Near-surface stratigraphy in comets inferred from observation,laboratory studies,and modeling

A brief discussion is given of the physical processes that may lead to a differentiation of the nucleus of short period comets. It is concluded that samples from the near-surface layers of such comets may give us important information on the initial state of cometary organics and refractories. Cometary ices are more likely to be indicators of the recent evolution of the comet.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Rosetta Alpha Particle X-Ray Spectrometer (APXS)

The Alpha Particle X-Ray Spectrometer (APXS) is a small instrument to determine the elemental composition of a given sample. For the ESA Rosetta mission, the periodical comet 67P/Churyumov-Gerasimenko was selected as the target comet, where the lander PHILAE (after landing) will carry out in-situ observations. One of the instruments onboard is the APXS to make measurements on the landing site. The APXS science goal is to provide basic compositional data of the comet surface. As comets consist of a mixture of ice and dust, the dust component can be characterized and compared with known meteoritic compositions. Various element ratios can be used to evaluate whether chemical fractionations occurred in cometary material by comparing them with known chondritic material. To enable observations of the local environment, APXS measurements of several spots on the surface and one spot as function of temperature can be made. Repetitive measurements as function of heliocentric distance can elucidate thermal processes at work. By measuring samples that were obtained by drilling subsurface material can be analyzed. The accumulated APXS data can be used to shed light on state, evolution, and origin of 67P/Churyumov- Gerasimenko.     

Dust Environment Modelling of Comet 67P/Churyumov-Gerasimenko

Dust is an important constituent of cometary emission; its analysis is one of the major objectives of ESA’s Rosetta mission to comet 67P/Churyumov-Gerasimenko (C–G). Several instruments aboard Rosetta are dedicated to studying various aspects of dust in the cometary coma, all of which require a certain level of exposure to dust to achieve their goals. At the same time, impacts of dust particles can constitute a hazard to the spacecraft. To conciliate the demands of dust collection instruments and spacecraft safety, it is desirable to assess the dust environment in the coma even before the arrival of Rosetta. We describe the present status of modelling the dust coma of 67P/C–G and predict the speed and flux of dust in the coma, the dust fluence on a spacecraft along sample trajectories, and the radiation environment in the coma. The model will need to be refined when more details of the coma are revealed by observations. An overview of astronomical observations of 67P/C–G is given, because model parameters are derived from this data if possible. For quantities not yet measured for 67P/C–G, we use values obtained for other comets, e.g. concerning the optical and compositional properties of the dust grains. One of the most important and most controversial parameters is the dust mass distribution. We summarise the mass distribution functions derived from the in-situ measurements at comet 1P/Halley in 1986. For 67P/C–G, constraining the mass distribution is currently only possible by the analysis of astronomical images. We find that both the dust mass distribution and the time dependence of the dust production rate of 67P/C–G are those of a fairly typical comet.     

Morphology–Composition–Isotopes: Recent Results from Observations

This article presents some recent imaging and spectroscopic observations that led to results which are significant for understanding the properties of comet nuclei. The coma morphology and/or composition were investigated for 12 comets belonging to different dynamical classes. The data analysis showed that the coma morphology of three non-periodic comets is not consistent with the general assumption that dynamically new comets still have a relatively uniform nucleus surface and therefore do not exhibit gas and/or dust jets in their coma. The determination of carbon and nitrogen isotopic ratios revealed the same values for all comets investigated at various heliocentric distances. However, the relative abundance of the rare nitrogen isotope ¹⁵N is about twice as high as in the Earth’s atmosphere. Observations of comets at splitting events and during outbursts led to indications for differences between material from the nucleus surface and the interior. The monitoring of the induced outburst of 9P/Temple revealed that under non-steady state conditions the fast disintegration of species is detectable.     

The interpretations of ultraviolet observations of comets

Summary Ultraviolet observations of comets from above the Earth's atmosphere have provided excellent new results and improved older ground based observations (OH) by an order of magnitude. Satellites are especially suitable because long integration times and observations during extended time intervals are possible.The existing cometary L observations have confirmed the relatively high overall gas production rates on the order of 10³⁰ molecule s^–1. The results strongly support the concept of an icy conglomerate solid cometary nucleus. Additional observations of hydroxyl and oxygen favor water to be one of the most abundant molecules in comets. The observations are in agreement with the predominent role of water in the evaporation process of the nuclear ices but are not proof in themselves.Water did not outnumber other consitutents by orders of magnitude in comets Bennett and Kohoutek. At least in these comets, carbon-containing molecules were possibly as numerous as water. Determination of the carbon scale length is necessary for a more quantitative statement.A hydrogen velocity of 7–9 km s^–1 was observed in comet Bennett as well as in comet Kohoutek for a variety of heliocentric distances and varying production rates. Determinations of the outflow velocity from L isophotes agree with line profile observations of L and H. Hydroxyl may constitute the main source for the hydrogen atoms with v _H - 8 km s^–1. The decay process, however, leading to this particular velocity is not yet known. Possibly a large portion of the OH radicals do not decay into hydrogen atoms or at least not into slow ones. If the high velocity component of 20 km s^–1 or more comprises a larger amount (up to 50%), most of the quoted hydrogen production rates must be revised upward.The intrinsic cometary brightness is only a very crude indicator of a comet's actual gas production rate as shown by comparison of comets Bennett and TSK. Comets can be successfully used as (extra ecliptic) space probes to measure interplanetary quantities, e.g., the curvature of the extended hydrogen clouds can be used for the absolute determination of the solar emission independent of instrumental calibration. Generally time dependent hydrogen density models must be used for the interpretation. The strength of the ultraviolet L emission favors its measurement as a standard procedure for the observation of comets (possibly together with OH (3090 Å)). These observations provide the most accurate results on the total cometary gas production rate and its variation with heliocentric distance.Dedicated to Professor L. Biermann in recognition of his inspiring guidance.On leave of absence from Max-Planck-Institut für Physik und Astrophysik, Munich.     

Diversity of Comets: Formation Zones and Dynamical Paths

The past dozen years have produced a new paradigm with regard to the source regions of comets in the early solar system. It is now widely recognized that the likely source of the Jupiter-family short-period comets (those with Tisserand parameters, T > 2 and periods, P, generally < 20 years) is the Kuiper belt in the ecliptic plane beyond Neptune. In contrast, the source of the Halley-type and long-period comets (those with T < 2 and P > 20 years) appears to be the Oort cloud. However, the comets in the Oort cloud almost certainly originated elsewhere, since accretion is very inefficient at such large heliocentric distances. New dynamical studies now suggest that the source of the Oort cloud comets is the entire giant planets region from Jupiter to Neptune, rather than primarily the Uranus-Neptune region, as previously thought. Some fraction of the Oort cloud population may even be asteroidal bodies formed inside the orbit of Jupiter. These comets and asteroids underwent a complex dynamical random walk among the giant planets before they were ejected to distant orbits in the Oort cloud, with possible interesting consequences for their thermal and collisional histories. Observational evidence for diversity in cometary compositions is limited, at best. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary Refractory Grains: Interstellar and Nebular Sources

Comets are heterogeneous mixtures of interstellar and nebular materials. The degree of mixing of interstellar sources and nebular sources at different nuclear size scales holds the promise of revealing how cometary particles, cometesimals, and cometary nuclei accreted. We can ascribe cometary materials to interstellar and nebular sources and see how comets probe planet-forming process in our protoplanetary disk. Comets and cometary IDPs contain carbonaceous matter that appears to be either similar to poorly-graphitized (amorphous) carbon, a likely ISM source, or highly labile complex organics, with possible ISM or outer disk heritage. The oxygen fugacity of the solar nebula depends on the dynamical interplay between the inward migration of carbon-rich grains and of icy (water-rich) grains. Inside the water dissociation line, OH^? reacts with carbon to form CO or CO₂, consuming available oxygen and contributing to the canonical low oxygen fugacity. Alternatively, the influx of water vapor and/or oxygen rich dust grains from outer (cooler) disk regions can raise the oxygen fugacity. Low oxygen fugacity of the canonical solar nebula favors the condensation of Mg-rich crystalline silicates and Fe-metal, or the annealing of Fe-Mg amorphous silicates into Mg-rich crystals and Fe-metal via Fe-reduction. High oxygen fugacity nebular conditions favors the condensation of Fe-bearing to Fe-rich crystalline silicates. In the ISM, Fe-Mg amorphous silicates are prevalent, in stark contrast to Mg-rich crystalline silicates that are rare. Hence, cometary Mg-rich crystalline silicates formed in the hot, inner regions of the canonical solar nebula and they are the touchstone for models of the outward radial transport of nebular grains to the comet-forming zone. Stardust samples are dominated by Mg-rich crystalline silicates but also contain abundant Fe-bearing and Fe-rich crystalline silicates that are too large (?0.1 μm) to be annealed Fe-Mg amorphous silicates. By comparison with asteroids, the Stardust Fe-bearing and Fe-rich crystalline silicates suggests partial aqueous alteration in comet nuclei. However, aqueous alteration transforms Fe-rich olivine to phyllosilicates before Mg-rich olivine, and Stardust has Mg-rich and Fe-rich olivine and no phyllosilicates. Hence, we look to a nebular source for the moderately Fe-rich to nearly pure-Fe crystalline silicates. Primitive matrices have Mg-Fe silicates but no phyllosilicates, supporting the idea that Mg-Fe silicates but not phyllosilicates are products of water-rich shocks. Chondrule-formation is a late stage process in our protoplanetary disk. Stardust samples show comet 81P/Wild 2 formed at least as late to incorporate a few chondrules, requiring radial transport of chondrules out to perhaps >20 AU. By similar radial transport mechanisms, collisional fragments of aqueously altered asteroids, in particular achondrites that formed earlier than chondrules, might reach the comet-forming zones. However, Stardust samples do not have phyllosilicates and chondrules are rare. Hence, the nebular refractory grains in comet 81P/Wild 2, as well as other comets, appear to be pre-accretionary with respect to asteroid parent bodies. By discussing nebular pathways for the formation of Fe-rich crystalline silicates, and also phyllosilicates and carbonates, we put forth the view that comets contain both the interstellar ingredients for and the products of nebular transmutation.     

Composition of the Volatile Material in Halley's Coma from In Situ Measurements

The investigation of the volatile material in the coma of comets is a key to understanding the origin of cometary material, the physical and chemical conditions in the early solar system, the process of comet formation, and the changes that comets have undergone during the last 4.6 billion years. So far, in situ investigations of the volatile constituents have been confined to a single comet, namely P/Halley in 1986. Although, the Giotto mission gave only a few hours of data from the coma, it has yielded a surprising amount of new data and has advanced cometary science by a large step. In the present article the most important results of the measurements of the volatile material of Halley's comet are summarized and an overview of the identified molecules is given. Furthermore, a list of identified radicals and unstable molecules is presented for the first time. At least one of the radicals, namely CH₂, seems to be present as such in the cometary ice. As an outlook to the future we present a list of open questions concerning cometary volatiles and a short preview on the next generation of mass spectrometers that are being built for the International Rosetta Mission to explore the coma of Comet Wirtanen. This revised version was published online in June 2006 with corrections to the Cover Date.     

Expectations for Infrared Spectroscopy of 9P/Tempel 1 from Deep Impact

The science payload on the Deep Impact mission includes a 1.05–4.8 μm infrared spectrometer with a spectral resolution ranging from R∼200–900. The Deep Impact IR spectrometer was designed to optimize, within engineering and cost constraints, observations of the dust, gas, and nucleus of 9P/Tempel 1. The wavelength range includes absorption and emission features from ices, silicates, organics, and many gases that are known to be, or anticipated to be, present on comets. The expected data will provide measurements at previously unseen spatial resolution before, during, and after our cratering experiment at the comet 9P/Tempel 1. This article explores the unique aspects of the Deep Impact IR spectrometer experiment, presents a range of expectations for spectral data of 9P/Tempel 1, and summarizes the specific science objectives at each phase of the mission.     

Velocity changes of the Giotto spacecraft during the comet flybys: on the interpretation of perturbed Doppler data

Upon developing a new theory for the analysis of one-way and two-way Doppler shifts of the radio carrier signal transmitted by interplanetary spacecraft, Porsche (1999) urges a reassessment of the radio science data obtained during the Giotto flybys at comets P/Halley and P/Grigg–Skjellerup. We explain again the Doppler recording method and the operational strategy of the flybys and present both the two-way and one-way data sets from Giotto's flyby at comet Grigg–Skjellerup as an example. We find no reason to change our most probable flyby scenarios. Furthermore, we assert that Porsche's treatment of the classical Doppler effect is in error. All quantities derived from his analysis are gross overestimates and incompliant with observations and cometary physics.     

Origin of Comet Nuclei and Dynamics

We present a review of the main physical features of comet nuclei, their birthplaces and the dynamical processes that allow some of them to reach the Sun’s neighborhood and become potentially detectable. Comets are thought to be the most primitive bodies of the solar system although some processing—for instance, melting water ice in their interiors and collisional fragmentation and reaccumulation—could have occurred after formation to alter their primordial nature. Their estimated low densities (a few tenths g?cm^?3) point to a very fluffy, porous structure, while their composition rich in water ice and other highly volatile ices point to a formation in the region of the Jovian planets, or the trans-neptunian region. The main reservoir of long-period comets is the Oort cloud, whose visible radius is ～3.3×10⁴ AU. Yet, the existence of a dense inner core cannot be ruled out, a possibility that would have been greatly favored if the solar system formed in a dense galactic environment. The trans-neptunian object Sedna might be the first discovered member that belongs to such a core. The trans-neptunian population is the main source of Jupiter family comets, and may be responsible for a large renovation of the Oort cloud population.     

X-Ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/E1.5–3) instruments and focused on the morphology of x-rays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.     

Interstellar Reservoirs of Cometary Matter

We review the evidence for the products of interstellar chemistry in volatile cometary matter. We compare the organic inventory of star-forming cores with that measured in various comets and point out the similarities and differences. The conditions necessary to fractionate interstellar molecules in the heavier isotopes of H, C, O and N are summarised and compared to the measured fractionation ratios in cometary ices. We give a list of future measurements that would shed further light on the putative connection between cometary and interstellar molecules.     

Origins of Cometary Materials

In this introductory presentation, material is categorized according to our state of knowledge: What do we know, what do we think we know but don’t know certainly, and what do we not know but often describe it as if it were a well-established fact about comets, their nuclei, their composition, and processes within comets and their nuclei. The material is presented not with the intend to criticize laboratory work simulating condition in comet nuclei, or observers analyzing their observations, nor modelers using data from both these sources to improve our understanding and make predictions. The intent is to provoke discussion and dialog between these groups to avoid overstating the results. What is a Comet? A comet is a diffuse appearing celestial phenomenon moving in an orbit about the Sun. The central body, the nucleus, is composed of ice and dust. It is the source of all cometary activity, including comae and tails. We distinguish between molecular (including atoms and ions) and dust comae. At heliocentric distances of about 1 AU and less, the hydrogen coma typically has dimensions larger than the Sun. The tails are composed of dust, neutral atoms and molecules, and plasma.     

Cometary Materials: Progress Toward Understanding the Composition in the Outer Solar Nebula

A major objective of the workshop was to learn about the chemical composition, physical structure, and thermodynamic conditions of the outer parts of the solar nebula where comets formed. Here we sum up what we have learned from years of research about the molecular constituents of comet comae primarily from in situ measurements of Comet 1P/Halley and remote sensing of Comets 1P/Halley, Hale-Bopp (C/1995 O1), and Hyakutake (C/1996 B2). These three bright comets are presumably captured Oort cloud comets. We summarize the analyses of these data to predict the composition of comet nuclei and project them further to the composition, structure, and thermodynamic conditions in the nebula. Near-future comet missions are directed toward less active short-period Jupiter-family comets. Thus, future analyses will afford a better understanding of the diversity of these two major groups of comets and their respective regions of origin in the solar or presolar nebula. We conclude with recommendations for determining critical data needed to aid in further analyses. Results of the workshop provide new guidelines and constraints for modeling the solar nebula. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

Remote Observations of the Composition of Cometary Volatiles

The volatile species released in the coma are an important clue to the composition of the cometary nucleus ices. Their identification and the measurement of their abundances is possible by remote sensing. Considerable progress has been made recently using radio and infrared spectroscopy, especially with the observations of the two exceptional comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp).) 24 molecules likely to be parent molecules outgassed from the nucleus have now been identified. Significant upper limits exist for many other species, and the presence of unidentified lines suggests that further species are to be identified. In addition, isotopic varieties have been observed for hydrogen, carbon, nitrogen and sulphur. We will review these results with a special emphasis on the reliability of the identifications and of the molecular production rate determinations. A critical point is to assess whether a given species is a genuine parent molecule outgassed from nuclear ices, or is a secondary product coming from grains or from gas-phase photochemistry. Ground-based spectral imaging, such as radio interferometry, may help resolving this problem. This revised version was published online in June 2006 with corrections to the Cover Date.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

Dynamical Origin of Comets and Their Reservoirs

It is widely believed that cometary orbits contain important clues to both the outer solar system’s current structure and its past dynamical evolution. The first part of this paper summarizes the results of numerical simulations designed to study the dynamical origins of observed comets and to link the observed populations to the reservoirs from which they are currently leaking. The second part reviews simulations which are designed to study the dynamical origin of the reservoirs themselves. The paper concludes with a brief discussion of the currently unresolved issue of where in the primordial solar nebula the different dynamical classes of observed comets originated.