Structure and UV absorption of QCCs: carbonaceous dust analogues.

"Quenched Carbonaceous Composites (QCCs)" are carbonaceous interstellar dust analogues synthesized in the laboratory from a hydrocarbon plasma. We produced new types of carbonaceous condensates from the ejecta of plasma with mixtures of methane and hydrogen as source gases. We find that QCC with an absorbance peak at 220 nm is composed of onion-like spherules, and QCCs with an absorbance peak at 230-240 nm are composed of polyhedral particles. The onion-like QCC contains aromatic hydrogen bonds, and it shows the 3.3 and 11.4 micrometers absorption bands. The QCC with an absorbance peak at 230-240 nm is composed of ribbons with bent graphitic layers. This suggests that the carrier of the interstellar 220 nm extinction band might also be an emitter of the interstellar diffuse emission bands.     

Spectroscopic properties of polycyclic aromatic hydrocarbons (PAHs) and astrophysical implications.

PAHs (polycyclic aromatic hydrocarbons) are probably present as a mixture of neutral and ionized species and are responsible for the set of infrared emission bands in the 2-15 microns regions, which are observed in many different objects like reflection and planetary nebulae and external galaxies. PAHs are suggested to be the most abundant free organic molecules and ubiquitous in space. PAHs might also exist in the solid phase, included in interstellar ices in dense clouds. A complex aromatic network is expected on interstellar grains in the diffuse interstellar medium. The existence of an aromatic kerogen-like structure in carbonaceous meteorites and its similarity with interstellar spectra suggests a link between interstellar matter and primitive Solar System bodies.     

Spectroscopy of the extreme ultraviolet background radiation

Observations in the far ultraviolet and soft x-ray bands suggest that the interstellar medium contains several components of high temperature gas and should be emitting in the extreme ultraviolet. Indeed diffuse radiation has been detected in the extreme ultraviolet with photometric instruments, but no spectral measurements exist below 520Å. We have designed a unique grazing incidence spectrometer to study the diffuse emission between 80 and 650Å with 10 to 20Å resolution. The instrument was launched on a Black Brant sounding rocket from White Sands Missile Range on April 22, 1986. Our preliminary analysis shows the expected geocoronal and interplanetary HeI 584Å emission, and possibly other features which may originate in the hot ionized interstellar gas. Flux limits to these possible emission lines are compatible with previous broad band measurements.     

Polycyclic aromatic hydrocarbon ions and the diffuse interstellar bands.

Neutral naphthalene (C10H8), phenanthrene (C14H10), and pyrene (C16H10) absorb strongly in the ultraviolet and may contribute to the extinction curve. High abundances are required to produce detectable structures. The cations of these PAHs absorb in the visible. C10H8+ has 12 discrete absorption bands which fall between 6800 and 5000 angstroms. The strongest band at 6741 angstroms falls close to the weak 6742 angstroms diffuse interstellar band (DIB). Five other weaker bands also match DIBs. The possibility that C10H8+ is responsible for some of the DIBs can be tested by searching for new DIBs at 6520, 6151, and 5965 angstroms, other moderately strong naphthalene cation band positions. If C10H8+ is indeed responsible for the 6742 angstroms feature, it accounts for 0.3% of the cosmic carbon. The spectrum of C16H10+ is dominated by a strong band at 4435 angstroms in an Ar matrix and 4395 angstroms in a Ne matrix, a position which falls very close to the strongest DIB, that at 4430 angstroms. If C16H10+, or a closely related pyrene-like ion is indeed responsible for the 4430 angstroms feature, it accounts for 0.2% of the cosmic carbon. We also report an intense, very broad UV-to-visible continuum which is associated with both ions and could explain how PAHs convert interstellar UV and visible radiation into IR.     

Formation of amino acid precursors in cometary ice environments by cosmic radiation.

Cometary ices are believed to contain water, carbon monoxide, methane and ammonia, and are possible sites for the formation and preservation of organic compounds relating to the origin of life. Cosmic rays, together with ultraviolet light, are among the most effective energy sources for the formation of organic compounds in space. In order to study the possibility of the formation of amino acids in comets or their precursory bodies (interstellar dust grains), several types of ice mixtures made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. After irradiation, the volatile products were analyzed with a quadrupole mass spectrometer, while temperature of the cryostat was raised to room temperature. The non-volatile products remaining in the cryostat at room temperature were collected with water. They were acid-hydrolyzed, and analyzed by ion-exchange chromatography. When an ice mixture of carbon monoxide (or methane), ammonia and water was irradiated, some hydrocarbons were formed, and amino acids such as glycine and alanine were detected in the hydrolyzate. These results suggest the possible formation of "amino acid precursors" (compounds yielding amino acids after hydrolysis) in interstellar dust grains by cosmic radiation. We previously reported that amino acid precursors were formed when simulated primitive planetary atmospheres were irradiated with cosmic ray particles. It will be of great interest to compare the amount of bioorganic compounds that were formed in the primitive earth and that brought by comets to the earth.     

Production and evolution of carbonaceous material by ion irradiation in space.

We review recent experimental studies concerning the evolution, driven by ion irradiation, of carbonaceous material from frozen gas to a refractory molecular solid. Under further irradiation the latter changes to a polymer-like material and ultimately to amorphous carbon. Most of the results have been obtained by "in situ" and remote IR and Raman spectroscopy. The results have been applied to demonstrate that molecular solids may be easily formed by irradiation of frozen mantles in dense interstellar clouds. Polymer-like material and amorphous carbons may result by further irradiation of organic mantles on grains in the diffuse interstellar medium. Those grains, during the aggregation to form extended bodies like comets (T-Tau phase of the Sun), are further modified. These latter are also irradiated, after the comet formation, during their long stay in the Oort cloud. In particular it has been suggested that comet may develop an ion-produced cometary organic crust that laboratory evidences show to be stable against temperature increases experienced during passages near the Sun. The comparison between the Raman spectra of some IDP (Interplanetary Dust Particles) and the Raman spectra of some ion-produced amorphous carbons, is also discussed.     

Origin of organic compounds in carbonaceous chondrites.

Carbonaceous chondrites, a class of primitive meteorite, have long been known to contain their complement of carbon largely in the form of organic, i.e., hydrocarbon-related, matter. Both discrete organic compounds and an insoluble, macromolecular material are present. Several characteristics of these materials provide evidence for their abiotic origin. The principal formation hypotheses have invoked chemistry occurring either in the solar nebula or on the parent body. However, recent stable isotope analyses of the meteorite carboxylic acids and amino acids indicate that they may be related to interstellar cloud compounds. These results suggest a formation scheme in which interstellar compounds were incorporated into the parent body and subsequently converted to the present suite of meteorite organics by the hydrothermal process believed to have formed the clay minerals of the meteorite matrix.     

Observational astrochemistry: recent results.

More than 80 molecular species have now been observed by astronomers in the dense interstellar clouds where stars and planets form or in the envelopes expelled by evolved stars. Elemental constituents of these compounds include all of the "biogenic" elements, hydrogen, carbon, nitrogen, oxygen, sulfur, and (most recently) phosphorus. In addition, silicon is found in several molecules, and a series of metal halides have recently been detected in the outflowing envelope of a nearby carbon star. Additions to the list of known interstellar molecules since the last COSPAR meeting are discussed individually. Recent measurements of the hydrogen isotopic fractionation for the cyclic molecule C3H2 are described; values up to 10,000 times the cosmic deuterium-to-hydrogen ratio are found. Knowledge of the chemical reservoirs for the major volatile elements and a comparison between observed molecular abundances and theoretical models are both discussed.     

Organic chemistry by irradiation in space

The irradiation of grains and/or ices by particles from solar or stellar winds, as well as cosmic rays, induces the synthesis of molecular species. We have shown by in-situ infrared spectroscopy of irradiated samples that this chemistry may be responsible for the presence of organic compounds in a large variety of astrophysical sites such as: lunar and asteroidal regoliths, cometary nucleus, rings and satellites of outer planets, circumstellar shells, interstellar clouds. We present our experimental results concerning the nature and efficiency of C and N irradiation chemistries, and give plausible astrophysical implications.     

Similarity of the infrared spectrum of an Orgueil organic polymer with interstellar organic compounds in the line of sight towards IRS 7.

We present a comparison between the IR spectrum of the galactic center source IRS 7 and the spectrum of a carbonaceous polymer from the Orgueil meteorite. We have obtained an almost perfect match between the two spectra in the region between 3020-2790 cm-1, which suggests that the chemical composition of the interstellar organic matter and that of the meteorite polymer are similar or that the meteoritic polymer could be a well preserved interstellar organic molecule. Assuming that the meteoritic polymer has the same C/H ratio as these interstellar molecules, we find that 45 % of the total abundance of carbon in the line of sight toward IRS 7 is trapped in such an interstellar organic grain material.     

Comets and life.

Some of the chemical species which have been detected in comets include H2O, HCN, CH3CN, CO, CO2, NH3, CS, C2 and C3. All of these have also been detected in the interstellar medium, indicating a probable relationship between interstellar dust and gas clouds and comets. Laboratory experiments carried out with different mixtures of these molecules give rise to the formation of the biochemical compounds which are necessary for life, such as amino acids, purines, pyrimidines, monosaccharides, etc. However, in spite of suggestions to the contrary, the presence of life in comets is unlikely. On the other hand, the capture of cometary matter by the primitive Earth is considered essential for the development of life on this planet. The amount of cometary carbon-containing matter captured by the Earth, as calculated by different authors, is several times larger than the total amount of organic matter present in the biosphere (10(18)g). The major classes of reactions which were probably involved in the formation of key biochemical compounds are discussed. Our tentative conclusions are that: 1) comets played a predominant role in the emergence of life on our planet, and 2) they are the cosmic connection with extraterrestrial life.     

Complex organics in meteorites.

Complex macromolecular organic matter is present in carbonaceous chondrites as the most abundant organic matter and may be present in interstellar dusts and comets. With this view, our studies of the complex organic matter isolated from six CM2 chondrites, namely Yamato-74662, Yamato-791198, Yamato-793321, Yamato-86720, Belgica-7904, and Murchison are introduced and discussed in the text. The complex organic matter is acid-insoluble and organic solvent-insoluble, and therefore, it was examined by heating experiments to obtain information on its chemical constituents and characteristics. Three chondrites, Yamato-74662, Yamato-791198, and Murchison which have solvent-extractable organic compounds, such as amino acids, carboxylic acid, hydrocarbons, etc. possess thermally labile organic fraction in the complex organic matter. Organic compounds detected in the pyrolyzate of the complex organic matter number over 130 of which aromatic hydrocarbons are dominant. They appeared around 300 degrees C, and disappeared at about 600 degrees C with a maximum at 400-500 degrees C during the heating. On the other hand, the other three chondrites do not have the extractable organic compounds nor a thermally labile organic fraction. The presence or absence of the fraction in the complex organic matter likely indicates the presence or absence of the solvent-extractable organic compounds and relates to thermal history of the chondrite.     

Heliospheric implications of structure in the interstellar medium

Equilibrium models of diffuse interstellar material (ISM) near the Sun show a range of cloud densities, ionization, and temperatures which are consistent with data, although the local ISM must be inhomogeneous over ∼2 pc scales. The ISM close to the Sun has properties that are consistent with the sheetlike warm neutral (and partially ionized) gas detected in the Arecibo Millennium Survey. Local interstellar magnetic fields are poorly understood, but data showing weak polarization for nearby stars indicate dust may be trapped in fields or currents in the heliosheath nose region. Implications of this dust capture are widespread, and may impact the interpretation of the cosmic microwave background data. Observations of interstellar H⁰ inside of the solar system between 1975 and 2000 do not suggest any variation in the properties or structure of local interstellar H⁰ over distance scales of ∼750 AU to within the uncertainties.     

Low and medium energy gamma-ray astronomy — present status and future aspects

During the last few years quite some progress has been achieved in the field of low and medium energy gamma-ray astronomy below about 30 MeV. Gamma rays from the galactic center and anti-center region have been detected, which require a high interstellar electron flux in the 100 MeV range, if they are predominantly diffuse in nature. Though the Crab pulsar and its nebula are still the only galactic gamma-ray sources which definitely have been detected, some recently determined upper limits to the gamma-ray fluxes of other radio pulsars are close to the theoretically expected values. Active galaxies seem to have a maximum of luminosity in the range between several 100 keV and a few MeV and, therefore, are of special interest. First observational results have been reported on the Seyfert galaxies NGC 4151 and MCG 8-11-11, and the radio galaxy CenA. The nature of the diffuse cosmic gamma-ray component at low gamma-ray energies is not yet solved. Unresolved active galaxies are good candidates for its origin.Considering the present status of gamma ray astronomy the study of galactic sources like radio pulsars and the unidentified high energy gamma-ray sources, the Milky Way as a whole, active galaxies and the diffuse cosmic sky seem to be the prime targets for broad band observations below 30 MeV in the GRO area. An unexplored field like that of low energy gamma-ray astronomy, however, is always open for surprises.     

Solar modulation model with reentrant particles

We developed a one dimensional model of particle transport in the heliosphere. As opposite to widely used models, we apply a method where a quasi-particle is traced back in time. The model gives us the possibility to work on the possible existence of reentrant particles in the heliosphere that can be hardly solved by the traditional forward tracking method. Particles escape from the heliosphere and may reenter back. We estimate how these particles affect the modulation process in the heliosphere. Presented here are the results for different values of particles mean free path in the interstellar space and for different interstellar magnetic field values.     

The formation of organic molecules in astronomical ices.

An absorption feature at 3.4 micrometers has been observed in various lines-of-sight through the diffuse interstellar medium. Its position and width lead to an identification with the C-H stretching mode of solid organic material. A possible mechanism for the production of organic solids in the interstellar medium is UV photoprocessing of icy mantles which accrete on dust grains in dense clouds. Furthermore, thermally induced reactions involving formaldehyde molecules in the mantles could be an important source of organics. Laboratory simulation of these processes shows that a large variety of oxygen- and nitrogen-rich species may be produced. It is shown that the occurrence of periodic transient heating events plays an important role in the production of organic material in the ice mantles. Finally, it is pointed out how future missions like the Infrared Space Observatory (ISO) as well as analysis of comet material by Rosetta may be able to clarify the nature and evolution of interstellar organics.     

Origin of organic matter in the protosolar nebula and in comets.

Comet organics are traced to their origin in interstellar space. Possible sources of comet organics from solar nebula chemistry are briefly discussed. The infrared spectra of interstellar dust are compared with spectra of solar (space) irradiated laboratory organic residues and with meteorites. The spectra compare very favorably. The atomic composition of first generation laboratory organic residues compares favorably with that of comet Halley organics if divided into appropriate "volatile" (less refractory) and "refractory" (more refractory) complex organics.     

Initial results from COMPTEL onboard GRO

COMPTEL is the first imaging telescope to explore the MeV gamma-ray range (0.7 to 30 MeV). At present, it is performing a complete sky survey. In later phases of the mission selected celestial objects will be studied in more detail. The data from the first year of the mission have demonstrated that COMPTEL performs very well. First sky maps of the inner part of the Galaxy clearly identify the plane as a bright MeV-source (probably due to discrete sources as well as diffuse radiation). The Crab and Vela pulsar lightcurves have been measured with unprecedented accuracy. The quasars 3C273 and 3C279 have been seen for the first time at MeV energies. Both quasars show a break in their energy spectra in the COMPTEL energy range. The 1.8 MeV line from radioactive ²⁶A1 has been detected from the central region of the Galaxy and a first sky map of the inner part of the Galaxy has been obtained in the light of this line. Upper limits to gamma-ray line emission at 847 keV and 1.238 MeV from SN 1991T have been derived. Upper limits to the interstellar gamma-ray emissivity have been determined at MeV-energies. Several cosmic gamma-ray bursts within the field-of-view have been located with an accuracy of about 1°. On 1991 June 9, 11 and 15, COMPTEL observed gamma-ray emission (continuum and line) from three solar flares. Also neutrons were detected from the June 9 and June 15 flares.