The Contributions of Comets to Planets, Atmospheres, and Life: Insights from Cassini-Huygens, Galileo, Giotto, and Inner Planet Missions

Comets belong to a group of small bodies generally known as icy planetesimals. Today the most primitive icy planetesimals are the Kuiper Belt objects (KBOs) occupying a roughly planar domain beyond Neptune. KBOs may be scattered inward, allowing them to collide with planets. Others may move outward, some all the way into the Oort cloud. This is a spherical distribution of comet nuclei at a mean distance of ～50,000 AU. These nuclei are occasionally perturbed into orbits that intersect the paths of the planets, again allowing collisions. The composition of the atmosphere of Jupiter—and thus possibly all outer planets—shows the effects of massive early contributions from extremely primitive icy bodies that must have been close relatives of the KBOs. Titan may itself have a composition similar to that of Oort cloud comets. The origin and early evolution of its atmosphere invites comparison with that of the early Earth. Impacts of comets must have brought water and other volatile compounds to the Earth and the other inner planets, contributing to the reservoir of key ingredients for the origin of life. The magnitude of these contributions remains unknown but should be accessible to measurements by instruments on spacecraft.     

Element Abundances and Isotope Ratios in the Giant Planets and Titan

This paper reviews our present knowledge about elemental and isotopic ratios in the Giant Planets and Titan. These parameters can provide key information about the formation and evolution of these objects. Element abundances, especially after the results of the Galileo Probe Mass Spectrometer in Jupiter, strongly support the formation model invoking an initial core formation (Mizuno, 1980; Pollack et al., 1996). They also suggest that solar composition icy planetesimals (SCIPs) brought the heavy elements to Jupiter. The Jupiter value of D/H appears to be representative of the protosolar value, while the D/H enrichment observed on Uranus and Neptune is consistent with the formation scenario of these planets. The ¹⁵N/¹⁴N measurement in Jupiter seems to be representative of its protosolar value. Future measurements are expected to come from the Cassini and Herschel space mission, as well as the ALMA submillimeter observatory. This revised version was published online in August 2006 with corrections to the Cover Date.     

Water and the Interior Structure of Terrestrial Planets and Icy Bodies

Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived ²⁶Al decay may govern the amount of hydrous silicates and leftover rock–ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors.     

Dust Evolution in Protoplanetary Discs and the Formation of Planetesimals

After 25 years of laboratory research on protoplanetary dust agglomeration, a consistent picture of the various processes that involve colliding dust aggregates has emerged. Besides sticking, bouncing and fragmentation, other effects, like, e.g., erosion or mass transfer, have now been extensively studied. Coagulation simulations consistently show that \(\upmu\mbox{m}\)-sized dust grains can grow to mm- to cm-sized aggregates before they encounter the bouncing barrier, whereas sub-\(\upmu\mbox{m}\)-sized water-ice particles can directly grow to planetesimal sizes. For siliceous materials, other processes have to be responsible for turning the dust aggregates into planetesimals. In this article, these processes are discussed, the physical properties of the emerging dusty or icy planetesimals are presented and compared to empirical evidence from within and without the Solar System. In conclusion, the formation of planetesimals by a gravitational collapse of dust “pebbles” seems the most likely.     

Spectroscopy of Icy Moon Surface Materials

Remote sensing of icy objects in the outer solar system relies upon availability of appropriate laboratory measurements. Surface deposits of specific substances often provide our most direct route to understanding interior composition, thereby informing theories of endogenic surface modification, exogenic surface processing and processes involving exchange of material with the interiors. Visible to near-infrared reflectance spectra of properly prepared compounds are required to enable retrieval of surface abundances through linear and nonlinear mixture analysis applied to spacecraft observations of icy bodies. This chapter describes the techniques, conditions and approaches necessary to provide reference spectra of use to theoretical models of icy satellite surface compositions, and summarizes the current state of knowledge represented in the published literature.     

Formation and Composition of Planetesimals

The composition of planetesimals depends upon the epoch and the location of their formation in the solar nebula. Meteorites produced in the hot inner nebula contain refractory compounds. Volatiles were present in icy planetesimals and cometesimals produced in the cold outer nebula. However, the mechanism responsible for their trapping is still controversial. We argue for a general scenario valid in all regions of the turbulent nebula where water condensed as a crystalline ice (Hersant et al., 2004). Volatiles were trapped in the form of clathrate hydrates in the continuously cooling nebula. The epoch of clathration of a given species depends upon the temperature and the pressure required for the stability of the clathrate hydrate. The efficiency of the mechanism depends upon the local amount of ice available. This scenario is the only one so far which proposes a quantitative interpretation of the non detection of N₂ in several comets of the Oort cloud (Iro et al., 2003). It may explain the large variation of the CO abundance observed in comets and predicts an Ar/O ratio much less than the upper limit of 0.1 times the solar ratio estimated on C/2001 A2 (Weaver et al., 2002). Under the assumption that the amount of water ice present at 5 AU was higher than the value corresponding to the solar O/H ratio by a factor 2.2 at least, the clathration scenario reproduces the quasi uniform enrichment with respect to solar of the Ar, Kr, Xe, C, N and S elements measured in Jupiter by the Galileo probe. The interpretation of the non-uniform enrichment in C, N and S in Saturn requires that ice was less abundant at 10 AU than at 5 AU so that CO and N₂ were not clathrated in the feeding zone of the planet while CH₄, NH₃ and H₂S were. As a result, the 14N/15N ratio in Saturn should be intermediate between that in Jupiter and the terrestrial ratio. Ar and Kr should be solar while Xe should be enriched by a factor 17. The enrichments in C, N and S in Uranus and Neptune suggest that available ice was able to form clathrates of CH₄, CO and the NH₃ hydrate, but not the clathrate of N₂. The enrichment of oxygen by a factor 440 in Neptune inferred by Lodders and Fegley (1994) from the detection of CO in the troposphere of the planet is higher by at least a factor 2.5 than the lower limit of O/H required for the clathration of CO and CH4 and for the hydration of NH₃. If CO detected by Encrenaz et al. (2004) in Uranus originates from the interior of the planet, the O/H ratio in the envelope must be around of order of 260 times the solar ratio, then also consistent with the trapping of detected volatiles by clathration. It is predicted that Ar and Kr are solar in the two planets while Xe would be enriched by a factor 30 to 70. Observational tests of the validity of the clathration scenario are proposed.     

Planetary Accumulation with a Continuous Supply of Planetesimals

Previous calculations of the accumulation of small (∼10 km) planetesimals at ∼1 AU to form Mars-sized bodies assumed that the initial assemblage of planetesimals were all present at the outset. This is an obviously reasonable assumption in systems in which the time scale for growth time of ∼10²⁶ g planetary bodies is long compared to estimates of the evolutionary time scale of a protosolar disk, as was the case in the pioneering work of Safronov (1969). It is now found that as a result of the preplanetary assemblage being unstable with respect to the runaway growth of the largest bodies, this is unlikely to be the case. The more realistic alternative of adding the initial planetesimals on a ∼10⁵ year time scale is considered here, as well as the consequences of the initial planetesimals being considerably smaller than those assumed previously. It is found that although the time scale for runaway growth is now actually controlled by the availability of planetesimals, for planetesimal production time scales of ∼10⁵ yrs, the final consequences are very similar. These calculations do show, however, that as a consequence of continuous infall during the runaway growth process, the late initial planetesimals are likely to be catastrophically disrupted by mutual collisions. For this reason, a more detailed treatment of the growth of planetesimals into planetary embryos will require a better understanding of the difficult problem of formation of the initial planetesimals themselves. This revised version was published online in June 2006 with corrections to the Cover Date.     

Skylab measurements of low energy cosmic rays

In this review the present state of our knowledge on the properties of heavy ions in low energy cosmic rays measured in the Skylab mission and in other spacecrafts is summarised and the possible mechanisms of their origin are discussed. A brief review of the general features of the galactic and solar cosmic rays is given in order to understand the special features of the low energy heavy ions of cosmic rays. The results of the cosmic ray experiment in the Skylab show that in the low energy interval of 8–30 MeV/N, the abundances of oxygen, nitrogen, and neon ions, relative to carbon are enhanced by a factor of 5 to 2 as compared to high energy cosmic rays; while Mg, Si, S, and A are depleted. In 50–150 MeV/N energy interval the abundance of nuclei of Ca-Cr relative to iron-group (Z = 25–28) is found to be highly enhanced, as compared to high energy cosmic rays. Furthermore the observations of the energy spectra of O, N, and Ne ions and their fairly large fluences in the energy interval of 8–30 MeV/N below the geomagnetic cut off energy of 50 MeV/N for fully stripped nuclei at the Skylab orbit indicate that these heavy ions are probably in partly ionised states. Thus, it is found that the Skylab results represent a new type of heavy ion population of low energy cosmic rays below 50 MeV/N, in the near Earth space and their properties are distinctly different from those of high energy cosmic rays and are similar to those of the anomalous component in the interplanetary space. The available data from the Skylab can be understood at present on the hypothesis that low energy interplanetary cosmic ray ions of oxygen etc. occur in partly ionised state such as O⁺¹,O⁺², etc. and these reach the inner magnetosphere at high latitudes where stripping process occurs near mirror points and this leads to temporarily trapped ions such as O⁺³, O⁺⁴, etc. It is noted that the origin of these low energy heavy cosmic ray ions in the magnetosphere and in interplanetary space is not yet fully understood and new type of sources or processes are responsible for their origin and these need further studies.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Stable Isotope Ratios as a Biomarker on Mars

As both Earth and Mars have had similar environmental conditions at least for some extended time early in their history (Jakosky and Phillips in Nature 412:237–244, 2001), the intriguing question arises whether life originated and evolved on Mars as it did on Earth (McKay and Stoker in Rev. Geophys. 27:189–214, 1989). Conceivably, early autotrophic life on Mars, like early life on Earth, used irreversible enzymatically enhanced metabolic processes that would have fractionated stable isotopes of the elements C, N, S, and Fe. Several important assumptions are made when such isotope fractionations are used as a biomarker. The purpose of this article is two-fold: (1) to discuss these assumptions for the case of carbon and to summarize new insights in abiologic reactions, and (2) to discuss the use of other stable isotope systems as a potential biomarker. It is concluded that isotopic biomarker studies on Mars will encounter several important obstacles. In the case of carbon isotopes, the most important obstacle is the absence of a contemporary abiologic carbon reservoir (such as carbonate deposits on Earth) to act as isotopic standard. The presence of a contemporary abiologic sulfate reservoir (evaporite deposits) suggests that sulfur isotopes can be used as a potential biomarker for sulfate-reducing bacteria. The best approach for tracing ancient life on Mars will be to combine several biomarker approaches; to search for complexity, and to combine small-scale isotopic variations with chemical, mineralogical, and morphological observations. An example of such a study can be a layer-specific correlation between δ ¹³C and δ ³⁴S within an ancient Martian evaporite, which morphologically resembles the typical setting of a shallow marine microbial mat.     

Biogenerated Rock Structures

Earth as a planet under firm control of life processes since more than 3 Ga has evolved global biogeochemical cycles, biogeomorphogenetic processes and structures also called plates or global tectonics including global climate and movement of water masses. These processes have deep impact on the shape and thickness of continental land masses as well as the chemistry and mineralogy of the crust and upper mantle. Biogenerated rock structures in this sense can be visualised through the analysis of sedimentary rock structures exhibiting e.g., biogenerated stromatolites, onkolites, oolites or cementing structures of sandstones which clearly preserve biochemical processes and biophysical structures. Further the chemical composition including the segregation of mineral layers, ore deposits, sedimentary and metamorphic rocks and granites hint to sun powered energy storage (gas, gas hydrates, hydrocarbons, coal) and tectonic processes initiated or at least modified through the enormous input of external energy through reduced carbon and iron compounds. One can state with considerable reliability that a planet under control of life must exhibit rock chemistry, mineralogy and structures typical for the impact of life on the geodynamic cycles. This includes the idea of top-down geotectonics instead of bottom-up processes.     

Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Feedstocks of the Terrestrial Planets

The processes of planet formation in our Solar System resulted in a final product of a small number of discreet planets and planetesimals characterized by clear compositional distinctions. A key advance on this subject was provided when nucleosynthetic isotopic variability was discovered between different meteorite groups and the terrestrial planets. This information has now been coupled with theoretical models of planetesimal growth and giant planet migration to better understand the nature of the materials accumulated into the terrestrial planets. First order conclusions include that carbonaceous chondrites appear to contribute a much smaller mass fraction to the terrestrial planets than previously suspected, that gas-driven giant planet migration could have pushed volatile-rich material into the inner Solar System, and that planetesimal formation was occurring on a sufficiently rapid time scale that global melting of asteroid-sized objects was instigated by radioactive decay of ²⁶Al. The isotopic evidence highlights the important role of enstatite chondrites, or something with their mix of nucleosynthetic components, as feedstock for the terrestrial planets. A common degree of depletion of moderately volatile elements in the terrestrial planets points to a mechanism that can effectively separate volatile and refractory elements over a spatial scale the size of the whole inner Solar System. The large variability in iron to silicon ratios between both different meteorite groups and between the terrestrial planets suggests that mechanisms that can segregate iron metal from silicate should be given greater importance in future investigations. Such processes likely include both density separation of small grains in the nebula, but also preferential impact erosion of either the mantle or core from differentiated planets/planetesimals. The latter highlights the important role for giant impacts and collisional erosion during the late stages of planet formation.     

Neutral Atmospheres of the Giant Planets: An Overview of Composition Measurements

Measurements of the chemical composition of the giant planets provide clues of their formation and evolution processes. According to the currently accepted nucleation model, giant planets formed from the initial accretion of an icy core and the capture of the protosolar gas, mosly composed of hydrogen and helium. In the case of Jupiter and Saturn (the gaseous giants), this gaseous component dominates the composition of the planet, while for Uranus and Neptune (the icy giants) it is only a small fraction of the total mass. The measurement of elemental and isotopic ratios in the giant planets provides key diagnostics of this model, as it implies an enrichment in heavy elements (as well as deuterium) with respect to the cosmic composition. Neutral atmospheric constituents in the giant planets have three possible sources: (1) internal (fromthe bulk composition of the planet), (2) photochemical (fromthe photolysis ofmethane) and(3) external (from meteoritic impacts, of local or interplanetary origin). This paper reviews our present knowledge about the atmospheric composition in the giant planets, and their elemental and istopic composition. Measurements concerning key parameters, like C/H, D/H or rare gases in Jupiter, are analysed in detail. The conclusion addresses open questions and observations to be performed in the future.     

Rheological and Thermal Properties of Icy Materials

Laboratory measurements of physical properties of planetary ices generate information for dynamical models of tectonically active icy bodies in the outer solar system. We review the methods for measuring both flow properties and thermal properties of icy planetary materials in the laboratory, and describe physical theories that are essential for intelligent extrapolation of data from laboratory to planetary conditions. This review is structured with a separate and independent section for each of the two sets of physical properties, rheological and thermal. The rheological behaviors of planetary ices are as diverse as the icy moons themselves. High-pressure water ice phases show respective viscosities that vary over four orders of magnitude. Ices of CO₂, NH₃, as well as clathrate hydrates of CH₄ and other gases vary in viscosity by nearly ten orders of magnitude. Heat capacity and thermal conductivity of detected/inferred compositions in outer solar system bodies have been revised. Some low-temperature phases of minerals and condensates have a deviant thermal behavior related to paramount water ice. Hydrated salts have low values of thermal conductivity and an inverse dependence of conductivity on temperature, similar to clathrate hydrates or glassy solids. This striking behavior may suit the dynamics of icy satellites.     

Subsurface Water Oceans on Icy Satellites: Chemical Composition and Exchange Processes

The state of knowledge about the structure and composition of icy satellite interiors has been significantly extended by combining direct measurements from spacecraft, laboratory experiments, and theoretical modeling. The existence of potentially habitable liquid water reservoirs on icy satellites is dependent on the radiogenic heating of the rock component, additional contributions such as the dissipation of tidal energy, the efficiency of heat transfer to the surface, and the presence of substances that deplete the freezing point of liquid water. This review summarizes the chemical evolution of subsurface liquid water oceans, taking into account a number of chemical processes occuring in aqueous environments and partly related to material exchange with the deep interior. Of interest are processes occuring at the transitions from the liquid water layer to the ice layers above and below, involving the possible formation of clathrate hydrates and high-pressure ices on large icy satellites. In contrast, water-rock exchange is important for the chemical evolution of the liquid water layer if the latter is in contact with ocean floor rock on small satellites. The composition of oceanic floor deposits depends on ambient physical conditions and ocean chemistry, and their evolutions through time. In turn, physical properties of the ocean floor affect the circulation of oceanic water and related thermal effects due to tidally-induced porous flow and aqueous alteration of ocean floor rock.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Phase Behaviour of Ices and Hydrates

The primary volatile ‘rock-forming’ minerals in the icy satellites of the outer solar system include water-ice and various hydrated crystals of methane and ammonia. The rich polymorphism of these substances as a function of pressure and temperature are described in this chapter. This polymorphism has a fundamental influence on the exchange of mass and energy between the core and the surface of icy satellites. We describe the current state-of-the-art in our understanding of the high pressure phase behaviour and the measurements of thermoelastic and transport properties of these substances. In addition we describe the structures and properties of hydrated phases of methanol, sulfuric acid, and various sulfate salts.     

Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Recent Advancements and Motivations of Simulated Pluto Experiments

This review of Pluto laboratory research presents some of the recent advancements and motivations in our understanding enabled by experimental simulations, the need for experiments to facilitate models, and predictions for future laboratory work. The spacecraft New Horizons at Pluto has given a large amount of scientific data already rising to preliminary results, spanning from the geology to the atmosphere. Different ice mixtures have now been detected, with the main components being nitrogen, methane, and carbon monoxide. Varying geology and atmospheric hazes, however, gives us several questions that need to be addressed to further our understanding. Our review summarizes the complexity of Pluto, the motivations and importance of laboratory simulations critical to understanding the low temperature and pressure environments of icy bodies such as Pluto, and the variability of instrumentation, challenges for research, and how simulations and modeling are complimentary.