Cometary Dust

This review presents our understanding of cometary dust at the end of 2017. For decades, insight about the dust ejected by nuclei of comets had stemmed from remote observations from Earth or Earth’s orbit, and from flybys, including the samples of dust returned to Earth for laboratory studies by the Stardust return capsule. The long-duration Rosetta mission has recently provided a huge and unique amount of data, obtained using numerous instruments, including innovative dust instruments, over a wide range of distances from the Sun and from the nucleus. The diverse approaches available to study dust in comets, together with the related theoretical and experimental studies, provide evidence of the composition and physical properties of dust particles, e.g., the presence of a large fraction of carbon in macromolecules, and of aggregates on a wide range of scales. The results have opened vivid discussions on the variety of dust-release processes and on the diversity of dust properties in comets, as well as on the formation of cometary dust, and on its presence in the near-Earth interplanetary medium. These discussions stress the significance of future explorations as a way to decipher the formation and evolution of our Solar System.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

The STEREO Mission: An Introduction

The twin STEREO spacecraft were launched on October 26, 2006, at 00:52 UT from Kennedy Space Center aboard a Delta 7925 launch vehicle. After a series of highly eccentric Earth orbits with apogees beyond the moon, each spacecraft used close flybys of the moon to escape into orbits about the Sun near 1 AU. Once in heliospheric orbit, one spacecraft trails Earth while the other leads. As viewed from the Sun, the two spacecraft separate at approximately 44 to 45 degrees per year. The purposes of the STEREO Mission are to understand the causes and mechanisms of coronal mass ejection (CME) initiation and to follow the propagation of CMEs through the inner heliosphere to Earth. Researchers will use STEREO measurements to study the mechanisms and sites of energetic particle acceleration and to develop three-dimensional (3-D) time-dependent models of the magnetic topology, temperature, density and velocity of the solar wind between the Sun and Earth. To accomplish these goals, each STEREO spacecraft is equipped with an almost identical set of optical, radio and in situ particles and fields instruments provided by U.S. and European investigators. The SECCHI suite of instruments includes two white light coronagraphs, an extreme ultraviolet imager and two heliospheric white light imagers which track CMEs out to 1 AU. The IMPACT suite of instruments measures in situ solar wind electrons, energetic electrons, protons and heavier ions. IMPACT also includes a magnetometer to measure the in situ magnetic field strength and direction. The PLASTIC instrument measures the composition of heavy ions in the ambient plasma as well as protons and alpha particles. The S/WAVES instrument uses radio waves to track the location of CME-driven shocks and the 3-D topology of open field lines along which flow particles produced by solar flares. Each of the four instrument packages produce a small real-time stream of selected data for purposes of predicting space weather events at Earth. NOAA forecasters at the Space Environment Center and others will use these data in their space weather forecasting and their resultant products will be widely used throughout the world. In addition to the four instrument teams, there is substantial participation by modeling and theory oriented teams. All STEREO data are freely available through individual Web sites at the four Principal Investigator institutions as well as at the STEREO Science Center located at NASA Goddard Space Flight Center.     

Dust Near The Sun

We review the current knowledge and understanding of dust in the inner solar system. The major sources of the dust population in the inner solar system are comets and asteroids, but the relative contributions of these sources are not quantified. The production processes inward from 1 AU are: Poynting-Robertson deceleration of particles outside of 1 AU, fragmentation into dust due to particle-particle collisions, and direct dust production from comets. The loss processes are: dust collisional fragmentation, sublimation, radiation pressure acceleration, sputtering, and rotational bursting. These loss processes as well as dust surface processes release dust compounds in the ambient interplanetary medium. Between 1 and 0.1 AU the dust number densities and fluxes can be described by inward extrapolation of 1 AU measurements, assuming radial dependences that describe particles in close to circular orbits. Observations have confirmed the general accuracy of these assumptions for regions within 30° latitude of the ecliptic plane. The dust densities are considerably lower above the solar poles but Lorentz forces can lift particles of sizes < 5 μm to high latitudes and produce a random distribution of small grains that varies with the solar magnetic field. Also long-period comets are a source of out-of-ecliptic particles. Under present conditions no prominent dust ring exists near the Sun. We discuss the recent observations of sungrazing comets. Future in-situ experiments should measure the complex dynamics of small dust particles, identify the contribution of cometary dust to the inner-solar-system dust cloud, and determine dust interactions in the ambient interplanetary medium. The combination of in-situ dust measurements with particle and field measurements is recommended.     

Reservoir for Comet Material: Circumstellar Grains

Primitive meteorites and interplanetary dust particles contain small quantities of dust grains with highly anomalous isotopic compositions. These grains formed in the winds of evolved stars and in the ejecta of stellar explosions, i.e., they represent a sample of circumstellar grains that can be analyzed with high precision in the laboratory. Such studies have provided a wealth of information on stellar evolution and nucleosynthesis, Galactic chemical evolution, grain growth in stellar environments, interstellar chemistry, and the inventory of stars that contributed dust to the Solar System. Among the identified circumstellar grains in primitive solar system matter are diamond, graphite, silicon carbide, silicon nitride, oxides, and silicates. Circumstellar grains have also been found in cometary matter. To date the available information on circumstellar grains in comets is limited, but extended studies of matter returned by the Stardust mission may help to overcome the existing gaps.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Assessing the elemental composition of comet 81P/Wild 2 by analyzing dust collected by Stardust

One of the prime objectives in the analysis of cometary dust collected by the Stardust space mission is to determine the elemental composition of comet 81P/Wild 2. For this analysis, samples captured by two sampling media, silica aerogel and Al foil, were available. While aerogel was qualified to sample the dust almost intact, particles impinging on Al foils produced hypervelocity impact craters with residual cometary matter. Both sample types delivered valuable information on the cometary inventory, even though a slight loss of volatiles was observed for impact residues on Al foils. Altogether an elemental composition close to solar elemental abundances was observed, indicating that the early solar system was chemically rather homogeneous from the innermost regions close to the sun to the outer edge of the solar system, the presumed region of cometary origin.     

Composition of the Volatile Material in Halley's Coma from In Situ Measurements

The investigation of the volatile material in the coma of comets is a key to understanding the origin of cometary material, the physical and chemical conditions in the early solar system, the process of comet formation, and the changes that comets have undergone during the last 4.6 billion years. So far, in situ investigations of the volatile constituents have been confined to a single comet, namely P/Halley in 1986. Although, the Giotto mission gave only a few hours of data from the coma, it has yielded a surprising amount of new data and has advanced cometary science by a large step. In the present article the most important results of the measurements of the volatile material of Halley's comet are summarized and an overview of the identified molecules is given. Furthermore, a list of identified radicals and unstable molecules is presented for the first time. At least one of the radicals, namely CH₂, seems to be present as such in the cometary ice. As an outlook to the future we present a list of open questions concerning cometary volatiles and a short preview on the next generation of mass spectrometers that are being built for the International Rosetta Mission to explore the coma of Comet Wirtanen. This revised version was published online in June 2006 with corrections to the Cover Date.     

Ptolemy – an Instrument to Measure Stable Isotopic Ratios of Key Volatiles on a Cometary Nucleus

A fundamental goal of cometary studies is to determine the exact relationship between these bodies and the Solar System – the question(s) can be summarised as follows: did comets originate during the same events that spawned the Sun and planets, are they more primitive bodies that record a pre-solar history, or are they interstellar materials collected in relatively more recent times? Now, whatever the origin of comets, it is entirely possible that they could, in part, contain interstellar or pre-solar components – indeed, it seems rather likely in light of the fact that primitive meteorites contain such entities. These particular components are likely to be refractory (dust, macromolecular organic complexes, etc.). Of more relevance to the issues above are the volatile constituents, which make up the bulk of a comet's mass. Since these materials, by their very nature, volatilise during perihelion passage of a comet they can, in some instances, be detected and measured spectroscopically. Perhaps the most useful species for isotopic investigations are C₂, HCN and CN. Unfortunately, spectroscopic measurements can only currently be made with accuracies of ±10 to ±20%. As such it is very often not practical to conclude anything further than the fact that isotopic measurements are compatible with ‘`solar’' values, which tends to imply an origin from the margins of the solar accretion disk. But there is another problem with the spectroscopic measurements – since these are made on gaseous species in the coma (and relatively minor species at that) it is impossible to be certain that these represent the true nuclear values. In other words, if the processes of sublimation, active jetting, and photochemistry in the coma impart isotopic fractionation, the spectroscopic measurements could give a false impression of the true isotope ratios. What is required is an experiment capable of measuring isotopic ratios at the very surface of a comet. Herein we describe the Ptolemy instrument, which is included on the Philae lander as part of the Rosetta mission to 67P/Churyumov-Gerasimenko. The major objective of Ptolemy is a detailed appraisal of the nature and isotopic compositions of all materials present at the surface of a comet.     

The STEREO Observatory

The Solar Terrestrial Relations Observatory (STEREO) is the third mission in NASA’s Solar Terrestrial Probes program. The mission is managed by the Goddard Space Flight Center (GSFC) and implemented by The Johns Hopkins University Applied Physics Laboratory (JHU/APL). This two-year mission provides a unique and revolutionary view of the Sun–Earth system. Consisting of two nearly identical observatories, one ahead of Earth in its orbit around the Sun and the other trailing behind the Earth, the spacecraft trace the flow of energy and matter from the Sun to Earth and reveal the three-dimensional structure of coronal mass ejections (CMEs) to help explain their genesis and propagation. From its unique side-viewing vantage point, STEREO also provides alerts for Earth-directed solar ejections. These alerts are broadcast at all times and received either by NASA’s Deep Space Network (DSN) or by various space-weather partners.     

Rocky Cometary Particulates: Their Elemental,Isotopic and Mineralogical Ingredients

The determination of the chemical composition of solid cometary dust particles was one of the prime objectives of the three missions to Comet Halley in 1986. The dust analysis was performed by time-of-flight mass-spectrometry. Within the experimental uncertainty the mean abundances of the rock-forming elements in cometary dust particles are comparable to their abundances in CI-chondrites and in the solar photosphere, i.e. they are cosmic. H, C, and N, on the other hand, in cometary dust are significantly more abundant than in CI-chondrites, approach solar abundances, are to some extent related to O, and reside in an omnipresent refractory organic component dubbed CHON. Element variations between individual dust grains are characterized by correlations of Mg, Si, and O, and to a lesser extent of Fe and S. From particle-to-particle variations of the rock forming elements information on the mineralogy of cometary dust can be obtained. Cluster analysis revealed certain groups that partly match the classifications of stratospheric interplanetary dust particles. About half of Halley's analyzed particles are characterized by anhydrous Fe-poor Mg-silicates, Fe-sulfides, and rarely Fe metal. The Fe-poor Mg-silicates link Halley's dust to that of Hale-Bopp as shown by recent IR observations. No significant deviation from normal of the isotopic composition of the elements is unequivocally present with the notable exception carbon: ¹²C-rich grains with ¹²C/¹³C-ratios up to ≈ 5,000 link cometary dust to presolar circumstellar grains identified in certain chondrites. This revised version was published online in June 2006 with corrections to the Cover Date.     

The SOHO concept and its realisation

The Solar and Heliospheric Observatory (SOHO) — a space observatory to be placed, in 1995, 1.5 Gm sunward from the Earth in a halo orbit around the L1 Lagrange point — will investigate:

the solar corona, its heating and expansion into the solar wind, by both studying the radiation emerging from the outer solar atmosphere and in-situ solar wind measurements near 1 AU, and

the structure and dynamics of the solar interior by the method of helioseismology.

The science policy evolution leading to this comprehensive observatory concept is described. SOHO's link to the space-plasma-physics mission CLUSTER — devoted to the three-dimensional study of small structures in the magnetosphere — within the Solar Terrestrial Science Programme (STSP) and the embedding of STSP in the much larger International Solar Terrestrial Physics (ISTP) Programme are cited as well. The scientific subjects to be addressed by SOHO are introduced, and their current status assessed. Subsequently, the measurements required to advance these subjects are stated quantitatively and the payload, which will actually perform these measurements, is presented. The mission design, comprising spacecraft, orbit, operations and the data and ground systems are described. The special efforts made to obtain a reliable radiometric calibration of the instruments observing the Sun in the extreme-ultraviolet and to achieve a stable sensitivity through extreme cleanliness of spacecraft and instruments are emphasized and substantiated.     

The Chemical Composition of Interstellar Matter at the Solar Location

The Local Interstellar Cloud (LIC) surrounds the Solar System and sets the boundary conditions for the heliosphere. Using both in situ and absorption line data towards ε CMa we are able to constrain both the ionization and the gas phase abundances of the LIC gas at the Solar Location. We find that the abundances are consistent with all of the carbonaceous dust grains having been destroyed, and in fact with a supersolar abundance of C. The constituents of silicate grains, Si, Mg, and Fe, appear to be sub-solar, indicating that silicate dust is present in the LIC. N, O and S are close to the solar values.     

Solar flare particle measurements with neutron monitors

We discuss the important parameters of solar neutron and proton emissions that can be determined by measurements with neutron monitors at the Earth. First, the methods of analysis for solar neutron events detected by neutron monitors are presented. Illustrations are given to show how these measurements can be used to understand the physics of the neutron production at the Sun. Second, the analytical methods for high-energy interplanetary solar proton events are presented. We then indicate how these observations of interplanetary solar protons can be used to infer the proton acceleration mechanisms at or near the Sun. This revised version was published online in June 2006 with corrections to the Cover Date.     

Sesame – An Experiment of the Rosetta Lander Philae: Objectives and General Design

SESAME is an instrument complex built in international co-operation and carried by the Rosetta lander Philae intended to land on comet 67P/Churyumov-Gerasimenko in 2014. The main goals of this instrument suite are to measure mechanical and electrical properties of the cometary surface and the shallow subsurface as well as of the particles emitted from the cometary surface. Most of the sensors are mounted within the six soles of the landing gear feet in order to provide good contact with or proximity to the cometary surface. The measuring principles, instrument designs, technical layout, operational concepts and the results from the first in-flight measurements are described. We conclude with comments on the consequences of the last minute change of the target comet and how to improve and to preserve the knowledge during the long-duration Rosetta mission.     

An ISO View on Interstellar and Cometary Ice Chemistry

The ISO-SWS instrument offering a large wavelength coverage and a resolution well adapted to the solid phase has changed our knowledge of the physical-chemical properties of ices in space. The discovery of many new ice features was reported and the comparison with dedicated laboratory experiments allowed the determination of more accurate abundances of major ice components. The presence of CO₂ ice has recently been confirmed with the SWS (Short Wavelength Spectrometer) as a dominant ice component of interstellar grain mantles. The bending mode of CO₂ ice shows a particular triple-peak structure which provides first evidence for extensive ice segregation in the line-of-sight toward massive protostars. A comparison of interstellar and cometary ices using recent ISO data and ground-based measurements has revealed important similarities but also indicated that comets contain, beside pristine interstellar material, admixtures of processed material. The investigation of molecules in interstellar clouds is essential to reveal the link between dust in the interstellar medium and in the Solar System. This revised version was published online in June 2006 with corrections to the Cover Date.     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

Isotopic Abundances in Comets

Isotopic ratios in comets provide keys for the understanding of the origin of cometary material, and the physical and chemical conditions in the early Solar Nebula. We review here measurements acquired on the D/H, ¹²C/¹³C, ¹⁶O/¹⁸O, ¹⁴N/¹⁵N, ³²S/³⁴S ratios in dust and gases, and discuss their cosmogonic implications. The prospects for future measurements from cometary space missions and remote sensing observations at millimeter and submillimeter wavelengths are presented. This revised version was published online in August 2006 with corrections to the Cover Date.