Satellite measurements of atmospheric composition: Three years' observations of CH4 and N2O

The stratospheric and mesospheric sounder (SAMS) was launched in October 1978 on the NIMBUS 7 satellite. Between then and its eventual failure in June 1983 the instrument was used to collect over four years of radiance data from which atmospheric temperature and the abundances of a number of minor constituents have been derived. The paper will present fields of CH₄ and N₂O between 50S and 70N derived from SAMS data for the period 1979–1981. Global distributions of CH₄ and N₂O will be presented in various forms and the observed seasonal changes and interannual variability will be described. The paper will compare the SAMS CH₄ and N₂O data with model predictions and will comment upon some other areas of interest.     

Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

Meteorites in Antarctica — Statistics on falls, concentration, recovery and alteration on ice-sheet

The Antarctic meteorites are distributed on the blue-ice area surfaces in the ablation zone of the Antarctic ice-sheet, to where meteorites have been transported by the ice-flow within the ice-sheet from the wider accumulation zone. Among the Antarctic meteorite collection H- and L-chondrites are most abundant; this is also true in the non-Antarctic meteorite collection. Meteorite showers also are involved in the collection. Several new types of stony meteorites have been discovered from the Antarctic meteorite collection. The mass and shape of Antarctic meteorites are in agreement with those of resultant fragments of high-speed impact basaltic rocks. In Antarctica, small fragments of meteorite smaller than 1 kg in weight can easily be found and collected. The solidification and the gas retention ages of Antarctic meteorites also are concentrated around 4.5×10⁹ years, but some of them are considerably younger. Their cosmic-ray exposure ages are extended up to 9×10⁶ years and their terrestrial ages are 9×10⁴-7×10⁵ years.     

Statistical comparison of night-time NO2 observations in 2003–2006 from GOMOS and MIPAS instruments

GOMOS (Global Ozone Monitoring by Occultation of Stars) and MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) are remote sensing instruments on board the European Space Agency’s Envisat satellite. GOMOS and MIPAS have been designed for observations of stratospheric and mesospheric constituents, including ozone and nitrogen dioxide. Both instruments have a good global coverage of observations and can provide data also from the polar regions. In this paper, we compare night-time NO₂ data from GOMOS with those from MIPAS. We present statistics of selected sets of data spanning from the year 2003 to 2006. The results for low-to-mid latitudes show that the two instruments are in a good agreement in the middle stratosphere, the differences being typically less than 5%. In the upper stratosphere, GOMOS observations generally show 15% higher values than those from MIPAS. The bias is in virtually all cases smaller than the combined systematic error of the measurements, giving great confidence in the GOMOS and MIPAS data quality. The result for high mesospheric NO₂ mixing ratios observed in the polar regions during winter times indicate a good agreement between GOMOS and MIPAS. In the mesosphere, the difference is less than 35% and smaller than the systematic error. Due to the high mesospheric signal, MIPAS sensitivity decreases in the stratosphere which results in larger differences between the two instruments.     

The improvement of IRI profiles of O2+, NO+ and O+ by means of airglow measurements

Methods were suggested in /1,2,3/ to find the maximum electron density N_mF (or N_mF2) and the) corresponding height h_mF (h_mF2) in the ionosphere through a combination of measurements on two airglow lines: the UV oxygen line at λ135.6 nm and the red oxygen line near λ630 nm.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Estimation of the Love and Shida numbers: h2, l2 using SLR data for the low satellites

In this paper we present results for the global elastic parameters: Love number h₂ and Shida number l₂ derived from the analysis of Satellite Laser Ranging (SLR) data. SLR data for the two low satellites STELLA (H = 800 km) and STARLETTE (H = 810 km) observed during 2.5 years from January 3, 2005 until July 1, 2007 with 18 globally distributed ground stations were analyzed. The analysis was done separately for the two satellites. We do a sequential analysis and study the stability and convergence of the estimates as a function of length of the data set used.     

Probable interstellar MgX (X = CN, NC, CCH, CC, C3N, NCCC, CCNC, C4H, and C4): A DFT study

The geometries, dipole moments, and rotational constants for several magnesium compounds and their anions were calculated by using the B3LYP/Aug-cc-pVTZ method. The rotational constants of linear forms have been derived to be used for laboratory experiment and astronomical observation.     

Nighttime thermospheric meridional neutral winds inferred from ionospheric h′F and hpF2 data

Nighttime thermospheric meridional winds aligned to the magnetic meridian have been inferred using h′F and hpF2 ionosonde data taken from two equatorial stations, Manaus (2.9°S, 60.0°W, dip latitude 6.0°N) and Palmas (10.17°S, 48.2°W, dip latitude 6.2°S), and one low-latitude station, Sao Jose dos Campos (23.21°S, 45.86°W, dip latitude 17.26°S), during geomagnetic quiet days of August and September, 2002. Using an extension of the ionospheric servo model and a simple formulation of the diffusive vertical drift velocity, the magnetic meridional component of the thermospheric neutral winds is inferred, respectively, at the peak (hpF2) and at the base (h′F) heights of the F region over Sao Jose dos Campos. An approach has been included in the models to derive the effects of the electrodynamic drift over Sao Jose dos Campos from the time derivative of hpF2 and h′F observed at the equatorial stations. The magnetic meridional winds inferred from the two methods, for the months of August and September, are compared with winds calculated using the HWM-90 model and with measurements from Fabry–Perot technique. The results show varying agreements and disagreements. Meridional winds calculated from hpF2 ionospheric data (servo model) may produce errors of about 59 m/s, whereas the method calculated from the F-region base height (h′F) ionospheric data gives errors of about 69 m/s during the occurrence of equatorial spread-F.     

The effects of CO2 on growth and transpiration of radish (Raphanus sativus) in hypobaria

Plants grown on long-term space missions will likely be grown in low pressure environments (i.e., hypobaria). However, in hypobaria the transpiration rates of plants can increase and may result in wilting if the water is not readily replaced. It is possible to reduce transpiration by increasing the partial pressure of CO₂ (pCO₂), but the effects of pCO₂ at high levels (>120 Pa) on the growth and transpiration of plants in hypobaria are not known. Therefore, the effects of pCO₂ on the growth and transpiration of radish (Raphanus sativus var. Cherry Bomb II) in hypobaria were studied. The fresh weight (FW), leaf area, dry weight (DW), CO₂ assimilation rates (C_A), dark respiration rates (DR), and transpiration rates from 26 day-old radish plants that were grown for an additional seven days at different total pressures (33, 66 or 101 kPa) and pCO₂ (40 Pa, 100 Pa and 180 Pa) were measured. In general, the dry weight of plants increased with CO₂ enrichment and with lower total pressure. In limiting pCO₂ (40 Pa) conditions, the transpiration for plants grown at 33 kPa was approximately twice that of controls (101 kPa total pressure with 40 Pa pCO₂). Increasing the pCO₂ from 40 Pa to 180 Pa reduced the transpiration rates for plants grown in hypobaria and in standard atmospheric pressures. However, for plants grown in hypobaria and high pCO₂ (180 Pa) leaf damage was evident. Radish growth can be enhanced and transpiration reduced in hypobaria by enriching the gas phase with CO₂ although at high levels leaf damage may occur.     

Detection of volcanic,CO2, and ENSO signals in surface air temperature

The Russian surface air temperature data set (Northern Hemisphere, gridded, monthly average, 1891–1981) is analyzed to separate signals from large volcanic eruptions, ENSO (El Niño/Southern Oscillation) events, and signals in conjunction with hemispheric temperature changes. Characteristic patterns of zonal average temperature as a function of month and latitude as well as monthly average maps are produced for each forcing. The largest response to volcanic forcing appears at a lag of 2 and 3 years following volcanic eruptions. The zonal average response shows cooling at all latitudes and months, except in the Arctic in summer. The largest cooling is in the high latitudes in the winter. This agrees very well with energy balance model calculations of the response pattern to large volcanic eruptions, and can be explained by sea ice/thermal inertia and, to a lesser extent, snow/albedo feedbacks. The spatial pattern shows large areas of cooling at all longitudes. In response to ENSO oscillations the largest response is synchronous or with the temperature lagging ENSO oscillations by 6 months. The zonal average response is virtually zero, but the spatial patterns show large variations of opposite sign at different longitudes. Patterns produced by weighting temperature anomalies with hemispheric mean temperature indicate patterns to be expected following a CO₂ warming.     

Symmetry,reduction and relative equilibria of a rigid body in the J2 problem

The J₂ problem is an important problem in celestial mechanics, orbital dynamics and orbital design of spacecraft, as non-spherical mass distribution of the celestial body is taken into account. In this paper, the J₂ problem is generalized to the motion of a rigid body in a J₂ gravitational field. The relative equilibria are studied by using geometric mechanics. A Poisson reduction process is carried out by means of the symmetry. Non-canonical Hamiltonian structure and equations of motion of the reduced system are obtained. The basic geometrical properties of the relative equilibria are given through some analyses on the equilibrium conditions. Then we restrict to the zeroth and second-order approximations of the gravitational potential. Under these approximations, the existence and detailed properties of the relative equilibria are investigated. The orbit–rotation coupling of the rigid body is discussed. It is found that under the second-order approximation, there exists a classical type of relative equilibria except when the rigid body is near the surface of the central body and the central body is very elongated. Another non-classical type of relative equilibria can exist when the central body is elongated enough and has a low average density. The non-classical type of relative equilibria in our paper is distinct from the non-Lagrangian relative equilibria in the spherically-simplified Full Two Body Problem, which cannot exist under the second-order approximation. Our results also extend the previous results on the classical type of relative equilibria in the spherically-simplified Full Two Body Problem by taking into account the oblateness of the primary body. The results on relative equilibria are useful for studies on the motion of many natural satellites, whose motion are close to the relative equilibria.     

A low dose pre-irradiation induces radio- and heat-resistance via HDM2 and NO radicals,and is associated with p53 functioning

The aim of this work was to clarify the effect of low dose pre-irradiation on radio- and heat-sensitivity. Wild-type (wt) p53 and mutated (m) p53 cells derived from the human lung cancer H1299 cell line were used. The parental H1299 cell line is p53-null. Cellular sensitivities were determined with a colony-forming assay. When wtp53 cells were exposed to a low dose X-irradiation, induction of radio- and heat-resistance was observed only in the absence of RITA (an inhibitor of p53-HDM2 interactions), aminoguanidine (an iNOS inhibitor) and c-PTIO (an NO radical scavenger). In contrast, the induced radio- and heat-resistance was not observed under similar conditions in mp53 cells. Moreover, heat-resistance as well as radio-resistance developed when wtp53 cells were treated with ISDN (an NO generating agent) alone. These findings suggest that NO radicals are an initiator of radio- and heat-resistance, and function through the activation of HDM2 and the depression of p53 accumulation.     

Thermal properties of molten InSb,GaSb, and InxGa1−xSb alloy semiconductor materials in preparation for crystal growth experiments on the international space station

The thermal properties of InSb, GaSb and In_xGa_1−xSb, such as the viscosity, wetting property, and evaporation rate, were investigated in preparation for the crystal growth experiment on the International Space Station (ISS). The viscosity of InGaSb, which is an essential property for numerical modeling of crystal growth, was evaluated. In addition, the wetting properties between molten In_xGa_1−xSb and quartz, BN, graphite, and C-103 materials were investigated. The evaporation rate of molten In_xGa_1−xSb was measured to determine the affinity of different sample configurations. From the measurements, it was found that the viscosity of In_xGa_1−xSb was between that of InSb and GaSb. The degree of wetting reaction between molten In_xGa_1−xSb and the C-103 substrate was very high, whereas that between molten In_xGa_1−xSb and quartz, BN, and graphite substrates was very low. The results suggest that BN and graphite can be used as materials to cover InSb and GaSb samples inside a quartz ampoule during the microgravity experiments. In addition, the difference of the evaporation rate of molten In_xGa_1−xSb, GaSb, and InSb was small at low, and large at high temperature.     

SCIAMACHY limb measurements of NO2, BrO and OClO. Retrieval of vertical profiles: Algorithm,first results,sensitivity and comparison studies

The Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) measures scattered sun light also in limb viewing mode (i.e. tangential to Earth’s surface and its atmosphere), which allows determining vertical profiles of atmospheric trace gases. First results on the retrieval of NO₂, BrO and OClO profiles from the SCIAMACHY Limb measurements are presented and compared to independent satellite and balloon borne observations.     

Directional solidification of complex-forming eutectic melt of the PbCl2-AgCl dielectric system under conditions of zero, normal and increased gravity

First results in the area of studying the influence of gravity field on the degree of ordering of directionally solified eutectict are presented. As the model complex-forming melts, PbCl₂ and its eutectic with AgCl was chosen. Directional solidification of the mentioned eutectic was realised under conditions of zero, normal and increased gravity. It was shown that increasing level of gravity results in a marked improvement of the degree of spacial ordering of the lamelar structure.     

Seasonal and diurnal behavior of NO2 column density in Antarctica as observed by Mark IV,Brewer Ozone Spectrophotometer Number 153

The Meteorology Department of India has been measuring vertical column density of NO₂ at Maitri (70.7°S, 11.7°E), Antarctica since July 1999 using a Mark IV, Brewer Ozone Spectrophotometer. Maitri is situated at the south of the Antarctic circle. An analysis of 6 years of data shows that NO₂ column has seasonal variation with a maximum value during summer. It is also found that during the period when sun does not set, the NO₂ column exhibits a diurnal variation, with a peak around noon and lower values in the morning and afternoon hours. Using a simple steady-state chemical reaction scheme, an attempt has been made to explain these features.     

Upgrading CCIR's foF2 maps using available ionosondes and genetic algorithms

We have developed a new approach towards a new database of the ionospheric parameter $f_{o}F2$. This parameter, being the frequency of the maximum of the ionospheric electronic density profile and its main modeller, is of great interest not only in atmospheric studies but also in the realm of radio propagation. The current databases, generated by CCIR (Committee Consultative for Ionospheric Radiowave propagation) and URSI (International Union of Radio Science), and used by the IRI (International Reference Ionosphere) model, are based on Fourier expansions and have been built in the 60s from the available ionosondes at that time. The main goal of this work is to upgrade the databases by using new available ionosonde data. To this end we used the IRI diurnal/spherical expansions to represent the $f_{o}F2$ variability, and computed its coefficients by means of a genetic algorithm (GA). In order to test the performance of the proposed methodology, we applied it to the South American region with data obtained by RAPEAS (Red Argentina para el Estudio de la Atmósfera Superior, i.e. Argentine Network for the Study of the Upper Atmosphere) during the years 1958–2009. The new GA coefficients provide a global better fit of the IRI model to the observed $f_{o}F2$ than the CCIR coefficients. Since the same formulae and the same number of coefficients were used, the overall integrity of IRI’s typical ionospheric feature representation was preserved. The best improvements with respect to CCIR are obtained at low solar activities, at large (in absolute value) modip latitudes, and at night-time. The new method is flexible in the sense that can be applied either globally or regionally. It is also very easy to recompute the coefficients when new data is available. The computation of a third set of coefficients corresponding to days of medium solar activity in order to avoid the interpolation between low and high activities is suggested. The same procedure as for $f_{o}F2$ can be perfomed to obtain the ionospheric parameter M(3000)F2.