受控生态生保系统内红萍供氧特性研究

研究红萍载人供O₂特征, 为红萍生物部件进行系统总体地面模拟试验及空间应用奠定基础,构建了受控生态生保系统密闭试验舱和红萍栽培装置, 在“红萍-鱼-人”共存情况下, 测定密闭舱内O₂, CO₂浓度的变化. 试验结果显示, 单位重量的鱼耗O₂量. 0805～0.0831 L·kg-1·h-1, 排放CO₂量为0.0705～0.0736 L·kg-1·h-1; 试验志愿者耗O₂量19.71 L·h-1, 呼吸释放CO₂量18.90 L·h-1. 人工光照保持7000～8000 lx条件下, 红萍的光合作用与人和鱼的呼吸作用相辅相成, 舱内O₂, CO₂浓度趋于平衡. 密闭舱内CO₂浓度升高对促进红萍群体净光合效率有明显效果, 红萍光合放O₂能力很强, 能有效促使密闭舱内O₂, CO₂浓度朝着有利于人生存的环境方向平衡, 进而验证了红萍的空间应用前景.      

On the possible detection of solid O2 and O3 interstellar grains with ISO

In various models of interstellar grain chemistry, solid O₂ is formed by accretion as well as by surface reactions on grains. In dense molecular cloud models, at a later stage of the evolution, the O₂ molecule may become a substantial grain mantle constituent. Since IR dipole vibrational transitions for the homonuclear diatomic molecule O₂ are forbidden, the abundance of this potentially important grain mantle component can not be determined. However, embedded in a dirty ice matrix, the fundamental vibration of O₂ at 1550 cm⁻¹ becomes observable at 10 K, due to interactions with surrounding molecules, which break the symmetry of molecular oxygen. This process might be applicable for the dust mantle environment of interstellar grains. We have studied the role of solid O₂ and O₃ in astrophysically relevant ice mixtures and discuss the possible detection of solid O₂ and its major photolysis product O₃ in interstellar grains, in dense molecular clouds. Both molecules represent a specific target to be observed by the ISO satellite in the near future.     

电离对高超声速热化学非平衡气动热环境的影响

高超声速飞行,激波后高温气体会发生电离,飞行器气动热环境复杂。5组元（N₂,O₂,NO,O,N）、7组元（N₂,O₂,NO,O,N,NO+,e-）和11组元（N₂,O₂,NO,O,N,N₂+,O₂+,NO+,O+,N+,e-）热化学反应采用Gupta化学反应模型,分别数值研究电离作用对高超声速热化学非平衡气动热环境影响。本文分析了不同催化壁面条件下,高超声速热化学非平衡电离流场气动热环境特性。电离作用对激波离体距离和气动力载荷的影响很小。5组元热化学非平衡不考虑电离作用,流场温度和壁面热流密度偏大。11组元热化学平衡强电离流场温度最低;7组元热化学非平衡弱电离流场NO+和e-生成量过低;11组元热化学反应能对热化学非平衡电离流场气动力和热流密度载荷可靠预测。壁面催化作用会增大壁面热流密度,但它对高超声速热化学非平衡电离流场温度和气动力载荷的影响很小。      

氧气A(0,0)波段气辉体发射率和临边辐射强度模拟与分析

临近空间大气参数如温度、密度、风场等对预报模型精度及航天器运行安全等有较大的影响,而气辉的辐射模拟是大气参数反演的重要过程.本文基于光化学模型计算了氧气A（0,0）波段气辉的体发射率和临边辐射强度.基于氧气A（0,0）波段气辉的光化学反应机制、大气动力学和光化学反应理论,建立产生O₂（b1Σ_g+）的光化学模型.计算气辉体发射率,基于临边探测几何路径进行气辉辐射强度模拟.体发射率计算结果与AURIC模型结果的辐射值及辐射高度均一致.基于计算和模拟结果,对氧气A波段气辉体发射率和辐射强度的影响因素进行了分析.      

基于SABER的平流层顶温度的时空特征分析

利用SABER探测器2002—2017年超过一个太阳活动周的数据,以大气垂直方向上40～60km的最大温度作为平流层顶温度（T_sp）,分析50°S—50°N T_sp的时空分布特征.结果表明:T_sp具有明显的纬度特征和季节特征,在赤道和南北半球夏季温度较高,而在南北半球冬季的40°—50°纬度附近温度有最低值.再利用EOF方法分析T_sp,发现其第一模态的解释率达91%,且时间系数与平流层顶高度相关性最大,为-0.75,与平流层顶臭氧体积混合比相关性约0.49,与日地距离相关性为0.44,与太阳活动性（太阳活动指数,太阳黑子数）的相关性约0.33.依据该相关关系,进一步分析各变量原始场,发现T_sp和平流层顶臭氧体积混合比的纬度变化近似相反;与日地距离的季节变化有明显的负相关,约-0.81,且这种相关性与日地距离有弱的正相关关系;年平均T_sp在2002—2017年的变化约为2K,与F_10.7的相关系数为0.6,在南北纬20°附近与太阳活动指数F_10.7的相关性最大,约0.74.      

Radiation stability of organic matter in liquid and frozen H2O, NH3 and water-ammonia mixtures

The redox properties of irradiated liquid and frozen H₂O, NH₃ and H₂O/NH₃ mixtures at 298 K and 77 K, resp., towards some simple organic molecules have been checked by injecting carrierfree ¹¹C atoms and analyzing their chemical state by means of radiochromatography. The reactions and the stability of organic products versus radiation dose (in this study by MeV protons) depend on temperature, phase state, mobility of radicals, their concentration and reactivity. Especially dangerous are the reactive OH and O₂H radicals which oxidize organic material to inorganic CO₂. Highest stability has been found at low temperatures (solid state, reduced mobility of radicals) and for systems containing H-donors (H₂O/NH₃ mixtures), which reduce the concentration of oxidizing radicals. The fact that many bodies in space consist of H₂O-ice with NH₃ and CH₄ additives at temperatures between 10 and 150 K is promising in view of the survival of organic matter under high doses of radiation.     

H2O对空间站5A分子筛CO2去除性能影响

为进一步研究分子筛CO2去除系统应用于空间站的工作可靠性和鲁棒性,针对空间站4床分子筛(4-BMS)系统中可能出现的湿度失效保护问题展开了实验研究.测试了两种载人航天分子筛材料TC-5A与PSA-5A,研究了不同相对湿度对CO2吸附性能的影响;比较了相同湿度条件下,进口气体CO2浓度、粒径及吸附温度的变化对分子筛吸附CO2性能的影响,采用不同实验方法探究了H2O和CO2在两种分子筛材料中的竞争吸附关系.结果表明:PSA-5A吸附CO2性能优于TC-5A,但对H2O的吸附率略低于TC-5A.H2O的存在对分子筛吸附CO2影响非常大,空气中相对湿度达到60%时,分子筛基本失去了吸附CO2的能力.此外,温度升高会造成CO2的吸附量显著下降,但对H2O的吸附量影响相对较小,尤其是当相对湿度较高时.这对中国未来长期运行的空间站分子筛CO2去除系统工作有效性与工作鲁棒性的评价具有指导意义.     

Comparison of ion composition from the goddard comprehensive ionosphere database with the international reference ionosphere model

We compared the IRI values of T_e, N_e, T_i, O⁺, H⁺, He⁺, O₂₊, and NO⁺ with AE-C values, obtained from the Goddard Comprehensive Ionosphere Database (GCID), composed of data from the satellites, AE-B, OGO-6, ISIS-2, AE-C, AE-D, and AE-E. O⁺ - H⁺ transition levels were derived from the IRI and AE-C altitude profiles. Some discrepancies were found between IRI and the AE-C data. The IRI electron density was found to be about a factor of 2 higher than the data. The H⁺ composition agreed best among the IRI ions, with an average AE-C/IRI ratio of 1.05. The temperatures of both electrons and ions agreed quite well: the average ratios of AE-C/IRI was found to be .99 for electrons and 1.17 for ions.     

太赫兹火星大气临边探测仿真研究

对火星大气进行连续高分辨率观测是研究火星大气物理和化学过程的重要手段.太赫兹临边探测技术通过测量火星大气中的风和光化学循环中的重要气体（CO,O₃,H₂O,H₂O₂等）提高对火星的认知.针对火星大气遥感的探测需求,分析了300～1000GHz频段的频谱特征.针对探测卫星对于载荷质量、功耗等参数的要求,提出一个560GHz频段的火星大气太赫兹临边探测仪设计方案,并利用辐射传输模型ARTS中的行星工具箱进行仿真.仿真结果显示:火星大气温度的反演精度优于4K,其中45km高度以下优于2K;H₂O丰度的反演精度在90km以下优于50%,30km以下优于2%;H₂O₂的反演精度在40km以下优于50%;O₃的反演精度在50km以下优于60%;大气风速度的反演精度在65km以上优于5m·s-1,最高可以达到2m·s-1.研究结果表明,利用太赫兹波段的吸收谱线可以很好地探测火星大气中各成分的丰度、变化趋势以及中高层大气的风,可为后续火星表面及大气探测提供参考.      

多舱段载人航天器CO2去除系统性能仿真分析

多舱段载人航天器通常由主控舱段利用舱间通风对组合体空气环境参数进行集中控制.利用Ecosimpro建立了一种多舱段载人航天器CO₂去除系统性能仿真分析模型,包括舱体模块、乘员模块、CO₂净化模块、舱间通风模块,并对三舱段载人航天器CO₂去除系统性能进行了计算分析.结果表明,当净化装置进风量为0.007 2 kg/s,非主控舱段驻留人数达到6人时,会造成非主控舱段CO₂分压超出700 Pa的指标上限.此时增大舱间通风量对降低非主控舱段CO₂分压的效果并不明显,有效的控制方式是增大净化装置进风量.当净化装置进风量增加至0.011 3 kg/s时,非主控舱段CO₂分压可降至700 Pa以下.该工作有助于加快载人航天器空气环境控制系统的设计和改进流程.     

量子点与TiO2电极参数对光阳极电子寿命及性能影响

通过对P25Ti O2光阳极薄膜厚度、敏化的量子点种类及量子点敏化方法研究,探讨了使用连续离子层吸附反应法的敏化方法(SILAR)时,P25Ti O2薄膜厚度与光阳极电子寿命的关系,以及量子点种类、共敏化工艺对光阳极光电性能的影响.采用电化学阻抗(EIS)、开路电压衰减(OCVD)及紫外-可见吸收方法,对影响光阳极光电性能的Ti O2薄膜厚度、量子点种类及共敏化工艺因素进行测试分析.实验结果表明:当光阳极薄膜厚度为12μm时,电子复合几率最小,光阳极的电子寿命相对最长;采用连续离子层吸附反应法(SILAR)对多种量子点共敏化的光阳极(Ti O2/Cd S/Cd Se/Zn S)与单一量子点敏化的光阳极(Ti O2/Cd S)相比,短路电流提高了34%,光转换效率提高了42%;合适的共敏化工艺也有助于提高光阳极的电子寿命、光谱吸收范围和吸收强度.     

Neutral upper atmospheres of Venus and Mars

Numerous measurements of the neutral upper atmosphere above 100 km have been made from spacecraft over Venus and over Mars. The Venus exospheric temperatures are unexpectedly low (less than 300°K near noon and less than 130°K near midnight). These very low temperatures may be partially caused by collisional excitation of CO₂ vibrational states by atomic oxygen and partially by eddy cooling. The Venus atmosphere is unexpectedly insensitive to solar EUV variability. On the other hand, the Martian dayside exospheric temperature varies from 150°K to 400°K over the 11-year solar cycle, where CO₂ 15-μm cooling may be less effective because of lower atomic oxygen mixing ratios. On Venus, temperature increases with altitude on the dayside (thermosphere), but decreases with altitude from 100 to 150 km on the nightside (cryosphere). However, dayside Martian temperatures near solar minimum for maximum planet-sun distance and low solar activity are essentially isothermal from 40 km to 200 km. During high solar activity, the thermospheric temperatures of Mars sharply increase. The Venus neutral upper atmosphere contains CO₂, O, CO, C, N₂, N, He, H, D and hot nonthermal H, O, C, and N, while the dayside Mars neutral upper atmosphere contains CO₂, O, O₂, CO, C, N₂, He, H, and Ar. There is evidence on Venus for inhibited day-to-night transport as well as superrotation of the upper atmosphere. Both atmospheres have substantial wave activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.     

VEGA three-channel spectrometer experiment: Spectroscopy of comet Halley in the visible and near-ultraviolet ranges

A total of 3600 spectra of Comet Halley in the 275–710 nm were obtained on March, 8, 9, 10 and 11, 1986, from the VEGA 2 spacecraft. The emissions of OH, NH, CN, C₃, CH, C₂, NH₂ and H₂O⁺ are identified. From the OH intensity in the (0,0) band: 1.1 Megarayleigh at 5400 km from the nucleus, it can be inferred that the OH production rate was (1.4 ± 0.5)×10³⁰ molecules s⁻¹. The NH, C₃, CH and NH₂ bands became comparatively more intense at distances from the nucleus shorter than 3000km. At 06:40 U.T. when the instrument field of view was 6000×4500 km, two jets were observed. Spectra from the jets show significant differences with other spectra. Inside a jet NH, C₃ and NH₂ are comparatively more intense and the rotational distributions of OH, CN and C₂ are strongly distorted. This shows that part of the observed emissions probably comes from radicals directly produced in the excited state during the initial process of photolysis of the parent molecules.     

Measurement of the partial oxygen pressure and oxygen utilization in the skin of cosmonauts aboard Salyut 6

The oxygen tension (PO₂) in the dorsal skin surface of the forearm was studied during the stay of cosmonauts on board Salyut 6. Between the fourth and fifth day of stay on the orbital station a considerable reduction of the PO₂ level was observed. The oxygen utilization values were also reduced. In the early postflight period the low PO₂ level persisted, with gradual normalization.     

混合球磨对YAl_2颗粒形貌及表面改性的影响

采用扫描电镜、能谱分析、透射电镜等分析方法研究了球磨对YAl₂及YAl₂/Mg颗粒的组织形貌、YAl₂颗粒在YAl₂/Mg颗粒中的分散性及YAl₂/Mg界面结合状况的影响.结果表明:YAl₂颗粒经球磨20 h后,其平均粒径约为1.5 μm,颗粒边缘尖角数量明显减少,呈圆滑的近球形.加入Mg颗粒进行混合球磨20 h后,YAl₂颗粒在混合颗粒中呈弥散分布,且表面包裹一层单质Mg,YAl₂/Mg的界面为直接结合型,未发现有界面反应.     

基于地磁坐标和Kriging技术的高纬地区f0F2重构方法

为能够在高纬区域获取高精度电离层参数特性结果,提出了基于地磁坐标的高纬度区域电离层F₂层临界频率（f₀F₂）的重构方法.该方法确定了基于地磁坐标的变异函数,通过求解改进Kriging方程得出估计值.方法的确定取决于对2种坐标系、2类电离层距离计算方法以及尺度因子的选取.通过对俄罗斯6个垂直探测站在太阳活动高年（2013年）和低年（2017年）的f₀F₂历史观测数据使用月中值进行交叉验证,证明了引入地磁坐标和利用球面距离计算方法对高纬度地区进行重构能够达到最优效果.相比现有方法,其整体标准误差和绝对误差均有所降低.上述研究证实了该方法的有效性,对电子信息系统的可用频率预测以及通信效能保障具有重要意义.      

基于MIV的碳钢大气腐蚀速率影响因子权重分析

通过平均影响值（MIV）影响因子权重分析算法,以碳钢Q235、Ste355、St12和Q450腐蚀速率的暴露时间、气候因素和环境因素数据为依据,以|MIV|值为评价依据,定量分析15种影响因子（暴露时间、平均温度、平均相对湿度、日照时数、降水量、平均风速、海盐粒子浓度、SO₂、HCl、NO₂、H₂S、硫酸盐化速率、NH₃、降尘量-非水溶性、降尘量-水溶性）对碳钢腐蚀速率影响的权重大小。结果表明: 当MIV调节率从5%逐步递增至25%时,同种影响因子对腐蚀速率的影响权重变化不大,但4种碳钢对各影响因子的敏感度略有不同;气候因素对腐蚀速率影响最大,其次为暴露时间,环境因素中SO₂和降尘量对腐蚀速率影响较大;平均相对湿度、日照时数、平均温度是影响腐蚀速率最主要的3个因子。      

国际参考电离层模型输出参数峰值高度性能

电离层峰值高度H_mF₂是描述电离层形态的重要参数之一,国际参考电离层模型IRI-2016中融入了大量电离层测高仪和无线电掩星探测数据,用以提升H_mF₂的预测精度.本文利用太阳活动低年（2007—2010年）气象、电离层和气候卫星联合观测系统COSMIC探测数据描述全球范围内COSMIC H_mF₂的三维形态变化,对比分析了IRI-2016与IRI-2012模型的预测结果,同时分析了IRI-2016模型输出H_mF₂的性能.结果表明,IRI模型在中高纬度地区的输出结果高于COSMIC反演结果,而赤道及低纬地区则大都偏低.与IRI-2012模型相比,IRI-2016模型的输出结果在夜间至凌晨时段呈现较为明显的纬向梯度变化且大部分区域输出值偏高,但在白天时段赤道附近区域的输出值大都偏低.上述结果为电离层IRI模型的完善提供了一定参考.      

曲靖地区电离层多参数变化特征

利用电波环境观测网曲靖站电离层垂直探测仪数据（2008－2018）,分析了该站电离层多参数（包括f_min,f₀E_s,h'E_s,f₀E,f₀F₁,f₀F₂,h'F,MUF(3000)F₂等）随太阳活动、季节、地方时的变化特征。结果表明,f_min,f₀E_s,h'E_s随太阳活动变化不明显,f₀E,f₀F₁,f₀F₂,h'F,MUF(3000)F₂与太阳活动变化具有相关性,f₀F₂经常发生日落增强现象,同时各自具有独立性;与拉萨、乌鲁木齐地区f₀F₂,h'F,f₀E_s变化特征对比,发现地方时与月份变化趋势相同,但是极值出现的位置有所不同,这可能与各地区的地理纬度和地形等因素有关;h'F夜间大于白天,在日出日落时段有突然上升现象,冬季的h'F一般都小于其他季节;MUF(3000)F₂与f₀F₂的变化特征相似,白天值高于夜晚值,春秋分季高于夏冬季,太阳活动高年日落后MUF(3000)F₂一直维持较高值并持续到03:00－04:00 LT。