The PROCESS experiment: amino and carboxylic acids under Mars-like surface UV radiation conditions in low-earth orbit

The search for organic molecules at the surface of Mars is a top priority of the next Mars exploration space missions: Mars Science Laboratory (NASA) and ExoMars (ESA). The detection of organic matter could provide information about the presence of a prebiotic chemistry or even biological activity on this planet. Therefore, a key step in interpretation of future data collected by these missions is to understand the preservation of organic matter in the martian environment. Several laboratory experiments have been devoted to quantifying and qualifying the evolution of organic molecules under simulated environmental conditions of Mars. However, these laboratory simulations are limited, and one major constraint is the reproduction of the UV spectrum that reaches the surface of Mars. As part of the PROCESS experiment of the European EXPOSE-E mission on board the International Space Station, a study was performed on the photodegradation of organics under filtered extraterrestrial solar electromagnetic radiation that mimics Mars-like surface UV radiation conditions. Glycine, serine, phthalic acid, phthalic acid in the presence of a mineral phase, and mellitic acid were exposed to these conditions for 1.5 years, and their evolution was determined by Fourier transform infrared spectroscopy after their retrieval. The results were compared with data from laboratory experiments. A 1.5-year exposure to Mars-like surface UV radiation conditions in space resulted in complete degradation of the organic compounds. Half-lives between 50 and 150?h for martian surface conditions were calculated from both laboratory and low-Earth orbit experiments. The results highlight that none of those organics are stable under low-Earth orbit solar UV radiation conditions.     

The PROCESS experiment: exposure of amino acids in the EXPOSE-E experiment on the international space station and in laboratory simulations

To understand the chemical behavior of organic molecules in the space environment, amino acids and a dipeptide in pure form and embedded in meteorite powder were exposed in the PROCESS experiment in the EXPOSE-E facility mounted on the European Technology Exposure Facility (EuTEF) platform on board the International Space Station (ISS). After exposure to space conditions for 18 months, the samples were returned to Earth and analyzed in the laboratory for reactions caused by solar UV and cosmic radiation. Chemical degradation and possible racemization and oligomerization, the main reactions caused by photochemistry in the vacuum ultraviolet domain (VUV, wavelength range 100-200?nm for photon energy from 6.2 to 12.4?eV) were examined in particular. The molecules were extracted and derivatized by silylation and analyzed by gas chromatograph coupled to a mass spectrometer (GC-MS) to quantify the rate of the degradation of the compounds. Laboratory exposure in several wavelength ranges from UV to VUV was carried out in parallel in the Cologne Deutsches Zentrum für Luft- und Raumfahrt (DLR) Center and Centre de biophysique moléculaire (CBM) laboratories. The results show that resistance to irradiation is a function of the chemical nature of the exposed molecules and the wavelengths of the UV light. The most altered compounds were the dipeptide, aspartic acid, and aminobutyric acid. The most resistant were alanine, valine, glycine, and aminoisobutyric acid. Our results also demonstrate the protective effect of meteorite powder, which reemphasizes the importance of exogenic contribution to the inventory of prebiotic organics on early Earth.     

The Urey instrument: an advanced in situ organic and oxidant detector for Mars exploration

The Urey organic and oxidant detector consists of a suite of instruments designed to search for several classes of organic molecules in the martian regolith and ascertain whether these compounds were produced by biotic or abiotic processes using chirality measurements. These experiments will also determine the chemical stability of organic molecules within the host regolith based on the presence and chemical reactivity of surface and atmospheric oxidants. Urey has been selected for the Pasteur payload on the European Space Agency's (ESA's) upcoming 2013 ExoMars rover mission. The diverse and effective capabilities of Urey make it an integral part of the payload and will help to achieve a large portion of the mission's primary scientific objective: "to search for signs of past and present life on Mars." This instrument is named in honor of Harold Urey for his seminal contributions to the fields of cosmochemistry and the origin of life.     

CROCODILE: an automated apparatus for organic crystal growth from solution

CROCODILE (CROissance de Cristaux Organiques par DIffusion Liquide dans l'Espace) is a space instrument dedicated to crystal growth from solution. The selected material N (4 nitrophenyl) (L) prolinol (NPP) is the result of studies on organic crystal in the frame of an extended program initiated by CNES for many years. The apparatus was flown aboard PHOTON, an automatic satellite, in April 1990, for a flight duration of more than 15 days. This paper describes the instrument design, with emphasis on specific and original technology well adapted to crystal growth from solution, and extendable to any space experiment on fluids. Preliminary details of the flight campaign will also be discussed.     

Astromedicine and astrolaw: Emerging issues for advanced missions beyond Earth orbit

It is generally agreed within the scientific community that provision of appropriate medical facilities and administration of quality health care to astronauts are of great importance. However, for the more complex and remote missions envisaged for the future, issues of liability, responsibility and damage relating to medical practice may take on a greater significance and will need to be addressed. The author briefly reviews potential issues which may arise in the context of medical emergencies, crew autonomy and environmentally altered physiological status which characterize some projected advanced space missions and argues that the law of outer space will need to be expanded to take account of them.     

Fourth-order theories for orbit predictions for low- and high-eccentricity orbits in an oblate atmosphere with scale height dependent on altitude

Two new fourth-order non-singular analytical theories for the motion of near-Earth satellite orbits with air drag are developed for low- and high-eccentricity orbits in an oblate atmosphere with variation of density scale height with altitude. Uniformly regular Kustaanheimo–Stiefel (KS) canonical elements are utilized for low-eccentricity orbits and KS element equations are employed for high-eccentricity orbits. Only two of the nine equations are solved analytically to compute the state vector and change in energy at the end of each revolution, due to symmetry in the equations of motion. The analytical solutions are compared with the numerically integrated values up to 100 revolutions, and found to be quite accurate over a wide range of eccentricity, perigee height and inclination.     

New methods for microbial contamination monitoring: an experiment on board the MIR orbital station

Experiment T2, carried out during the Euromir'95 mission, was an important step toward innovative methods for spacecraft microbial contamination monitoring. A new standard sampling technique permitted samples to be analysed by different means. On board, two analysis methods were tested in parallel: Bioluminescence and Miniculture. In turn, downloaded samples are being analysed by polymerase chain reaction (PCR), a powerful and promising method for the rapid detection, identification and quantification of pathogens and biofouling agents in closed manned habitats.     

The Skylab sleep monitoring experiment: methodology and initial results

The sleep monitoring experiment permitted an objective evaluation of sleep characteristics during the first two manned Skylab flights. Hardware located onboard the spacecraft accomplished data acquisition, analysis, and preservation, thereby permitting near-real-time evaluation of sleep during the flights and more detailed postmission analysis. The crewman studied during the 28-Day Mission showed some decrease in total sleep time an increase in the percentage of Stage 4 sleep, while the subject in the 59-Day Mission exhibited little change in total sleep time and a small decrease in Stage 4 and REM sleep. Some disruption of sleep characteristics was seen in the final days of both missions, and both subjects exhibited decreases in REM-onset latency in the immediate postflight period. The relatively minor changes seen were not of the type nor magnitude which might be expected to be associated with significant degradation of performance capability.     

The formation of sulfate and elemental sulfur aerosols under varying laboratory conditions: implications for early earth

The presence of sulfur mass-independent fractionation (S-MIF) in sediments more than 2.45?×?10(9) years old is thought to be evidence for an early anoxic atmosphere. Photolysis of sulfur dioxide (SO(2)) by UV light with λ?相似文献   

From Earth's orbit to the outer planets and beyond: Psychological issues in space

Current planning for the first interplanetary expedition to Mars envisions a crew of 6 or 7 people and a mission duration of around 2.5 years. However, this time frame is much less than that expected on expeditions to the outer solar system, where total mission durations of 10 years or more are likely. Although future technological breakthroughs in propulsion systems and space vehicle construction may speed up transit times, for now we must realistically consider the psychological impact of missions lasting for one or more decades.Available information largely deals with on-orbit missions. In research that involved Mir and ISS missions lasting up to 7 months, our group and others have studied the effects of psychological and interpersonal issues on crewmembers and on the crew-ground relationship. We also studied the positive effects of being in space. However, human expeditions to the outer planets and beyond will introduce a number of new psychological and interpersonal stressors that have not been experienced before. There will be unprecedented levels of isolation and monotony, real-time communication with the Earth will not be possible, the crew will have to work autonomously, there will be great dependence on computers and other technical resources located on board, and the Earth will become an insignificant dot in space or will even disappear from view entirely.Strategies for dealing with psychological issues involving missions to the outer solar system and beyond will be considered and discussed, including those related to new technologies being considered for interstellar missions, such as traveling at a significant fraction of the speed of light, putting crewmembers in suspended animation, or creating giant self-contained generation ships of colonists who will not return to Earth.     

The global positioning system: policy issues for an information technology

This article, based on the executive summary of a RAND Corporation study, analyses the policy issues facing the USA in the use of its Global Positioning System (GPS), in terms of both national security and commercial applications. Foreign policy issues, including how to react to the emergence of non-US (Russian, European and Inmarsat-sponsored) alternatives to the GPS are also examined. The article concludes with a series of recommendations for policy makers. Reprinted by permission.     

固体姿轨控发动机燃气电磁阀快速驱动电路研究

提出了一种高压RC延时控制的高低压驱动电路,用于姿轨控发动机燃气阀控制。在闭合的启动阶段对线圈施加高电压提供大电流,加速电磁阀闭合;闭合的保持阶段施加低电压维持较小电流,保证线圈安全,降低功耗;开启阶段加速线圈电流泄放,提高开启速度,满足了发动机快速关断和开启的要求;信号电路和功率电路相互隔离;RC电路作为高电压延时器件,只需1路控制信号,电路得以简化。     

Design, performance, and experiment capabilities of the AGHF: ESA''s advanced gradient furnace for spacelab

AGHF is a Bridgman Furnace Facility for directional solidification experiments in microgravity environment with very well controlled heater temperatures up to 1400°C. A laboratory model and an engineering model exist, the flight model will be built at the end of 1991. The furnace uses heater elements made of W-Re wire wound on a solid TZM heat diffuser, diffuser temperature control by Pt/PtRh thermocouples to ±0.2 K, and a water cooled cooling zone regulated by a thermostatic valve to ±0.3 K. AGHF experiments use front loaded cartridges, which can use conductive coupling to the cooling zone by a liquid metal ring or radiative cooling. The laboratory model furnace, mounted in a dedicated vacuum chamber with peripherals controlled by a commercial computer, was intensively tested up to 1400°C, as specified for the AGHF by ESA, and at 1500°C in a life test under a technology development programme of ESA. Notable laboratory model results are gradients of 95 K/cm in solid Ni of 18 mm dia, with conductive cooling zone coupling by liquid metal, and 70 K/cm with radiative cooling in ZrO₂. EM test are not yet complete, but first tests indicate similar or better results, especially of gradient constancy vs pulling stroke over 140 mm. The first heater model sustained 400 h at 1000°C, 800 h at 1300°C, and 400 h at 1500°C.     

固体火箭冲压发动机补燃室掺混与燃烧流场数值模拟

用雷诺平均N-S方程和k-ε双方程湍流模型,对壅塞式固体火箭冲压发动机补燃室内的掺混与燃烧流场进行了数值模拟。考虑了进气道尺寸、进气夹角、头部距离、一次喷嘴扩张比和喷嘴数目等结构因素对补燃室掺混与燃烧性能的影响。模拟结果表明,进气道尺寸和进气夹角对掺混与补燃性能的影响与非壅塞式相同;增加一次喷嘴的数目和加大喷嘴的扩张比增加了燃气的分散性,提高了补燃效率。该研究从理论上找到了提高补燃效率的途径。     

Hydrogen in rocks: an energy source for deep microbial communities

To survive in deep subsurface environments, lithotrophic microbial communities require a sustainable energy source such as hydrogen. Though H2 can be produced when water reacts with fresh mineral surfaces and oxidizes ferrous iron, this reaction is unreliable since it depends upon the exposure of fresh rock surfaces via the episodic opening of cracks and fissures. A more reliable and potentially more voluminous H2 source exists in nominally anhydrous minerals of igneous and metamorphic rocks. Our experimental results indicate that H2 molecules can be derived from small amounts of H2O dissolved in minerals in the form of hydroxyl, OH- or O3Si-OH, whenever such minerals crystallized in an H2O-laden environment. Two types of experiments were conducted. Single crystal fracture experiments indicated that hydroxyl pairs undergo an in situ redox conversion to H2 molecules plus peroxy links, O3Si/OO\SiO3. While the peroxy links become part of the mineral structure, the H2 molecules diffused out of the freshly fractured mineral surfaces. If such a mechanism occurred in natural settings, the entire rock column would become a volume source of H2. Crushing experiments to facilitate the outdiffusion of H2 were conducted with common crustal igneous rocks such as granite, andesite, and labradorite. At least 70 nmol of H2/g diffused out of coarsely crushed andesite, equivalent at standard pressure and temperature to 5,000 cm3 of H2/m3 of rock. In the water-saturated, biologically relevant upper portion of the rock column, the diffusion of H2 out of the minerals will be buffered by H2 saturation of the intergranular water film.     

Mutagenesis in bacterial spores exposed to space and simulated martian conditions: data from the EXPOSE-E spaceflight experiment PROTECT

As part of the PROTECT experiment of the EXPOSE-E mission on board the International Space Station (ISS), the mutagenic efficiency of space was studied in spores of Bacillus subtilis 168. After 1.5 years' exposure to selected parameters of outer space or simulated martian conditions, the rates of induced mutations to rifampicin resistance (Rif(R)) and sporulation deficiency (Spo(-)) were quantified. In all flight samples, both mutations, Rif(R) and Spo(-), were induced and their rates increased by several orders of magnitude. Extraterrestrial solar UV radiation (>110?nm) as well as simulated martian UV radiation (>200?nm) led to the most pronounced increase (up to nearly 4 orders of magnitude); however, mutations were also induced in flight samples shielded from insolation, which were exposed to the same conditions except solar irradiation. Nucleotide sequencing located the Rif(R) mutations in the rpoB gene encoding the β-subunit of RNA polymerase. Mutations isolated from flight and parallel mission ground reference (MGR) samples were exclusively localized to Cluster I. The 21 Rif(R) mutations isolated from the flight experiment showed all a C to T transition and were all localized to one hotspot: H482Y. In mutants isolated from the MGR, the spectrum was wider with predicted amino acid changes at residues Q469K/L/R, H482D/P/R/Y, and S487L. The data show the unique mutagenic power of space and martian surface conditions as a consequence of DNA injuries induced by solar UV radiation and space vacuum or the low pressure of Mars.     

Rate measurements of the hydrolysis of complex organic macromolecules in cold aqueous solutions: implications for prebiotic chemistry on the early Earth and Titan

Organic macromolecules ("complex tholins") were synthesized from a 0.95 N(2)/0.05 CH(4) atmosphere in a high-voltage AC flow discharge reactor. When placed in liquid water, specific water soluble compounds in the macromolecules demonstrated Arrhenius type first order kinetics between 273 and 313 K and produced oxygenated organic species with activation energies in the range of approximately 60+/-10 kJ mol(-1). These reactions displayed half lives between 0.3 and 17 days at 273 K. Oxygen incorporation into such materials--a necessary step toward the formation of biological molecules--is therefore fast compared to processes that occur on geologic timescales, which include the freezing of impact melt pools and possible cryovolcanic sites on Saturn's organic-rich moon Titan.     

The study of Marangoni convection and the solid/liquid interface shape on a germanium float zone in microgravity

The study of the instability of the float zone in microgravity is necessary in order to produce pure and homogeneous crystals. Three types of instabilities may be present in a float zone. The first two, the static and dynamic instabilities, have been investigated by many authors. The third, onset of Marangoni convection is investigated in this study. The Navier-Stokes equations and the energy equation, in cylindrical coordinates, were solved using the finite element method. These pure and homogeneous germanium crystals will find application as integral components of sensitive γ radiation measuring equipment.