Core Formation and Mantle Differentiation on Mars

Geochemical investigation of Martian meteorites (SNC meteorites) yields important constraints on the chemical and geodynamical evolution of Mars. These samples may not be representative of the whole of Mars; however, they provide constraints on the early differentiation processes on Mars. The bulk composition of Martian samples implies the presence of a metallic core that formed concurrently as the planet accreted. The strong depletion of highly siderophile elements in the Martian mantle is only possible if Mars had a large scale magma ocean early in its history allowing efficient separation of a metallic melt from molten silicate. The solidification of the magma ocean created chemical heterogeneities whose ancient origin is manifested in the heterogeneous ¹⁴²Nd and ¹⁸²W abundances observed in different meteorite groups derived from Mars. The isotope anomalies measured in SNC meteorites imply major chemical fractionation within the Martian mantle during the life time of the short-lived isotopes ¹⁴⁶Sm and ¹⁸²Hf. The Hf-W data are consistent with very rapid accretion of Mars within a few million years or, alternatively, a more protracted accretion history involving several large impacts and incomplete metal-silicate equilibration during core formation. In contrast to Earth early-formed chemical heterogeneities are still preserved on Mars, albeit slightly modified by mixing processes. The preservation of such ancient chemical differences is only possible if Mars did not undergo efficient whole mantle convection or vigorous plate tectonic style processes after the first few tens of millions of years of its history.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

An Oxygen Isotope Mixing Model for the Accretion and Composition of Rocky Planets

The oxygen isotope systematics in planetary and nebular matter are used to constrain the types of nebular material accreted to form a planet. The basic assumption of this model is that the mean oxygen isotopic composition of a planet is determined by the weighted mean oxygen isotopic composition of nebular matter accreted by the planet. Chondrites are taken as representatives of nebular matter. The chemical composition (which determines core size, mantle oxidation state, density, moment of inertia) of a planet results from the weighted mean compositions of the accreted nebular material, once the mass fractions of the different types of accreting matter are known. Here some results for Earth, Moon, Mars, and Vesta are discussed. The model implies that loss of volatile elements, such as alkalis and halogens, occurs during accretion and early planetary differentiation (e. g., by catastrophic impacts). The possible depletion mechanisms of moderately volatile elements are discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

Water and Volatile Inventories of Mercury,Venus, the Moon,and Mars

We review the geochemical observations of water, \(\mbox{D}/\mbox{H}\) and volatile element abundances of the inner Solar System bodies, Mercury, Venus, the Moon, and Mars. We focus primarily on the inventories of water in these bodies, but also consider other volatiles when they can inform us about water. For Mercury, we have no data for internal water, but the reducing nature of the surface of Mercury would suggest that some hydrogen may be retained in its core. We evaluate the current knowledge and understanding of venusian water and volatiles and conclude that the venusian mantle was likely endowed with as much water as Earth of which it retains a small but non-negligible fraction. Estimates of the abundance of the Moon’s internal water vary from Earth-like to one to two orders of magnitude more depleted. Cl, K, and Zn isotope anomalies for lunar samples argue that the giant impact left a unique geochemical fingerprint on the Moon, but not the Earth. For Mars, an early magma ocean likely generated a thick crust; this combined with a lack of crustal recycling mechanisms would have led to early isolation of the Martian mantle from later delivery of water and volatiles from surface reservoirs or late accretion. The abundance estimates of Martian mantle water are similar to those of the terrestrial mantle, suggesting some similarities in the water and volatile inventories for the terrestrial planets and the Moon.     

Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

ARTEMIS Science Objectives

NASA??s two spacecraft ARTEMIS mission will address both heliospheric and planetary research questions, first while in orbit about the Earth with the Moon and subsequently while in orbit about the Moon. Heliospheric topics include the structure of the Earth??s magnetotail; reconnection, particle acceleration, and turbulence in the Earth??s magnetosphere, at the bow shock, and in the solar wind; and the formation and structure of the lunar wake. Planetary topics include the lunar exosphere and its relationship to the composition of the lunar surface, the effects of electric fields on dust in the exosphere, internal structure of the Moon, and the lunar crustal magnetic field. This paper describes the expected contributions of ARTEMIS to these baseline scientific objectives.     

On the Isotopic Composition of Primordial Xenon in Terrestrial Planet Atmospheres

Xenon plays a crucial role in models of atmospheric evolution in which noble gases are fractionated from their initial compositions to isotopically heavier distributions by early hydrodynamic escape of primordial planetary atmospheres. With the assumption that nonradiogenic Xe isotope ratios in present-day atmospheres were generated in this way, backward modeling from these ratios through the fractionating process can in principle identify likely parental Xe compositions and thus the probable sources of noble gases in pre-escape atmospheres. Applied to Earth, this approach simultaneously establishes the presence of an atmospheric Xe component due principally to fission of extinct ²⁴⁴Pu and identifies a composition called U-Xe as primordial Xe. Pu-Xe comprises 4.65±0.30% of atmospheric ¹³⁶Xe, and 6.8±0.5% of the present abundance of ¹²⁹Xe derives from decay of extinct ¹²⁹I. U-Xe is identical to the measured composition of solar-wind Xe except for deficits of the two heaviest isotopes – an unexpected difference since the modeling otherwise points to solar wind compositions for the lighter noble gases in the primordial terrestrial atmosphere. Evidence for the presence of U-Xe is not restricted to the early Earth; modeling based on a purely meteoritic data set defines a parental component in chondrites and achondrites with the same isotopic distribution. Results of experimental efforts to measure this composition directly in meteorites are promising but not yet conclusive. U-Xe also appears as a possible base component in interstellar silicon carbide, here with superimposed excesses of ¹³⁴Xe and ¹³⁶Xe six-fold larger than those in the solar wind. These compositional differences imply mixing of U-Xe with a nucleogenetic heavy-isotope component whose relative abundance in the solar accretion disk and in pre-solar environments varied both spatially and temporally. In contrast to Earth, the U-Xe signature on Mars was apparently overwhelmed by local accretion of materials rich in either chondritic Xe or solar-wind Xe. Data currently in hand from SNC meteorites on the composition of the present atmosphere are insufficiently precise to constrain a modeling choice between these two candidates for primordial martian Xe. They likewise do not permit definitive resolution of a ²⁴⁴Pu component in the atmosphere although its presence is allowed within current measurement uncertainties. This revised version was published online in June 2006 with corrections to the Cover Date.     

Thermal Evolution and Magnetic Field Generation in Terrestrial Planets and Satellites

Of the terrestrial planets, Earth and Mercury have self-sustained fields while Mars and Venus do not. Magnetic field data recorded at Ganymede have been interpreted as evidence of a self-generated magnetic field. The other icy Galilean satellites have magnetic fields induced in their subsurface oceans while Io and the Saturnian satellite Titan apparently are lacking magnetic fields of internal origin altogether. Parts of the lunar crust are remanently magnetized as are parts of the crust of Mars. While it is widely accepted that the magnetization of the Martian crust has been caused by an early magnetic field, for the Moon alternative explanations link the magnetization to plasma generated by large impacts. The necessary conditions for a dynamo in the terrestrial planets and satellites are the existence of an iron-rich core that is undergoing intense fluid motion. It is widely accepted that the fluid motion is caused by convection driven either by thermal buoyancy or by chemical buoyancy or by both. The chemical buoyancy is released upon the growth of an inner core. The latter requires a light alloying element in the core that is enriched in the outer core as the solid inner core grows. In most models, the light alloying element is assumed to be sulfur, but other elements such as, e.g., oxygen, silicon, and hydrogen are possible. The existence of cores in the terrestrial planets is either proven beyond reasonable doubt (Earth, Mars, and Mercury) or the case for a core is compelling as for Venus and the Moon. The Galilean satellites Io and Ganymede are likely to have cores judging from Galileo radio tracking data of the gravity fields of these satellites. The case is less clear cut for Europa. Callisto is widely taken as undifferentiated or only partially differentiated, thereby lacking an iron-rich core. Whether or not Titan has a core is not known at the present time. The terrestrial planets that do have magnetic fields either have a well-established inner core with known radius and density such as Earth or are widely agreed to have an inner core such as Mercury. The absence of an inner core in Venus, Mars, and the Moon (terrestrial bodies that lack fields) is not as well established although considered likely. The composition of the Martian core may be close to the Fe–FeS eutectic which would prevent an inner core to grow as long as the core has not cooled to temperatures around 1500 Kelvin. Venus may be on the verge of growing an inner core in which case a chemical dynamo may begin to operate in the geologically near future. The remanent magnetization of the Martian and the lunar crust is evidence for a dynamo in Mars’ and possibly the Moon’s early evolution and suggests that powerful thermally driven dynamos are possible. Both the thermally and the chemically driven dynamo require that the core is cooled at a sufficient rate by the mantle. For the thermally driven dynamo, the heat flow from the core into the mantle must by larger than the heat conducted along the core adiabat to allow a convecting core. This threshold is a few mW?m^?2 for small planets such as Mercury, Ganymede, and the Moon but can be as large as a few tens mW?m^?2 for Earth and Venus. The buoyancy for both dynamos must be sufficiently strong to overcome Ohmic dissipation. On Earth, plate tectonics and mantle convection cool the core efficiently. Stagnant lid convection on Mars and Venus are less efficient to cool the core but it is possible and has been suggested that Mars had plate tectonics in its early evolution and that Venus has experienced episodic resurfacing and mantle turnover. Both may have had profound implications for the evolution of the cores of these planets. It is even possible that inner cores started to grow in Mars and Venus but that the growth was frustrated as the mantles heated following the cessation of plate tectonics and resurfacing. The generation of Ganymede’s magnetic field is widely debated. Models range from magneto-hydrodynamic convection in which case the field will not be self-sustained to chemical and thermally-driven dynamos. The wide range of possible compositions for Ganymede’s core allows models with a completely liquid near eutectic Fe–FeS composition as well as models with Fe inner cores or cores in with iron snowfall.     

Short-Lived Radioactivities and the Birth of the sun

Now extinct short-lived radioactive isotopes were apparently extant in the early solar system. Their abundances can be inferred from isotopic effects in their daughter nuclei in primitive meteorites, and the deviation of these abundances from expectations from continuous galactic nucleosynthesis yields important information on the last nucleosynthetic events that contributed new nuclei to the solar system and on the general circumstances of the Sun's birth. In this paper we present a rudimentary model that attempts to reconcile the abundances of ten short-lived radioactivities in the early solar system. In broad outlines, the picture requires 1) that Type Ia supernovae maintained a steady ISM supply of ⁵³Mn and ¹⁴⁶Sm, 2) that the r-process events that slowly admixed new ¹⁰⁷Pd, ¹²⁹I, ¹⁸²Hf, and ²⁴⁴Pu nuclei to the solar system occurred over an interval of several hundred million years prior to solar system formation, and 3) that a massive star, by injecting only material outside its helium-exhausted core into the proto-solar nebula, contributed ²⁶Al, ³⁶Cl, ⁴¹Ca, ⁶⁰Fe, and ¹⁸²Hf no more than one million years prior to the Sun's birth. In this picture, the live ¹⁸²Hf present in the early solar system was not due to r-process production but rather to a fast s-process in helium or carbon burning shell in the massive star. We conclude with a possible chemical-memory explanation for the putative ⁵³Cr/⁵²Cr gradient in the solar system. This revised version was published online in June 2006 with corrections to the Cover Date.     

Solar and Solar-Wind Composition Results from the Genesis Mission

The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and ¹⁵N/¹⁴N and ¹⁸O/¹⁷O/¹⁶O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.     

Planetary Magnetic Fields and Solar Forcing: Implications for Atmospheric Evolution

The solar wind and the solar XUV/EUV radiation constitute a permanent forcing of the upper atmosphere of the planets in our solar system, thereby affecting the habitability and chances for life to emerge on a planet. The forcing is essentially inversely proportional to the square of the distance to the Sun and, therefore, is most important for the innermost planets in our solar system—the Earth-like planets. The effect of these two forcing terms is to ionize, heat, chemically modify, and slowly erode the upper atmosphere throughout the lifetime of a planet. The closer to the Sun, the more efficient are these process. Atmospheric erosion is due to thermal and non-thermal escape. Gravity constitutes the major protection mechanism for thermal escape, while the non-thermal escape caused by the ionizing X-rays and EUV radiation and the solar wind require other means of protection. Ionospheric plasma energization and ion pickup represent two categories of non-thermal escape processes that may bring matter up to high velocities, well beyond escape velocity. These energization processes have now been studied by a number of plasma instruments orbiting Earth, Mars, and Venus for decades. Plasma measurement results therefore constitute the most useful empirical data basis for the subject under discussion. This does not imply that ionospheric plasma energization and ion pickup are the main processes for the atmospheric escape, but they remain processes that can be most easily tested against empirical data. Shielding the upper atmosphere of a planet against solar XUV, EUV, and solar wind forcing requires strong gravity and a strong intrinsic dipole magnetic field. For instance, the strong dipole magnetic field of the Earth provides a “magnetic umbrella”, fending of the solar wind at a distance of 10 Earth radii. Conversely, the lack of a strong intrinsic magnetic field at Mars and Venus means that the solar wind has more direct access to their topside atmosphere, the reason that Mars and Venus, planets lacking strong intrinsic magnetic fields, have so much less water than the Earth? Climatologic and atmospheric loss process over evolutionary timescales of planetary atmospheres can only be understood if one considers the fact that the radiation and plasma environment of the Sun has changed substantially with time. Standard stellar evolutionary models indicate that the Sun after its arrival at the Zero-Age Main Sequence (ZAMS) 4.5 Gyr ago had a total luminosity of ≈70% of the present Sun. This should have led to a much cooler Earth in the past, while geological and fossil evidence indicate otherwise. In addition, observations by various satellites and studies of solar proxies (Sun-like stars with different age) indicate that the young Sun was rotating more than 10 times its present rate and had correspondingly strong dynamo-driven high-energy emissions which resulted in strong X-ray and extreme ultraviolet (XUV) emissions, up to several 100 times stronger than the present Sun. Further, evidence of a much denser early solar wind and the mass loss rate of the young Sun can be determined from collision of ionized stellar winds of the solar proxies, with the partially ionized gas in the interstellar medium. Empirical correlations of stellar mass loss rates with X-ray surface flux values allows one to estimate the solar wind mass flux at earlier times, when the solar wind may have been more than 1000 times more massive. The main conclusions drawn on basis of the Sun-in-time-, and a time-dependent model of plasma energization/escape is that:

1. Solar forcing is effective in removing volatiles, primarily water, from planets,
2. planets orbiting close to the early Sun were subject to a heavy loss of water, the effect being most profound for Venus and Mars, and
3. a persistent planetary magnetic field, like the Earth’s dipole field, provides a shield against solar wind scavenging.

     

Are There Chemical Gradients in the Inner Solar System?

The solar system is apparently stratified with regard to the contents of volatile constituents, as judged from the rocky, volatile-poor inner solar system planets and meteorites and the huge volatile-rich outer planets. However, beyond this gross structure there is no evidence for a systematic increase of the volatiles' abundances with distance from the Sun. Although meteorites show comparatively large differences in volatile element contents they also differ in many other respects, such as Mg/Si-ratios, bulk Fe and refractory element contents. These variations reflect variations in the nebular environment from which meteorites formed. The various conditions of meteorite formation cannot, however, be related in a simple way to heliocentric distances. There are also no systematic variations in the chemistry of the inner planets Mercury, Venus, Earth, Moon, Mars, and including the fourth largest asteroid Vesta, that could be interpreted as a relationship between volatility and composition. Although Mars (as judged from the composition of Martian meteorites) is more oxidized and contains more volatile elements than Earth, this trend cannot be extrapolated to the dry volatile poor Vesta (sampled by HED meteorites) in the asteroid belt. If the Earth-Mars trend reflects global inner solar system gradients then Vesta must have formed inside Earth's orbit and moved out later to its present location. The quality of Mercury and Venus composition data is not sufficient to allow reliable extrapolation to distances closer to the Sun. Recent nebula models predict small temperature gradients in the inner solar system supporting the view that no large variations in volatile element contents of inner solar system materials are expected. This revised version was published online in June 2006 with corrections to the Cover Date.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Chemistry,accretion, and evolution of Mars

The high FeO concentrations measured by VIKING for the Martian soils correspond to all probability to a FeO-rich mantle. In general, the VIKING XRF-data indicate a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust.In recent years evidence has been collected which points towards Mars being the parent body of SNC-meteorites and, hence, these meteorites have become a valuable source of information about the chemistry of Mars. Using element correlations observed in SNC-meteorites and general cosmochemical constraints, it is possible to estimated the bulk composition of Mars. Normalized to Si and Cl, the mean abundance value for the elements Ga, Fe, Na, P, K, F, and Rb in the Martian mantle is found to be 0.35 and thus exceeds the terrestrial value by about a factor of two. Aside pressure effects and the H₂O poverty, the high P and K content of the Martian mantle may lead to magmatic processes different from those on Earth.The composition of the Earth's mantle can successfully be described by a two component model. Component A: highly reduced and almost free of all elements more volatile than Na; component B: oxidized and containing all elements in Cl-abundances including volatile elements. The same two components can be used as building blocks for Mars, if one assumes that, contrary to the inhomogeneous accretion of the Earth, Mars accreted almost homogeneously. The striking depletion of all elements with chalcophile character indicates that chemical equilibrium between component A and B was achieved on Mars which lead to the formation of significant amounts of FeS which, on segregation, extracted the elements according to their sulphide-silicate partition coefficients. While for the Earth a mixing ratio AB = 8515 was derived, the Mars ratio of 6040 reflects the higher concentrations of moderately volatile elements like Na, K, and sulphur on Mars. A homogeneous accretion of Mars could also explain the obvious low abundances of water and primordial rare gases.     

Atmosphere Impact Losses

Determining the origin of volatiles on terrestrial planets and quantifying atmospheric loss during planet formation is crucial for understanding the history and evolution of planetary atmospheres. Using geochemical observations of noble gases and major volatiles we determine what the present day inventory of volatiles tells us about the sources, the accretion process and the early differentiation of the Earth. We further quantify the key volatile loss mechanisms and the atmospheric loss history during Earth’s formation. Volatiles were accreted throughout the Earth’s formation, but Earth’s early accretion history was volatile poor. Although nebular Ne and possible H in the deep mantle might be a fingerprint of this early accretion, most of the mantle does not remember this signature implying that volatile loss occurred during accretion. Present day geochemistry of volatiles shows no evidence of hydrodynamic escape as the isotopic compositions of most volatiles are chondritic. This suggests that atmospheric loss generated by impacts played a major role during Earth’s formation. While many of the volatiles have chondritic isotopic ratios, their relative abundances are certainly not chondritic again suggesting volatile loss tied to impacts. Geochemical evidence of atmospheric loss comes from the \({}^{3}\mathrm{He}/{}^{22}\mathrm{Ne}\), halogen ratios (e.g., F/Cl) and low H/N ratios. In addition, the geochemical ratios indicate that most of the water could have been delivered prior to the Moon forming impact and that the Moon forming impact did not drive off the ocean. Given the importance of impacts in determining the volatile budget of the Earth we examine the contributions to atmospheric loss from both small and large impacts. We find that atmospheric mass loss due to impacts can be characterized into three different regimes: 1) Giant Impacts, that create a strong shock transversing the whole planet and that can lead to atmospheric loss globally. 2) Large enough impactors (\(m_{\mathit{cap}} \gtrsim \sqrt{2} \rho_{0} (\pi h R)^{3/2}\), \(r_{\mathit{cap}}\sim25~\mbox{km}\) for the current Earth), that are able to eject all the atmosphere above the tangent plane of the impact site, where \(h\), \(R\) and \(\rho_{0}\) are the atmospheric scale height, radius of the target, and its atmospheric density at the ground. 3) Small impactors (\(m_{\mathit{min}}>4 \pi\rho_{0} h^{3}\), \(r_{\mathit {min}}\sim 1~\mbox{km}\) for the current Earth), that are only able to eject a fraction of the atmospheric mass above the tangent plane. We demonstrate that per unit impactor mass, small impactors with \(r_{\mathit{min}} < r < r_{\mathit{cap}}\) are the most efficient impactors in eroding the atmosphere. In fact for the current atmospheric mass of the Earth, they are more than five orders of magnitude more efficient (per unit impactor mass) than giant impacts, implying that atmospheric mass loss must have been common. The enormous atmospheric mass loss efficiency of small impactors is due to the fact that most of their impact energy and momentum is directly available for local mass loss, where as in the giant impact regime a lot of energy and momentum is ’wasted’ by having to create a strong shock that can transverse the entirety of the planet such that global atmospheric loss can be achieved. In the absence of any volatile delivery and outgassing, we show that the population of late impactors inferred from the lunar cratering record containing 0.1% \(M_{\oplus }\) is able to erode the entire current Earth’s atmosphere implying that an interplay of erosion, outgassing and volatile delivery is likely responsible for determining the atmospheric mass and composition of the early Earth. Combining geochemical observations with impact models suggest an interesting synergy between small and big impacts, where giant impacts create large magma oceans and small and larger impacts drive the atmospheric loss.     

Transforming Dust to Planets

We review recent progress in understanding how nebular dust and gas are converted into the planets of the present-day solar system, focusing particularly on the “Grand Tack” and pebble accretion scenarios. The Grand Tack can explain the observed division of the solar system into two different isotopic “flavours”, which are found in both differentiated and undifferentiated meteorites. The isotopic chronology inferred for the development of these two “flavours” is consistent with expectations of gas-giant growth and nebular gas loss timescales. The Grand Tack naturally makes a small Mars and a depleted, dynamically-excited and compositionally mixed asteroid belt (as observed); it builds both Mars and the Earth rapidly, which is consistent with the isotopically-inferred growth timescale of the former, but not the latter. Pebble accretion can explain the rapid required growth of Jupiter and Saturn, and the number of Kuiper Belt binaries, but requires specific assumptions to explain the relatively protracted growth timescale of Earth. Pure pebble accretion cannot explain the mixing observed in the asteroid belt, the fast proto-Earth spin rate, or the tilt of Uranus. No current observation requires pebble accretion to have operated in the inner solar system, but the thermal and compositional consequences of pebble accretion have yet to be explored in detail.     

Planetary Radiation Budgets

The energy state of a planet depends fundamentally on its radiation budget. Measurements made from space over past decades have led to significant revisions of ground-based estimates, both of the reflected fraction (the Bond albedo) of solar radiative flux and of the emitted thermal infrared radiation flux, for the Earth as well as for the other planets. After a brief survey of methods and difficulties in accurately determining planetary radiation budgets, we note contradictions in existing tabulations of global parameters, in particular Bond albedo. For the Earth, such contradictions are unjustified, considering that global and annual means as well as the seasonal cycle of Earth Radiation Budget components have now been determined with high accuracy. The Earth's Bond albedo is close to 0.3. Net storage of energy in the Earth-ocean system is close to zero, with a well-established annual cycle of amplitude close to ±12 Wm⁻². Some contradictions remain for the other terrestrial planets. For the giant planets, modern reduced values of the Bond albedo imply reduced but still significant internal energy generation.     

Stable Isotope Ratios as a Biomarker on Mars

As both Earth and Mars have had similar environmental conditions at least for some extended time early in their history (Jakosky and Phillips in Nature 412:237–244, 2001), the intriguing question arises whether life originated and evolved on Mars as it did on Earth (McKay and Stoker in Rev. Geophys. 27:189–214, 1989). Conceivably, early autotrophic life on Mars, like early life on Earth, used irreversible enzymatically enhanced metabolic processes that would have fractionated stable isotopes of the elements C, N, S, and Fe. Several important assumptions are made when such isotope fractionations are used as a biomarker. The purpose of this article is two-fold: (1) to discuss these assumptions for the case of carbon and to summarize new insights in abiologic reactions, and (2) to discuss the use of other stable isotope systems as a potential biomarker. It is concluded that isotopic biomarker studies on Mars will encounter several important obstacles. In the case of carbon isotopes, the most important obstacle is the absence of a contemporary abiologic carbon reservoir (such as carbonate deposits on Earth) to act as isotopic standard. The presence of a contemporary abiologic sulfate reservoir (evaporite deposits) suggests that sulfur isotopes can be used as a potential biomarker for sulfate-reducing bacteria. The best approach for tracing ancient life on Mars will be to combine several biomarker approaches; to search for complexity, and to combine small-scale isotopic variations with chemical, mineralogical, and morphological observations. An example of such a study can be a layer-specific correlation between δ ¹³C and δ ³⁴S within an ancient Martian evaporite, which morphologically resembles the typical setting of a shallow marine microbial mat.     

Stratigraphy and Isotope Ages of Lunar Geologic Units: Chronological Standard for the Inner Solar System

The absolute ages of cratered surfaces in the inner solar system, including Mars, are derived by extrapolation from the impact flux curve for the Moon which has been calibrated on the basis of absolute ages of lunar samples. We reevaluate the lunar flux curve using isotope ages of lunar samples and the latest views on the lunar stratigraphy and the principles of relative and absolute age dating of geologic surface units of the Moon. The geological setting of the Apollo and Luna landing areas are described as far as they are relevant for this reevaluation. We derive the following best estimates for the ages of the multi-ring basins and their related ejecta blankets and present alternative ages for the basin events (in parentheses): 3.92 ± 0.03 Gyr (or 3.85 ± 0.05 Gyr) for Nectaris, 3.89 ± 0.02 Gyr (or 3.84 ± 0.04 Gyr) for Crisium, 3.89 ± 0.01 Gyr (or 3.87 ± 0.03 Gyr) for Serenitatis, and 3.85 ± 0.02 Gyr (or 3.77 ± 0.02 Gyr) for Imbrium. Our best estimates for the ages of the mare landing areas are: 3.80 ± 0.02 Gyr for Apollo 11 (old surface), 3.75 ± 0.01 Gyr for Apollo 17, 3.58 ± 0.01 Gyr for Apollo 11 (young surface), 3.41 ± 0.04 Gyr for Luna 16, 3.30 ± 0.02 Gyr for Apollo 15, 3.22 ± 0.02 Gyr for Luna 24, and 3.15 ± 0.04 Gyr for Apollo 12. The ages of Eratosthenian and Copernican craters remain: ～ 2.1 (?) Gyr (Autolycus), 800 ± 15 Myr (Copernicus), 109 ± 4 Myr (Tycho), 50.3 ± 0.8 (North Ray crater, Apollo 16), and 25.1 ± 1.2 (Cone crater, Apollo 14). When plotted against the crater densities of the relevant lunar surface units, these data result in a revised lunar impact flux curve which differs from the previously used flux curve in the following respects: (1) The ages of the stratigraphically most critical impact basins are notably younger, (2) the uncertainty of the calibration curve is decreased, especially in the age range from about 4.0 to 3.0 Gyr, (3) any curve for ages older than 3.95 Gyr (upper age limit of the Nectaris ejecta blanket) is abandoned because crater frequencies measured on such surface formations cannot be correlated with absolute ages obtained on lunar samples. Therefore, the impact flux curve for this pre-Nectarian time remains unknown. The new calibration curve for lunar crater retention ages less than about 3.9 Gyr provides an updated standard reference for the inner solar system bodies including Mars.     

The geologic development of Mars: A review

The planet Mars has been the subject of a continuing program of exploration with the flyby missions of 1964 and 1969, the orbiter of 1971, and the present Viking Project with both orbiters and landers. The overall view of Mars has changed from Earthlike in the prespacecraft era to Moonlike following the flyby missions and finally to a planet with intermediate characteristics. There are many impact craters as on the Moon, but tectonic and volcanic features resembling structures on Earth are also present. However, there is a lack of evidence for the compressional deformation associated with terrestrial plate tectonics and continental drift.The current analyses indicate that Mars has a differentiated interior with a crust and mantle and perhaps a core. Whatever the nature of interior processes, whether overall mantle expansion, plumes, or full scale convection, the effects at the surface have been predominantly vertical with formation of broad regions of uplift and depression. One of the results is hemispheric asymmetry with cratered terrain in the south and younger uncratered plains in the north.