The seeding of life by comets.

The evidence that living organisms were already extant on the earth almost 4 Gyr ago and that early bombardment by comets and asteroids created a hostile environment up to about this time has revived the question of how it was possible for prebiotic chemical evolution to have provided the necessary ingredients for life to have developed in the short intervening time. The actual bracketed available temporal space is no more than 0.5 Gyr and probably much less. Was this sufficient time for an earth-based source of the first simple organic precursor molecules to have led to the level of the prokaryotic cell? If not, then the difficulty would be resolved if the ancient earth was impregnated by organic molecular seed from outer space. Curiously, it seems that the most likely source of such seeds was the same a one of the sources of the hostile enviroment, namely the comets which bombarded the earth. With the knowledge of comets gained by the space missions it has become clear that a very large fraction of the chemical composition of comet nuclei consists of quite complex organic molecules. Furthermore it has been demonstrated that comets consist of very fluffy aggregates of interstellar dust whose chemistry derives from photoprocessing of simple ice mixtures in space. Thus, the ultimate source of organics in comets comes from the chemical evolution of interstellar dust. An important and critical justification for assuming that interstellar dust is the ultimate source of prebiotic molecular insertion on the earth is the proof that comets are extremely fluffy aggregates, which have the possibility of breaking up into finely divided fragments when the comet impacts the earth's atmosphere. In the following we will summarize the properties of interstellar dust and the chemical and morphological structure of comets indicated by the most recent interpretations of comet observations. It will be shown that the suitable condition for comets having provided abundant prebiotic molecules as well as the water in which they could have further evolved are consistent with theories of the early earth environment.     

Origin of organic matter in the protosolar nebula and in comets.

Comet organics are traced to their origin in interstellar space. Possible sources of comet organics from solar nebula chemistry are briefly discussed. The infrared spectra of interstellar dust are compared with spectra of solar (space) irradiated laboratory organic residues and with meteorites. The spectra compare very favorably. The atomic composition of first generation laboratory organic residues compares favorably with that of comet Halley organics if divided into appropriate "volatile" (less refractory) and "refractory" (more refractory) complex organics.     

Chemical evolution in space--a source of prebiotic molecules.

In Laboratory Astrophysics at Leiden University a laboratory analog for following the chemical evolution of interstellar dust in space shows that the dust contains the bulk of organic material in the universe. We follow the photoprocessing of low temperature (10 K) mixtures of ices subjected to vacuum ultraviolet radiation in simulation of interstellar conditions. The most important, but necessary, difference is in the time scales for photo-processing. One hour in the laboratory is equivalent to one thousand years in low density regions of space and as much as, or greater than, ten thousand to one million years in the depths of dense molecular clouds. The ultimate product of photoprocessing of grain material in the laboratory is a complex nonvolatile residue which is yellow in color and soluble in water and methanol. The molecular weight is greater than the mid-hundreds. The infrared absorption spectra indicate the presence of carboxylic acid and amino groups resembling those of other molecules of presumably prebiological significance produced by more classical methods. One of our residues, when subjected to high resolution mass spectroscopy gave a mass of 82 corresponding to C4H6H2 after release of CO2 and trace ammounts of urea suggesting amino pyroline rings. The deposit of prebiotic dust molecules occurred as many as 5 times in the first 500-700 million years on a primitive Earth by accretion during the passage of the solar system through a dense interstellar cloud. The deposition rate during each passage is estimated to be between 10(9) and 10(10) g per year during the million or so years of each passage; i.e., a total deposition of 1O(9)-10(10) metric tons of complex organic material per passage.     

Interstellar hydrogen bonding

This paper reports the first extensive study of the existence and effects of interstellar hydrogen bonding. The reactions that occur on the surface of the interstellar dust grains are the dominant processes by which interstellar molecules are formed. Water molecules constitute about 70% of the interstellar ice. These water molecules serve as the platform for hydrogen bonding. High level quantum chemical simulations for the hydrogen bond interaction between 20 interstellar molecules (known and possible) and water are carried out using different ab-intio methods. It is evident that if the formation of these species is mainly governed by the ice phase reactions, there is a direct correlation between the binding energies of these complexes and the gas phase abundances of these interstellar molecules. Interstellar hydrogen bonding may cause lower gas abundance of the complex organic molecules (COMs) at the low temperature. From these results, ketenes whose less stable isomers that are more strongly bonded to the surface of the interstellar dust grains have been observed are proposed as suitable candidates for astronomical observations.     

The effect of aerosols on climate and aerosol climatology on the basis of observations from space

Principal aspects of the effect of aerosols on climate are discussed and the possibilities of obtaining a climatic data set of global aerosols are analyzed. Based on the analysis of space images, new data have been obtained on gigantic dust outbreaks in various regions of the Earth. It has been shown that dust outbreaks can propagate over hundreds and sometimes thousands of kilometers. The western Sahara - Atlantic Ocean is the major region of propagation of these outbreaks. The continent-to-continent trajectories of dust clouds have been discovered (from Africa to the coast of America, from Central Asia to the Pacific Ocean). Maps of the sources of strong dust transformations have been studied and drawn. In particular, an anthropogenic dust source has been found out on the northeastern coast of the Aral Sea. A striped mesostructure of dust formations has been analyzed, determined by both the inhomogeneous surface and peculiarities of the eddy dust transport. The techniques have been discussed in detail for retrieving the parameters of aerosol size distribution and the vertical profiles of the coefficients of aerosol extinction in the stratosphere and lower mesosphere from the data on the brightness of the twilight and daytime horizon as well as occultation measurements of solar radiation attenuation by the atmosphere.The difficulty of reliably predicting possible environmental changes arises both from the problems of estimating complex interactions of numerous processes and from a lack of information concerning various environmental parameters. For example, an important factor in present day climatic changes is the increased dust content of the atmosphere due to man's activities. However, a reliable estimate of this influence is found to be impossible due to the absence of definitive data on the global distribution of atmospheric dust and the properties of dust in various parts of the world [4,5,13–15]. The impact of aerosols on climate has been discussed in detail in a number of monographs [12–15].Observations from space have opened up new possibilities for studying atmospheric dust. For this purpose, both the imagery and spectrometry of the Earth's atmosphere from space are used. Rather attractive are the prospects for laser sounding [1].     

载人深空探测任务的空间环境工程关键问题

对载人深空探测过程中将遭受的太阳宇宙射线、银河宇宙射线、微重力、尘与尘暴、深空微生物等环境进行分析。对不同深空环境给航天员带来的威胁进行了探讨。从物理屏蔽防护、辐射风险的监测和预警、辐射防护药物、航天员选拨等角度对采取的措施进行了阐述。从空间辐射对航天员的损伤机理、抗辐射和微重力药物开发、空间辐射屏蔽防护结构与材料、航天服自清洁、抗微生物侵蚀材料的研发等多个角度对需要进一步开展的工作进行了讨论。     

Thermal emission from cometary dust

The thermal emission from the dust coma of a comet can be analyzed to yield the flux and size distribution of the dust grains and the relative abundance of silicate and absorbing grains.     

空间尘埃等离子体中尘粒电荷的相关涨落对尘埃磁声波的影响

本文运用自洽的三流体方程组, 考虑了尘埃的充电过程, 得到均匀磁化尘埃等离子体中垂直于磁场传播的尘埃磁声波的色散关系, 结合空间环境讨论了尘埃电荷的相关涨落对尘埃磁声波的影响.      

彗星环境中尘埃等离子体的电荷涨落和静电波动

本文分析了尘埃等离子体中尘埃颗粒的带电过程，给出了一套自洽的工流体方程组．运用这组方程研究了尘埃电荷的起伏涨落，得到了非磁化均匀尘埃等离子体中静电波动的色散关系．针对彗星空间环境中尘埃等离子体的特点，讨论了尘埃电荷的涨落对各种静电波动的影响．     

月球受光面上月尘静电浮扬特性分析

基于单粒子轨道理论及空间尘埃等离子体充电方程,建立了月球受光面上尘埃微粒的静态荷电模型.基于光电子能量Maxiwellian分布假设,确定了月面垂直空间电场强度和光电子鞘层内带电粒子密度的函数表达式.利用牛顿运动定律和静电场力表达式,构建了月球受光面上尘埃微粒的静电浮扬动力学模型,并进行月尘静态浮扬特性的数值计算.研究结果显示:太阳高度角与颗粒粒径是控制月尘静电浮扬发生及动力学特性的两个基本参量;月尘静电浮扬发生在月球的黎明和黄昏;随着粒径的减少,月尘颗粒的最大浮扬高度不断增加.     

Survivability of biomolecules during extraterrestrial delivery: new results on pyrolysis of amino acids and poly-amino acids.

The hypothesis on exogenous origin of organic matter on the early Earth is strongly supported by the detection of a large variety of organic compounds (including amino acids and nucleobases) in carbonaceous chondrites. Whether such complex species can be successively delivered by other space bodies (comets, asteroids and interplanetary dust particles) is unclear and depends primarily on capability of the biomolecules to survive high temperatures during atmospheric deceleration and impacts to the terrestrial surface. Recent simulation experiments on amino acid and nucleic acid base pyrolysis under oxygen-free atmosphere demonstrated that simple representatives of these (considered thermally unstable) compounds can survive at 1-10% level a rapid heating at 500-600 degrees C. In the present work, we report on new data on the pyrolysis of amino acids and their homopolymers and discuss implications of their thermal behavior for extraterrestrial delivery.     

Cosmic dust physical properties and theICAPS facility on board the ISS

Cometary comae, cometary tails, and the interplanetary dust cloud, are low density dust clouds built of cosmic dust particles. Light scattering observations, from in-situ space probes and remote observatories, are a key to their physical properties. This presentation updates results on cometary and interplanetary dust derived from such observations (with emphasis on polarization), and compares them with results on asteroidal regoliths. The polarization phase curves follow similar trends, with parameters that may vary from one object to another. The wavelength dependence is highly variable, although it is usually linear in the visible domain. It may be suggested (from observations, modeling and laboratory measurements) that these dust particles are irregular, with a size greater than the wavelength, and that cometary dust is highly porous, as compared to asteroidal or interplanetary dust. Sophisticated numerical models and laboratory measurements on dust analogues are indeed required to interpret without any ambiguity the ensemble of results. The opportunity offered by the ICAPS facility (an ESA project selected for the ISS, now in phase B) to deduce the physical properties of cosmic dust particles from their optical properties, as well as their evolution (breaking-off and agglomeration, ices condensation and evaporation), is presented.     

Applications of PVDF dust sensor systems in space

The advantages of ruggedness, no bias requirement, ease of large area sensor construction, high counting rate capability, and space reliability inherent in the Polyvinylidene Fluoride (PVDF) dust sensors which have been under development at the University of Chicago over the last decade have led to PVDF flux/mass/velocity/trajectory systems which have advantages over other systems and are well suited for a variety of dust studies in space. The thermal stability characteristics and flux/mass/velocity/trajectory determining characteristics of PVDF and Vinylidene Fluoride/Trifluoroethylene (PVDF copolymer) dust sensors are described. We summarize the objectives and designs of our earlier VEGA- comet Halley instruments, a PVDF velocity/trajectory dust instrument for launch on the Advanced Research and Global Observation Satellite (ARGOS) in January 1996, and a PVDF high flux dust instrument for launch on the CASSINI spacecraft to Saturn in October 1997.     

悬浮月尘的遮挡模型

探月活动中,月表的尘埃会对太阳翼等光电器件的工作效率造成严重影响.基于附着月尘的遮挡模型,从立体空间的角度分析了悬浮月尘对工作器件的遮挡,提出了悬浮月尘的单粒度遮挡模型,利用月尘的平均粒度可计算在指定立体空间内,定量月尘造成的遮挡量;引入月尘的粒度分布函数,提出了悬浮月尘的多粒度遮挡模型,能够计算已知粒度分布函数的月尘在指定立体空间内造成的遮挡量;通过设计悬浮月尘遮挡的仿真实验,分别利用3种不同粒度大小的月尘进行实验,实验数据与悬浮月尘的单粒度、多粒度遮挡模型的理论计算值都较好吻合,实验结果证实了悬浮月尘遮挡模型的正确性与可靠性.      

月尘/月壤环境效应地面模拟方法研究

月壤/月尘会附着并污染航天器、月球车的表面,如果不及时清除,还会进一步诱发部件过热、机械机构卡死、密封失效、材料磨损等一系列问题.本文综述了关于月尘特性、月尘与航天器系统的互相作用机理、月尘环境模拟方法等方面的研究成果,提出了一种小型月尘环境模拟系统的设计方案.该系统将使关于月尘特性的实验研究成为可能,并可作为登月飞船及月球车材料选择、机械机构可靠性试验、除尘策略试验的平台.      

Cometary constraints on the planet forming environment.

Molecular elemental and isotopic abundances of comets provide sensitive diagnostics for models of the primitive solar nebula. New measurements of the N2, NH and NH2 abundances in comets together with the in situ Giotto mass spectrometer and dust analyzer data provide new constraints for models of the comet forming environment in the solar nebula. An inventory of nitrogen-containing species in comet Halley indicates that NH3 and CN are the dominant N carriers observed in the coma gas. The elemental nitrogen abundance in the gas component of the coma is found to be depleted by a factor approximately 75 relative to the solar photosphere. Combined with the Giotto dust analyzer results for the coma dust component, we find for comet Halley Ngas + dust approximately 1/6 the solar value. The measurement of the CN carbon isotope ratio from the bulk coma gas and dust in comet Halley indicates a significantly lower value, 12C/13C = 65 +/- 9 than the solar system value of 89 +/- 2. Because the dominant CN carrier species in comets remains unidentified, it is not yet possible to attribute the low isotope ratio predominantly to the bulk gas or dust components. The large chemical and isotopic inhomogeneities discovered in the Halley dust particles on 1 mu scales are indicative of preserved circumstellar grains which survived processing in the interstellar clouds, and may be related to the presolar silicon carbide, diamond and graphite grains recently discovered in carbonaceous chondrites. Less than 0.1% of the bulk mass in the primitive meteorites studied consists of these cosmically important grains. A larger mass fraction (approximately 5%) of chemically heterogeneous organic grains is found in the nucleus of comet Halley. The isotopic anomalies discovered in the PUMA 1 Giotto data in comet Halley are probably also attributable to preserved circumstellar grains. Thus the extent of grain processing in the interstellar environment is much less than predicted by interstellar grain models, and a significant fraction of comet nuclei (approximately 5%) may be in the form of preserved circumstellar matter. Comet nuclei probably formed in much more benign environments than primitive meteorites.     

A preliminary look at the dust in comet Halley

Highlights of infrared observations of the dust are discussed and compared with first results from the space probes. An emission feature was detected at 3.4 μm; the 10 and 20 μm silicate features were well-observed; and far-infrared data out to 160 μm were obtained. Organic material seems to be abundant in grains and may explain the 3.4 μm emission. Calculations are presented for one example of organic material. A component of the grains may volatize at temperatures around 300 K.     

天基微小空间碎片探测研究

随着空间碎片数量的不断增多,天基微小空间碎片探测已经成为一个热点．首先介绍了空间碎片在低地球轨道上的分布情况以及它对于航天器的危害,然后介绍了国外微小碎片探测器的基本情况,并在这些探测结果的基础上提出了一个探测器方案．这种探测器的传感器采用了新型的压电材料聚偏二氟乙稀(PVDF),使用了飞行时间法(TOF)准确测定空间碎片的飞行速度,以及快脉冲分析系统分析碎片的质量．     

Ablation and chemistry of meteoric materials in the atmosphere of Titan

We compute the input of meteoric materials expected on Titan, and integrate this dust model with an ablation model and a comprehensive chemical model, investigating the effects on the atmosphere and surface. We find that a water deposition of 10-100 times the expected interplanetary dust flux /7/, or a recent large impact, is required to produce the observed CO₂ abundance /2/. Ionisation due to meteoric activity is not likely to be higher than that due to other sources.     

Formation of amino acid precursors in cometary ice environments by cosmic radiation.

Cometary ices are believed to contain water, carbon monoxide, methane and ammonia, and are possible sites for the formation and preservation of organic compounds relating to the origin of life. Cosmic rays, together with ultraviolet light, are among the most effective energy sources for the formation of organic compounds in space. In order to study the possibility of the formation of amino acids in comets or their precursory bodies (interstellar dust grains), several types of ice mixtures made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. After irradiation, the volatile products were analyzed with a quadrupole mass spectrometer, while temperature of the cryostat was raised to room temperature. The non-volatile products remaining in the cryostat at room temperature were collected with water. They were acid-hydrolyzed, and analyzed by ion-exchange chromatography. When an ice mixture of carbon monoxide (or methane), ammonia and water was irradiated, some hydrocarbons were formed, and amino acids such as glycine and alanine were detected in the hydrolyzate. These results suggest the possible formation of "amino acid precursors" (compounds yielding amino acids after hydrolysis) in interstellar dust grains by cosmic radiation. We previously reported that amino acid precursors were formed when simulated primitive planetary atmospheres were irradiated with cosmic ray particles. It will be of great interest to compare the amount of bioorganic compounds that were formed in the primitive earth and that brought by comets to the earth.