The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O₃) over the 10-km to 65-km range and water vapor (H₂O), nitrogen dioxide (NO₂), and nitric acid (HNO₃) over the 10-km to ～50-km range. Latitude coverage extended from 64°S to 84°N. Several general features of the atmosphere have emerged from data analyses thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO₃ data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O₃, NO₂, and HNO₃ are strongly affected during a stratospheric warming. There is a persistently low water vapor mixing ratio in the tropical lower stratosphere (～2–3 ppmv), a poleward gradient at all times in the mission, and evidence of increasing mixing ratio with altitude at tropical and middle latitudes.     

Observations of the ozone and nitrogen dioxide profiles in the TROICA-4 experiment

To investigate the vast area of Russia, a mobile scientific facility based in a railway carriage was developed. It is capable to perform continues measurements being coupled in a passenger train traveling along railroads. It was first equipped with a spectrometer for remote sensing of ozone and nitrogen dioxide in the atmosphere for the transcontinental observations into the chemistry of the atmosphere-4 expedition performed from February 18 to March 5, 1998. A twilight DOAS method, which was applied for retrieval of the nitrogen dioxide profiles basing on spectral measurements at the visible wavelengths (434–451 nm), is described in the paper. Main features of a new algorithm for retrieval of the ozone profile and total content using the differential structure of the UV spectrum (310–335 nm) are presented. The ozone and nitrogen dioxide contents are obtained and shortly validated against available alternative data.     

Validation of SAGE II data inversions by the European correlative experiments

An European program of correlative experiments has been organized in order to validate SAGE II data during three periods of observation over Europe (November 1984, April 1985, October 1985). About ten groups from France, Belgium, Germany and Italy were participating. The correlative data are lidar aerosol profiles, soundings of ozone profiles, and balloon observations, including limb photographies, polarimetric measurements of the aerosol scattered light and nitrogen dioxide extinction measurements. Results of the comparisons between SAGE II inverted data and correlative data are presented. The analysis of the aerosol correlative observations with the SAGE II four aerosol channel data, in term of profile and size distribution is perfectly consistent and provide a good indirect validatioin. The NO₂ comparison shows a good agreement between SAGE II and correlative data.     

Comparison of ground reflectance measurement with satellite derived atmospherically corrected reflectance: A case study over semi-arid landscape

Atmospheric corrections to satellite data are important for comparing multitemporal data sets over tropical regions with variable aerosol loading. In this study, we evaluated the potential of 6S radiative transfer model for atmospheric corrections of IRS-P6 AWiFS satellite data sets, in a semi-arid landscape. Ground measurements of surface reflectance representing different land use/land cover categories were conducted to relate IRS-P6 AWiFS top of atmospheric reflectance. The 6S radiative transfer model was calibrated for local conditions using ground measurements for aerosol optical depth, water vapor and ozone with a sun photometer. Surface reflectance retrieved from 6S code was compared with top of atmosphere (TOA) reflectance and ground based spectroradiometer measurements. Accurate parameterization of the 6S model using measurements of aerosol optical depth, water vapor and ozone plays an important role while comparing ground and satellite derived reflectance measurements.     

Statistical global and regional atmospheric models of temperature and gas components over the northern hemisphere

Statistical mid-latitude models of altitude distribution of temperature, water vapor, ozone, carbon dioxide and trace gases (CO, CH₄, N₂O, NO, NO₂) are considered. The mean characteristics of altitude profiles of these parameters, as well as their time and space variability, have been taken into account. The statistical regional models were constructed using a temperature-humidy complex. The considered statistical mid-latitude models have been constructed as applied to solutions of the problems on remote sounding of the atmosphere and underlying surface from outer space.     

Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model,and model calculations

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago (Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O₃ and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.     

Global monitoring of tropospheric water vapor with GPS radio occultation aboard CHAMP

The global positioning system radio occultation (GPS RO) technique provides a powerful tool for atmospheric sounding which requires no calibration, is not affected by clouds, aerosols or precipitation, and provides an almost uniform global coverage. The paper deals with application of GPS RO measurements from CHAllenging Minisatellite Payload (CHAMP) for the retrieval of tropospheric water vapor profiles. CHAMP RO data are available since 2001 with up to 200 high resolution atmospheric profiles per day. We introduce a new direct method for water vapor retrieval from GPS RO data. Additionally, a 1Dvar algorithm is used for this purpose. The so derived CHAMP water vapor profiles are validated with radiosonde data on a global scale. Here, both methods come to statistically comparable results revealing a negative bias of less than 0.1 g/kg and a standard deviation of less than 1 g/kg specific humidity in the mid troposphere. Potentials of CHAMP RO retrievals for monitoring the mean tropospheric water vapor distribution on a global scale are presented.     

Water vapor in the stratosphere: Preliminary results of the LIMS experiment aboard NiMBUS 7

The validation status of the LIMS (Limb Infrared Monitor of the Stratosphere) measurements in the water vapor channel is presented in a brief form. The agreement with other water vapor data taken in correlative balloon underflights is encouraging for this stage of the processing. Future efforts will be made to resolve remaining discrepancies so that operational reduction can begin. Preliminary maps for atmospheric layers between 50 mb and 1 mb show a fairly smooth water vapor field in the summer hemisphere.     

Investigation of the atmospheric aerosols by the visible and IR channels of the AVHRR radiometer on NOAA-6

The diffusely reflected radiation in the daytime and diffusely transmitted radiation at night from an inhomogeneous, plane parallel planetary atmosphere bounded by the ocean surface was calculated at the visible and IR region. In the daytime the effect of the solar radiation from top was taken into account. The present study has dealt with the problem of no cloud contamination in data. In the atmosphere, water vapor, molecular nitrogen, nitrous oxide, carbon dioxide and methane as absorbent constituents and aerosols as the scattering constituent were taken into account. The ocean surface as a lower boundary was simulated by many facets whose slopes are according to the isotropic Gaussian distribution [1]. It was found that it is suitable for deriving the total optical thickness in the direction of about 15 degrees away from the specular direction at 3.7μm in the daytime, with the aid of visible region of spectrum [2]. As for sea surface temperature, for a sample analysis, derived SST was within the accuracy of 1–2K at the center of the sun glint and within the accuracy of 0.5K in the rest of the region at 3.7μm in the daytime, Furthermore computational results suggest that the comparison of temperature in the daytime with that at night at 3.7μm make it possible to separate the effect of aerosols from the total optical thickness. Thus it was found from the computations that with the aid of daytime and night time data, it is possible to derive the atmospheric water vapor, aerosols and sea surface temperature simultaneously.     

Planet temperatures with surface cooling parameterized

A semigray (shortwave and longwave) surface temperature model is developed from conditions on Venus, Earth and Mars, where the greenhouse effect is mostly due to carbon dioxide and water vapor. In addition to estimating longwave optical depths, parameterizations are developed for surface cooling due to shortwave absorption in the atmosphere, and for convective (sensible and latent) heat transfer. An approximation to the Clausius–Clapeyron relation provides water–vapor feedback. The resulting iterative algorithm is applied to three “super-Earths” in the Gliese 581 system, including the “Goldilocks” planet g (Vogt et al., 2010). Surprisingly, none of the three appear habitable. One cannot accurately locate a star’s habitable zone without data or assumptions about a planet’s atmosphere.     

The problem of indirect sounding of high clouds

Remote sounding of high cloud top temperatures by passive methods is a difficult venture due to the semitransparency of the clouds. Window channel measurements often overestimate the cloud top temperature. In this study it is experimentally shown and supported by theoretical considerations that water vapor channels, which are originally intended to sense the high tropospheric water vapor content, are more suitable than window channels. In addition, it is shown that measurements in the H₂O rotational band are superior to 6.3 μm channels due to higher intensity of the outgoing radiation and less contribution by scattering by cloud particles.     

The cold summer mesopause

One of the most characteristic features of the summer mesopause at high latitudes is the very low temperature. Earlier measurements have shown temperatures in the range down to 135 K around 86 km altitude, whereas the most recent $\text{in situ}$ measurements have revealed temperatures still much lower than that in a rather wide altitude region. The reasons for these low temperatures are to be found in the dynamics of the strato- and mesospheres. Upwinds and gravity wave activity over the summer hemisphere cause efficient cooling of the atmosphere.Also other effects are caused by the updrafts. The vertical transport velocity for important minor constituents is increased, which for instance causes the concentration of water vapor around the mesopause to be enhanced by large factors. This situation is of major importance for the possibility of forming noctilucent clouds (NLC).NLC are believed to be composed of small water ice particles, which because of the low temperatures can be formed on existing condensation nuclei. Two of the main questions regarding the formation of NLC concern the water vapor budget of the upper mesosphere and the origin of the condensation nuclei.This paper gives a general introduction to mesospheric physics and composition. Some results from recent satellite and rocket experiments are reviewed and the campaign layout and the performed experiments within the MAP project CAMP are described. The results from the different experiments are presented in four accompanying papers on CAMP results.     

Subcritical and supercritical water oxidation of CELSS model wastes.

Controlled-Ecological-Life-Support-System (CELSS) model wastes were wet-oxidized at temperatures from 250 to 500 degrees C, i.e., below and above the critical point of water (374 degrees C and 218 kg/cm2 or 21.4 MPa). A solution of ammonium hydroxide and acetic acid and a slurry of human urine, feces, and wipes were used as model wastes. Almost all of the organic matter in the model wastes was oxidized in the temperature range from 400 to 500 degrees C, i.e., above the critical conditions for water. In contrast, only a small portion of the organic matter was oxidized at subcritical conditions. Although the extent of nitrogen oxidation to nitrous oxide (N2O) and/or nitrogen gas (N2) increased with reaction temperature, most of the nitrogen was retained in solution as ammonia near 400 degrees C. This important finding suggests that most of the nitrogen in the waste feed can be retained in solution as ammonia during oxidation at low supercritical temperatures and be subsequently used as a nitrogen source for plants in a CELSS while at the same time organic matter is almost completely oxidized to carbon dioxide and water. It was also found in this study the Hastelloy C-276 alloy reactor corroded during waste oxidation. The rate of corrosion was lower above than below the critical temperature for water.     

Statistical comparison of night-time NO2 observations in 2003–2006 from GOMOS and MIPAS instruments

GOMOS (Global Ozone Monitoring by Occultation of Stars) and MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) are remote sensing instruments on board the European Space Agency’s Envisat satellite. GOMOS and MIPAS have been designed for observations of stratospheric and mesospheric constituents, including ozone and nitrogen dioxide. Both instruments have a good global coverage of observations and can provide data also from the polar regions. In this paper, we compare night-time NO₂ data from GOMOS with those from MIPAS. We present statistics of selected sets of data spanning from the year 2003 to 2006. The results for low-to-mid latitudes show that the two instruments are in a good agreement in the middle stratosphere, the differences being typically less than 5%. In the upper stratosphere, GOMOS observations generally show 15% higher values than those from MIPAS. The bias is in virtually all cases smaller than the combined systematic error of the measurements, giving great confidence in the GOMOS and MIPAS data quality. The result for high mesospheric NO₂ mixing ratios observed in the polar regions during winter times indicate a good agreement between GOMOS and MIPAS. In the mesosphere, the difference is less than 35% and smaller than the systematic error. Due to the high mesospheric signal, MIPAS sensitivity decreases in the stratosphere which results in larger differences between the two instruments.     

A facility for simulating Titan’s environment

As a result of measurements acquired by the Cassini–Huygens mission of Titan’s near surface atmospheric composition and temperature, Titan conditions can now be simulated in the laboratory and samples can subsequently be subjected to those conditions. Titan demonstrates an active hydrological-like cycle with its thick atmosphere, dynamic clouds, polar lakes of methane and ethane, moist regolith, and extensive fluvial erosive features. Unlike Earth, Titan’s hydrological-like cycle likely involves several constituents, primarily methane and ethane. Here the properties of a new Titan simulation facility are presented, including conceptual methodology, design, implementation, and performance results. The chamber maintains Titan’s surface temperature and pressure, and the sample cryogenic liquids undergoing experimentation are condensed within the chamber itself. During the experiments, the evaporation rates of the sample liquids are directly determined by continually measuring mass. Constituents are analyzed utilizing a Fourier Transform Infrared Spectroscopy (FTIR), and vapor concentrations are determined using a gas chromatograph fitted with a Flame Ionization Detector (FID). All pertinent data is logged via computer. Under laboratory conditions, the direct measurements of the evaporation rates of methane, ethane, and mixtures thereof can be achieved. Among the processes to be studied are the effects of regolith on transport from the subsurface to the atmosphere, the freezing point depression effects of dissolved nitrogen, and the solubility of various relevant organic compounds.     

平流层上部负离子成分的直接测量和硫酸离子热化学分析

本文报道了在法国南部(44°N)上空进行的两次气球飞行实验的部分负离子成分探测结果.利用自然负离子谱计算了某些硫酸离子的热化学常数ΔG, ΔH和ΔS.讨论了上升段测量中气球表面放气造成的离子化学污染.      

Comparison of OClO nadir measurements from SCIAMACHY and GOME

The scanning imaging absorption spectrometer for atmospheric chartography was launched successfully onboard ENVISAT on March 1, 2002. It observes the solar radiation transmitted and backscattered from the atmosphere and reflected from the ground in nadir, limb and occultation viewing modes. Chlorine dioxide (OClO), an important indicator for stratospheric chlorine activation, can be measured in the UV spectral range by differential optical absorption spectroscopy (DOAS).

First results of the DOAS retrieval of OClO slant column densities from the SCIAMACHY nadir measurements are presented and compared to measurements of the global ozone monitoring experiment (GOME), which has successfully measured OClO since 1995. While SCIAMACHY operates in the same orbit, it measures ≈30 min earlier than GOME and has an increased spatial resolution (30 × 60 km² compared to 40 × 320 km² for GOME).     

Validation on MERSI/FY-3A precipitable water vapor product

The precipitable water vapor is one of the most active gases in the atmosphere which strongly affects the climate. China's second-generation polar orbit meteorological satellite FY-3A equipped with a Medium Resolution Spectral Imager (MERSI) is able to detect atmospheric water vapor. In this paper, water vapor data from AERONET, radiosonde and MODIS were used to validate the accuracy of the MERSI water vapor product in the different seasons and climatic regions of East Asia. The results show that the values of MERSI water vapor product are relatively lower than that of the other instruments and its accuracy is generally lower. The mean bias (MB) was ?0.8 to ?12.7?mm, the root mean square error (RMSE) was 2.2–17.0?mm, and the mean absolute percentage error (MAPE) varied from 31.8% to 44.1%. On the spatial variation, the accuracy of MERSI water vapor product in a descending order was from North China, West China, Japan -Korea, East China, to South China, while the seasonal variation of accuracy was the best for winter, followed by spring, then in autumn and the lowest in summer. It was found that the errors of MERSI water vapor product was mainly due to the low accuracy of radiation calibration of the MERSI absorption channel, along with the inaccurate look-up table of apparent reflectance and water vapor within the water vapor retrieved algorithm. In addition, the surface reflectance, the mixed pixels of image cloud, the humidity and temperature of atmospheric vertical profile and the haze were also found to have affected the accuracy of MERSI water vapor product.     

Remote sensing based continuous hydrologic modeling

There are two principal ways in which remote sensing can be used with continuous hydrological models: (1) by providing a cost effective way for obtaining input data and (2) by providing synoptic measurements of various state variables. This paper discusses existing hydrologic models and the modifications required to adapt them for using remotely sensed data that may significantly improve their simulation performance. Microwave and thermal infrared measurements show promise for use in hydrologic models because they can measure certain physical properties of the watershed (emissivity and temperature) from which a hydrologic condition can be inferred. Additional applications of remote sensing data include the use of spatial data, mechanisms for extrapolating point data and direct measurement of several hydrologic state variables such as soil moisture, surface temperature, snow water equivalent, frozen soils, and rainfall distribution. Results are presented from several aircraft flights where thermal infrared and microwave data were collected over a small research basin. These results are discussed with respect to their application in continuous hydrologic simulation models.