Isotopic ratios in planetary atmospheres.

Recent progress on measurements of isotopic ratios in planetary or satellite atmospheres include measurements of the D/H ratio in the methane of Uranus, Neptune and Titan and in the water of Mars and Venus. Implications of these measurements on our understanding of the formation and evolution of the planets and satellite are discussed. Our current knowledge of the carbon, nitrogen and oxygen isotopic ratios in the atmospheres of these planets, as well as on Jupiter and Saturn, is also reviewed. We finally show what progress can be expected in the very near future due to some new ground-based instrumentation particularly well suited to such studies, and to forthcoming space missions.     

Formation of bioorganic compounds in planetary atmospheres by cosmic radiation.

Simulated planetary atmospheres (mixtures of simple gases) were irradiated with high energy particles to simulate an action of cosmic rays. When a mixture of carbon monoxide, nitrogen and water was irradiated with 2.8-40 MeV protons, a wide variety of bioorganic compounds including amino acids, imidazole, and uracil were identified in the products. The amount of amino acids was proportional to the energy deposit to the system. Various kinds of simulated planetary atmospheres, such as "Titan type" and "Jovian type", were also irradiated with high energy protons, and gave amino acids in the hydrolyzed products. Since cosmic rays are a universal energy source in space, it was suggested that formation of bioorganic compounds in planetary atmospheres is inevitable in the course of cosmic evolution.     

Electromagnetic effects on planetary rings

The role of electromagnetic effects in planetary rings is reviewed. The rings consist of a collection of solid particles with a size spectrum ranging from submicron to 10's of meters (at least in the case of Saturn's rings). Due to the interaction with the ambient plasma, and solar UV radiation, the particles carry electrical charges. Interactions of particles with the planetary electromagnetic field, both singly and collectively, are described, as well as the reactions and influence on plasma transients. The latter leads to a theory for the formation of Saturn's spokes, which is briefly reviewed.     

Photochemical growing of complex organics in planetary atmospheres

UV induced syntheses of organic compounds from the main atmospheric constituents can be a very important source of organics in a given planetary environment provided the atmosphere is in a reduced state. The evolution of a CO₂ rich medium only produces very low yields of formaldehyde and related oxygenated compounds. Considering a CO rich atmosphere, the photochemical yield of O-organics formation is much higher, when the synthesis of N-organics remains difficult. The most favourable atmosphere as far as photochemical organic synthesis is concerned is a CH₄ rich milieu.. The photochemical evolution of such a CH₄ atmosphere under UV irradiation leads to a chain of various organics, the complexity of which increases together with the number of pathways involved in their formation. Their complexity also closely correlates with their UV photoabsorption spectrum: the more complex they are, the more shifted is their UV spectrum toward the visible range. Direct photodissociation of methane requires UV photon of wavelengths shorter than about 145 nm. It mainly produces ethane which absorbs UV at wavelengths shorter than about 160 nm, and acetylene, that presents an absorption spectrum extending up to 200 nm. This shift still continuously increases with further increase in number of C atoms. Unsaturated hydrocarbons with 4 and more C atoms have UV absorption characteristics including noticeable band structures in the 250–300 nm range. This trend has very important implication in the photochemical behaviour of a CH₄-rich planetary atmosphere, as it induces many catalytic processes. The occurrence of such processes is closely related to vertical atmospheric and energy deposition profiles. Titan provides a very good example of such a UV-directed organic atmospheric chemistry.     

Raman scattering as a probe of planetary atmospheres

The observable effects of Raman scattering on the spectra of the giant planets may provide new information on the composition and structure of these atmospheres. Satellite observations have already shown the influence of Raman scattering on the UV continuum albedo. A cross correlation technique is presented for detecting rotational and vibrational transitions of the Raman active gases in the atmosphere. This technique has been applied to ground-based visible spectra of Venus, Jupiter, Saturn and Uranus. Extension of this method into the UV would improve the detectability of the Raman lines because the ratio of Raman to Rayleigh cross section increases with decreasing wavelength. The technology currently exists to efficiently obtain high signal-to-noise ratio UV spectra through the use of silicon diode array detectors. Application of the cross-correlation technique to UV spectra obtained from space vehicles would give us a new important probe of the structure and composition of planetary atmospheres by enabling us to use the UV spectra of a planet to observe that would normally be an infrared molecular transition.     

Mass loading of planetary atmospheres by rocky satellites—II: Transport and enhanced lifetimes of satellite ejecta in planetary magnetospheres

Extensive studies have been conducted concerning individual mass, temporal and positional distribution of submicron rocky ejecta existing in the satellite-planetary gravitational sphere of influence. The transit time of the major portion of the ejecta that is transported from the satellite's gravitational sphere of influence to the planetary magnetopause is about one week and represents a mass loading pulse occurring each satellite orbit. The mass-flux distributions of lunar ejecta at the surface of the magnetopause for a complete lunar orbit are presented. Spatial mass densities of lunar ejecta in specific zones of the magnetosphere provide a means to compare sporadic interplanetary dust spatial mass densities in the same zones.     

Effects of electrostatic forces on the vertical structure of planetary rings

We have calculated the vertical structure of planetary dust rings as it results from a balance between an electrostatic force on the dust grains and the vertical component of the gravitational force from the central planet. The electrostatic force results from the charging of the dust grains by the ambient plasma and a large scale electric field due to a shielding electric field and the resulting vertical dust distribution are strongly dependent on dust size, dust and plasma density, plasma temperature and plasma ion type. The dust density distribution has a different dependence on these parameters in tenuous and in dense dust rings. We solve the relevant equations numerically and also by linearization in the limiting cases of tenuous or dense rings. Our results indicate that the effects treated in this paper may be important in both Jupiter's and Saturn's rings.     

Formation of bioorganic compounds in simulated planetary atmospheres by high energy particles or photons.

Various types of organic compounds have been detected in Jupiter, Titan, and cometary coma. It is probable that organic compounds were formed in primitive Earth and Mars atmospheres. Cosmic rays and solar UV are believed to be two major energy sources for organic formation in space. We examined energetics of organic formation in simulated planetary atmospheres. Gas mixtures including a C-source (carbon monoxide or methane) and a N-source (nitrogen or ammonia) was irradiated with the followings: High energy protons or electrons from accelerators, gamma-rays from 60Co, UV light from a deuterium lamp, and soft X-rays or UV light from an electron synchrotron. Amino acids were detected in the products of particles, gamma-rays and soft X-rays irradiation from each gas mixture examined. UV light gave, however, no amino acid precursors in the gas mixture of carbon monoxide, nitrogen and nitrogen. It gave only a trace of them in the gas mixture of carbon monoxide, ammonia and water or that of methane, nitrogen and water. Yield of amino acid precursors by photons greatly depended on their wavelength. These results suggest that nitrogen-containing organic compounds like amino acid precursors were formed chiefly with high energy particles, not UV photons, in Titan or primitive Earth/Mars atmospheres where ammonia is not available as a predominant N-source.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

Characterization of complex organic compounds formed in simulated planetary atmospheres by the action of high energy particles.

A wide variety of organic compounds, which are not simple organics but also complex organics, have been found in planets and comets. We reported that complex organics was formed in simulated planetary atmospheres by the action of high energy particles. Here we characterized the experimental products by using chromatographic and mass spectrometric techniques. A gaseous mixture of CO, N2 and H2O was irradiated with high energy protons (major components of cosmic rays). Water-soluble non-volatile substances, which gave amino acids after acid-hydrolysis, were characterized by HPLC and mass spectrometry. Major part of the products were complex compounds with molecular weight of several hundreds. Amino acid precursors were produced even when no water was incorporated with the starting materials. It was suggested that complex molecules including amino acid precursors were formed not in solution from simple molecules like HCN, but directly in gaseous phase.     

The escape of molecular hydrogen and the synthesis of organic nitriles in planetary atmospheres.

What is the influence of hydrogen escape from the atmosphere of small planetary bodies on the synthesis of organic molecules in that atmosphere? To answer this question, laboratory experiments have been performed to study the evolution of different reducing model atmospheres submitted to electrical discharges, with and without the simulation of H₂ escape. A study of mixtures of nitrogen and methane shows a very strong effect of H₂ escape on the formation of organic nitriles, the only nitrogen containing organics detected in the gas phase. These are HCN, CH  CCN, (CN)₂, CH₂CHCN, CH₃ CN and CH₃CH₂CN. The yield of synthesis of most of these compounds is noticeably increased, up to several orders of magnitude, when hydrogen escape is simulated. The escape of H₂ from the atmosphere of the primitive Earth may have played a crucial role in the formation of reactive organic molecules such as CHCCN or (CN)₂, which can be considered as important prebiotic precursors. These experimental results may also explain extant data concerning the nature and relative abundance of organics present in the atmosphere of Titan, a planetary satellite which may be an ideal model within our solar system for the study of organic cosmochemistry and exobiology.     

Conjecture on superrotation in planetary atmospheres: A diffusion model with mixing length theory

Superrotation on Venus is discussed in the context of comparative planetary atmospheres. In our planetary system, the rigid shell component (global average) of superrotation is ubiquitous (Jupiter, Saturn, Earth, Venus, Mars, Titan). The largest equatorial values of the component are between 25 and 150 m/sec. We present a simplified, heuristic analysis, utilizing mixing length theory to describe the small scale non-linear advections of energy and angular momentum, thereby providing a closure of the dynamic system. This leads to the conjecture that the zonal velocity may be crudely estimated by

, approximating the observed planetary trends; with c the speed of sound, the parameter a being 1 or 2 for geostrophic or cyclostrophic conditions respectively, P_α an effective Prandtl number which becomes less than one when radiative cooling is important, S_o the average stability, Γ the adiabatic lapse rate and γ the ratio of specific heats.     

Numerical simulation of organic compounds formation in planetary atmospheres: comparison with laboratory experiments.

A numerical model of CH4 and CH4-NH3 photochemistry at 147 nm has been developed and results are directly compared with experimental simulations carried out for the same mixtures. Simulations with varying quantities of ammonia and hydrogen show how amines and nitriles can be produce in planetary atmospheres. These comparisons allow one to test schemes of reactions used in photochemical models. In particular, it is shown that the scheme of reactions of CH4 is fairly well consistent with experimental data. On the other hand, the photochemistry of NH3 should be improved.     

Comparative analysis of chemical composition and optical properties of gaseous and disperse phases of the Earth-group planetary atmospheres

The models of chemical composition and structure of the Earth-type planetary atmospheres are offered. The optical properties of gaseous and disperse phases of the atmospheres are investigated.     

Ultraviolet emissions from the upper atmospheres of the planets

A large number of atoms and molecules have strong emission lines in the vacuum ultraviolet. As a result, this spectral region is particularly suited to studying the upper atmospheres of the planets. The observed emissions not only identify the constituents, but also provide information on the solar and magnetospheric excitation processes. Long term monitoring of these emissions, particularly with modest spatial resolution, can elucidate the effects of variations in the solar input as well as changes in magnetospheric conditions. Also, earth orbiting telescopes generally provide better spectral resolution than is available on flyby vehicles. A modest beginning in planetary upper atmospheric studies from earth orbit has been made using orbiting observatories designed primarily for stellar astronomy. As examples of the power of this technique, some recent results will be reviewed with an emphasis on Jupiter and the Io torus. The unusual scheduling requirements and the effects of scattered intense long wavelength radiation put demands on orbiting planetary observatories which are somewhat different from those of stellar astronomy. The implications of these demands for continued advances in this area are discussed.     

X-ray emission from the planetary nebula NGC 1360

The EXOSAT observatory has detected the nucleus of NGC 1360 in four photometric energy bands. The data rules out that the emission is from blackbody origin. Initial fits made with LTE model atmosphere spectra require the presence of highly ionized Oxygen and Neon in the stellar atmosphere.     

Calculations of the planetary albedo from satellite radiance measurements

The concept to estimate space averages of the reflected solar exitance at the top of the atmosphere (TOA) from narrow field of view satellite instruments is presented. The largest errors, of about 2–25 %, in the estimated exitance are induced by the bidirectional function to convert radiances to exitances.     

Equatorial planetary waves in the mesosphere observed by airglow periodic oscillations

Planetary scale waves in the equatorial upper mesosphere were studied by measuring the airglow OI557.7 nm, O₂b(0,1) and OH(6,2) emission intensities and OH rotational temperature at São João do Cariri (7.4°S; 36.5°W). From four years of data, 1998–2001, periodic oscillations of the airglow emissions were analyzed using the Lomb–Scargle spectral analysis. An oscillation of 3–4 days was frequently observed, which might be ultra-fast Kelvin waves. No seasonal dependency of the wave activity was found. On some occasions we found a quasi-5-day oscillation with a phase difference between the emissions, suggesting an upward energy flow. This is interpreted as a normal mode Rossby wave.     

Theory of planetary radio-emissions

In this short review, we limit our comments to the different theories which have been proposed to explain the observed features of the terrestrial, Jovian and Saturnian radio-emissions, and mainly to the high frequency portion of the spectra.