Protein crystal growth aboard the U.S. space shuttle flights STS-31 and STS-32.

The first microgravity protein crystal growth experiments were performed on Spacelab I by Littke and John. These experiments indicated that the space grown crystals, which were obtained using a liquid-liquid diffusion system, were larger than crystals obtained by the same experimental system on earth. Subsequent experiments were performed by other investigators on a series of space shuttle missions from 1985 through 1990. The results from two of these shuttle flights (STS-26 and STS-29) have been described previously. The results from these missions indicated that the microgravity grown crystals for a number of different proteins were larger, displayed more uniform morphologies, and yielded diffraction data to significantly higher resolutions than the best crystals of these proteins grown on earth. This paper presents the results obtained from shuttle flight STS-32 (flown in January, 1990) and preliminary results from the most recent shuttle flight, STS-31 (flown in April, 1990).     

Non-intrusive techniques for thermal measurements in microgravity fluid science experiments

Non intrusive techniques for thermal measurements in Microgravity Fluidynamics are considered in the paper: Liquid Crystals Tracers, Thermographic System, and Thin Foil Fluxmeter. Liquid crystals have been employed both as tracers (for the evaluation of the flow field organization) and as point thermometers (for the temperature distribution). Liquid surface measurements are performed in closed and open cells. Heat fluxes measurements have been performed by Thin Foil Fluxmeters and temperature by Thermographic Method. The Laboratory experimentation substantiate the applicability of these techniques in fluidynamics experimentation on Space Platforms.     

EXPERIMENTAL AND THEORETICAL STUDIES ON VELOCITY FIELD OF BUOYANCY CONVECTION IN KNbO3 MELT

The Schlieren technique coupling with a differential interference microscope was applied to visualize the KNbO3 melt motion in a loop-shaped Pt wire heater. The natural convection in KNbO3 melt was traced by observing the movement of the tiny KNbO3 crystals (～10μm) and the stream velocities of these tracer crystals were measured. In theoretical analysis, the Navier-Stokes equation was solved as a stable field. The general solution for this system of the differential equation was expressed by an approximate power series of azimuth and radius vector. The expression was substituted in the differential equation; a non-trivial solution was obtained exactly.The velocity distribution in the vertical section was obtained which is in qualitative agreement with the experimental result.     

THE SPACE EXPERIMENT OF PROTEIN CRYSTALLIZATION ABOARD THE CHINESE SPACECRAFT SZ-3

Using a new flight hardware, a Chinese mission of space protein crystallization has been performed on the Chinese spacecraft SZ-3 for seven days from March 25 to Apr. 1, 2002. The rate of yielding crystals in the 60 samples is 75%, a little higher than the ground control experiment. Preliminary analysis of the experimental results have shown that among the 16 proteins involved in the mission, about 4 kinds of better diffraction-quality protein crystals were produced in space. At least one kind of protein crystals, i.e. crystals of cytochrome b5 mutant could diffract X ray beyond the highest resolution reported so far. In addition, some rules derived from our numerical studies of the liquid/liquid diffusion protein crystallization were proved by the crystallization of lysozyme as model protein in this space experiment,which also clearly showed the advantages and disadvantages of the gelled protein solution used in microgravity growth of protein crystals. In order to exploit this mission, more diffraction work with the grown crystals and detailed analysis of data to be obtained will be done in the next few months.     

Solidification of GeSi solid solution in near-zero-G conditions

In summary, it should be stated that the existing theories of segregation during directional crystallization which consider mass transport in melt due only to either concentration diffusion or convective stirring (or both) cannot account for solute segregation picture observed in solid solution crystals which have been obtained aboard Apollo-Soyuz orbital complex. To do this, some other, new models are required.     

Observations and predictions of secondary neutrons on Space Shuttle and aircraft.

The Cosmic Radiation Effects and Activation Monitor has flown on six Shuttle flights between September 1991 and February 1995 covering the full range of inclinations as well as altitudes between 220 and 570 km, while a version has flown at supersonic altitudes on Concorde between 1988 and 1992 and at subsonic altitudes on a SAS Boeing 767 between May and August 1993. The Shuttle flights have included passive packages in addition to the active cosmic ray monitor which comprises an array of pin diodes. These are positioned at a number of locations to investigate the influence of shielding and local materials. Use of both metal activation foils and scintillator crystals enables neutron fluences to be inferred from the induced radioactivity which is observed on return to Earth. Supporting radiation transport calculations are performed to predict secondary neutron spectra and the energy deposition due to nuclear reactions in silicon pin diodes and the induced radioactivity in the various scintillator crystals. The wide variety of orbital and atmospheric locations enables investigation of the influence of shielding on cosmic ray, trapped proton and solar flare proton spectra.     

空间用硅太阳电池带通滤波器的研究

为改善硅太阳电池在轨工作期间的性能,通过对空间用太阳电池带通滤波器结构设计和制备工艺的研究,研制出一种空间用硅太阳电池的带通滤波器并对其性能进行了测试,结果表明,采用该带通滤波器可使硅太阳电池在轨工作温度降低6°C～12°C,输出功率增加1.8%～4.1%.带通滤波器的研制对于促进高效硅太阳电池的空间应用具有积极意义.     

Secondary radiation environments in heavy space vehicles and instruments.

Secondary radiations produced by the interactions of primary cosmic rays and trapped protons with spacecraft materials and detectors provides an important, and sometimes dominant, radiation environment for sensitive scientific instruments and biological systems. In this paper the success of a number of calculations in predicting a variety of effects will be examined. The calculation techniques include Monte Carlo transport codes and semi-empirical fragmentation calculations. Observations are based on flights of the Cosmic Radiation Environment and Activation Monitor at a number of inclinations and altitudes on Space Shuttle. The Shuttle experiments included an active cosmic-ray detector as well as metal activation foils and passive detector crystals of sodium iodide which were counted for induced radioactivity soon after return to earth. Results show that cosmic-ray secondaries increase the fluxes of particles of linear energy transfer less than 200 MeV/(gm cm-2), while the activation of the crystals is enhanced by about a factor of three due to secondary neutrons. Detailed spectra of induced radioactivity resulting from spallation products have been obtained. More than a hundred significant radioactive nuclides are included in the calculation and overall close agreement with the observations is obtained.     

空间低温溶液晶体生长的地基实验

首次使用疏水型聚四氟乙烯微孔滤膜,利用其透气不透水的特性,密封晶体生长容器,采用恒温蒸发法进行晶体生长.溶剂通过蒸发离开生长容器后,被生长容器外的吸附剂吸附,使得溶液维持一定过饱和度,以实现单晶的连续生长.在此基础上研制出一套空间低温溶液晶体生长地基模拟装置.利用此装置进行了一系列地基模拟实验,获得一批高质量α-LiIO₃单晶,证实了该生长装置的溶剂蒸发量和容器密封性能够满足空间低温溶液晶体生长需要,为未来空间低温溶液晶体生长实验奠定了基础.      

Convection and impurity distribution in crystal growth in low-gravity environments

Investigations conducted earlier by the authors have established that due to the steady-state field of body forces, convection is capable of giving rise to macroinhomogeneity in transverse impurity distribution in crystals. In the case of semiconductor materials the maximal value of this inhomogeneity is due to a weak convection in the melt, typical of low-gravity conditions. However, in addition to steady gravitational convection, other factors ignored previously, may also be employed in conducting experiments in low-g environments. The present paper discusses the results of theoretical studies of some factors influencing impurity distribution in the melt and the crystal.     

用国产装置进行的空间蛋白质结晶实验

使用国内研制的管式汽相扩散结晶装置,在我国返回式卫星上,成功地完成了两次空间蛋白质晶体生长实验,10种不同种类的蛋白质配制的48个样品在空间的出晶率分别达52%和80%,其中少数蛋白质生长出了较高质量的蛋白质晶体。结果表明,空间的微重力环境利于改善蛋白质晶体的生长,而且在结晶条件优化足够好的条件下,在空间里能生长出比地面晶体尺寸较大、形态较好和内部有序性较高的蛋白质晶体。本文还就微重力对蛋白质晶体生长的具体作用及其开发利用做了讨论。      

Phase transitions in a dusty plasma with two distinct particle sizes

In semiconductor manufacturing, contamination due to particulates significantly decreases the yield and quality of device fabrication, therefore increasing the cost of production. Dust particle clouds can be found in almost all plasma processing environments including both plasma etching devices and in plasma deposition processes. Dust particles suspended within such plasmas will acquire an electric charge from collisions with electrons and ions in the plasma. If the ratio of inter-particle potential energy to the average kinetic energy is sufficient, the particles will form either a “liquid” structure with short-range ordering or a crystalline structure with long-range ordering. Many experiments have been conducted over the past decade on such colloidal plasmas to discover the character of the systems formed, but more work is needed to fully understand these structures. The preponderance of previous experiments used monodisperse spheres to form complex plasma systems. However, most plasma processing environments contain more arbitrary distributions of particle size. In order to examine in more detail the effects of a size distribution, experiments were carried out in a GEC rf reference cell modified for use as a dusty plasma system. Using two monodisperse particle sizes, experiments were conducted to determine the manner in which phase transitions and other thermodynamic properties depended upon the overall dust grain size distribution. Plasma crystals were formed from different mixtures of 8.89 and 6.50 μm monodisperse particles in argon plasma. With the use of various optical techniques, the pair correlation function was determined at different pressures and powers and then compared to measurements obtained for monodisperse spheres.     

Metallic multilayers: New possibilities in X-UV optics

Reflectivities measured on metallic multilayers obtained by evaporation methods have demonstrated the validity of theoretical predictions. Experimental tests using wavelengths from 1.54 Å to several hundred of angstroems give a firm basis for proposed new designs for X-UV optics. This new kind of Bragg reflector can be tailored for any wavelength and any incidence angle, because the period of evaporation of the layered synthetic medium can be freely chosen. Such artificial Bragg reflectors are more efficient than natural, organic or molecular crystals which have been employed until now in the X-UV, and can overcome the weak luminosity and astigmatism problems encountered in grazing incidence optics. The possibility of evaporating multilayers on shaped substrates will lead to optics with focussing and selectivity fuctions given by a single reflection.     

燃烧室头部进气规律对煤粉燃烧效率的影响

用实验方法研究了火焰筒式煤粉燃烧室头部进气规律对燃烧效率的影响。通过对6种结构的头部配气方案的分析比较,得出了煤粉燃烧室合理的头部配气方案,为今后煤粉燃烧室的设计和工作状态的选择提供了重要的实验依据。     

Mathematical simulation of impurity distribution in space processing experiments with semiconductors

The effect of natural convection in the melt on impurity distribution is investigated by numerical simulation in the case of uniaxial growth of semiconductor crystals at low gravity conditions.     

EVALUATION OF MORPHOLOGY-STABLE CRITICAL SIZE OF KNbO3 CRYSTALS

Skeletal form of KNbO3 crystals growing in Li2B4O7 solvent was in-situ observed at 900°C and it was found that shallow depression started to develop on the surface of KNbO3 crystals when the crystal size exceeded several micron, typically 7 micron.Based on the quantitative criterion derived by Chernov, the estimated critical size of KNbO3 crystals was 1 micron, which was consistent with the experimental measure ment. The kinetic coefficients, kcorner and kcr, in the criterion were experimentally obtained in the diffusive-convective and diffusive-advective flow states respectively.     

多头锗空间γ谱仪探测效率的提高

在γ谱线天文观测中采用多头锗晶体作为γ谱仪中的中心探测器,以提高探测器的观测灵敏度。本文以一个九头高纯锗探测器系统为实例,用蒙特卡洛模拟方法,分析了入射光子在各晶体中的能损分配和各类效率的比例,给出在几种晶体输出幅度组合相加情况下,探测的全能峰效率可提高的份额。并用较完整的模型对单个晶体的模拟结果与实测结果进行了详细讨论。      

平面工艺功率型半导体晶体管铝迁移实验

在平面工艺制造的功率型半导体晶体管芯片表面,发现高强度电场条件下存在跨越0.05 mm半绝缘硅带的铝迁移现象,对此开展了一系列实验研究. 通过开帽物理观察与分析、低温测试与烘干验证、迁移物质分析对比,确定了迁移现象中的迁移物质,同时分别取证环境温度、湿度、芯片表面污染物以及器件局部结构与此迁移现象的关联性,以此提出了迁移机理假说,为在不同的诱发条件下对此迁移机理进行确认和量化研究提供指导.      

Convection in melts and crystal growth

Convection plays a significant role in determining the electronic properties of semiconductor crystals grown from the melt. Inhomogeneities (doping striations) in these crystals can be caused by unsteady natural convection. Therefore, the origins of unsteady natural convection, which means fluctuating temperatures in a fluid, are investigated in this paper. Several effects have been found at increasing Rayleigh numbers Ra which cause fluctuating temperatures. But it was also observed, that unsteady convection became again steady if Ra was increased to higher values. This effect, which is called relaminarization, is very interesting for crystal growth and is discussed in this paper.     

Progress in Space Material Researches

New progress in the post researches on space grown materials, the development of experiment facilities, and the experiment techniques for space materials researches were introduced. Besides the conventional materials, such as alloys, semiconductors, and optical crystals, new materials have also been prepared on the ground.