Two-dimensional convection in liquid layer related to crystal growth techniques in space

In this paper, the Marangoni convection including buoyancy convection in two-dimensional fluid model was investigated experimentally and theoretically. The transparent liquid in the test cell was heated and cooled under various conditions. The fluid flow driven by surface tension and by buoyancy force was visualized and measured. The flow patterns, velocity distributions and temperature field were obtained and they were compared with the results of the numerical solutions. The effect of the configuration and the convection in microgravity on crystal growth was discussed. The temperature field of the crystallizing surface was predicted.     

Natural convection driven by buoyancy and surface tension forces under external magnetic field

Two-dimensional natural convection driven both by buoyancy and surface tension in the horizontal layer of an electrically conducting liquid which is subjected to a horizontal temperature gradient and a vertical magnetic field is studied theoretically. The flow and temperature distribution in the liquid layer is analysed for two cases; (1) the top surface is free and the bottom is a rigid wall, and (2) both surfaces are rigid. The effect of the magnetic field on the flow velocity and the temperature distribution is made clear and the simple expressions are obtained for two extreme cases of the sufficiently large magnetic field and the small magnetic field.     

天舟一号货运飞船空间实验装置蒸发相变地面实验

以天舟一号货运飞船为依托,开展空间蒸发相变传热规律的科学实验研究,探索重力对蒸发传热传质过程的影响规律.设计了一套地面蒸发实验平台,以蒸发相变液体FC-72为研究对象,通过红外热像仪测温、热流量计、差分热电偶等手段,观测FC-72液层在不同台面温度、注液量等情况下的相变界面变化、蒸发表面特性、流体物性及Marangoni对流涡胞的变化等,获取其蒸发两相流体的液层温度差、表面温度场、热流量值、蒸发速率和涡胞结构等.实验结果表明:在其他条件不变的情况下,FC-72液层与蒸发台面的温差越高,其蒸发速率越快;注液量越大,蒸发速率也越大;在蒸发过程中出现了浮力对流涡胞和Marangoni对流涡胞.此外,通过地面蒸发实验可以确定空间科学实验选用的实验介质和材料,进而优化确定空间科学实验的工况、参数及流程等,部分地面实验结果也将直接成为天地对比实验的科学成果.      

微重力环境下蒸发液层热毛细对流的数值模拟

提出了一种新模型来研究由单一物质构成的液层在其纯蒸气中的蒸发.液层置于微重力环境中并且受到水平方向温度梯度的作用,液层的热毛细对流和蒸发耦合在一起,使得气液界面的传热传质规律更加复杂.用理论分析的方法求解了不考虑热毛细效应的纯蒸发模型,得出温度场分布和界面质量流量的解析表达式.对于热毛细对流和蒸发耦合情况,采用有限差分的投影算法同时求解Navier-Stokes方程和能量方程,得到了不同蒸发Biot数和Marangoni数下流场和温度场的稳态数值解.论述了蒸发Biot数和Marangoni数对界面传热传质的影响,提出并解释了蒸发和热毛细对流耦合的三种模式.      

THE CONVECTIVE EFFECT ON THE MORPHOLOGICAL INSTABILITY OF KNbO3 CRYSTALS

Experimentally, it was observed that there were various morphologies of KNbO3 crystals in different regions of the melt of Li2B4O7 and KNbO3 mixture in Pt loop heater. Dendrites grew in the central area of the melt, the diffusive-advective region,in which the temperature gradient is negligible; whereas crystals with smooth sur face were observed in the marginal area, the diffusive-convective region, with large temperature gradient. Based on the solute concentration over the KNbO3 crystal surface examined by electronic probe analysis, it was proved that the combinative effect of buoyancy and surface tension convection induced by temperature gradient enhanced the homogeneity of the solute concentration around KNbO3 crystals and thus their morphological stability.     

热毛细对流模式转换及温度振荡特征

研究了矩形液池中由于两端温差引起的热毛细对流的温度振荡临界条件.在实验室中,设计了一个高分辨率的温度测量系统,用于实时观测并记录流体的温度.该系统主要由热电偶温度传感器、纳伏表和数据采集电脑3部分组成.得到了各种实验条件下温度振荡的临界条件,并且讨论了它与Prandtl数和Bond数之间的关系.利用flow3d软件数值模拟了微重力条件下的热毛细对流,发现了一种由于自由面变形和液层流场相互作用导致的晃荡的现象.     

蒸发效应与热毛细对流耦合现象的实验研究

实验研究了矩形液池中蒸发薄液居中蒸发效应与热毛细对流的耦合机理. 对于单纯的热毛细对流稳定性从实验和理论上已有深入研究,但目前国际上对带有菇发界面的热毛细对流问题尚缺乏研究. 特别是近来的研究发现,气液界面的蒸发对热毛细对流稳定性有很大的影响. 本实验以温度为主要控制参数,测量了不同工况下蒸发界面不同点的蒸发速率和表层温度,并利用 PIV 方法分析得到了液体内的嘛场分布. 实验结果发现,随着沿界面的温差增加,蒸发液体内的流型从稳定的单涡胞结构变为稳定的多祸胞结构,并最终演变为紊流结构. 综合分析以上测量结果并与理论分析结果进行了比较。      

Marangoni convection when the surface tension increases with the temperature in normal and low gravity conditions

Thermocapillary convection has been studied in n-heptanol aqueous solutions whose surface tension is increasing with the temperature.

The fluid was confined in a parallelipipedic enclosure and a thermal gradient was imposed parallel to the free liquid/gas interface. The motions induced by the thermocapillary forces have been studied under low gravity conditions during Texus sounding rocket experiments and during the Spacelab D1 mission.

The combined thermocapillary and buoyancy convection have been extensively studied during ground based experiments.

The influence of the aspect ratio and of the alcohol concentration were investigated. Detailed velocity field was determined at the steady state under normal gravity conditions by Laser Doppler Anemometry (LDA).

The aspect ratio was of 0.3 and the temperatures imposed to the lateral sides of the cell were respectively 45°C and 60°C. With these experimental conditions, two superposed contrarotative cells were observed with rapid motions in the surface from the cold to the hot side. This convective pattern was also observed during the normal and high gravity periods of parabolic flights but during the low gravity period of the parabola the motions stopped everywhere in the fluid even in the surface and reappeared immediatly at the pull out of the parabola.     

实践十号卫星蒸发对流箱地面科学实验结果分析

实践十号卫星蒸发对流实验旨在研究置于加热底板的蒸发液滴在相变过程中,表面蒸发与表面张力驱动对流的耦合机理及其不稳定性.为与空间实验结果进行对比,利用蒸发对流箱完成在轨工况的科学匹配实验,获得相应工况的地面科学数据、工程参数及实验图像.通过对地面科学匹配实验结果进行分析,得到不同工况下液滴形貌（体积、表面积、接触角、液滴高度、液滴直径）变化规律,以及液滴蒸发过程中温度、热流量、蒸发速率和蒸发流量的变化规律.依据实验结果分析研究了具有质量交换的复杂流体相变界面的热质传输规律.      

气体在矿物油中扩散现象的可视化研究

介绍了利用马赫-泽德干涉仪法实现气体-矿物油扩散过程的可视化测量的原理、作用与意义。由于运用马赫-泽德干涉仪法获得的图像干涉条纹数及其图像的形状变化与折射率n直接与液体介质折射率相关,用马赫-泽德干涉仪法可获得十分清晰的影像。在N2,O2-矿物油扩散过程中,干涉条纹式样并未发生显著的紊乱变化,表明N2与O2气体在矿物油中发生扩散后,所引起的矿物油折射率变化过程较为缓慢。在CO2-矿物油扩散过程中,由于溶解的作用,矿物油近表面层中的气体溶解度增加,导致自然对流的出现。通过可视化测量,成功地观测到这一重要实验现象。同时,利用可视化技术,还可很好地判明对流出现的时间,从而确保扩散研究的有效性。     

超临界压力RP-3在竖直细圆管内混合对流研究

研究了超临界压力下碳氢燃料航空煤油RP-3在竖直细圆管内混合对流,分析了浮升力及热物性对碳氢燃料在垂直管中对流换热的影响。实验中控制热流密度从200~500 kW/m2变化,进口压力变化范围为3~5 MPa,进口雷诺数从5 000~10 500范围内变化。研究表明:在向上流动情况中进口段存在较为明显的入口效应,换热出现恶化现象,而在向下流动中未出现;对于向上和向下流动,由于热物性的综合影响,换热系数沿流动方向增大;在较低进口雷诺数(Re=5 700)时,对于向下流动,随着浮升力影响的增大,浮升力改变了流体径向速度分布,出现了换热强化;在较高进口雷诺数(Re=10 500)时,浮升力对换热的影响依然显著;判别式Bo*数小于5.6×10-7未能预测浮升力对碳氢燃料换热影响。      

EFFECTS OF CONVECTIVE FLUID MOTION UPON OXIDE CRYSTAL GROWTH IN HIGH TEMPERATURE SOLUTION

For understanding of the influence of convective flow on crystal growth, space high temperature in situ observation instrument (SHITISOI) is dedicated to visualize and record the whole growth process of oxide crystals in high temperature up to 1000°C. Model experiments using transparent liquids such as KNbO3 and a mix ture of Li2B4O7+KNbO3 were chosen to investigate effects on ground and in space.On the earth, an investigation of growth kinetics of KNbO3 crystal related to two different states of convection: diffusive-advective flow and diffusive-convective flow,has been performed. The per unit length of a step e is calculated from the exper imental data for two different states of convection. Analyses of these data show the effect of buoyancy convection is to enhance the sharpness of the interface. The growth of KNbO3 crystals from solution of KNbO3+Li2B4O7 was investigated in space. The streamlines of the steady thermocapillary convection in Li2B4O7 solvent was observed. Due to thermocapillary convection, KNbO3 crystal grains grew and filled the whole solution homogeneously. Earth-based quenching experiments are de signed in order to study polyhedral instability of KNbO3 crystal, which is controlled by diffusion mechanism limitation. In all cases, when the crystal was nucleated near air/solution surface, it lost its polyhedral stability and varied from polyhedrons to dedrites. The thickness of diffusion mechanism limitation layer is about 60μm.     

微重力条件下悬浮区中的Marangoni对流

本文研究微重力条件下悬浮区中的表面张力梯度驱动对流。采用有限元方法数值研究二维、轴对称悬浮区中的定常流动和温度分布,讨论P_r数及自由面上散热条件的影响。计算表明,P_r数(M_α数)增大时,流区大部分自由表面上温度梯度减小,流区流速较小,对流热输运较扩散效应增强。只要能维持自由面上一定的温度梯度,在较大的P_r数(M_α数)时,仍能得到收敛的定常解。     

池沸腾现象中热毛细对流的成因

针对微重力条件下单组份液体池沸腾现象,探讨了有关热毛细效应作用及其成因的不同观点,指出正确描述气液相变界面两侧的温度关系是解决争议的关键.详细评述了现有的气液相变界面温度模型,发现气液相变的非平衡特征会导致气液界面上产生温度梯度,引起表面张力的显著差异,从而驱动热毛细对流的形成.但现有气液相变界面温度模型机理差异迥然,预测结果也差别很大,因此,需要更深入研究.      

Hydrothermal instability of thermocapillary convection in large-Prandtl-number liquid bridges under microgravity

Linear stability analysis was performed to study the mechanism of transition of thermocapillary convection in liquid bridges with liquid volume ratios ranging from 0.4 to 1.2, aspect ratio of 0.75 and Prandtl number of 100. 2-D governing equations were solved to obtain the steady axi-symmetric basic flow and temperature distributions. 3-D perturbation equations were discretized at the collocation grid points using the Chebyshev-collocation method. Eigenvalues and eigenfunctions were obtained by using the Q–R method.The predicted critical Marangoni numbers and critical frequencies were compared with data from space experiments. The disturbance of the temperature distribution on the free surface causes the onset of oscillatory convection. It is shown that the origin of instability is related to the hydrothermal origin for convections in large-Prandtl-number liquid bridges.     

碲化铋基热电半导体晶体空间生长

碲化铋基热电半导体是中低温区高性能热电材料,在热电致冷、电子器件精确控温领域获得了重要应用,且在更多领域具有广泛应用前景.碲化铋基材料通常采用区熔法制备,材料的性能优值ZT约为0.8.应用要求进一步提高其ZT值.合金化和掺杂优化是提高碲化铋基材料性能的有效途径,但会使得材料的化学成分越来越复杂.重力条件下区熔的固有问题是,重力导致的浮力对流和壁附效应凸显,使区熔碲化铋基材料成分和性能波动较大.空间微重力可以消除重力导致的浮力对流和壁附效应,有望提高碲化铋基材料的成分均匀性和热电性能.本文根据碲化铋基材料空间微重力下区熔生长研究状况,对实践十号科学实验卫星和天宫二号空间实验室将开展的碲化铋基材料空间微重力区熔生长研究进行了分析.      

Steady and time-dependent Rayleigh-Bénard convection under influence of shear flows

The influence of shear flows on Rayleigh-Bénard convection inside a rectangular box heated from below and cooled from above has been studied both theoretically and experimentally for different Prandtl numbers. Two basic models have been used to study how a shear flow, a basic flow in our particular case, influences the stability phenomenon. In the first model the basic flow was induced by a horizontal temperature gradient while in the second this was done by means of a tilted convection box.     

Strong magnetic field effect on the dissolution process of tetragonal lysozyme crystals.

Either a homogeneous or inhomogeneous magnetic field has been known to dampen the protein crystal growth. To date the mechanism is not clear. However, it was generally proposed that the magnetic field may dampen the convection in the solution, resulting in a reduced crystal growth rate and possibly a good crystal quality, similar to the case of protein crystal growth in space. To understand the mechanism of the magnetic field effect on protein crystal growth, further explorations on the magnetic field effect on protein solution, on the processes of crystal growth and dissolution, and on different crystallization (solution) systems, should be valuable. In this paper we present our recent efforts to study magnetic field effects on the dissolution processes of tetragonal lysozyme crystals under a strong magnetic field. A layer of oriented tetragonal lysozyme crystals was prepared under a temperature gradient and magnetic field, after that the crystals were dissolved by increasing the temperature of the solution. The lysozyme molecules will diffuse upwards due to the steep concentration gradient at the lower side of the cell caused by the dissolution. The evolution of the concentration in the solution was measured in-situ using a Mach-Zehnder interferometer. The results confirmed that the dissolution process of the crystals was slowed by the magnetic field. Judging from the concentration evolution versus time at different positions in the solution, we concluded that the apparent diffusion coefficient of lysozyme molecules was decreased by the magnetic field. The results were discussed using a suspended crystal model in the initial dissolution stage.     

Surface tension-driven flows in horizontal liquid metal layers

The problem of surface tension-driven flows in horizontal liquid layers has been studied experimentally, and theoretically by direct numerical simulation and small perturbation analysis. We focus our attention on situations in which the depth of the fluid (liquid tin; small Prandtl number, Pr=0.015) is small enough to ensure the predominance of the surface tension forces over those due to the buoyancy. The surface velocity has been experimentally obtained for liquid tin layer with various aspect ratio (length to height) in the range 5<A<83. The thermal gradients are ranged from 5 to 40°K/cm. In the numerical study, the Navier-Stokes and energy equations are solved by an efficient finite difference technique. The parameters governing the flow behaviour in the liquid are varied to determine their effects on thermocapillary convection: the Reynolds number 10<Re<210⁴ and the aspect ratio 2<A<25; with Pr kept constant at Pr=0.015. The linear eigenequation resulting from small spatial disturbances of the Couette flow solution is solved using an Tau-Chebyshev approximation. A notable feature of the theoretical study is the totally different end circulations. In the region near the cold wall a multicell structure is evident. This agrees with the eigensolution which is of complex type, indicating spatial periodicity. In the hot wall region the flow is accelerated to reach the velocity value for the fully-developed Couette flow which is reached under conditions such as Re/A<20. The transition from viscous to boundary layer regime occurs for a critical value (Re/A)_c of nearly about 200, as deduced from the numerical and experimental results.     

Dynamical stability of plasma irregularities produced by powerful radio wave in the F region of the ionosphere

The paper demonstrates that the artificial plasma irregularities in the F region of the ionosphere are dynamical structures caused by the component of temperature gradient parallel with gravitational field. The concept is justified by theoretical estimates of critical parameters of thermal convection in the heated ionospheric volume. Presented results of radar observations of small-scale irregularities are explained by the thermal convection.