Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Perspectives on the Comet-Asteroid-Meteorite Link

We discuss the possibility that CI and CM carbonaceous chondrites are fragments of extinct cometary nuclei. Theoretical and observational work suggests that comets evolve into asteroids, and several extinct cometary nuclei are now suspected to be among the near Earth object population. This population is the most likely source of meteorites and consequently, we may expect that some meteorites are from extinct comets in this population. The mineralogy and chemistry of CI and CM chondrites is consistent with the view that they originate from asteroidal objects of carbonaceous spectral classes, and these objects in turn may have a cometary origin. We do not suggest that CI or CM chondrites are directly delivered by active comets during perihelion passage or that these chondrites come from cometary debris in meteor streams. Instead, we summarize arguments suggesting that CI and CM chondrites represent fragments of cometary nuclei which evolved into near Earth asteroids after losing their volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Organic constituents of the carbonaceous chondrites

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers.Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded that most of the organic constituents are indigenous to the meteorites and are extra terrestial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin.A brief review on studies of organized elements contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some micro-structures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.Contribution from the Chemistry Section, Space Science Division of Jet Propulsion Laboratory.     

Gas-rich meteorites: Probes for particle environment and dynamical processes in the inner solar system

The discovery in the early sixties of precompaction solar wind irradiation records in the gas-rich meteorites opened up the possibility of studying the solar activity at different epochs in the distant past. Subsequent studies in several meteorites have led to the discovery of the precompaction records of irradiation of constituent grains by solar wind, solar flare and galactic cosmic ray particles. There are also microcraters resulting from their collisions with interplanetary dust grains. Analyses of these records and their observed similarity with those found in the lunar samples led to the hypothesis that the precompaction records in individual components of these meteorites were imprinted while they were residing in the near surface region of their parent bodies, most probably the asteroids. Although the asteroids are the most plausible candidates for the parent bodies of gas-rich meteorites, there exist certain dynamical arguments which tend to favor a cometary origin in certain cases. Also, recent studies indicate that in the case of gas-rich carbonaceous chondrites solar flare irradiation of grains may have occurred prior to formation of the parent bodies.In this review we summarize the significant advances that have taken place in the multi-disciplinary studies (petrography, chemistry, and radiation effects) of the gas-rich meteorites and critically evaluate the present state of our knowledge regarding the origin and evolution of the gas-rich meteorites. The information on the spatial and temporal variations in the interplanetary radiation and particle fluxes, obtained from the analysis of precompaction irradiation records in these meteorites is presented and further studies in certain specific topics are suggested for resolving some of the unsolved problems.     

Asteroid surface materials: Mineralogical characterizations from reflectance spectra

The interpretation of diagnostic parameters in the spectral reflectance data for asteroids provides a means of characterizing the mineralogy and petrology of asteroid surface materials. An interpretive technique based on a quantitative understanding of the functional relationship between the optical properties of a mineral assemblage and its mineralogy, petrology and chemistry can provide a considerably more sophisticated characterization of a surface material than any matching or classification technique for those objects bright enough to allow spectral reflectance measurements. Albedos derived from radiometry and polarization data for individual asteroids can be used with spectral data to establish the spectral albedo, to define the optical density of the surface material and, in general, to constrain mineralogical interpretations.Mineral assemblages analogous to most meteorite types, with the exception of ordinary chondritic assemblages, have been found as surface materials of Main Belt asteroids. C1- and C2-like assemblages (unleached, oxidized meteoritic clay minerals plus opaques such as carbon) dominate the population (80%) throughout the Belt, especially in the outer Belt. A smaller population of asteroids exhibit surface materials similar to C3 (CO, CV) meteoritic assemblages (olivine plus opaque, probably carbon) and are also distributed throughout the Belt. The relative size (diameter) distributions for these two populations of objects are consistent with an origin by sequential accretion from a cooling nebula (C2 as surface layers, C3 as interior layers or cores). Based on information from meteoritic analogues and on qualitative models for the behavior of these materials during a heating episode, it seems unlikely that these C2- and C3-like asteroidal bodies have experienced any significant post-accretionary heating event either near surface or in the deep interior.The majority of remaining studied asteroids (20) of 65 asteroids exhibit spectral reflectance curves dominated by the presence of metallic nickel-iron in their surface materials. These objects are most probably the several end products of an intense thermal event leading to the melting and differentiating of their protobodies. These thermalized bodies are concentrated toward the inner part of the Asteroid Belt but exist throughout the Belt.The size of the proto-asteroid has apparently exercised control over the post-accretionary thermal history of these bodies. The available evidence indicates that all asteroids larger than about 450 km in (present) diameter have undergone a significant heating episode since their formation. The post-accretionary thermal history of the asteroidal parent bodies was apparently affected by both distance from the Sun and body size.The C2-like materials which dominate the main asteroid belt population appear to be relatively rare on earth-approaching asteroids. This suggests that most of these Apollo-Amor objects are not randomly derived from the main belt, but (a) may derive from a single event in recent time (10⁷ yr), (b) may derive from a favorably situated source body, (c) may derive from a particular, compositionally anomalous region of the belt, or (d) may derive from an alternate source (e.g. comets).     

Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.     

Ureilites

Ureilites are a rare group of five stony meteorites — feldsparless achondrites containing diamonds of preterrestrial origin the total weight of them being 315 carats. The whole carbon content in ureilites makes up 1.5–4.1%. Ureilites substantially differ from the other stony meteorites. In comparison with chondrites they are enriched in Mg but depleted in metal, troilite, alkaline elements. All ureilites are very similar by their structure. They contain elongated cavities generally stretched in the same direction. The structure of ureilites is an achondritic porphyric one. These meteorites consist of large olivine grains, there is less clinopyroxene (pigeonite). They contain kamacite (Ni content being 1.5–4%), troilite FeS, chromite. Carbon material is represented by diamond, graphite and organic material being present in a disequilibrium state. Two ureilites (North Haig and Dingo Pup Donga) were considerably oxidized during terrestrial weathering and contain secondary iron oxides.Diamonds are present in ureilites in thin intergrowths with graphite being disposed between silicate grains more or less evenly in the meteorite. The sizes of such black diamond-graphite aggregates are 0.3–0.9 mm. The sizes of the micromonocrystals of diamond and graphite are less than 1. The diamond-graphite aggregates contain dispersed particles of kamacite, troilite, chromite, nickelchrome, being present in very thin intergrowths with one another. Besides the usual diamond there is an admixture of lonsdaleite in the aggregates representing a hexagonal diamond with a würtzite-like structure. Lonsdaleite has been identified in the ureilites Novo Urei, Goalpara, North Haig. The diamonds of ureilites are characterized by inhomogeneities in the crystalline structure which are at least partly caused by the presence of donor nitrogen. According to the isotopic carbon composition the diamond in the meteorite Novo Urei has the value C¹³ = -5.7.The structure peculiarities of ureilites bear witness of the fact that these meteorites had been subject to the action of dynamic pressure about 300–600 kbar. The impact had taken place in cosmic space. All ureilites subdivide into two types: the first type are Novo Urei, Dyalpur, Dingo Pup Donga, the second type are Goalpara, North Haig according to the following signs: (1) olivine grains are finer in ureilites of the second type; (2) twinning is more typical of clinopyroxenes of ureilites belonging to the first type; (3) in ureilites of the first type a net-like iron distribution is observed, in ureilites of the second type kamacite plates are chiefly present between silicate grains; (4) the size of diamondgraphite intergrowths in ureilites of the first type does not exceed 0.3 mm, in ureilites of the second type it reaches 0.9 mm. Ureilites of the first type have undergone a less intensive impact than ureilites of the second type. Certain similarity of the material composition of ureilites and of the material composition of carbonaceous chondrites, the distinction of these two groups of meteorites from all other meteorites bear witness of the fact that ureilites have formed from carbonaceous chondrites during a collision of asteroid bodies in cosmic space, diamonds having been formed from the carbon material of carbonaceous chondrites.     

The Mighei meteorite

The Mighei meteorite is generally considered to be unique amongst the group of stony meteorites known as the carbonaceous chondrites in a number of scientifically interesting aspects. The meteorite, which is related to the type II carbonaceous chondrites of Wiik's classification (or type C2 according to van Schmus and Wood), contains extraterrestrial organic compounds (general C content = 2.6%), and extraterrestrial water associated with iron-magnesium silicate crystals (general H₂O content=12%).The meteorite fall occurred in 1889, over a region in the Ukraine. In structure it was found to be a chondritic meteorite, having chondrules of order 0.5 mm in size. The composition of the meteorite is inhomogeneous. In mineralogical terms the meteorite is composed of two paragenetic associations, described as high and low temperature, which are generally distributed in equal proportions. The low temperature associations are a characteristic only of carbonaceous chondrites: the minerals involved are chlorites or the serpentine group, carbonates, free sulphur, sulphates and low temperature glass. In chemical terms the Mighei meteorite is somewhat enriched in the volatile elements S, C, H, N, O in comparison to the usual chondrites. These elements are found in different forms and the isotopic composition of the elements S, C, O, is different for different phases. The meteorite is also rich in a number of other fairly volatile element admixtures such as: B, F, Cl, Cu, Zn, Ga, Ge, Br, In, Te, I, Hg, Tl, Pb, Bi, and contains somewhat enhanced initial quantities of rare gases.The organic compounds are of an abiological nature in the meteorite and are located in finely dispersed distributions between the chondrules. They are present in the main, as polymerized organic compounds. Among these polymers there are gaseous hydrocarbons (saturated and non-saturated) and extractable organic compounds. In the latter condition the following organic compounds have been identified: aliphatic hydrocarbons, aromatic hydrocarbons, amino acids and others. The meteorite contains free organic radicals (10¹⁷ centres g^–1), uncoupled -electrons which are delocalized in the aromatic structure of the polymeric matter.The radiogenic age of the meteorite has been determined as from 2.4 to 3.2 × 10⁹ yr (by the K-Ar method) and up to 4.54 × 10⁹ yr (by the Rb-Sr method), while the radiation age is put at 0.5 to 2.4 × 10⁶ yr. Details of the meteorite structure give evidence of at least two processes in its formation; the accretion of the meteoritic matter, together with the simultaneous formation of organic compounds could have taken place at temperatures between 450 and 300 K.Reported on the XIV Meteoritic Conference, December 17, 1970, Moscow.     

The carbonaceous chondrites

The carbonaceous chondrites are a group of stony meteorites characterized by the presence of an appreciable amount of carbonaceous material other than free carbon (diamond and graphite). They have been divided into three subgroups known respectively as Type I, Type II, and Type III. Analyses of Type I meteorites show about 3–5% of carbon and 20% of combined water; they consist largely of hydrated magnesium-iron silicate, magnetite, and magnesium sulfate, contain no chondrules, and have a density about 2.2. Analyses of Type II meteorites show about 2–3% of carbon and 10–15% of combined water; they consist of a groundmass of hydrated magnesium-iron silicate enclosing chondrules of olivine and pyroxene which are almost iron-free, and have a density of 2.6–2.9. Analyses of Type III meteorites show about 0.5–2% of carbon and 2% combined water; they consist largely of olivine (often variable in composition, but averaging 30–40 mole per cent Fe₂SiO₄), with accessory pigeonite and sulfide minerals, and have a density about 3.4.The carbonaceous material and combined water in these meteorites are clearly of extraterrestrial origin, but their significance is not well understood. A biological origin has been claimed for some of the organic compounds on the basis of their composition, but this claim is the subject of considerable dispute. Microscopic objects with regular outline (organized elements) have been recognized in some of these meteorites; some investigators have claimed these to be extraterrestrial fossils, others have ascribed them to terrestrial contamination or considered them to be crystals or crystal aggregates of non-biological origin.     

Minor Bodies: Spectral Gradients and Relationships with Meteorites

The observational evidence of a gradient in composition of the solid matter in the Solar System as a function of heliocentric distance, with more volatile elements increasingly abundant at larger heliocentric distances, is in general agreement with commonly accepted ideas about condensation of solid material in the early protoplanetary disk. In this respect, the gradual transition from regions mostly populated by S-type objects in the inner asteroid belt to the C-type dominated outer belt, and to the D-type dominated Trojan clouds has generally been interpreted as diagnostic of a zoning of the asteroid population in terms of mineralogic composition and thermal history. The situation, however, is not completely clear, and several contradictory facts still need an explanation. Another major problem concerns the origin of meteorites. Understanding the history of these bodies is critically important, since most of our ideas about the composition of the original protosolar nebula and protoplanetary matter come from meteoritic data. In this respect, very recent advances have been achieved in the knowledge of dynamical transport mechanisms. This can have important consequences for the characterization of plausible meteorite parent bodies. This revised version was published online in June 2006 with corrections to the Cover Date.     

Meteors and the abundance of interplanetary matter

Estimates of the spatial density of interplanetary dust are derived from meteor, accretion and zodiacial cloud observations. When the most recent data are considered it is found that there is no longer any serious discrepancy between the extrapolated meteor values and those from the other sources and a density distribution is obtained which extends from meteoroids capable of producing the brightest optical meteors to particles approaching the limiting size beyond which they are removed from the solar system by solar radiation pressure. Impacts on rocket and satellite vehicles lead to much higher estimates of spatial densities and it is concluded that they originate from particles in geocentric orbits belonging to a dust cloud encompassing the earth. The evidence tends to support the view that these particles are captured from the interplanetary dust cloud rather than being produced, as suggested by Whipple, through the impact of meteorites on the moon.Some suggestions are made for the direction of future rocket and satellite investigations.Contribution to the COPERS symposium on The Interplanetary medium, held in Paris on June 19, 1962.     

Alteration Assemblages in Martian Meteorites: Implications for Near-Surface Processes

The SNC (Shergotty-Nakhla-Chassigny) meteorites have recorded interactions between martian crustal fluids and the parent igneous rocks. The resultant secondary minerals — which comprise up to 1 vol.% of the meteorites — provide information about the timing and nature of hydrous activity and atmospheric processes on Mars. We suggest that the most plausible models for secondary mineral formation involve the evaporation of low temperature (25 – 150 °C) brines. This is consistent with the simple mineralogy of these assemblages — Fe-Mg-Ca carbonates, anhydrite, gypsum, halite, clays — and the chemical fractionation of Ca-to Mg-rich carbonate in ALH84001 "rosettes". Longer-lived, and higher temperature, hydrothermal systems would have caused more silicate alteration than is seen and probably more complex mineral assemblages. Experimental and phase equilibria data on carbonate compositions similar to those present in the SNCs imply low temperatures of formation with cooling taking place over a short period of time (e.g. days). The ALH84001 carbonate also probably shows the effects of partial vapourisation and dehydration related to an impact event post-dating the initial precipitation. This shock event may have led to the formation of sulphide and some magnetite in the Fe-rich outer parts of the rosettes.Radiometric dating (K-Ar, Rb-Sr) of the secondary mineral assemblages in one of the nakhlites (Lafayette) suggests that they formed between 0 and 670 Myr, and certainly long after the crystallisation of the host igneous rocks. Crystallisation of ALH84001 carbonate took place 0.5 Gyr after the parent rock. These age ranges and the other research on these assemblages suggest that environmental conditions conducive to near-surface liquid water have been present on Mars periodically over the last 1 Gyr. This fluid activity cannot have been continuous over geological time because in that case much more silicate alteration would have taken place in the meteorite parent rocks and the soluble salts would probably not have been preserved.The secondary minerals could have been precipitated from brines with seawater-like composition, high bicarbonate contents and a weakly acidic nature. The co-existence of siderite (Fe-carbonate) and clays in the nakhlites suggests that the pCO₂ level in equilibrium with the parent brine may have been 50 mbar or more. The brines could have originated as flood waters which percolated through the top few hundred meters of the crust, releasing cations from the surrounding parent rocks. The high sulphur and chlorine concentrations of the martian soil have most likely resulted from aeolian redistribution of such aqueously-deposited salts and from reaction of the martian surface with volcanic acid volatiles.The volume of carbonates in meteorites provides a minimum crustal abundance and is equivalent to 50–250 mbar of CO₂ being trapped in the uppermost 200–1000 m of the martian crust. Large fractionations in ¹⁸O between igneous silicate in the meteorites and the secondary minerals (30) require formation of the latter below temperatures at which silicate-carbonate equilibration could have taken place (400°C) and have been taken to suggest low temperatures (e.g. 150°C) of precipitation from a hydrous fluid.     

Scanning with charge-coupled devices

The 0.91-m Spacewatch Telescope of the Steward Observatory of the University of Arizona on Kitt Peak is dedicated to scanning with charge-coupled devices (CCDs) during the dark half of the month. We explored six modes of using CCDs for searches of gamma-ray bursters, debris in geosynchronous space, satellites of asteroids, brown dwarfs, the tenth planet, comets, cometesimals, and various types of asteroids. In the process, we gained experience with cosmic rays and artifacts in CCD observations. Each of these topics is described. I especially note that the existence of cometesimals has not been confirmed by the Spacewatch Telescope, contrary to reports published by others.This paper describes a new discipline in astrophysics, scannerscopy, of surveying with a CCD rather than with photography at a Schmidt telescope. It uses the CCD in scanning rather than in sequencing of stare exposures as is done at most observatories. This may save telescope time, and flat-fielding is rarely needed. Usually we turn the drive off, but the scanning can be done with the telescope moving. In any case, the motion on the sky is precisely followed by slaving the charge transfer of the CCD to the drift rate of the image, while the CCD is read out continuously during the observing. Our primary application of CCD scanning is on moving objects such as comets and asteroids. We also do routine astronomy with CCDs, in a transit method, and this yields a precision of better than ±0.7 arc sec.We presently use a Tektronix 2048×2048 CCD, 38 arc min wide, to a limiting magnitude ofV=20.5 (6 detection). This is successful even for discovering rare and small near-Earth asteroids. 1990 UN with a diameter of 90 m and 1991 BA at 9 m are the smallest natural objects observed outside the Earth's atmosphere to date. In a month with good conditions we find typically 2000 new main-belt asteroids and, on average, nearly two near-Earth asteroids. Only the latter are followed up with astrometry. The goal is to study magnitude-frequency relations, as well as to complete the inventory of dangerous impactors on Earth. We are designing a new CCD-scanning telecope to become an order-of-magnitude more effective in the discovery of elusive objects than the Spacewatch Telescope. The paper also describes possibilities with cameras on spacecraft that pass through the asteroid belt; thousands of small asteroids can be observed with the CCDs of CRAF and CASSINI.     

Hydrocarbons in terrestrial samples and the Orgueil meteorite

Meteorites contain extraterrestrial carbonaceous materials. The Alais, Orgueil, Tonk, and Ivuna meteorites resemble in their carbon, free sulfur, and non-metamorphosed mineral contents, densities, and general appearances certain organic-rich terrestrial sediments. Structural and isotopic determinations of carbon compounds in the Orgueil chondrite indicate that these compounds are primarily indigenous. Physically and chemically the benzene extractable carbonaceous materials from the Orgueil and certain near-surface terrestrial sediments are similar. Mass spectrometric type analyses of the alkanes from an Orgueil fragment, terrestrial sediments and organisms are statistically indistinguishable at the 95 per cent confidence level. Theoretical considerations and experimental data are presented, and these permit an assessment of the potential and reliability of hydrocarbons as biological indicators. Based on the production and preservation or organic substances in terrestrial environments, alkanes in the Alais, Orgueil, Tonk, and Ivuna (Type I) carbonaceous chondrites could retain the best evidence of organisms that may have lived on a parent body of meteorites.A portion of the research reported in this article was supported by the National Aeronautics and Space Administration under Contract No. NASw 508.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

The Origin and Evolution of the Asteroid Belt��Implications for Vesta and Ceres

Vesta and Ceres are the largest members of the asteroid belt, surviving from the earliest phases of Solar System history. They formed at a time when the asteroid belt was much more massive than it is today and were witness to its dramatic evolution, where planetary embryos were formed and lost, where the collisional environment shifted from accretional to destructive, and where the current size distribution of asteroids was sculpted by mutual collisions and most of the asteroids originally present were lost by dynamical processes. Since these early times, the environment of the asteroid belt has become relatively quiescent, though over the long history of the Solar System the surfaces of Vesta and Ceres continue to record and be influenced by impacts, most notably the south polar cratering event on Vesta. As a consequence of such impacts, Vesta has contributed a significant family of asteroids to the main belt, which is the likely source of the HED meteorites on Earth. No similar contribution to the main belt (or meteorites) is evident for Ceres. Through studies of craters, the surfaces of these asteroids will offer an opportunity for Dawn to probe the modern population of small asteroids in a size regime not directly observable from Earth.     

A cosmochemical view of cosmic rays and solar particles

The composition of cosmic rays and solar particles is reviewed with emphasis on the question of whether they are representative samples of Galactic and solar matter. The composition of solar particles changes with energy and from flare to flare. A strong excess of heavy elements at energies below a few MeV/nuc decreases with energy, and at energies above 15 MeV/nuc the composition of solar particles resembles that of galactic cosmic rays somewhat better than that of the solar atmosphere. The elements Ne through Pb have remarkably similar abundances in cosmic ray sources and in the matter of the solar system. The lighter elements are depleted in cosmic rays, whereas U and Th may be enriched or not, depending on whether the meteoritic or solar abundance of Th is used. Two prototype sources of cosmic rays are considered: gas with solar system composition but enriched in elements with Z > 8 during acceleration and emission (by analogy with solar particle emission), and highly evolved matter enriched in r-process elements such as U, Th and transuranic elements. The energy-dependence of cosmic ray composition suggests that both sources may contribute at different energies.Miller Institute Professor, 1972–73.     

Organic matter in meteorites and comets: Possible origins

At least 6 extraterrestrial environments may have contributed organic compounds to meteorites and comets: solar nebula, giant-planet subnebulae, asteroid interiors containing liquid water, carbon star atmospheres, and diffuse or dark interstellar clouds. The record in meteorites is partly obscured by pervasive reheating that transformed much of the organic matter to kerogen; nonetheless, it seems that all 6 formation sites contributed. For comets, the large abundance of HCHO, HCN, and unsaturated hydrocarbons suggests an interstellar component of 50%, but the contributions of various interstellar processes, and of a solar-nebula component, are hard to quantify. A research program is outlined that may help reduce these uncertainties.     

Chemistry,accretion, and evolution of Mars

The high FeO concentrations measured by VIKING for the Martian soils correspond to all probability to a FeO-rich mantle. In general, the VIKING XRF-data indicate a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust.In recent years evidence has been collected which points towards Mars being the parent body of SNC-meteorites and, hence, these meteorites have become a valuable source of information about the chemistry of Mars. Using element correlations observed in SNC-meteorites and general cosmochemical constraints, it is possible to estimated the bulk composition of Mars. Normalized to Si and Cl, the mean abundance value for the elements Ga, Fe, Na, P, K, F, and Rb in the Martian mantle is found to be 0.35 and thus exceeds the terrestrial value by about a factor of two. Aside pressure effects and the H₂O poverty, the high P and K content of the Martian mantle may lead to magmatic processes different from those on Earth.The composition of the Earth's mantle can successfully be described by a two component model. Component A: highly reduced and almost free of all elements more volatile than Na; component B: oxidized and containing all elements in Cl-abundances including volatile elements. The same two components can be used as building blocks for Mars, if one assumes that, contrary to the inhomogeneous accretion of the Earth, Mars accreted almost homogeneously. The striking depletion of all elements with chalcophile character indicates that chemical equilibrium between component A and B was achieved on Mars which lead to the formation of significant amounts of FeS which, on segregation, extracted the elements according to their sulphide-silicate partition coefficients. While for the Earth a mixing ratio AB = 8515 was derived, the Mars ratio of 6040 reflects the higher concentrations of moderately volatile elements like Na, K, and sulphur on Mars. A homogeneous accretion of Mars could also explain the obvious low abundances of water and primordial rare gases.     

The Canyon Diablo meteorite

The giant diamond-containing Canyon Diablo meteorite is in composition a typical representative of the widespread group of iron meteorites — the coarse octahedrites. But it is unique in a number of scientifically important aspects. When it fell, it formed the Arizona (Barringer meteorite) crater (1220 m in diam), which is of the explosive type. The investigations of the shock recrystallization of the crater rocks and the meteoritic material are of importance for planetology, and in particular for the eludication of matter recrystallization conditions during the collisions of large cosmic bodies. The study of the diamonds contained in the Canyon Diablo meteorite is of importance to various branches of carbon cosmochemistry.The Canyon Diablo meteorite fell in Arizona, U.S.A., some tens of thousands years ago. However, the Arizona meteorite crater is well preserved owing to the semi-arid climatic conditions. Signs of shock recrystallization of the rocks — shatter cones, impactites, dense and super-dense silica modifications were revealed in the Arizona meteorite crater. Around the crater many samples of the Canyon Diablo iron meteorite have been found (at distances of up to 9 km from the crater), together with a great amount of finely dispersed meteorite matter. The total weight of the material attributed to the meteorite is put at 30 tons. A number of meteorite fragments have been oxidized to different degrees during terrestrial weathering.Typical samples of the Canyon Diablo meteorite are represented by coarse octahedrite matter with kamacite band widths of 1.8–2.2 mm. In many meteorite fragments, especially the fragments found on the crater rim, the Widmanstätten pattern has been destroyed as a result of the explosion which occurred when the meteorite hit the Earth. The meteorite is rich in accessory minerals (cohenite, schreibersite, troilite.). The Ni content is, in typical samples of the meteorite, about 7.16%, in rare, atypical, medium octahedrite samples the Ni content reached 8.2 %. In the content of trace elements the meteorite may be classified with the I Ga-Ge group. In the content of stable isotopes of elements there is no substantial difference between the Canyon Diablo meteorite and other octahedrites. Radioactive cosmogenic isotopes are represented by isotopes with a large half-life.The diamonds in the Canyon Diablo meteorite are unevenly distributed and are found inside the highly recrystallized meteorite fragments at the rim of the crater. Diamonds are present in the form of intergrowths of microcrystals, crystallite sizes are < 1, the sizes of the intergrowths reach 2–5 mm. Admixtures of graphite and the hexagonal diamond lonsdaleite are present in the intergrowths.From the evidence of shock recrystallization of the meteorite matter it would seem that the diamond containing fragments of the Canyon Diablo meteorite have undergone shock pressures of from 400 kbar to 1 mgbar at impact, at these pressures the diamonds would crystallise. The diamond-containing sample of the Canyon Diablo meteorite investigated by the author has experienced a shock pressure of up to 1 mgbar during the explosion.