Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.     

From interstellar matter to comets: Elemental abundances in interstellar dust and in comet Halley

Analogies between interstellar and cometary matter can be found in their chemical compositions, both in the gaseous and solid phases, but also in the physical processes involved like evidence for ion-molecules reactions at low temperature and for ice irradiation processes. Such analogies can be observed from 3 types of measurements: interstellar spectra, cometary observations, and analyses of interplanetary dust particles, with the help of laboratory simulation experiments. Taking into account all the present available information, a compilation of the elemental abundances in interstellar matter and in comet Halley is derived, without any assumption about the dust to gas ratio. It is found that there is a significant apparent depletion of nitrogen, presently unexplained, in both interstellar and cometary materials.     

An ISO View on Interstellar and Cometary Ice Chemistry

The ISO-SWS instrument offering a large wavelength coverage and a resolution well adapted to the solid phase has changed our knowledge of the physical-chemical properties of ices in space. The discovery of many new ice features was reported and the comparison with dedicated laboratory experiments allowed the determination of more accurate abundances of major ice components. The presence of CO₂ ice has recently been confirmed with the SWS (Short Wavelength Spectrometer) as a dominant ice component of interstellar grain mantles. The bending mode of CO₂ ice shows a particular triple-peak structure which provides first evidence for extensive ice segregation in the line-of-sight toward massive protostars. A comparison of interstellar and cometary ices using recent ISO data and ground-based measurements has revealed important similarities but also indicated that comets contain, beside pristine interstellar material, admixtures of processed material. The investigation of molecules in interstellar clouds is essential to reveal the link between dust in the interstellar medium and in the Solar System. This revised version was published online in June 2006 with corrections to the Cover Date.     

Temporal and Spatial Variations of Heliospheric x-ray Emissions Associated with Charge Transfer of the Solar Wind with Interstellar Neutrals

A simple model has been developed that demonstrates that heliospheric X-ray emission can account for about 25%–50% of observed soft X-ray background intensities. Similar to cometary soft X-ray emission, these X-rays are thought to be produced in the heliosphere due to charge transfer collisions between heavy solar wind ions and interstellar neutrals. A more complex model has now been developed to take into account temporal and spatial variations of the solar wind and interstellar neutrals. Measured time histories of the solar wind proton flux are used in the model and the results are compared with the ‘long-term enhancements’ in the soft X-ray background measured by ROSAT for the same time period. This revised version was published online in August 2006 with corrections to the Cover Date.     

Chemical and Physical Processing of Presolar Materials in the Solar Nebula and the Implications for Preservation of Presolar Materials in Comets

Chemical and physical processes in the outer solar nebula are reviewed. It is argued that the outer nebula was a chemically active environment with UV photochemistry and ion-molecule chemistry in its low density regions and grain-catalyzed chemistry in Jovian protoplanetary subnebulae. Presolar material was altered to greater or lesser extent by these spatially and temporally variable processes, which mimic many features of interstellar chemistry. Experiments, models, and observations are recommended to address the questions of presolar versus nebular dominance in the outer solar nebula and of how to distinguish interstellar and nebular sources of cometary volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary Refractory Grains: Interstellar and Nebular Sources

Comets are heterogeneous mixtures of interstellar and nebular materials. The degree of mixing of interstellar sources and nebular sources at different nuclear size scales holds the promise of revealing how cometary particles, cometesimals, and cometary nuclei accreted. We can ascribe cometary materials to interstellar and nebular sources and see how comets probe planet-forming process in our protoplanetary disk. Comets and cometary IDPs contain carbonaceous matter that appears to be either similar to poorly-graphitized (amorphous) carbon, a likely ISM source, or highly labile complex organics, with possible ISM or outer disk heritage. The oxygen fugacity of the solar nebula depends on the dynamical interplay between the inward migration of carbon-rich grains and of icy (water-rich) grains. Inside the water dissociation line, OH^? reacts with carbon to form CO or CO₂, consuming available oxygen and contributing to the canonical low oxygen fugacity. Alternatively, the influx of water vapor and/or oxygen rich dust grains from outer (cooler) disk regions can raise the oxygen fugacity. Low oxygen fugacity of the canonical solar nebula favors the condensation of Mg-rich crystalline silicates and Fe-metal, or the annealing of Fe-Mg amorphous silicates into Mg-rich crystals and Fe-metal via Fe-reduction. High oxygen fugacity nebular conditions favors the condensation of Fe-bearing to Fe-rich crystalline silicates. In the ISM, Fe-Mg amorphous silicates are prevalent, in stark contrast to Mg-rich crystalline silicates that are rare. Hence, cometary Mg-rich crystalline silicates formed in the hot, inner regions of the canonical solar nebula and they are the touchstone for models of the outward radial transport of nebular grains to the comet-forming zone. Stardust samples are dominated by Mg-rich crystalline silicates but also contain abundant Fe-bearing and Fe-rich crystalline silicates that are too large (?0.1 μm) to be annealed Fe-Mg amorphous silicates. By comparison with asteroids, the Stardust Fe-bearing and Fe-rich crystalline silicates suggests partial aqueous alteration in comet nuclei. However, aqueous alteration transforms Fe-rich olivine to phyllosilicates before Mg-rich olivine, and Stardust has Mg-rich and Fe-rich olivine and no phyllosilicates. Hence, we look to a nebular source for the moderately Fe-rich to nearly pure-Fe crystalline silicates. Primitive matrices have Mg-Fe silicates but no phyllosilicates, supporting the idea that Mg-Fe silicates but not phyllosilicates are products of water-rich shocks. Chondrule-formation is a late stage process in our protoplanetary disk. Stardust samples show comet 81P/Wild 2 formed at least as late to incorporate a few chondrules, requiring radial transport of chondrules out to perhaps >20 AU. By similar radial transport mechanisms, collisional fragments of aqueously altered asteroids, in particular achondrites that formed earlier than chondrules, might reach the comet-forming zones. However, Stardust samples do not have phyllosilicates and chondrules are rare. Hence, the nebular refractory grains in comet 81P/Wild 2, as well as other comets, appear to be pre-accretionary with respect to asteroid parent bodies. By discussing nebular pathways for the formation of Fe-rich crystalline silicates, and also phyllosilicates and carbonates, we put forth the view that comets contain both the interstellar ingredients for and the products of nebular transmutation.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

Spectroscopy Between the Stars

The emission and absorption spectra of interstellar molecules are reviewed with special consideration of recent observational and technical advances in the shorter submillimeter wave region of the electromagnetic spectrum. Single-dish observations have contributed in the past probably most of the information about the structure of interstellar molecular clouds. At present about 120 interstellar molecules have been identified in interstellar clouds and circumstellar envelopes, evidence of a rich and diversified chemistry. CO, the most abundant interstellar molecule and other diatomic molecules and radicals are found throughout molecular clouds, whereas the more complex molecules are found in high-density cores, which are often the sites of active star formation. These locations represent prime targets for the search for larger molecules, such as glycine. The ignition of young stars is accompanied by strong heating of the surrounding material by radiation and/or shocks, leading to photoevaporation of molecules depleted on dust grains driving a "hot core" chemistry, traceable by its rich organic chemistry and its prevailing high excitation conditions (up to about 2000 cm^-1). However, in the list of detected interstellar molecules many simple hydrides are still missing, e.g. SH, PH, PH₂, etc., which constitute the building blocks for larger molecules. With the technological opening of the terahertz region (ν ∼1 THz corresponds to λ ∼0.3 mm) to both laboratory and interstellar spectroscopy, great scientific advances are to be expected. Amongst these will be the direct detection of the lowest rotational transitions of the light hydrides, the low energy bending vibrations of larger (linear) molecules, and possibly the ring-puckering motion of larger ring molecules such as the polycyclic (multiring) aromatic hydrocarbons. This revised version was published online in June 2006 with corrections to the Cover Date.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Reaction Networks for Interstellar Chemical Modelling: Improvements and Challenges

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes—ion-neutral reactions, neutral-neutral reactions, radiative association, and dissociative recombination—is reviewed. Emphasis is placed on those key reactions that have been identified, by sensitivity analyses, as ‘crucial’ in determining the predicted abundances of the species observed in the interstellar medium. These sensitivity analyses have been carried out for gas-phase models of three representative, molecule-rich, astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the expanding circumstellar envelope IRC +10216. Our review has led to the proposal of new values and uncertainties for the rate coefficients of many of the key reactions. The impact of these new data on the predicted abundances in TMC-1 and L134N is reported. Interstellar dust particles also influence the observed abundances of molecules in the interstellar medium. Their role is included in gas-grain, as distinct from gas-phase only, models. We review the methods for incorporating both accretion onto, and reactions on, the surfaces of grains in such models, as well as describing some recent experimental efforts to simulate and examine relevant processes in the laboratory. These efforts include experiments on the surface-catalyzed recombination of hydrogen atoms, on chemical processing on and in the ices that are known to exist on the surface of interstellar grains, and on desorption processes, which may enable species formed on grains to return to the gas-phase.     

Composition of the Volatile Material in Halley's Coma from In Situ Measurements

The investigation of the volatile material in the coma of comets is a key to understanding the origin of cometary material, the physical and chemical conditions in the early solar system, the process of comet formation, and the changes that comets have undergone during the last 4.6 billion years. So far, in situ investigations of the volatile constituents have been confined to a single comet, namely P/Halley in 1986. Although, the Giotto mission gave only a few hours of data from the coma, it has yielded a surprising amount of new data and has advanced cometary science by a large step. In the present article the most important results of the measurements of the volatile material of Halley's comet are summarized and an overview of the identified molecules is given. Furthermore, a list of identified radicals and unstable molecules is presented for the first time. At least one of the radicals, namely CH₂, seems to be present as such in the cometary ice. As an outlook to the future we present a list of open questions concerning cometary volatiles and a short preview on the next generation of mass spectrometers that are being built for the International Rosetta Mission to explore the coma of Comet Wirtanen. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

Interstellar Dust in the Solar System

The Ulysses spacecraft has been orbiting the Sun on a highly inclined ellipse almost perpendicular to the ecliptic plane (inclination 79°, perihelion distance 1.3 AU, aphelion distance 5.4 AU) since it encountered Jupiter in 1992. The in situ dust detector on board continuously measured interstellar dust grains with masses up to 10⁻¹³ kg, penetrating deep into the solar system. The flow direction is close to the mean apex of the Sun’s motion through the solar system and the grains act as tracers of the physical conditions in the local interstellar cloud (LIC). While Ulysses monitored the interstellar dust stream at high ecliptic latitudes between 3 and 5 AU, interstellar impactors were also measured with the in situ dust detectors on board Cassini, Galileo and Helios, covering a heliocentric distance range between 0.3 and 3 AU in the ecliptic plane. The interstellar dust stream in the inner solar system is altered by the solar radiation pressure force, gravitational focussing and interaction of charged grains with the time varying interplanetary magnetic field. We review the results from in situ interstellar dust measurements in the solar system and present Ulysses’ latest interstellar dust data. These data indicate a 30° shift in the impact direction of interstellar grains w.r.t. the interstellar helium flow direction, the reason of which is presently unknown.     

Confronting Observations and Modeling: The Role of the Interstellar Magnetic Field in Voyager 1 and 2 Asymmetries

Magnetic effects are ubiquitous and known to be crucial in space physics and astrophysical media. We have now the opportunity to probe these effects in the outer heliosphere with the two spacecraft Voyager 1 and 2. Voyager 1 crossed, in December 2004, the termination shock and is now in the heliosheath. On August 30, 2007 Voyager 2 crossed the termination shock, providing us for the first time in-situ measurements of the subsonic solar wind in the heliosheath. With the recent in-situ data from Voyager 1 and 2 the numerical models are forced to confront their models with observational data. Our recent results indicate that magnetic effects, in particular the interstellar magnetic field, are very important in the interaction between the solar system and the interstellar medium. We summarize here our recent work that shows that the interstellar magnetic field affects the symmetry of the heliosphere that can be detected by different measurements. We combined radio emission and energetic particle streaming measurements from Voyager 1 and 2 with extensive state-of-the art 3D MHD modeling, to constrain the direction of the local interstellar magnetic field. The orientation derived is a plane ～60°–90° from the galactic plane. This indicates that the field orientation differs from that of a larger scale interstellar magnetic field, thought to parallel the galactic plane. Although it may take 7–12 years for Voyager 2 to leave the heliosheath and enter the pristine interstellar medium, the subsonic flows are immediately sensitive to the shape of the heliopause. The flows measured by Voyager 2 in the heliosheath indicate that the heliopause is being distorted by local interstellar magnetic field with the same orientation as derived previously. As a result of the interstellar magnetic field the solar system is asymmetric being pushed in the southern direction. The presence of hydrogen atoms tend to symmetrize the solutions. We show that with a strong interstellar magnetic field with our most current model that includes hydrogen atoms, the asymmetries are recovered. It remains a challenge for future works with a more complete model, to explain all the observed asymmetries by V1 and V2. We comment on these results and implications of other factors not included in our present model.     

Perspectives on the Comet-Asteroid-Meteorite Link

We discuss the possibility that CI and CM carbonaceous chondrites are fragments of extinct cometary nuclei. Theoretical and observational work suggests that comets evolve into asteroids, and several extinct cometary nuclei are now suspected to be among the near Earth object population. This population is the most likely source of meteorites and consequently, we may expect that some meteorites are from extinct comets in this population. The mineralogy and chemistry of CI and CM chondrites is consistent with the view that they originate from asteroidal objects of carbonaceous spectral classes, and these objects in turn may have a cometary origin. We do not suggest that CI or CM chondrites are directly delivered by active comets during perihelion passage or that these chondrites come from cometary debris in meteor streams. Instead, we summarize arguments suggesting that CI and CM chondrites represent fragments of cometary nuclei which evolved into near Earth asteroids after losing their volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Deuterium in Molecules of the Interstellar Medium

Deuterated molecules are detected both in interstellar translucent clouds and in cold dark clouds, as well as in star forming regions. We review the recent observational studies of deuterated molecules ranging from the VUV to the millimeter wavelength range. We outline some sources of uncertainties on the deuterium fractionation and on the subsequent derivation of the elemental deuterium to hydrogen ratio. Steady state versus time dependent models are discussed and the role of initial conditions is emphasized. This revised version was published online in August 2006 with corrections to the Cover Date.     

Local Interstellar Parameters as They Are Inferred from Analysis of Observations Inside the Heliosphere

This paper provides a brief summary on the current knowledge of the properties of the Circum-Heliospheric Interstellar Medium (CHISM). It discusses what can be learnt on the parameters of CHISM’s components from analysis of measurements performed inside the heliosphere. The analysis is based on the kinetic-gasdynamic models of the solar wind/interstellar medium interaction. We focus the analysis on three types of diagnostics: 1) interstellar H atom number density at the heliospheric termination shock inferred from pickup ion measurements, 2) the location and time of the Voyager 1 and 2 termination shock crossings, 3) the deflection of the interstellar H atom flow inside the heliosphere as been measured by SOHO/SWAN. From these results estimations of the unknown local interstellar parameters are deduced. The parameters are the number densities of interstellar H⁺ and H and the magnitude and direction of the interstellar magnetic field in the vicinity of the solar system.