Silicate core-organic refractory mantle particles as interstellar dust and as aggregated in comets and stellar disks.

The principal observational properties of silicate core-organic refractory mantle interstellar dust grains in the infrared at 3.4 microns and at 10 microns and 20 microns are discussed in terms of the cyclic evolution of particles forming in stellar atmospheres and undergoing subsequent accretion, photoprocessing and destruction (erosion). Laboratory plus space emulation of the photoprocessing of laboratory analog ices and refractories are discussed. The aggregated interstellar dust model of comets is summarized. The same properties required to explain the temperature and infrared properties of comet coma dust are shown to be needed to account for the infrared silicate and continuum emission of the beta Pictoris disk as produced by a cloud of comets orbiting the star.     

Very low temperature formaldehyde reactions and the build-up of organic molecules in comets and interstellar ices.

We have investigated thermally promoted reactions of formaldehyde (H2CO) in very low temperature ices. No such reactions occurred in ices of pure formaldehyde. However, addition of trace amounts of ammonia (NH3) were sufficient to catalyze reactions at temperatures as low as 40 K. Similar reactions could take place in interstellar ices and in Comets and produce considerable amounts of organic molecules.     

Measurements of X-ray scattering from interstellar dust

We have examined the surface brightness profiles of four of the brightest compact galactic X-ray sources observed with the Imaging Proportional Counter (IPC) aboard the Einstein Observatory for the existence of halos produced by the scattering of X-rays from interstellar dust. The sources are CYG X-3, 4U1658-48, GX13+1, and 4U1254-69. The halos are apparent when a comparison is made between each source's measured surface brightness profile and a model profile based upon a point response function (PRF) for each source. These model profiles depend upon knowledge of the source's spectrum, which is derived from the IPC itself and corroborated by the Einstein Monitor Proportional Counter and/or previous measurements.As conclusions rest entirely on a knowledge of the system (IPC and Mirror) PRF, we began this study with a comprehensive examination of the calibration data taken for the Observatory prior to launch. Point-source images for both the IPC and the HRI have been analyzed at various energies in order to gain a quantitative understanding of scattering by the mirror surface elements and the IPC's spatial resolution.All four sources show a significant excess above the response from a point-source. The attribution of the excess to X-rays scattered from interstellar dust is strengthened by the positive correlation of the magnitude of this excess with the observed column density of material along the line of sight. Furthermore, we have examined the surface brightness profiles of LMC X-1 and 3C273 and found them to have a greatly reduced excess above their model profiles. Because of their high galactic latitude and because only dust within our own galaxy will lead to the formation of a halo that extends beyond a few arcminutes, only a small effect is expected for these sources.     

A comparison of the dust properties in recent periodic comets

Measurements of the thermal emission from the cometary dust coma can be used to derive the rate of dust production from the nucleus as well as the size distribution of absorbing grains. More than ten short-period comets have now been observed in the infrared over a wide range in heliocentric distance. Dust production rates are derived for these comets based on theoretical models of the thermal emission from small absorbing grains and calculations of dust grain velocities. The mean size and albedo of the dust grains is similar in these comets, with the exception of Comet Crommelin, which seems to have had larger, darker grains.     

Extraterrestrial organic chemistry: from the interstellar medium to the origins of life. Part 2: complex organic chemistry in the environment of planets and satellites.

During COSPAR'00 in Warsaw, Poland, in the frame of Sub-Commission F.3 events (Planetary Biology and Origins of Life), part of COSPAR Commission F (Life Sciences as Related to Space), and Commission B events (Space Studies of the Earth-Moon System, Planets, and Small Bodies of the Solar System) a large joint symposium (F.3.4/B0.8) was held on extraterrestrial organic chemistry. Part 2 of this symposium was devoted to complex organic chemistry in the environment of planets and satellites. The aim of this event was to cover and review new data which have been recently obtained and to give new insights on data which are expected in the near future to increase our knowledge of the complex organic chemistry occurring in several planets and satellites of the Solar System, outside the earth, and their implications for exobiology and life in the universe. The event was composed of two main parts. The first part was mainly devoted to the inner planets and Europa and the search for signatures of life or organics in those environments. The second part was related to the study of the outer solar system.     

From the interstellar clouds, through the inner to the outer solar system: a universally distributed complex organic chemistry. Preface.

High molecular weight organic compounds are involved in the chemistry and physics of many astrophysical and planetary objects. They are or should be present in interstellar dust, in comets and meteorites, in the Giant planets and Titan, in asteroids Triton and icy satellites. They represent a class of very complex organic material, part of which may have played a role in the origin of life on Earth. Thus they directly concern prebiotic chemistry and exobiology.     

Similarity of the infrared spectrum of an Orgueil organic polymer with interstellar organic compounds in the line of sight towards IRS 7.

We present a comparison between the IR spectrum of the galactic center source IRS 7 and the spectrum of a carbonaceous polymer from the Orgueil meteorite. We have obtained an almost perfect match between the two spectra in the region between 3020-2790 cm-1, which suggests that the chemical composition of the interstellar organic matter and that of the meteorite polymer are similar or that the meteoritic polymer could be a well preserved interstellar organic molecule. Assuming that the meteoritic polymer has the same C/H ratio as these interstellar molecules, we find that 45 % of the total abundance of carbon in the line of sight toward IRS 7 is trapped in such an interstellar organic grain material.     

Heliospheric asymmetries due to the action of the interstellar magnetic field

We discuss the asymmetry of the heliospheric discontinuities obtained from the analysis of 3D modeling of the solar wind (SW) interaction with local interstellar medium (LISM). The flow of charged particles is governed by the ideal MHD equations and the flow of neutral particles is described by the Boltzmann equation. The emphasis is made on the asymmetries of the termination shock (TS) and the heliopause under the combined action of the interstellar and interplanetary magnetic fields (ISMF and IMF) in the presence of neutral hydrogen atoms whose transport through the heliosphere is modeled kinetically, using a Monte Carlo approach. We show that the deflection of neutral hydrogen flow from its original direction in the unperturbed LISM is highly anisotropic and evaluate a possible angle between the hydrogen deflection plane measured in the SOHO SWAN experiment and the plane containing the ISMF and LISM velocity vectors for different ISMF strengths. It is shown that the ISMF of a strength greater than 4 μG can account for the 10 AU difference in the TS heliocentric difference observed during its crossing by the Voyager 1 and Voyager 2 spacecraft, which however results in a larger discrepancy between the calculated and observed velocity distributions. The effect of a strong ISMF on the distribution of plasma quantities in the inner heliosheath and on 2–3 kHz radio emission is discussed.     

Polycyclic aromatic hydrocarbon ions and the diffuse interstellar bands.

Neutral naphthalene (C10H8), phenanthrene (C14H10), and pyrene (C16H10) absorb strongly in the ultraviolet and may contribute to the extinction curve. High abundances are required to produce detectable structures. The cations of these PAHs absorb in the visible. C10H8+ has 12 discrete absorption bands which fall between 6800 and 5000 angstroms. The strongest band at 6741 angstroms falls close to the weak 6742 angstroms diffuse interstellar band (DIB). Five other weaker bands also match DIBs. The possibility that C10H8+ is responsible for some of the DIBs can be tested by searching for new DIBs at 6520, 6151, and 5965 angstroms, other moderately strong naphthalene cation band positions. If C10H8+ is indeed responsible for the 6742 angstroms feature, it accounts for 0.3% of the cosmic carbon. The spectrum of C16H10+ is dominated by a strong band at 4435 angstroms in an Ar matrix and 4395 angstroms in a Ne matrix, a position which falls very close to the strongest DIB, that at 4430 angstroms. If C16H10+, or a closely related pyrene-like ion is indeed responsible for the 4430 angstroms feature, it accounts for 0.2% of the cosmic carbon. We also report an intense, very broad UV-to-visible continuum which is associated with both ions and could explain how PAHs convert interstellar UV and visible radiation into IR.     

Organic molecules in the gas phase of dense interstellar clouds.

Since a previous COSPAR review on this subject, the number of molecular species identified by astronomers in dense interstellar clouds or in the envelopes expelled by evolved stars has grown from about eighty to approximately one hundred. Recent detections in stellar envelopes include the radical CP, the second phosphorus-containing astronomical molecule; SiN, the first astronomical molecule with a Si-N bond; and the HCCN radical. In the dense interstellar clouds recent detections or verifications of previous possible identifications include the H3O+ ion, which is a critical intermediary in the production of H2O and O2; the CCO radical, which is isoelectronic with HCCN; the SO+ ion, which appears to be diagnostic of shock chemistry; two new isomers of cyanoacetylene, HCCNC and CCCNH; and the two cumulenes H2C3 and H2C4. Some recent work is also described on the mapping of interstellar clouds in multiple molecular transitions in order to separate variations in chemical abundance from gradients in physical parameters.     

Relation of the secular decrease of brightness to the orbital elements of short-period comets

Secular variations in the absolute brightness of short-period comets were derived on the basis of their maximum apparent magnitudes in individual returns. The present paper deals with all the comets of Jupiter family observed by 31 Dec 1987 in three returns at least. P/Encke, investigated in detail by many authors /1–3/, has not been included. The sample contains 405 observed returns of 61 short-period comets. Relations of the secular fading to the orbital period, perihelion distance and also to the numerical eccentricity were found. Two independent methods of determination of aging of short-period comets, i.e. the secular fading and nongravitational parameters, are compared. The distribution of the values of the secular decreases of brightness is not in agreement with the trends in nongravitational effects. More probably, the observed secular decrease is connected with the apparent magnitude of the comet and with the influence of instrumental effects upon it.     

Modelling the neutral gas environment of comets with special application to P/Halley

A technique has been developed which allows relatively accurate modelling of cometary gas production from nothing more than a visible light curve. Application to P/Halley suggests the production rate of parent molecules will be about 2.6 × 10²⁹ per second on March 10, 1986, for example. The uncertainties and intrinsic limitations in this approach are outlined. The theory is then extended to predictions of abundance of other gaseous species, and a photometric model of these gases provided. Combined with the dust model of N. Divine, preliminary predictions of the luminance of P/Halley as seen in any direction from inside the coma or outside can be provided for λλ3000–7000.     

First spatio-temporal results from the LDEF interplanetary dust experiment

The LDEF Interplanetary Dust Experiment was unique in providing a time history of impacts of micron-sized particles on six orthogonal faces of the vehicle over a span of nearly a full year. Over 15000 hits were recorded, representing a mix of zodiacal dust, meteor stream grains, orbital debris, perhaps beta-meteoroids, and possibly interstellar matter. Although the total number was higher than predicted, the relative panel activity distribution was near expectations. Detailed deconvolution of the impact record with orbital data is underway, to examine each of these populations. Very preliminary results of the fairly crude “first look” analysis suggest that debris is the major particle component at 500 km. The data show clear evidence of some known meteor streams as sharp, tightly-focused events, unlike their visible counterparts. Some apparent debris events show similar signatures. Data from the leading and trailing edges suggest a detection of beta-meteoroids, but the analysis is not yet conclusive. Absolute fluxes and flux ratios are not yet known, since the detector status analysis is yet incomplete.     

Ground-based observations of the dust emission from comet Halley

A preliminary analysis of the dust emission from comet Halley is presented based on large scale observations of its dust tail. Selected images obtained between February 22 and May 10, 1986 are compared to synchrone-syndyne graphs to infer the history of the dust production and the properties of the dust, at least qualitatively. Quantitative modeling of the dust tall has also been initiated and preliminary results are shown for the cases of isotropic and anisotropic (jet) dust production.     

Heterogeneous solid/gas chemistry of organic compounds related to comets,meteorites, Titan,and Mars: Laboratory and in lower Earth orbit experiments

To understand the evolution of organic molecules involved in extraterrestrial environments and with exobiological implications, many experimental programs in the laboratory are devoted to photochemical studies in the gaseous phase as well as in the solid state. The validity of such studies and their applications to extraterrestrial environments can be questioned as long as experiments conducted in space conditions, with the full solar spectrum, especially in the short wavelength domain, have not been implemented. The experiments that are described here will be carried out on a FOTON capsule, using the BIOPAN facility, and on the International Space Station, using the EXPOSE facility. Vented and sealed exposition cells will be used, which will allow us to study the chemical evolution in the gaseous phase as well as heterogeneous processes, such as the degradation of solid compounds and the release of gaseous fragments.     

Quenched Carbonaceous Composite: a laboratory analog for carbonaceous material in the interstellar medium.

We review the properties of Quenched Carbonaceous Composite (QCC), a residue produced from a hydrocarbon plasma, and the properties of its derivatives. A. Sakata and his colleagues have shown that QCC has a 220 nm absorption band, visible fluorescence matching the extended red emission seen in reflection nebulae, and infrared absorption bands that correspond to the infrared emission features in reflection nebulae, HII regions, and planetary nebulae. These properties make QCC a strong candidate material as a laboratory analog to the carbonaceous material in the interstellar medium. QCC is distinguished from the PAH hypothesis in that (1) it is a condensate composed of aromatic and aliphatic molecules, as well as radicals; (2) it exhibits a 220 nm absorption that is very similar in wavelength to the 217 nm absorption in the interstellar medium; (3) it exhibits visible fluorescence consistent with that seen in reflection nebulae; and (4) the bands at 7.7 and 8.6 microns are caused by ketone bands in oxidized QCC. The aromatic component in QCC is thought to be typically 1-4 rings, with the majority being about 1-2 rings.     

On the evolution of dust in the solar vicinity.

The analysis of interplanetary dust shows that the majority of particles in out-of-ecliptic regions comes from comets and also that near solar dust, in the ecliptic regions, results most probably largely from comets. The intense radiation flux in the solar vicinity is expected to cause strong modifications in the material composition and surface structure of interplanetary dust particles and hence the analysis of near solar dust provides interesting insights into the evolution of meteoritic, especially cometary materials. Because of the lack of in-situ measurements our present knowledge concerning these processes derives from remote sensing, i.e. observations of the solar F-corona. In particular these are observations of albedo, polarization and colour temperature given in terms of average particle properties. For example the analysis of near infra-red F-corona data points to the existence of a strong component of irregularly structured silicate particles, most probably of cometary origin. The data may indicate a subsequent sublimation of different particles or different constituents of the particles. Here we compare particle properties derived from F-corona observations with model calculations of single particle properties and discuss perspectives of future analysis of cometary dust in the interplanetary cloud.