The search for nitrogen compounds on the surface of Mars

Nitrogen is an essential element for life. Specifically, “fixed nitrogen” (i.e., NH₃, NH₄⁺, NO_x, or N that is chemically bound to either inorganic or organic molecules and is releasable by hydrolysis to NH₃ or NH₄⁺) is the form of nitrogen useful to living organisms. To date no direct analysis of Martian soil nitrogen content, or content of fixed nitrogen compounds has been done. Consequently, the planet's total inventory of nitrogen is unknown. What is known is that the N₂ content of the present-day Martian atmosphere is 0.2 mbar. It has been hypothesized that early in Mars' history (3 to 4 billion years ago) the Martian atmosphere contained much more N₂ than it does today. The values of N₂ proposed for this early Martian atmosphere, however, are not well constrained and range from 3 to 300 mbar of N₂. If the early atmosphere of Mars did contain much more N₂ than it does today the question to be answered is, Where did it go? The two main processes that could have removed it rapidly from the atmosphere include: 1) nonthermal escape of N-atoms to space; and 2) burial within the regolith as nitrates and nitrites. Nitrate will be stable in the highly oxidized surface soil of Mars, and will tend to accumulate in the soil. Such accumulations are observed in certain desert environments on Earth. Some NH₄⁺---N may also be fixed and stabilized in the soil by inclusion as a structural cation in the crystal lattices of certain phyllosilicates replacing K. Analysis of the Martian soil for traces of NO₃⁻ and NH₄⁺ during future missions will supply important information regarding the nitrogen abundance on Mars, its past climate as well as its potential for the evolution of life.     

MIRAX: a Brazilian X-ray astronomy satellite mission

We describe the “Monitor e Imageador de Raios-X” (MIRAX), an X-ray astronomy satellite mission proposed by the high-energy astrophysics group at the National Institute for Space Research (INPE) in Brazil to the Brazilian Space Agency. MIRAX is an international collaboration that includes, besides INPE, the University of California San Diego, the University of Tübingen in Germany, the Massachusetts Institute of Technology and the Space Research Organization Netherlands. The payload of MIRAX will consist of two identical hard X-ray cameras (10–200 keV) and one soft X-ray camera (2–28 keV), both with angular resolution of 5–7^′. The basic objective of MIRAX is to carry out continuous broadband imaging spectroscopy observations of a large source sample (9 months/yr) in the central Galactic plane region. This will allow the detection, localization, possible identification, and spectral/temporal study of the entire history of transient phenomena to be carried out in one single mission. MIRAX will have sensitivities of 5 mCrab/day in the 2–10 keV band (2 times better than the All Sky Monitor on Rossi X-ray Timing Explorer) and 2.6 mCrab/day in the 10–100 keV band (40 times better than the Earth Occultation technique of the Burst and Transient Source Experiment on the Compton Gamma-Ray Observatory). The MIRAX spacecraft will weigh about 200 kg and is expected to be launched in a low-altitude (600 km) circular equatorial orbit around 2007/2008.     

Variability in the solar constant from irradiances shortward of Lyman-Alpha

The variation in the solar constant, S(t), is reproduced by the SOLAR2000 Research Grade v1.05 empirical solar irradiance model and is described for 5 solar cycles between cycles 18 and 23 (February 14, 1947 through May 31, 2000). This solar constant variation is dependent upon the derivation data sets and the formulation of SOLAR2000 which are described in more detail. The S(t) temporal variability in SOLAR2000 is shown for the solar spectrum between 1–122 nm. The variability is consistent with previous discussions in the literature and a new result is shown where the 1–122 nm wavelength range accounts for about 5–14% of the standard deviation reported in the ASTM E-490 standard. The minimum-maximum range of S(t) variation due to 1–122 nm variability is between 1367.2768 Wm⁻² on 1986-152 and 1367.2877 Wm⁻² on 1957-340. The mean S(t) in these data is 1367.2796 Wm⁻².     

Energetic neutron and gamma-ray spectra under the earth radiation belts according to “SALUTE-7”-“KOSMOS-1686” orbital complex and “CORONAS-i” satellite data

The spectra of neutrons >10 MeV and gamma-rays 1.5–100 MeV under the Earth Radiation Belts, restored from the data, obtained onboard orbital complex “SALUTE-7”-“KOSMOS-1686”, are presented. The spectra shapes are similar to those for albedo neutrons and gamma-rays, but absolute values of their fluxes (0.2 cm⁻² s⁻¹ for neutrons, 0.8 cm⁻² s⁻¹ for gamma-rays at the equator and 1.2 cm⁻² s⁻¹, 1.9 cm⁻² s⁻¹, accordingly, at L=1.9) are several times as large. It is possibly explained by the fact that most of the detected particles were produced by the cosmic ray interactions with the orbital complex matter. Neutron and gamma-ray fluxes obtained from “CORONAS-I” data are near those for albedo particles.     

Energy deposition in the upper atmosphere in the EXCEDE III experiment

The EXCEDE III sounding rocket flight of April 27, 1990 used a 18 Ampere 2.5 keV electron beam to produce an artificial aurora in the region 90 to 115 km. A “daughter” sensor payload remotely monitored the low-energy X-ray spectrum while scanning photometers measured the spatial profile of prompt emissions of N₂⁺ (1N) and N₂ (2P) transitions (3914Å and 3805Å, respectively). Two Ebert-Fastie spectrometers measured the spectral region from 1800 to 8000Å. On the “mother” accelerator payload, the return current electron differential energy spectra were monitored by an electrostatic analyzer (up to 10 keV) and by a retarding potential analyzer (0 eV to 100 eV). We present an overview of the results from this experiment.     

A Far Infrared Photometer (FIRP) for the Infrared Telescope in Space (IRTS)

We describe the design and calibration of the Far-Infrared Photometer (FIRP), one of four focal plane instruments on the Infrared Telescope in Space (IRTS). The FIRP will provide absolute photometry in four bands centered at 150, 250, 400, and 700 μm with spectral resolution λ/Δλ ≈ 3 and spatial resolution ΔΘ = 0.5 degrees. High sensitivity is achieved by using bolometric detectors operated at 300 mK in an AC bridge circuit. The closed-cycle ³He refrigerator can be recycled in orbit. A 2 K shutter provides a zero reference for each field of view. More than 10% of the sky will be surveyed during the ≈3 week mission lifetime with a sensitivity of <10⁻¹³ W·cm⁻²·sr⁻¹ per 0.5 degree pixel.     

风云三号C星GNOS北斗掩星电离层探测初步结果

利用风云三号卫星C星GNOS掩星探测仪电离层数据,分析了2013年10月FY-3C GNOS探测的北斗掩星电离层廓线分布,将2013年10月1日至2015年10月10日期间FY-3C GNOS观测的F₂层峰值电子密度（N_mF₂）与地面电离层测高仪观测结果进行对比,验证了FY-3C GNOS北斗电离层掩星的探测精度.结果表明,FY3-C GNOS北斗电离层掩星与电离层测高仪探测的N_mF₂数据相关系数为0.96,平均偏差为10.21%,标准差为19.61%.在不同情况下其数据精度有如下特征:白天精度高于夜晚;夏季精度高于分季,分季精度高于冬季;中纬地区精度高于低纬地区,低纬地区精度高于高纬地区; BDS倾斜同步轨道（IGSO）卫星精度高于同步轨道（GEO）卫星和中轨道（MEO）卫星.FY-3C GNOS北斗电离层掩星与国际上其他掩星电离层数据精度的一致性对GNSS掩星探测资料的综合利用具有重大意义.      

The organic aerosols of Titan

A dark reddish organic solid, called tholin, is synthesized from simulated Titanian atmospheres by irradiation with high energy electrons in a plasma discharge. The visible reflection spectrum of this tholin is found to be similar to that of high altitude aerosols responsible for the albedo and reddish color of Titan. The real (n) and imaginary (k) parts of the complex refractive index of thin films of Titan tholin prepared by continuous D.C. discharge through a 0.9 N₂/0.1 CH₄ gas mixture at 0.2 mb is determined from x-ray to microwave frequencies. Values of n (1.65) and k (0.004 to 0.08) in the visible are consistent with deductions made by ground-based and spaceborne observations of Titan. Many infrared absorption features are present in k(λ), including the 4.6 μm nitrile band. Molecular analysis of the volatile component of this tholin was performed by sequential and non-sequential pyrolytic gas chromatography/mass spectrometry. More than one hundred organic compounds are released; tentative identifications include saturated and unsaturated aliphatic hydrocarbons, substituted polycyclic aromatics, nitriles, amines, pyrroles, pyrazines, pyridines, pyrimidines, and the purine, adenine. In addition, acid hydrolysis produces a racemic mixture of biological and non-biological amino acids. Many of these molecules are implicated in the origin of life on Earth, suggesting Titan as a contemporary laboratory environment for prebiological organic chemistry on a planetary scale.     

Hard X-ray spectral properties and discovery of narrow annihilation line in the spectrum of Nova Muscae

The observations of X-ray Nova in Musca (GRS1124-684) by two coded mask telescopes on board GRANAT observatory provided spectral data in broad 3 – 1300 keV band. During these observations, spanned over a year, the Nova was detected in a three apparently different spectral states, corresponding to different epochs of the soft X-ray light curve: (1) A spectrum with two distinct components (soft, below 8 keV and hard power law tail with slope 2.5, detected up to 300 keV). The soft emission changed gradually with characteristic decay time around 30 days, while power law component exhibited strong variability on the time scales of several hours and decreased much more slowly. (2) A soft spectrum (without hard power law tail), observed during the “kick” of the soft X-ray light curve. (3) A hard power law spectrum with slope 2.2. Thus, while the 3 – 300 keV luminosity decreased by more than order of magnitude, the source passed through all spectral states known for galactic black hole candidates (Cyg X-1, GX339-4, 1E1740.7-2942, GRS1758-258 etc.).

On January 20–21 1991, the SIGMA telescope aboard GRANAT detected a relatively narrow variable emission line near 500 keV (Fig.1,2) with net flux ≈ 6 · 10⁻³ phot/s/cm², most probably related with electron-positron annihilation processes, occurring in the source /1–4/. Additional excess above power law continuum, centered around 200 keV, was found during this observation.     

Modelling the neutral gas environment of comets with special application to P/Halley

A technique has been developed which allows relatively accurate modelling of cometary gas production from nothing more than a visible light curve. Application to P/Halley suggests the production rate of parent molecules will be about 2.6 × 10²⁹ per second on March 10, 1986, for example. The uncertainties and intrinsic limitations in this approach are outlined. The theory is then extended to predictions of abundance of other gaseous species, and a photometric model of these gases provided. Combined with the dust model of N. Divine, preliminary predictions of the luminance of P/Halley as seen in any direction from inside the coma or outside can be provided for λλ3000–7000.     

The Swift GRB MIDEX mission

Swift is a first-of-its-kind multiwavelength transient observatory for γ-ray burst astronomy. It has the optimum capabilities for the next breakthroughs in determining the origin of γ-ray bursts and their afterglows, as well as for using bursts to probe the early Universe. Swift will also monitor the soft gamma repeaters and perform the first sensitive hard X-ray survey of the sky. The mission is being developed by an international collaboration and consists of three instruments, the Burst Alert Telescope (BAT), the X-ray Telescope (XRT), and the Ultraviolet and Optical Telescope (UVOT). The BAT, a wide-field γ-ray detector, will detect >100 γ-ray bursts per year with a sensitivity 5× that of BATSE. The sensitive narrow-field XRT and UVOT will be autonomously slewed to the burst location within 20–70 s to determine 0.3–5.0″ positions and perform optical, UV, and X-ray spectrophotometry. Strong education/public outreach and follow-up programs will help to engage the public and the astronomical community. Swift launch is planned for late 2004.     

Towards validation of SCIAMACHY lunar occultation NO2 vertical profiles

Vertical profiles of stratospheric nitrogen dioxide (NO₂) have been retrieved from moderate resolution lunar occultation transmission spectra measured by Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) on board the European Environmental Satellite (ENVISAT). These measurements were taken over the high southern latitude of 50°–90° during the period of 2003–2005. To assess the accuracy of the retrieved NO₂ profiles, the SCIAMACHY nighttime NO₂ profiles were compared with NO₂ profiles retrieved from sunrise solar occultation spectra measured by the Halogen Occultation Experiment (HALOE) and the Stratospheric Aerosol and Gas Experiments II (SAGE II) using a photochemical correction model. The validation results show good agreement of SCIAMACHY lunar occultation NO₂ with scaled HALOE and SAGE II profiles. The relative mean differences (rmd) with scaled HALOE profiles are within −13% to +5% and standard deviations (rms) of the relative differences are within 3–19% between 25 and 38 km. The rmd and rms with scaled SAGE II NO₂ profiles are in the range of −9 to +7 and 10–17% respectively between 22 and 39 km.     

Dynamics of the low altitude secondary proton radiation belt

At the interface between the upper atmosphere and the radiation belt region, there exists a secondary radiation belt consisting mainly of energetic ions that have become neutralized in the ring current and the main radiation belt and then re-ionized by collisions in the inner exosphere. The time history of the proton fluxes in the 0.64 – 35 MeV energy range was traced in the equatorial region beneath the main radiation belts during the three year period from 21 February 1984 to 26 March 1987 using data obtained with the HEP experiment on board the Japanese OHZORA satellite. During most of this period a fairly small proton flux of −1.2 cm⁻² s⁻¹ sr⁻¹ was detected on geomagnetic field lines in the range 1.05 < L < 1.15. We report a few surprisingly deep and rapid flux decreases (flux reduction by typically two orders of magnitude). These flux decreases were also long in duration (lasting up to three months). We also registered abrupt flux increases where the magnitude of the proton flux enhancements could reach three orders of magnitude with an enhancement duration of 1–3 days. Possible reasons for these unexpected phenomena are discussed.     

Solar radiation variability in the last 1400 years recorded in the carbon isotope ratio of a mediterranean sea core

We present measurements and data analysis of the carbon stable isotopes (δ¹³C) in the planktonic Globigerinoides ruber extracted from the GT90/3 shallow water Ionian sea core, dated with high precision. It is commonly accepted that δ¹³C variations in symbiontic foraminifera mainly record the effects of productivity and of photosynthetic activity, varying with the ambient light level. Therefore from this time series we can deduce information on the sea surface illumination at the time of the planktonic foraminifera growth. The profile (359 points) covers the period 590–1979 AD, with a resolution of 3.87 years and it is an extension of the time series (215 points) previously published in this journal. The spectral analysis of the longer time series confirms the presence of the 11 y signal, with amplitude 0.08‰ (peak-to-trough), found in the shorter time series in phase with the sunspot solar cycle; furthermore it shows the presence of two centennial cycles of 100 and 200 years, with amplitude 0.08‰ and 0.02‰ respectively. These components are identified at high significance level by Monte Carlo singular spectrum analysis (MC-SSA). A comparison between the δ¹³C profile and the historical aurorae series (600–1500 AD) shows that the long-term δ¹³C variations are at least partially generated by the solar activity modulation and in phase with the solar output, as represented by the solar wind interaction with the magnetosphere.     

Hard X-ray focusing optics up to 80 keV for the future missions

X-ray telescopes have been providing high sensitivity X-ray observations in numerous missions. For X-ray telescopes in the future, one of the key technologies is to expand the energy band beyond 10 keV. We designed depth-graded multilayer, so-called supermirrors, for a hard X-ray telescope in the energy band up to 40 keV using lightweight thin-foil optics. They were successfully flown in a balloon flight and obtained a hard X-ray image of Cyg X-1 in the 20–40 keV band. Now supermirrors are promising to realize a hard X-ray telescope. We have estimated the performance of a hard X-ray telescope using a platinum–carbon supermirror for future satellite missions, such as NeXT (Japan) and XEUS (Europe). According to calculations, they will have a significant effective area up to 80 keV, and their effective areas will be more than 280 cm² even at 60 keV. Limiting sensitivity will be down to 1.7 × 10⁻¹³ erg cm⁻² s⁻¹ in the 10–80 keV band at a 100 ks observation. In this paper, we present the results of the balloon experiment with the first supermirror flown and projected effective areas of hard X-ray telescopes and action items for future missions.     

Real time localization of gamma ray bursts with INTEGRAL

The INTEGRAL satellite has been successfully launched in October 2002 and has recently started its operational phase. The INTEGRAL burst alert system (IBAS) will distribute in real time the coordinates of the gamma ray bursts (GRBs) detected with INTEGRAL. After a brief introduction on the INTEGRAL instruments, we describe the main IBAS characteristics and report on the initial results. During the initial performance and verification phase of the INTEGRAL mission, which lasted about two months, two GRBs have been localized with accuracy of 2–4 arcmin. These observations have allowed us to validate the IBAS software, which is now expected to provide quick (few seconds delay) and precise (few arcmin) localization for 10–15 GRBs per year.     

X-ray spectroscopy and variability of AGN detected in the 2 Ms Chandra Deep Field-North Survey

We investigate the nature of the faint X-ray source population through X-ray spectroscopy and variability analyses of 136 active galactic nuclei (AGN) detected in the 2 Ms Chandra Deep Field-North Survey with >200 background-subtracted 0.5–8.0 keV counts [F_{0.5–8.0 keV} = (1.4−200) × 10⁻¹⁵ erg cm⁻² s⁻¹]. Our preliminary spectral analyses yield median spectral parameters of Γ = 1.61 and intrinsic N_H = 6.2 × 10²¹ cm⁻² (z = 1 assumed when no redshift available) when the AGN spectra are fitted with a simple absorbed power-law model. However, considerable spectral complexity is apparent (e.g., reflection, partial covering) and must be taken into account to model the data accurately. Moreover, the choice of spectral model (i.e., free vs. fixed photon index) has a pronounced effect on the derived JVH distribution and, to a lesser extent, the X-ray luminosity distribution. We also find that among the 136 AGN, 10 (≈7%) show significant Fe K emission-line features with equivalent widths in the range 0.1–1.3 keV. Two of these emission-line AGN could potentially be Compton thick (i.e., Γ < 1.0 and large Fe K equivalent width). Finally, we find that 81 (≈60%) of the 136 AGN show signs of variability, and that this fraction increases significantly (≈80–90%) when better photon statistics are available.     

Diurnal variations of ion flux intensity on a synchronous orbit

The data from the synchronous-orbit satellites of the Gorizont series are used to study the dependences of the ion flux variation amplitudes in the synchronous altitude region (the diurnal behaviour) on particle energies and on the form and rigidity of the particle energy spectrum. The proton fluxes were measured in the energy range E 60–120 keV, and the [N,0]²⁺ and [C,N,0]⁴⁺ ion fluxes in the energy range E 60–70 keV/e.

The ratio of the diurnal variation amplitudes of the studied ions is shown to correspond to the similarity of their energy spectra in the E/Q representation. The magnetically-quiet time gradient of the distribution function F(μ,J,L) in the synchronous-orbit region is shown to be (∂F/∂L)=0 for the H⁺ and [N,0]²⁺ ions and (∂F/∂L) > 0 for the [C,N,0]⁴⁺ ions (at the values of μ corresponding to the examined energy ranges). During magnetically-disturbed periods the inner boundary of the (∂F/∂L)=0 region shifts to lower L and (∂ F/∂L) = O in the synchronous altitude region must be also for the [C,N,O]⁴⁺ ions.     

Contribution of solar UV radiation to the observed ozone variations during the 21st and 22nd solar cycles

A two-dimensional dynamical radiative-photochemical model of the ozonosphere including aerosol physics is used to examine the changes of the Earth's ozone layer occurred during the 21st and 22nd solar cycles. The calculated global total ozone changes in the latitude range 60°S—60°N caused by 11-year variation of solar UV radiation, volcanic eruptions, and anthropogenic atmospheric pollution containing CO₂, CH₄, N₂O and chlorine and bromine species are in a rather good agreement with the observed global ozone trend. The calculations show that the anthropogenic pollution of the atmosphere is a main reason of the ozone depletion observed during the last two solar cycles. However, the 11-year solar UV variation as well as volcanic eruptions of El Chichon and Mt. Pinatubo also gave a significant contribution to the observed global ozone changes.     

Energetic ion emission for active spacecraft control

Future space missions aiming at the accurate measurement of cold plasmas and DC to very low frequency electric fields will require that the potential of their conductive surfaces be actively controlled to be near the ambient plasma potential. In the near-Earth space these spacecraft are usually solar-cell powered; consequently, parts of their surface are most of the time exposed to solar photons. Outside the plasmasphere, a positive surface potential due the dominance of surface-emitted photoelectrons over ambient plasma electrons is to be expected. Photo- and ambient electrons largely determine the potential and positive values between a few Volts up to 100 V have been observed. Active ion emission is the obvious solution of this problem. A liquid metal ion emitter and a saddle field ion emitter are nearing the stage of flight unit fabrication. We will attempt to clamp the spacecraft potential to values close to the plasma potential. We present first results from vacuum chamber tests and describe the emission behaviour and characteristics of emitters producing, respectively, In⁺ and N₂⁺ beams with an energy of ≥ 5 keV.