the intensification of the polar night jet. The cooling is caused by the decrease of solar ultraviolet heating due to the ozone depletion, while the warming is caused by adiabatic heating due to the enhancement of downward motion.     

Proposed reference models for ozone

Ozone reference models are proposed here similar to the Keating and Young 1985 models which were prepared for the new COSPAR International Reference Atmosphere. This paper updates tables provided in the Keating and Young ozone model, giving improved monthly zonal mean total column ozone in 10° latitude increments, improved monthly zonal mean ozone volume mixing ratios (ppmv) from 20 to 0.003 mb in 10° latitude increments, and conversion tables providing ozone vertical structure in other units. Also, a new table is provided giving ozone vertical structure as a function of altitude (from 25 to 80 km), latitude, and month. The models are based on measurements from six contemporary satellite instruments.