Assessing the elemental composition of comet 81P/Wild 2 by analyzing dust collected by Stardust

One of the prime objectives in the analysis of cometary dust collected by the Stardust space mission is to determine the elemental composition of comet 81P/Wild 2. For this analysis, samples captured by two sampling media, silica aerogel and Al foil, were available. While aerogel was qualified to sample the dust almost intact, particles impinging on Al foils produced hypervelocity impact craters with residual cometary matter. Both sample types delivered valuable information on the cometary inventory, even though a slight loss of volatiles was observed for impact residues on Al foils. Altogether an elemental composition close to solar elemental abundances was observed, indicating that the early solar system was chemically rather homogeneous from the innermost regions close to the sun to the outer edge of the solar system, the presumed region of cometary origin.     

Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

Composition of the Volatile Material in Halley's Coma from In Situ Measurements

The investigation of the volatile material in the coma of comets is a key to understanding the origin of cometary material, the physical and chemical conditions in the early solar system, the process of comet formation, and the changes that comets have undergone during the last 4.6 billion years. So far, in situ investigations of the volatile constituents have been confined to a single comet, namely P/Halley in 1986. Although, the Giotto mission gave only a few hours of data from the coma, it has yielded a surprising amount of new data and has advanced cometary science by a large step. In the present article the most important results of the measurements of the volatile material of Halley's comet are summarized and an overview of the identified molecules is given. Furthermore, a list of identified radicals and unstable molecules is presented for the first time. At least one of the radicals, namely CH₂, seems to be present as such in the cometary ice. As an outlook to the future we present a list of open questions concerning cometary volatiles and a short preview on the next generation of mass spectrometers that are being built for the International Rosetta Mission to explore the coma of Comet Wirtanen. This revised version was published online in June 2006 with corrections to the Cover Date.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Studies of Comets in the Ultraviolet: The Past and the Future

The remote sensing of comets in the ultraviolet bandpass has been a valuable tool for studying the structure, composition, variability, and physical processes at work in cometary comae. By extension, these studies of comae have revealed key insights into the composition of cometary nuclei. Here we briefly review the ultraviolet studies of comets, and then take a look toward the future of such work as anticipated by the advent of several key new instruments. This revised version was published online in June 2006 with corrections to the Cover Date.     

Interstellar Reservoirs of Cometary Matter

We review the evidence for the products of interstellar chemistry in volatile cometary matter. We compare the organic inventory of star-forming cores with that measured in various comets and point out the similarities and differences. The conditions necessary to fractionate interstellar molecules in the heavier isotopes of H, C, O and N are summarised and compared to the measured fractionation ratios in cometary ices. We give a list of future measurements that would shed further light on the putative connection between cometary and interstellar molecules.     

Spectroscopic characterization of cometary samples

After presenting a summary of what is presently known from cometary vibrational spectroscopy, we discuss briefly some possible results to be anticipated from future non-sample-retum cometary missions which, however, will leave a number of key questions unanswered. Major efforts have to be made in the laboratory to properly prepare the analysis of returned cometary samples. We report, in particular, on Raman spectroscopy of cometary analogs (frozen gases and irradiated organic materials) performed in our laboratory applying sufficiently low laser power so as not to significantly alter the sample. Also discussed are our attempts to use REELS (Reflection Electron Energy Loss Spectroscopy) which may yield information not only on the elemental composition of the sample but also on its optical constants, especially in the far UV region.     

Ion Irradiation and the Origin of Cometary Materials

For about 20 years laboratory research has been carried out on the effects induced by energetic ions on materials (ices, silicates, carbons) of cometary relevance. Here I present some recent results and outline the relevance such laboratory investigations might have for understanding the origin of cometary materials. This revised version was published online in June 2006 with corrections to the Cover Date.     

The ionospheres and plasma tails of comets

The present understanding of cometary ionospheres and plasma tails is critically evaluated. Following a brief introduction of the significance of the study of cometary ionospheres and tails (Section 1), the observational statistics and spectroscopic observations are summarized in Sections 2 and 3.The complicated and time varying morphology of the plasma tail and the ionosphere as revealed both by photographs as well as visual drawings is discussed in Section 4.The evidence for a strong comet-solar wind interaction, the possible nature of this interaction and also the use of comets as probes of the solar wind are considered in the next 3 sections (5, 6, 7). This is followed by a discussion of the various processes so far proposed for the ionization of cometary gases and their limitations (Section 8).Hydrodynamic models of the solar wind-comet interaction, which refers essentially to the region outside the tangential discontinuity, are presented and evaluated in Section 9. A discussion of the ion chemistry and structure of the region inside the tangential discontinuity (which is here referred to as the cometary ionosphere) follows in Section 10.The largely indirect evidence for the existence of substantial magnetic fields in cometary ionospheres and type 1 tails is evaluated and their likely origin is considered in Section 11. The associated electric currents; their size and closure as well as their importance as sources of ionization in the inner coma are also discussed.Finally in Section 12, some of the directions in which future research should progress, in order to provide a more complete and secure knowledge of cometary ionospheres and plasma tails, are stressed.     

Perspectives on the Comet-Asteroid-Meteorite Link

We discuss the possibility that CI and CM carbonaceous chondrites are fragments of extinct cometary nuclei. Theoretical and observational work suggests that comets evolve into asteroids, and several extinct cometary nuclei are now suspected to be among the near Earth object population. This population is the most likely source of meteorites and consequently, we may expect that some meteorites are from extinct comets in this population. The mineralogy and chemistry of CI and CM chondrites is consistent with the view that they originate from asteroidal objects of carbonaceous spectral classes, and these objects in turn may have a cometary origin. We do not suggest that CI or CM chondrites are directly delivered by active comets during perihelion passage or that these chondrites come from cometary debris in meteor streams. Instead, we summarize arguments suggesting that CI and CM chondrites represent fragments of cometary nuclei which evolved into near Earth asteroids after losing their volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

From interstellar matter to comets: Elemental abundances in interstellar dust and in comet Halley

Analogies between interstellar and cometary matter can be found in their chemical compositions, both in the gaseous and solid phases, but also in the physical processes involved like evidence for ion-molecules reactions at low temperature and for ice irradiation processes. Such analogies can be observed from 3 types of measurements: interstellar spectra, cometary observations, and analyses of interplanetary dust particles, with the help of laboratory simulation experiments. Taking into account all the present available information, a compilation of the elemental abundances in interstellar matter and in comet Halley is derived, without any assumption about the dust to gas ratio. It is found that there is a significant apparent depletion of nitrogen, presently unexplained, in both interstellar and cometary materials.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cosima – High Resolution Time-of-Flight Secondary Ion Mass Spectrometer for the Analysis of Cometary Dust Particles onboard Rosetta

The ESA mission Rosetta, launched on March 2nd, 2004, carries an instrument suite to the comet 67P/Churyumov-Gerasimenko. The COmetary Secondary Ion Mass Anaylzer – COSIMA – is one of three cometary dust analyzing instruments onboard Rosetta. COSIMA is based on the analytic measurement method of secondary ion mass spectrometry (SIMS). The experiment’s goal is in-situ analysis of the elemental composition (and isotopic composition of key elements) of cometary grains. The chemical characterization will include the main organic components, present homologous and functional groups, as well as the mineralogical and petrographical classification of the inorganic phases. All this analysis is closely related to the chemistry and history of the early solar system. COSIMA covers a mass range from 1 to 3500 amu with a mass resolution m/Δm @ 50% of 2000 at mass 100 amu. Cometary dust is collected on special, metal covered, targets, which are handled by a target manipulation unit. Once exposed to the cometary dust environment, the collected dust grains are located on the target by a microscopic camera. A pulsed primary indium ion beam (among other entities) releases secondary ions from the dust grains. These ions, either positive or negative, are selected and accelerated by electrical fields and travel a well-defined distance through a drift tube and an ion reflector. A microsphere plate with dedicated amplifier is used to detect the ions. The arrival times of the ions are digitized, and the mass spectra of the secondary ions are calculated from these time-of-flight spectra. Through the instrument commissioning, COSIMA took the very first SIMS spectra of the targets in space. COSIMA will be the first instrument applying the SIMS technique in-situ to cometary grain analysis as Rosetta approaches the comet 67P/Churyumov-Gerasimenko, after a long journey of 10 years, in 2014.     

Isotopic analysis of cometary organic matter

Carbon isotope ratios have been measured for CN in the coma of comet Halley and for several CHON particles emitted by Halley. Of these, only the CHON-particle data may be reasonably related to organic matter in the cometary nucleus, but the true range of ¹³C/¹²C values in those particles is quite uncertain. The D/H ratio in H₂O in the Halley coma resembles that in Titan/Uranus. The next decade should substantially improve our understanding of the distribution of C, H, N, and O isotopes in cometary organics. The isotopic composition of meteoritic organic matter is better understood and can serve as a useful analog for the cometary case.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

Sesame – An Experiment of the Rosetta Lander Philae: Objectives and General Design

SESAME is an instrument complex built in international co-operation and carried by the Rosetta lander Philae intended to land on comet 67P/Churyumov-Gerasimenko in 2014. The main goals of this instrument suite are to measure mechanical and electrical properties of the cometary surface and the shallow subsurface as well as of the particles emitted from the cometary surface. Most of the sensors are mounted within the six soles of the landing gear feet in order to provide good contact with or proximity to the cometary surface. The measuring principles, instrument designs, technical layout, operational concepts and the results from the first in-flight measurements are described. We conclude with comments on the consequences of the last minute change of the target comet and how to improve and to preserve the knowledge during the long-duration Rosetta mission.     

Comet Geology with Deep Impact Remote Sensing

The Deep Impact mission will provide the highest resolution images yet of a comet nucleus. Our knowledge of the makeup and structure of cometary nuclei, and the processes shaping their surfaces, is extremely limited, thus use of the Deep Impact data to show the geological context of the cratering experiment is crucial. This article briefly discusses some of the geological issues of cometary nuclei.     

Rocky Cometary Particulates: Their Elemental,Isotopic and Mineralogical Ingredients

The determination of the chemical composition of solid cometary dust particles was one of the prime objectives of the three missions to Comet Halley in 1986. The dust analysis was performed by time-of-flight mass-spectrometry. Within the experimental uncertainty the mean abundances of the rock-forming elements in cometary dust particles are comparable to their abundances in CI-chondrites and in the solar photosphere, i.e. they are cosmic. H, C, and N, on the other hand, in cometary dust are significantly more abundant than in CI-chondrites, approach solar abundances, are to some extent related to O, and reside in an omnipresent refractory organic component dubbed CHON. Element variations between individual dust grains are characterized by correlations of Mg, Si, and O, and to a lesser extent of Fe and S. From particle-to-particle variations of the rock forming elements information on the mineralogy of cometary dust can be obtained. Cluster analysis revealed certain groups that partly match the classifications of stratospheric interplanetary dust particles. About half of Halley's analyzed particles are characterized by anhydrous Fe-poor Mg-silicates, Fe-sulfides, and rarely Fe metal. The Fe-poor Mg-silicates link Halley's dust to that of Hale-Bopp as shown by recent IR observations. No significant deviation from normal of the isotopic composition of the elements is unequivocally present with the notable exception carbon: ¹²C-rich grains with ¹²C/¹³C-ratios up to ≈ 5,000 link cometary dust to presolar circumstellar grains identified in certain chondrites. This revised version was published online in June 2006 with corrections to the Cover Date.