CRISTA-NF measurements of water vapor during the SCOUT-O3 Tropical Aircraft Campaign

The new remote sensing experiment CRISTA-NF (Cryogenic Infrared Spectrometers and Telescopes for the Atmosphere – New Frontiers) successfully participated in the SCOUT-O3 Tropical Aircraft Campaign in November and December 2005. CRISTA-NF operated aboard the high-altitude research aircraft M-55 Geophysica. Mid-infrared spectra (4–15 μm) were measured in the limb sounding geometry with high spatial resolution (250 m vertical sampling, 5–15 km along track sampling). Measurements were carried out during transfer flights between Oberpfaffenhofen, Germany, and Darwin, Australia, as well as during several local flights near Darwin. Water vapor volume mixing ratios in the upper troposphere and lower stratosphere were derived from the CRISTA-NF radiance measurements by utilizing a rapid radiative transfer forward model and the optimal estimation retrieval approach. CRISTA-NF water vapor measurements below the hygropause have a total retrieval error of 15–40% (i.e. root mean square of accuracy and precision). The systematic terms are dominating in the retrieval error budget. The contributions of a priori information to the retrieval results are less than 5–10%. The vertical resolution of the observations is about 250–500 m when permitted by instrument sampling. In this paper we present first results for three transfer flights of the campaign. Being generally in good agreement with corresponding ECMWF operational analyzes, the CRISTA-NF measurements show significantly higher variability and local structures in the upper tropospheric water vapor distributions.     

Gravity waves and wind-shear in the MLT at 23°S

We have used the technique suggested by Hocking [Hocking, W. A new approach to momentum flux determinations using SKiYMET meteor radars. Ann. Geophys. 23, 2005.] to derive short period wind variances in the 80–100 km region from meteor radar data. We find that these fluctuating winds, assumed to correspond to gravity waves and turbulence, are closely correlated with the vertical shear of the horizontal tidal winds. This close correlation suggests that in situ wind shear may be a major source of gravity waves and turbulence in the MLT. If this is the case, gravity waves generated in the troposphere and propagating up to the MLT region, generally assumed to constitute an important influence on the climatology of the region, may be a less important source of energy and momentum in the 80–100 km region than has been hitherto believed.     

Carbon monoxide spatial gradients over source regions as observed by SCIAMACHY: A case study for the United Kingdom

Carbon monoxide (CO) is an important air pollutant whose emissions and atmospheric concentrations need to be monitored. The measurements of the SCIAMACHY instrument on ENVISAT are sensitive to CO concentration changes at all atmospheric altitude levels including the boundary layer. The SCIAMACHY CO measurements therefore contain information on CO emissions. Until now no studies have been published where the SCIAMACHY CO measurements have been used to quantify CO emissions by applying, for example, inverse modelling approaches. Here we report about a step in this direction. We have analysed three years of CO columns to investigate if spatial gradients resulting from United Kingdom (UK) CO emissions can be observed from space. The UK is an interesting target area because the UK is a relatively well isolated CO source region. On the other hand, the UK is not the easiest target as its emissions are only moderate and because the surrounding water has low reflectivity in the 2.3 μm spectral region used for CO retrieval. We determined horizontal CO gradients from seasonally and yearly averaged CO during 2003–2005 over the UK taking into account daily wind fields. We show that the measured CO longitudinal (downwind) gradients have the expected order of magnitude. The estimated 2σ error of the gradients depends on time period and applied filtering criteria (e.g., land only, cloud free) and is typically 10–20% of the total column. The gradients are barely statistically significant within the 2σ error margin. This is mainly because of the relatively high noise of the SCIAMACHY CO measurements in combination with a quite low number of measurements (∼100) mainly due to cloud cover.     

A feasibility study for the detection of the diurnal variation of tropospheric NO2 over Tokyo from a geostationary orbit

We have conducted a feasibility study for the geostationary monitoring of the diurnal variation of tropospheric NO₂ over Tokyo. Using NO₂ fields from a chemical transport model, synthetic spectra were created by a radiative transfer model, SCIATRAN, for summer and winter cases. We then performed a Differential Optical Absorption Spectroscopy (DOAS) analysis to retrieve NO₂ slant column densities (SCDs), and after converting SCDs into vertical column densities (VCDs), we estimated the precision of the retrieved VCDs. The simulation showed that signal-to-noise ratio (SNR) ? 500 is needed to detect the diurnal variation and that SNR ? 1000 is needed to observe the local minimum occurring in the early afternoon (LT13–14) in summer. In winter, the detection of the diurnal variation during LT08–15 needs SNR ? 500, and SNR ? 1000 is needed if early morning (LT07) and early evening (LT16) are included. The currently discussed sensor specification for the Japanese geostationary satellite project, GMAP-Asia, which has a horizontal resolution of 10 km and a temporal resolution of 1hr, has demonstrated the performance of a precision of several percent, which is approximately corresponding to SNR = 1000–2000 during daytime and SNR ? 500 in the morning and evening. We also discuss possible biases caused by the temperature dependence of the absorption cross section utilized in the DOAS retrieval, and the effect of uncertainties of surface albedo and clouds on the estimation of precisions.     

Application of HF Doppler measurements for the investigation of internal atmospheric waves in the ionosphere

We present results of the spectral analysis of data series of Doppler frequency shifted signals reflected from the ionosphere, using experimental data received at Kazan University, Russia. Spectra of variations with periods from 1 min to 60 days have been calculated and analyzed for different scales of periods. The power spectral density for spring and winter differs by a factor of 3–4. Local maxima of variation amplitude are detected, which are statistically significant. The periods of these amplitude increases range from 6 to 12 min for winter, and from 24 to 48 min for autumn. Properties of spectra for variations with the periods of 1–72 h have been analyzed. The maximum of variation intensity for all seasons and frequencies corresponds to the period of 24 h. Spectra of variations with periods from 3 to 60 days have been calculated. The maxima periods of power spectral density have been detected by the MUSIC method for the high spectral resolution. The detected periods correspond to planetary wave periods. Analysis of spectra for days with different level of geomagnetic activity shows that the intensity of variations for days with a high level of geomagnetic activity is higher.     

A numerical model approximating extreme energetic electron events involved in the physical and chemical processes of the middle atmosphere

Relativistic electrons (with energies >150 keV) which originate in the outer radiation belt and detected by the Russian ‘Meteor’ series of satellites have been correlated with the atmospheric total ozone data compiled by almost 90 stations located around the world within the latitude zone 40°–70°N. In more than 60% of the stations examined we have detected a clear decrease of the ozone 3–5 days after the electron flux excess. A numerical model has been applied to approximate this effect based on relativistic electron initiated nitric oxides creation in the upper mesosphere with subsequent atmospheric transport (both vertical and horizontal) towards the upper stratosphere. A first attempt of local and temporal prediction of ozone depletion because of energetic electrons impact in the middle atmosphere has been illustrated.     

Vertical motions in Thailand after the 2004 Sumatra–Andaman Earthquake from GPS observations and its geophysical modelling

Following previous findings from ongoing GPS research in Thailand since 2004 we continue to exploit the GPS technique to monitor and model land motions induced by the Sumatra–Andaman Earthquake. Our latest results show that up to the end of 2010, Thailand has been co-seismically displaced and is subsequently undergoing a post-seismic horizontal deformation with total displacements (co-seismic plus post-seismic) ranging from 10.5 to 74.7 cm. We observed the largest horizontal displacements in the southern part of Thailand and moderate and small displacements in the central and northern parts. In addition to horizontal displacements throughout Thailand, continuous GPS measurements show that large parts of Thailand are subsiding at rates up to 1 cm/yr. It is the first time that such vertical post-seismic deformations at large distances (650–1500 km away from the Earthquake’s epicentre) have been recorded. We have investigated the physical processes leading to the observed subsidence. While after-slip on the subduction interface induces negligible or even slightly positive vertical motions, relaxation in the asthenosphere is associated with a sizable subsidence. Predictions from a 3D finite element model feature an asthenosphere with an effective viscosity of the order of 3 * 10¹⁸ Pas, fit the horizontal post-seismic data and the observed subsidence well. This model is then used to predict the subsidence over the whole seismic cycle. The subsidence should go on with a diminishing rate through the next two decades and its final magnitude should not exceed 10 cm in the Bangkok area.     

Remote sounding of atmospheric gravity waves with satellite limb and nadir techniques

Recent advances in satellite techniques hold great potential for mapping global gravity wave (GW) processes at various altitudes. Poor understanding of small-scale GWs has been a major limitation to numerical climate and weather models for making reliable forecasts. Observations of short-scale features have important implication for validating and improving future high-resolution numerical models. This paper summarizes recent GW observations and sensitivities from several satellite instruments, including MLS, AMSU-A, AIRS, GPS, and CLAES. It is shown in an example that mountain waves with horizontal wavelengths as short as 30 km now can be observed by AIRS, reflecting the superior horizontal resolution in these modern satellite instruments. Our studies show that MLS, AMSU-A and AIRS observations reveal similar GW characteristics, with the observed variances correlated well with background winds. As a complementary technique, limb sounding instruments like CRISTA, CLAES, and GPS can detect GWs with better vertical but poorer horizontal resolutions. To resolve different parts of the broad GW spectrum, both satellite limb and nadir observing techniques are needed, and a better understanding of GW complexities requires joint analyses of these data and dedicated high-resolution model simulations.     

Kinetic temperature and carbon dioxide from broadband infrared limb emission measurements taken from the TIMED/SABER instrument

The Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) experiment is one of four instruments on NASA’s Thermosphere–Ionosphere–Energetics and Dynamics (TIMED) satellite. SABER measures broadband infrared limb emission and derives vertical profiles of kinetic temperature (Tk) from the lower stratosphere to approximately 120 km, and vertical profiles of carbon dioxide (CO₂) volume mixing ratio (vmr) from approximately 70 km to 120 km. In this paper we report on SABER Tk/CO₂ data in the mesosphere and lower thermosphere (MLT) region from the version 1.06 dataset. The continuous SABER measurements provide an excellent dataset to understand the evolution and mechanisms responsible for the global two-level structure of the mesopause altitude. SABER MLT Tk comparisons with ground-based sodium lidar and rocket falling sphere Tk measurements are generally in good agreement. However, SABER CO₂ data differs significantly from TIME-GCM model simulations. Indirect CO₂ validation through SABER-lidar MLT Tk comparisons and SABER-radiation transfer comparisons of nighttime 4.3 μm limb emission suggest the SABER-derived CO₂ data is a better representation of the true atmospheric MLT CO₂ abundance compared to model simulations of CO₂ vmr.     

Highlights of the Brazilian Solar Spectroscope

The digital, decimetric (950–2500 MHz) Brazilian Solar Spectroscope (BSS, Sawant, H.S., Subramanian, K.R., Faria, C., et al. Brazilian Solar Spectroscope (BSS). Solar Phys. 200, 167–176, 2001) with high time (10–1000 ms) and frequency (1–10 MHz) resolution is in regular operation since April, 1998, at the National Space Research Institute (INPE) at São José dos Campos, Brazil. The BSS has now been upgraded with a new digital data acquisition and data processing system. The new version of the BSS has improved the observational possibilities with the capability to record up to 200 frequency channels available in the selectable frequency range 950–2500 MHz. The GPS receiver permits the acquisition of data with time accuracy in the order of 0.1 ms. The software system of the BSS is composed by two distinct modules: the first, data acquisition system provides a flexible Graphical User Interface (GUI) that allows one to choose the observational parameters. The second module is the real time visualization system that permits real time visualization of the observed dynamic spectrum and additionally allows procedures for visualization and preliminary analysis of the recorded solar spectra. Using the new visualization system, we have realized two new types of dm-radio fine structures: narrow band type III bursts with positive as well as negative group frequency drift and dots emissions arranged in zebra-like and fiber-like chains. Furthermore, we have found flare generated fast wave trains according to their tadpole signature in wavelet power spectra for a decimetric type IV radio event (June 6, 2000 flare).     

A laboratory study on the thermally induced transformation of hydrogen cyanide (HCN) to the cyanogen anion (CN) in Solar System analog ices

Mixtures of molecular nitrogen and methane have been identified in numerous outer Solar Systemices including the icy surfaces of Pluto and Triton. We have simulated the interaction of ionizing radiation in the Solar System by carrying out a radiolysis experiment on a methane – molecular nitrogen ice mixture with energetic electrons. We have identified the hydrogen cyanide molecule as the most prominent carbon–nitrogen-bearing reaction product formed. Upon warming the irradiated sample, we followed for the first time the kinetics and temporal evolution of the underlying acid–base chemistry which resulted in the formation of the cyanide ion from hydrogen cyanide. On the surfaces of Triton and Pluto and on comets in Oort’s cloud this sort of complex chemistry is likely to occur. In particular, hydrogen cyanide can be produced in low temperature environments (Oort cloud comets) and may be converted into cyanide ions once the comets reach the warmer regions of the Solar System.     

Vertical wavenumber spectra of atmospheric ozone measured from ozonesonde observations

Vertical profiles of ozone have been measured at balloon altitudes. Our purpose is to examine the character of vertical wavenumber spectra of ozone fluctuations, to assess the possible roles of gravity wave field in ozone fluctuations, and to determine dominant vertical wavelengths of ozone spectra. Vertical wavenumber spectra of 12 ozone fluctuations obtained during June–August 2003 are presented. Results indicate that mean spectral slopes in the wavenumber range from 4.69 × 10⁻⁴ to 2.50 × 10⁻³ cyc/m are about −2.91 in the troposphere and −2.87 in the lower stratosphere, which is close to the slope of −3 predicted by current gravity wave saturation models. The consistency of the observed spectral slopes with the value of −3 predicted by current gravity wave saturation models suggests that the observed ozone fluctuations are due primarily to atmospheric gravity waves. At m = 1/(1000 m) the mean spectral amplitude is over 30 times larger in the lower stratosphere than in the troposphere. Mean vertical wavenumber spectra in area-preserving form reveal dominant vertical wavelengths of ∼2.6 km in the troposphere and ∼2.7 km in the lower stratosphere, which is consistent with the values varying between 1.5 and 3.0 km estimated from the velocity field and temperature field at these heights.     

High vertical resolution water vapour profiles in the upper troposphere and lower stratosphere retrieved from MAESTRO solar occultation spectra

An algorithm has been developed that retrieves water vapour profiles in the upper troposphere and lower stratosphere from optical depth spectra obtained by the Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (MAESTRO) instrument onboard the SCISAT satellite as part of the Atmospheric Chemistry Experiment (ACE) mission. The retrieval relies on ro-vibrational absorption of solar radiation by water vapour in the 926–970 nm range. During the iterative inversion process, the optical depth spectra are simulated at the spectral resolution and sampling frequency of MAESTRO using the correlated-k approximation. The Chahine inversion updates the water vapour volume mixing ratio (VMR), adjusting all retrieval layers simultaneously, to match the observed differential optical depth due to absorption by water vapour and ozone at each tangent height. This approach accounts for significant line saturation effects. Profiles are typically obtained from ∼22 km down to the cloud tops or to 5 km, with relative precision as small as 3% in the troposphere. In the lower stratosphere, the precision on water vapour VMR is ∼1.3 μmol/mol in an individual retrieval layer (∼1 km thick). The spectral capability of MAESTRO allows for the clear separation of extinction due to water vapour and aerosol, and for the fitting quality to be quantified and used to determine an altitude-dependent convergence criterion for the retrieval. In the middle troposphere, interhemispheric differences in water vapour VMR are driven by oceanic evaporation whereas in the upper troposphere, deep convection dominates and a strong seasonal cycle is observed at high latitudes.     

Ambiguity resolution in precise point positioning with hourly data for global single receiver

Integer ambiguity resolution (IAR) can improve precise point positioning (PPP) performance significantly. IAR for PPP became a highlight topic in global positioning system (GPS) community in recent years. More and more researchers focus on this issue. Progress has been made in the latest years. In this paper, we aim at investigating and demonstrating the performance of a global zero-differenced (ZD) PPP IAR service for GPS users by providing routine ZD uncalibrated fractional offsets (UFOs) for wide-lane and narrow-lane. Data sets from all IGS stations collected on DOY 1, 100, 200 and 300 of 2010 are used to validate and demonstrate this global service. Static experiment results show that an accuracy better than 1 cm in horizontal and 1–2 cm in vertical could be achieved in ambiguity-fixed PPP solution with only hourly data. Compared with PPP float solution, an average improvement reaches 58.2% in east, 28.3% in north and 23.8% in vertical for all tested stations. Results of kinematic experiments show that the RMS of kinematic PPP solutions can be improved from 21.6, 16.6 and 37.7 mm to 12.2, 13.3 and 34.3 mm for the fixed solutions in the east, north and vertical components, respectively. Both static and kinematic experiments show that wide-lane and narrow-lane UFO products of all satellites can be generated and provided in a routine way accompanying satellite orbit and clock products for the PPP user anywhere around the world, to obtain accurate and reliable ambiguity-fixed PPP solutions.     

Infrared spectrometry of Venus from “Venera-15” and “Venera-16”

Fourier spectrometers for the investigation of infrared spectra of Venus were installed on the recent Soviet orbiters “Venera-15” and “Venera-16”. Many spectra with reliable absolute calibration were obtained in the 280–1500 cm^?1 region with a spectral resolution of 5 cm^?1 (ground based processing) and about 7 cm^?1 (preoprocessed on board) and a spatial resolution of about 100 km at the Venusian cloud top level. Bands of CO₂, H₂O, H₂SO₄ and SO₂ are identified. The 15 μm-CO₂- fundamental band was used for retrieval of altitude dependent temperature profiles. There are significant differences in the cloud structure above 60 km for distinct regions of Venus, demonstrated by differences in the spectra.     

极区中层顶区域重力波谱的季节变化

使用MAP/WINE和MAC/SINE两次试验中测量的25m高分辨率水平速度数据和1km低分辨率温度数据,研究极区中层顶区域重力波谱的季节变化.温度的直接测量使计算的谱振幅和Richardson数更接近真实大气.结果显示,极区中层顶区域水平速度垂直波数谱的斜率和振幅存在相当大的变率,这些大的观测变率用各种饱和模式及普适垂直波数谱不能解释.然而平均垂直波数谱显示了明显的季节变化,在夏季,平均谱具有饱和特性;在冬季,平均谱具有非饱和特性.这意味着饱和过程存在于夏季而不是冬季.因此,夏季比冬季应有更强的湍流.这个结果与湍流季节变化的观测大致一致.从Brunt-Vaisala频率N和水平风切变计算的Richardson数Ri剖面也显示出季节差异,Ri<1/4的动力不稳定区出现在夏季,而Ri>0.4的稳定区出现在冬季.这些不稳定区与夏季谱结合很好,而稳定区则与冬季谱结合很好.     

Bacterial cellulose may provide the microbial-life biosignature in the rock records

Bacterial cellulose (BC) is a matrix for a biofilm formation, which is critical for survival and persistence of microbes in harsh environments. BC could play a significant role in the formation of microbial mats in pristine ecosystems on Earth. The prime objective of this study was to measure to what extent spectral and other characteristics of BC were changed under the performance of BC interaction with the earthly rock – anorthosite – via microorganisms. The spectral analyses (Fourier Transform Infrared FT-IR, spectroscopy, and atomic absorption spectroscopy) showed unprecedented accumulation of chemical elements in the BC-based biofilm. The absorption capacity of IR by BC was shielded a little by mineral crust formed by microorganisms on the BC-based biofilm surface, especially clearly seen in the range of 1200–900 cm⁻¹ in FT-IR spectra. Confocal scanning laser microscopy analysis revealed that elements bioleached from anorthosite created surface coats on the BC nanofibril web. At the same time, the vibrational spectra bands showed the presence of the characteristic region of anomeric carbons (960–730 cm⁻¹), wherein a band at 897 cm⁻¹ confirmed the presence of β-1, 4-linkages, which may serve as the cellulose fingerprint region. Results show that BC may be a biosignature for search signs of living organisms in rock records.     

GRB observed by IBIS/PICsIT in the MeV energy range

We present the preliminary results of a systematic search for GRB and other transients in the publicly available data for the IBIS/PICsIT (0.2–10 MeV) detector on board INTEGRAL. Lightcurves in 2–8 energy bands with time resolution from 1 to 62.5 ms have been collected and an analysis of spectral and temporal characteristics has been performed. This is the nucleus of a forthcoming first catalog of GRB observed by PICsIT.     

Measurement of stratospheric trace constituent distributions from balloon-borne far infrared observations

Far infrared limb thermal emission spectra obtained from balloon borne measurements made as a part of the Balloon Intercomparison Campaign (BIC) have been analyzed for retrieval of stratospheric trace constituent distributions. The measurements were made with a high resolution Michelson Interferometer and covered the 15–180 cm⁻¹ spectral range with an unapodized spectral resolution of 0.0033 cm⁻¹. The retrieved vertical profiles of O₃, H₂O, HDO, HCN, CO and isotopes of O₃ are presented. The results are compared with the BIC measurements for O₃ and H₂O made from the same balloon gondola and with other published data. A comparison of the simultaneously retrieved profiles for several gases with the published data shows good agreement and indicates the validity of the far infrared data, the retrieval techniques and the accuracy of the inferred profiles.     

Instrument concept and preliminary performance analysis of GLORIA

The Global Radiance Limb Imager Experiment for the Atmosphere (GLORIA) shall provide a detailed global picture of the upper troposphere/lower stratosphere region (UTLS) and make available novel information on small-scale atmospheric dynamics.

The instrument will be a space borne imaging Fourier Transform Spectrometer operating in the thermal infrared spectral region. It will produce spectrally resolved images of the earth’s limb with a vertical extension of 60 km and a horizontal extension of 400 km. The paper focuses on the preliminary instrument concept and on results of studies concerning sensitivity and spectrometric performance. GLORIA has been proposed as a national German space mission. An aircraft version is currently under development.