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1.
The primary goal of the Genesis Mission is to collect solar wind ions and, from their analysis, establish key isotopic ratios that will help constrain models of solar nebula formation and evolution. The ratios of primary interest include 17O/16O and 18O/16O to ±0.1%, 15N/14N to ±1%, and the Li, Be, and B elemental and isotopic abundances. The required accuracies in N and O ratios cannot be achieved without concentrating the solar wind and implanting it into low-background target materials that are returned to Earth for analysis. The Genesis Concentrator is designed to concentrate the heavy ion flux from the solar wind by an average factor of at least 20 and implant it into a target of ultra-pure, well-characterized materials. High-transparency grids held at high voltages are used near the aperture to reject >90% of the protons, avoiding damage to the target. Another set of grids and applied voltages are used to accelerate and focus the remaining ions to implant into the target. The design uses an energy-independent parabolic ion mirror to focus ions onto a 6.2 cm diameter target of materials selected to contain levels of O and other elements of interest established and documented to be below 10% of the levels expected from the concentrated solar wind. To optimize the concentration of the ions, voltages are constantly adjusted based on real-time solar wind speed and temperature measurements from the Genesis ion monitor. Construction of the Concentrator required new developments in ion optics; materials; and instrument testing and handling. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

2.
The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and 15N/14N and 18O/17O/16O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.  相似文献   

3.
Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H2O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H2O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the 15N/14N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

4.
The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gy ago from the protosolar nebula. The solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. Data from space missions and theoretical models indicate that the isotopes of the volatile elements N, O, Ne, and Ar are fractionated by at most a few percent per atomic mass unit in different solar wind regimes. In contrast, isotopic abundances of solar and heliospheric energetic particles at energies larger than about 100 keV/amu are observed to strongly vary relative to solar abundances. Processes such as resonant acceleration or pre-acceleration by plasma waves, first-order Fermi acceleration, or propagation in the interplanetary plasma are discussed as causes for charge-to-mass dependent fractionation. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

5.
Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO2, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H2, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO2, N2 and H2O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O+ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×1024 g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.  相似文献   

6.
Using the high-resolution mass spectrometer CELIAS/MTOF on board SOHO we have measured the solar wind isotope abundance ratios of Si, Ne, and Mg and their variations in different solar wind regimes with bulk velocities ranging from 330 km/s to 650 km/s. Data indicate a small systematic depletion of the heavier isotopes in the slow solar wind on the order of (1.4±1.3)% per amu (2σ-error) compared to their abundances in the fast solar wind from coronal holes. These variations in the solar wind isotopic composition represent a pure mass-dependent effect because the different isotopes of an element pass the inner corona with the same charge state distribution. The influence of particle mass on the acceleration of minor solar wind ions is discussed in the context of theoretical models and recent optical observations with other SOHO instruments. This revised version was published online in June 2006 with corrections to the Cover Date.  相似文献   

7.
The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the 20Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×106 K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.  相似文献   

8.
Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, 3He/4He (D+3He)/H, 20Ne/22Ne and 21Ne/22Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

9.
Although the elemental composition in all parts of the solar photosphere appears to be the same this is clearly not the case with the solar upper atmosphere (SUA). Spectroscopic studies show that in the corona elemental composition along solar equatorial regions is usually different from polar regions; composition in quiet Sun regions is often different from coronal hole and active region compositions and the transition region composition is frequently different from the coronal composition along the same line of sight. In the following two issues are discussed. The first involves abundance ratios between the high-FIP O and Ne and the low-FIP Mg and Fe that are important for meaningful comparisons between photospheric and SUA compositions and the second involves a review of composition and time variability of SUA plasmas at heights of 1.0≤h≤1.5R .  相似文献   

10.
This is the first study of the isotopic composition of solar wind helium with the SWICS time-of flight mass spectrometer. Although the design of SWICS is not optimized to measure3He abundances precisely,4He/3He flux ratios can be deduced from the data. The long term ratio is 2290±200, which agrees with the results obtained with the ICI magnetic mass spectrometer on ISEE-3 and with the Apollo SWC foil experiments.The ULYSSES spacecraft follows a trajectory which is ideal for the study of different solar wind types. During one year, from mid-1992 to mid-1993, it was in a range of heliographic latitudes where a recurrent fast stream from the southern polar coronal hole was observed every solar rotation. Solar wind bulk velocities ranged from 350 km/s to 950 km/s which would, in principle allow us to identify velocity-correlated compositional variations. Our investigation of solar wind helium, however, shows an isotopic ratio which does not depend on the solar wind speed.  相似文献   

11.
We discuss data of light noble gases from the solar wind implanted into a metallic glass target flown on the Genesis mission. Helium and neon isotopic compositions of the bulk solar wind trapped in this target during 887 days of exposure to the solar wind do not deviate significantly from the values in foils of the Apollo Solar Wind Composition experiments, which have been exposed for hours to days. In general, the depth profile of the Ne isotopic composition is similar to those often found in lunar soils, and essentially very well reproduced by ion-implantation modelling, adopting the measured velocity distribution of solar particles during the Genesis exposure and assuming a uniform isotopic composition of solar wind neon. The results confirm that contributions from high-energy particles to the solar wind fluence are negligible, which is consistent with in-situ observations. This makes the enigmatic “SEP-Ne” component, apparently present in lunar grains at relatively large depth, obsolete. 20Ne/ 22Ne ratios in gas trapped very near the metallic glass surface are up to 10% higher than predicted by ion implantation simulations. We attribute this superficially trapped gas to very low-speed, current-sheet-related solar wind, which has been fractionated in the corona due to inefficient Coulomb drag.  相似文献   

12.
Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.  相似文献   

13.
The composition of the solar wind is largely determined by the composition of the source material, i.e. the present-day composition of the outer convective zone. It is then modified by the processes which operate in the transition region and in the inner corona. In situ measurements of the solar wind composition give a unique opportunity to obtain information on the isotopic and elemental composition of the Sun. However, elemental — and to some degree also isotopic — fractionation can occur in the flow of matter from the outer convective zone into the interplanetary space. The most important examples of elemental fractionation are the well-known FIP/FIT effect (First Ionization Potential/Time) and the sometimes dramatic variations of the helium abundance relative to hydrogen in the solar wind. A thorough investigation of fractionation processes which cause compositional variations in different solar wind regimes is necessary to make inferences about the solar source composition from solar wind observations. Our understanding of these processes is presently improving thanks to the detailed diagnostics offered by the optical instrumentation on SOHO. Correlated observations of particle instruments on Ulysses, WIND, and SOHO, together with optical observations will help to make inferences for the solar composition. Continuous in situ observations of several isotopic species with the particle instruments on WIND and SOHO are currently incorporated into an experimental database to infer isotopic fractionation processes which operate in different solar wind regimes between the solar surface and the interplanetary medium. Except for the relatively minor effects of secular gravitational sedimentation which works at the boundary between the outer convective zone and the radiative zone, refractory elements such as Mg can be used as faithful witnesses to monitor the magnitude of these processes. With theoretical considerations it is possible to make inferences about the importance of isotopic fractionation in the solar wind from a comparison of optical and in situ observations of elemental fractionation with the corresponding models. Theoretical models and preliminary results from particle observations indicate that the combined isotope effects do not exceed a few percent per mass unit. In the worst case, which concerns the astrophysically important 3He/4He ratio, we expect an overall effect of at most several percent in the sense of a systematic depletion of the heavier isotope. Continued observations with WIND, SOHO, and ACE, and, with the revival of the foil technique, with the upcoming Genesis mission will further consolidate our knowledge about the relation between solar wind dynamics and solar wind composition. This revised version was published online in June 2006 with corrections to the Cover Date.  相似文献   

14.
Recent observations with UVCS on SOHO of high outflow velocities of O5+ at low coronal heights have spurred much discussion about the dynamics of solar wind acceleration. On the other hand, O6+ is the most abundant oxygen charge state in the solar wind, but is not observed by UVCS or by SUMER because this helium-like ion has no emission lines falling in the wave lengths observable by these instruments. Therefore, there is considerable interest in observing O5+ in situ in order to understand the relative importance of O5+ with respect to the much more abundant O6+. High speed streams are the prime candidates for the search for O5+ because all elements exhibit lower freezing-in temperatures in high speed streams than in the slow solar wind. The Ulysses spacecraft was exposed to long time periods of high speed streams during its passage over the polar regions of the Sun. The Solar Wind Ion Composition Spectrometer (SWICS) on Ulysses is capable of resolving this rare oxygen charge state. We present the first measurement of O5+ in the solar wind and compare these data with those of the more abundant oxygen species O6+ and O7+. We find that our observations of the oxygen charge states can be fitted with a single coronal electron temperature in the range of 1.0 to 1.2 MK assuming collisional ionization/recombination equilibrium with an ambient Maxwellian electron gas. This revised version was published online in June 2006 with corrections to the Cover Date.  相似文献   

15.
The most significant information about fields and plasmas in the outer solar system, based on observations by Pioneer 10 and 11 investigations, is reviewed. The characteristic evolution of solar wind streams beyond 1 AU has been observed. The region within which the velocity increases continuously near 1 AU is replaced at larger distances by a thick interaction region with abrupt jumps in the solar wind speed at the leading and trailing edges. These abrupt increases, accompanied by corresponding jumps in the field magnitude and in the solar wind density and temperature, consist typically of a forward and a reverse shock. The existence of two distinct corotating regions, separated by sharp boundaries, is a characteristic feature of the interplanetary medium in the outer solar system. Within the interaction regions, compression effects are dominant and the field strength, plasma density, plasma temperature and the level of fluctuations are enhanced. Within the intervening quiet regions, rarefaction effects dominate and the field magnitude, solar wind density and fluctuation level are very low. These changes in the structure of interplanetary space have significant consequences for the many energetic particles propagating through the medium. The interaction regions control the access to the inner solar system of relativistic electrons from Jupiter's magnetosphere. The interaction regions and shocks appear to be associated with an acceleration of solar protons to MeV energies. Flare-generated shocks are observed to be propagating through the outer solar system with constant speed, implying that the previously recognized deceleration of flare shocks takes place principally near the Sun. Radial gradients in the solar wind and interplanetary field parameters have been determined. The solar wind speed is nearly constant between 1 and 5 AU with only a slight deceleration of 30 km s+1 on the average. The proton flux follows an r +2 dependence reasonably well, however, the proton density shows a larger departure from this dependence. The proton temperature decreases steadily from 1 to 5 AU and the solar wind protons are slightly hotter than anticipated for an adiabatic expansion. The radial component of the interplanetary field falls off like r +2 and, on the average, the magnitude and spiral angle also agree reasonably well with theory. However, there is evidence, principally within quiet regions, of a significant departure of the azimuthal field component and the field magnitude from simple theoretical models. Pioneer 11 has obtained information up to heliographic latitudes of 16°. Observations of the interplanetary sector structure show that the polarity of the field becomes gradually more positive, corresponding to outward-directed fields at the Sun, and at the highest latitudes the sector structure disappears. These results confirm a prior suspicion that magnetic sectors are associated with an interplanetary current sheet surrounding the Sun which is inclined slightly to the solar equator.Proceedings of the Symposium on Solar Terrestrial Physics held in Innsbruck, May–June 1978.  相似文献   

16.
The solar wind emanating from coronal holes (CH) constitutes a quasi-stationary flow whose properties change only slowly with the evolution of the hole itself. Some of the properties of the wind from coronal holes depend on whether the source is a large polar coronal hole or a small near-equatorial hole. The speed of polar CH flows is usually between 700 and 800 km/s, whereas the speed from the small equatorial CH flows is generally lower and can be <400 km/s. At 1 AU, the average particle and energy fluxes from polar CH are 2.5×108 cm–2 sec–1 and 2.0 erg cm–2 s–1. This particle flux is significantly less than the 4×108 cm–2 sec–1 observed in the slow, interstream wind, but the energy fluxes are approximately the same. Both the particle and energy fluxes from small equatorial holes are somewhat smaller than the fluxes from the large polar coronal holes.Many of the properties of the wind from coronal holes can be explained, at least qualitatively, as being the result of the effect of the large flux of outward-propagating Alfvén waves observed in CH flows. The different ion species have roughly equal thermal speeds which are also close to the Alfvén speed. The velocity of heavy ions exceeds the proton velocity by the Alfvén speed, as if the heavy ions were surfing on the waves carried by the proton fluid.The elemental composition of the CH wind is less fractionated, having a smaller enhancement of elements with low first-ionization potentials than the interstream wind, the wind from coronal mass ejections, or solar energetic particles. There is also evidence of fine-structure in the ratio of the gas and magnetic pressures which maps back to a scale size of roughly 1° at the Sun, similar to some of the fine structures in coronal holes such as plumes, macrospicules, and the supergranulation.  相似文献   

17.
The concentrator on Genesis provided samples of increased fluences of solar wind ions for precise determination of the oxygen isotopic composition. The concentration process caused mass fractionation as a function of the radial target position. This fractionation was measured using Ne released by UV laser ablation and compared with modelled Ne data, obtained from ion-trajectory simulations. Measured data show that the concentrator performed as expected and indicate a radially symmetric concentration process. Measured concentration factors are up to ∼30 at the target centre. The total range of isotopic fractionation along the target radius is 3.8%/amu, with monotonically decreasing 20Ne/22Ne towards the centre, which differs from model predictions. We discuss potential reasons and propose future attempts to overcome these disagreements.  相似文献   

18.
Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.  相似文献   

19.
The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).  相似文献   

20.
At energies above the bulk solar wind and pick-up ion cutoff, observations reveal an interplanetary suprathermal ion population extending to ~1?MeV/nucleon and even higher energies. These suprathermal ions are found under a wide variety of conditions including periods when there are no obvious nearby accelerating shocks. We review the observational properties of these ions in quiet solar wind periods near 1?AU, including transient Corotating Interaction Region (CIR) events, and other, quieter periods in between transient enhancements. The particle energy spectra are power laws close to E ?1.5 in the range above the solar wind, rolling over at energies of a few hundred keV/nucleon to a few MeV/nucleon. Although the C/O and Fe/O ratios of the tails is close to that of the solar wind, pickup ions and 3He found in the tails indicate sources distinct from the solar wind. We briefly review several mechanisms that have been proposed to explain these ions.  相似文献   

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