Mass spectrometry in the stratosphere

During the last few years a gas expansion system, combined with a mass spectrometer has been developed and successfully flown in the stratosphere. Neutral gas particles are formed into a molecular beam which traverses the ion source of the mass spectrometer without wall interactions. Vertical profiles of constituents such as H₂O, CO₂ and O₃ have been measured in the altitude range of 20 to 40 km during balloon descents. Isotopes of major atmospheric gases (N₂, O₂, Ar) provided in-flight calibration standards.Before each flight the mass spectrometer system was calibrated in the laboratory for many gases of interest, including ozone. Mixing ratios of ozone determined from recent flights have accuracies of better than 5%. The sensitivity of the system was sufficiently high to detect, in addition, the heavy isotope of ozone at mass 50. A pronounced enhancement of heavy ozone in the upper stratosphere has been found. The mass spectrometer system provides the unique opportunity to perform in the stratospherein-situ measurements combined with isotopic studies.     

Models of the high latitude stratosphere and mesosphere

Methods of calculation of interhemispheric and longitudinal differences are discussed. It is noted that in models one should take into account the solar activity influence. Network rocket sounding accuracy, devices and technique compatibility are analysed.     

Synopsis of troposphere and lower stratosphere

The use of different types of balloons for the investigation of the troposphere and lower stratosphere is reviewed with a special emphasis on the application for the next 10 years. The instrumentation currently flown aboard balloons or under development is described. Some possible scientific objectives of such balloon experiments are presented. The specific applications of the different types of balloons available within the next few years for scientific flights are discussed.     

Back-scattering of MF electromagnetic energy from the Antarctic stratosphere

A short review of the partial reflection experiment is presented along with the commonly made assumptions regarding the scattering mechanisms of the MF magneto-ionic modes in the mesosphere. It is shown that the traditional method of analysing differential absorption data can give rise to considerable errors in the determination of ionisation density at a particular scattering height. A new analysis approach is presented which yields a profile of the product of electron density and collisional frequency, rather than estimates of the electron density only. A by-product of this analysis technique is an estimate of the reflection coefficient factor F_xo(h) which traditionally has been set identically equal to unity. Analysis of data collected from 1983 to 1998 at Scott Base, Antarctica, has revealed that this reflection coefficient factor exhibits a seasonal dependence and differs substantially from unity, particularly at scattering heights between 40km and 60km. It is shown that neglecting this factor could easily lead to the conclusion that differential absorption is present at certain scattering heights with the consequent implication of the presence of ionisation.     

Periodic and aperiodic ozone variations in the middle and upper stratosphere

Umkehr, ozonesonde and satellite observations were used to determine the height/latitude distribution of the amplitude and phase of the periodic components of the variation of the ozone mixing ratio in the middle and upper stratosphere. The amplitude of the first (annual) harmonic is small in the subtropics and increases to a maximum at polar latitudes. It also increases with height in the mid and upper stratosphere to an apparent maximum just below the stratopause. The second (semi-annual) harmonic has an amplitude that is largest in tropical regions and in subpolar regions at a level of about 40 km. There seems to be very little ozone variation above 30 km with dominant periods close to the quasi-biennial period of total ozone observed in the tropics. The percent of the total variance of the ozone mixing ratio accounted for by the first harmonic is larger than 60 percent at all heights from 20° – 60° latitude in both hemispheres (except near 40 km in the Northern Hemisphere). The percent of the total variance accounted for by the second harmonic is maximum at a height of about 40 km in the tropics and at subpolar latitudes where, as mentioned, its amplitude is also largest.The phase of the first harmonic shows a marked transition from a winter/spring maximum below 30 km to a summer maximum at 30 km, changing rapidly to a maximum in winter in both hemispheres. The regions of minimum amplitude of the annual variation and the marked phase shifts with height both indicate the separation by levels of the dominant physical control mechanisms on the periodic changes of the ozone mixing ratio in the middle and upper stratosphere. Changes below 30 km respond primarily to dynamic influences in the lower stratosphere while above 30 km the periodic variations result mainly from photochemical processes. Above 40 km these variations are strongly temperature dependent.     

Height-latitude structure of stationary planetary waves in the stratosphere and lower mesosphere

Daily UK Met Office stratospheric assimilated data for the Northern and Southern Hemispheres, accumulated for the period from 2004 to 2012 and pressure range of 1000–0.1 hPa, are used in this paper. The paper presents and thoroughly discusses spatial–temporal distributions of stationary planetary wave (SPW) amplitudes and phases, calculated on the basis of geopotential height, temperature, zonal and meridional wind data for zonal wave numbers 1 and 2 (SPW1 and SPW2). The climatological planetary wave amplitudes and phases are calculated by extracting waves from three types of data: daily, monthly mean and climatological monthly mean. It has been established that magnitude of amplitudes and height-latitude distribution of amplitudes of SPW1 and SPW2 depend on data processing method for all parameters. It has also been established that height-latitude distribution amplitudes and phases significantly differ for geopotential height, temperature, zonal and meridional wind and depend on wave number and hemisphere. However, height-latitude distributions of phases are little different from each other for the used methods of data processing.     

The influence of interplanetary shocks on solar protons measured in the stratosphere.

Since the beginning of the 22nd solar cycle twenty solar proton events were observed by the regular balloon measurements of cosmic rays. Temporal changes of intensities and energy spectra of solar protons with energy 100-500 MeV were obtained. The strong influence of interplanetary shock waves on the proton flux characteristics near the Earth was observed. Possible effects of solar proton transport in the vicinity of shock fronts are discussed to explain the observational data.     

A new reeling technique for very long extension scanning in the stratosphere

A balloon borne winching system has been developed for extending a very long tether with payload down into the stratosphere and recovering it; this has been flight proven by being carried to an altitude of 40 km, lowering a 62 kg stratospheric photochemistry experiment 12 km at a descent velocity of ～6–8 m/sec and recovering it at comparable velocities. During the first flight, data gave no evidence of dynamic instabilities due to the system or the stratospheric interactions. The future utility of this payload is discussed with attention to the design factors that bound the range of performance of this type of system.     

Study of seasonal variation of winds in upper stratosphere over Hyderabad

A predictability of the stratospheric zonal winds above 38 km during the turnaround is an essential parameter for planning of the high-altitude scientific balloon flights. This information is more relevant in the case of Hyderabad balloon facility which is closer to equator and has much more unstable wind reversal patterns which appears to have changed enormously during the last decade probably in correlation with the global warming. With a majority of our flights reaching the altitudes of 38–42 km and the requirement of long float durations, a prior knowledge of wind pattern during the summer and winter turnaround seasons is highly desirable. Furthermore, the flight operation corridor for balloon flights from Hyderabad is limited to 400 km and though in the west direction there are flat lands, in all other three directions, the landscape is dotted by water bodies, reserve forests and hilly terrain, and therefore need of such a data is essential. In order to establish the climatology of the stratospheric winds and study their inter-annual variability over Hyderabad for the turnaround periods, we have made a detailed analysis of the United Kingdom Meteorological office data between 2000 and 2007, to derive average wind parameters (magnitude, direction) at different ceiling altitudes above 38 km. These results can be used only as general trend of stratospheric wind and should not be the limitation of the UKMO Data.     

Water vapor in the stratosphere: Preliminary results of the LIMS experiment aboard NiMBUS 7

The validation status of the LIMS (Limb Infrared Monitor of the Stratosphere) measurements in the water vapor channel is presented in a brief form. The agreement with other water vapor data taken in correlative balloon underflights is encouraging for this stage of the processing. Future efforts will be made to resolve remaining discrepancies so that operational reduction can begin. Preliminary maps for atmospheric layers between 50 mb and 1 mb show a fairly smooth water vapor field in the summer hemisphere.     

Climatic influence of background and volcanic stratosphere aerosol models

A simple modelization of the earth atmosphere system including tropospheric and stratospheric aerosols has been derived and tested. Analytical expressions are obtained for the albedo variation due to a thin stratospheric aerosol layer. Also outlined are the physical procedures and the respective influence of the main parameters: aerosol optical thickness, single scattering albedo and asymmetry factor, and sublayer albedo. The method is applied to compute the variation of the zonal and planetary albedos due to a stratospheric layer of background H₂SO₄ particles and of volcanic ash.     

Global water vapour distribution in the upper troposphere and lower stratosphere during CRISTA 2

Water vapour measurements during the second mission of the CRyogenic Infrared Spectrometers and Telescopes for the Atmosphere (CRISTA) instrument are presented in the altitude regime 8–20 km. Mixing ratios are shown on isentropic surfaces (300–500 K) as global zonal means and as averages in 60° longitude sectors. Transports are indicated to occur preferentially on isentropic surfaces in the northern hemisphere, but not in the tropics and in the south. The hygropause is found shifted away from the equator towards the winter hemisphere. The amount of shift is longitude dependent and can be as great as 20–30°. The water content of the hygropause area shows considerable zonal asymmetries.     

A neutral gas mass spectrometer to measure the chemical composition of the stratosphere

The Polar Balloon Atmospheric Composition Experiment (P-BACE) is a new generation of neutral gas mass spectrometer based on the time-of-flight principle. P-BACE is the scientific experiment on the Mars Environment Analog Platform (MEAP) flown successfully on a balloon mission in summer 2008. The MEAP mission was flown with a 334,000 m³ helium balloon in the stratosphere on a semicircular trajectory from northern Sweden around the North Pole to Canada using the summer northern hemispheric wind current. The atmospheric conditions at an atmospheric altitude of 35–40 km are remarkably similar to those on the surface of Mars and thus the balloon mission was an ideal testbed for our mass spectrometer P-BACE. Originally this instrument was designed for in situ measurements of the chemical composition of the Martian atmosphere.P-BACE has a unique mass range from 0 to 1000 amu/q with a mass resolution m/Δm (FWHM) > 1000, and the dynamic range is at least six orders of magnitude. During this experiment, the acquisition of one mass spectrum is a sum of 65,535 single spectra, recorded in a time frame of 66 s.The balloon mission lasted 5 days and had successfully demonstrated the functionality of the P-BACE instrument during flight conditions. We had recorded more than 4500 mass spectra. With little modifications, P-BACE can be used on a planetary mission for Mars, but for example also for Venus or Mercury, if placed on a satellite.     

A mathematical description of the annual variation of the temperature-height profile of the stratosphere at Berlin

Since 1958, daily temperature-height profiles have been measured up to 35–40 km at Berlin by means of radiosondes. An attempt is made here to describe these profiles as a function of the noon solar zenith angle, χ. It is shown that the basic annual variation of the measured profiles, T(h), can be presented as T(h) = T_o(h) cos^n(h)_χ. The subsolar temperature, T_o(h), and exponent, n(h), have been determined empirically from the summer and autumn data when the radiative balance is obviously dominant. Neither term depends on the solar cycle. Warmings in winter and coolings in spring are treated as disturbances in the annual variation, due to dynamics, and are described separately as ± ΔT(h).     

Rocket studies of atmospheric scattering and the aerosol size distribution in the troposphere and lower stratosphere over Thumba

Measurements have been made of the atmospheric scattering in the ultraviolet (λ = 0.31 μm) during the 16 February 1980 solar eclipse rocket campaign. The amplitude of the scattered fluxes as well as the angular distribution could be measured from ground up to an altitude of about 24 km. The Rayleigh scattering component was estimated using standard atmospheric models and the observations have been used to study the scattering due to aerosols at tropospheric and lower stratospheric altitudes.     

Temperature comparison between CHAMP radio occultation and TIMED/SABER measurements in the lower stratosphere

Global Positioning System (GPS) receiver on the CHAllenging Mini-satellite Payload (CHAMP) and the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument, one of four on board the TIMED satellite, provide middle atmosphere temperature profiles by Radio Occultation (RO) and limb viewing infrared emission measurements, respectively. These temperature profiles retrieved by two different techniques in the stratosphere are compared with each other using more than 1300 correlative profiles in March, September and December 2005. The over-all mean differences averaged over 15 and 35 km are approximately −2 K and standard deviation is less than 3 K. Below 20 km of altitude, relatively small mean temperature differences ∼1 K are observed in wide latitudinal range except for June (during the SABER nighttime observation). In the middle to low latitudes, between 30°S and 30°N, the temperature difference increases with height from ∼0–1 K at 15 km, to ∼−4 K at 35 km of altitude. Large temperature differences about −4 to −6 K are observed between 60°S and 30°N and 31–35 km of altitude for all months and between 0° and 30°N below 16 km during June (nighttime).     

Measurements of the upper troposphere and lower stratosphere during tropical cyclones using the GPS radio occultation technique

Water vapour transport to the upper troposphere and lower stratosphere by deep convective storms affects the radiation balance of the atmosphere and has been proposed as an important component of climate change. The aim of the work presented here is to understand if the GPS radio occultation technique is useful for characterization of this process. Our assessment addresses the question if severe storms leave a significant signature in radio occultation profiles in the upper troposphere/lower stratosphere. Radio occultation data from the Constellation Observing System for Meteorology, Ionosphere and Climate (COSMIC) were analyzed, focusing on two particular tropical cyclones with completely different characteristics, the hurricane Bertha, which formed in the Atlantic Basin during July 2008 and reached a maximum intensity of Category 3, and the typhoon Hondo, which formed in the south Indian Ocean during 2008 reaching a maximum intensity of Category 4. The result is positive, suggesting that the bending angle of a GPS radio occultation signal contains interesting information on the atmosphere around the tropopause, but not any information regarding the water vapour. The maximum percentage anomaly of bending angle between 14 and 18 km of altitude during tropical cyclones is typically larger than the annual mean by 5–15% and it can reach 20% for extreme cases. The results are discussed in connection to the GPS radio occultation receiver which will be part of the Atomic Clock Ensemble in Space (ACES) payload on the International Space Station.     

Wind structure and small-scale wind variability in the stratosphere and mesosphere during the November 1980 energy budget campaign

Between November 6 and December 1, 1980, a series of rocket observations obtained from two sites in northern Scandinavia as part of the Energy Budget Campaign indicated that significant vertical and temporal changes in the wind structure were present and were noted to coincide with different geomagnetic conditions, i.e., quiet and enhanced. This series of observations represents for the first time the largest amount of data ever gathered at high latitudes over such a short interval of time. It is observed that prior to November 16, the meridional wind component above 60 kilometers was found to be positive (southerly) while the magnitude of the zonal wind component increased with altitude. After November 16 the meridional component became negative (northerly) and the magnitude of the zonal wind component was noted to decrease with altitude. Time-sections of the perturbations of the zonal wind show the presence of vertically propagating waves which suggest gravity wave activity. These waves increase in wavelength from 3–4 kilometers near 40 kilometers to over 12 kilometers near 80 kilometers. The observational techniques employed at Andoya, Norway, and ESRANGE in Sweden, consisted of chaff foil, chemical trails, inflatable spheres, and parachutes.     

North–South asymmetry in cosmic ray fluxes as measured in the stratosphere and in selected solar wind parameters in the near-Earth space

North–South asymmetry in the cosmic ray fluxes as resulted from the long-term balloon measurements in the northern and southern polar stratosphere does not agree with that found from the neutron monitor data. In order to reveal possible sources of the observed asymmetry, selected interplanetary parameters were examined. North–South asymmetry relative to the heliospheric neutral sheet was considered for solar wind velocity, plasma density and some other solar plasma parameters. It is shown that North–South asymmetry of the solar wind velocity and plasma density depends on the Earth’s heliolatitude and the phase of the 11-year solar activity cycle. This may be relevant to the results of cosmic ray measurements in the stratosphere.