Microstructure and Hot Deformation Behavior of Mg-9Al-3Si-0.375Sr-0.78Y Alloy

Using Gleeble-3500 thermal simulator, the high temperature plastic deformation behavior and microstructure evolution of Mg-9Al-3Si-0.375Sr-0.78Y alloy are investigated at the temperature of 523 K?673 K and the strain rate of 10-3 s-1?10 s-1. True strain-true stress curves show the characteristics of the typical dynamically recrystallization process. The Arrhenius constitutive equation of the hyperbolic model is established. The average activation energy and the strain rate sensitivity index are, respectively, 221.578 kJ.mol-1 and 0.137. The result shows that the α-Mg phase exhibits dynamic recrystallization (DRX) characteristics obviously. But no DRX occurs in theβ-Mg17Al12 phase. Hot deformation does not affect the primary Mg2Si phase. Under the conditions of low temperature (523 K?673 K) and high strain rate (1 s-1?10 s-1), the flow instability and macro-defects such as crack appear in the specimens. However, there are finer recrystallization grains. Under the conditions of high temperature (≥673 K) or low strain rate, the microstructure of the alloy shows good homogeneity. The size of the primary Mg2Si phase is uniform, the size of the β-Mg17Al12 phase is small, and the distribution of the β-Mg17Al12 phase is uniform.     

航空航天用高强度Mg-RE系合金的研究进展

近年来,镁稀土合金由于其高强度、低密度和高温性能良好等特点,在追求轻量化的航空航天产业当中受到越来越多的关注。总结当前主流的2系高强度Mg-RE合金(Mg-Gd和Mg-Y系合金)的性能特点、强化机制和研究进展,简要介绍其他Mg-RE合金的研究情况,最后回顾镁稀土合金在航空航天领域的应用。     

超高强高韧马氏体时效钢热变形及航天应用研究

对于航天用超高强高韧C300马氏体时效钢来说,热加工过程中获得等轴细小的再结晶晶粒是实现该钢强韧性最佳匹配的关键环节。采用Gleeble-3800热模拟试验机在温度为850～1 150℃、应变速率为0.01～10 s~(-1)的条件下,对超高强高韧C300马氏体时效钢进行高温轴向压缩变形试验,获得了高温流变曲线,并观察变形后的金相组织。结果表明:C300马氏体时效钢的流变应力和峰值应变随着变形温度的升高和应变速率的降低而减小;试验钢在真应变为0.92、应变速率为0.01～10 s~(-1)的条件下,随着变形速率的提高,其发生完全动态再结晶的温度也逐渐升高,最佳热变形温度区间为1 050～1 150℃;测得试验钢的热变形激活能Q值为391.2 kJ/mol,建立了其热变形本构方程。结果能为C300马氏体钢的数值模拟和热加工工艺的制定提供理论基础。     

Corrosion Resistance of Ni-P Composite Coating on Mg Alloy： Critical Role of the Intermediate Phosphate Conversion Coating Layer for Suppressing Galvanic Couple Formation

Electroless nickel (EN) plating can give rise to the severe galvanic corrosion of the magnesium (Mg) alloy matrix, owing to its nobler electrochemical potential than Mg alloy. To hinder the formation of galvanic couple, an intermediate phosphate conversion coating (PCC) layer is introduced between the EN layer and the Mg alloy matrix. Since the ceramic-like PCC layer cannot be catalyzed, a low-cost Ag-activation technique is used to process the PCC layer before electroless plating. The cross-section morphology and element distribution of the PCC-EN composite coating indicate that the PCC intermediate layer can effectively separate the Mg alloy from the EN layer. Moreover, the results of electrochemical tests suggest that the PCC-EN composite coating has a better corrosion resistance in comparison with the EN coating and AZ91D Mg alloy.     

四唑类盐的制备及其在固体推进剂中的应用初探

合成了5-苯基四唑、5-亚甲基二四唑，并通过元素分析及质谱方法对其进行了分析鉴定，制备了其铜、铅、锶盐；对3种金属盐在改性双基推进剂配方中的应用进行了探索性研究。初步研究表明，四唑类的金属盐类可以作为复合改性双基推进剂(CMDB)的含能燃烧催化剂。     

丁羟推进剂拉伸断裂行为的扫描电镜研究

利用扫描电镜及附属微型动态拉伸装置实验手段，对丁羟基复合固体推进剂进行了断口微观形貌观察和电镜微型拉伸试件在应变状上的断裂行为分析。结果表明，从推进剂拉伸力学行为的微观结构变化以预示其宏 同力学性能，改善丁羟推进剂粘合剂与固体颗粒之间的界面性质，是固体推进剂力学性能的一个重要方向。     

考虑小波数相关性的SAR图像去斑算法

SAR(合成孔径雷达)发射的相干信号之间会使图像产生相干斑点噪声,严重影响SAR图像的应用,需加以抑制。通过研究分析,一副图像小波分解之后的小波系数在幅度、符号之间具有强烈的相关性,由此提出了一种小波去斑算法,该算法考虑了小波系数幅度、小波系数符号之间的相关性。利用合成斑点噪声图像和实际SAR图像验证了该算法的有效性。结果表明:该算法在抑制SAR图像斑点噪声的同时,具有更好的边缘细节保持能力,提升了SAR图像后续应用效能。     

原子氧辐照对MoS_2/酚醛环氧树脂粘结固体润滑涂层摩擦磨损性能的影响

为了揭示低地球轨道环境中的原子氧对粘结固体润滑涂层摩擦学性能的影响,制备了MoS2/酚醛环氧树脂粘结固体润滑涂层,并在原子氧地面模拟没备中对其进行辐照.采用球盘摩擦试验机考察了辐照前后涂层的摩擦磨损性能,并通过扫描电子显微镜(SEM)和X-射线光电子能谱仪(xPs)分析了辐照对涂层表面结构和组成的影响.研究发现,原子氧辐照增大了涂层的摩擦系数,降低了其耐磨性.表面结构和组成分析表明,原子氧辐照引起涂层中固体润滑剂MoS2发生部分氧化和粘结剂发生部分降解,使得涂层表面的O含量显著增大,而C含量明显降低.原子氧辐照引起的涂层表面结构和组成的变化是其改变粘结固体润滑涂层摩擦学性能的主要原因.